According to the physiological and anatomical characteristics of small intestine,neglecting the effect of its motility on the distribution and absorption of drug and nutrient,Y.Miyamoto et al.proposed a model of two-d...According to the physiological and anatomical characteristics of small intestine,neglecting the effect of its motility on the distribution and absorption of drug and nutrient,Y.Miyamoto et al.proposed a model of two-dimensional laminar flow in a circular porous tube with permeable wall and calculated the concentration profile of drugby numerical analysis.In this paper,we give a steady-state analytical solution of the above model including deactivationterm.The obtained results are in agreement with the results of their numerical analysis. Moreover the analytical solution presented in this paper reveals the relation among the physiological parameters of the model and describes the basic absorption rule of drug and nutrient through the intestinal wall and hence pro- vides a theoretical basis for determining the permeability and reflection coefficient through in situ experiments.展开更多
The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 a...The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 and λ 2, which are represented as a linear function of temperature, T . The molar excess Gibbs free energy, G m E, can be written in the form G m E= x A x B[( λ 11 + λ 12 T )+( λ 21 + λ 22 T ) x B ] The calculation is carried out numerically for three immiscible binary alloy systems, Al Pb, Cu Tl and In V. The agreement between the calculated and experimentally determined values of activity coefficient is excellent.展开更多
A weak nonlinear model of a two-layer barotropic ocean with Rayleigh dissipation is built.The analytic asymptotic solution is derived in the mid-latitude stationary wind field,and the physical meaning of the correspon...A weak nonlinear model of a two-layer barotropic ocean with Rayleigh dissipation is built.The analytic asymptotic solution is derived in the mid-latitude stationary wind field,and the physical meaning of the corresponding problem is discussed.展开更多
A simplified subregular solution model was developed for describing the activities of MgCl 2 in both KCl MgCl 2 LiCl and CaCl 2 MgCl 2 NaCl systems on the assumption that the electrolytes in the solution are ...A simplified subregular solution model was developed for describing the activities of MgCl 2 in both KCl MgCl 2 LiCl and CaCl 2 MgCl 2 NaCl systems on the assumption that the electrolytes in the solution are treated as independent particles in stead of their ion forms and the interchange energy between the KCl LiCl (or CaCl 2 NaCl) pair is ignored as compared to those of the KCl MgCl 2(or CaCl 2 MgCl 2) and MgCl 2 LiCl (or MgCl 2 NaCl) pairs. The calculating results on the model agree with the observed very well.展开更多
The dynamic characteristics of a single liquid-filled pipe have been broadly studied in the previous literature.The parallel liquid-filled pipe(PLFP)system is also widely used in engineering,and its structure is more ...The dynamic characteristics of a single liquid-filled pipe have been broadly studied in the previous literature.The parallel liquid-filled pipe(PLFP)system is also widely used in engineering,and its structure is more complex than that of a single pipe.However,there are few reports about the dynamic characteristics of the PLFPs.Therefore,this paper proposes improved frequency modeling and solution for the PLFPs,involving the logical alignment principle and coupled matrix processing.The established model incorporates both the fluid-structure interaction(FSI)and the structural coupling of the PLFPs.The validity of the established model is verified by modal experiments.The effects of some unique parameters on the dynamic characteristics of the PLFPs are discussed.This work provides a feasible method for solving the FSI of multiple pipes in parallel and potential theoretical guidance for the dynamic analysis of the PLFPs in engineering.展开更多
This survey is concerned with the new developments on existence and uniqueness of solutions of some basic models in atmospheric dynamics, such as two-and three-dimensional quasi-geostrophic models and three-dimensiona...This survey is concerned with the new developments on existence and uniqueness of solutions of some basic models in atmospheric dynamics, such as two-and three-dimensional quasi-geostrophic models and three-dimensional balanced model. The main aim of this paper is to introduce some results about the global and local (with respect to time) existence of solutions given by the authors in recent years, but others' important contributions and the literature on this subject are also quoted. We discuss briefly the relationships among the existence and uniqueness, physical instability and computational instability. In the appendixes, some key mathematical techniques in obtaining our results are presented, which are of vital importance to other problems in geophysical fluid dynamics as well.展开更多
In this paper, the interaction parameters in the subregular solution model, λ1 and λ2, are regarded as a linear function of temperature, T. Therefore, the molar excess Gibbs energy of A-B binary system may be reexpr...In this paper, the interaction parameters in the subregular solution model, λ1 and λ2, are regarded as a linear function of temperature, T. Therefore, the molar excess Gibbs energy of A-B binary system may be reexpressed as follows:Gm^E=xAxB[(λ11+λ12T)+(λ21+λ22T)xB]The calculation of the model parameters, λ11, λ12, λ21and λ22, was carried out numerically from the phase diagrams for 11 alkali metal-alkali halide or alkali earth metal-halide systems. In addition, artificial neural network trained by known data has been used to predict the values of these model parameters. The predicted results are in good agreement with the .calculated ones. The applicability of the subregular solution model to the alkali metal-alkali halide or alkali earth metal-halide systems were tested by comparing the available experimental composition along the boundary of miscibility gap with the calculated ones which were obtained by using genetic algorithm. The good agreement between the calculated and experimental results across the entire liquidus is valid evidence in support of the model.展开更多
In the present paper the authors prove that all the generalised entropy,solutions of the CJ-model, which for the given Riemann initial data are a oneparameter family u(eta) characterised by weak detonation discontinui...In the present paper the authors prove that all the generalised entropy,solutions of the CJ-model, which for the given Riemann initial data are a oneparameter family u(eta) characterised by weak detonation discontinuity point eta, are just the limits of the admissible solutions u(ek) Of the selfsimilar combustion model. In fact, the authors prove that for any possible eta, there exists a constant B>0 s.t.展开更多
The physicochemical properties of multicomponent systems are involved in all fields of chemistry and have received attention from various related areas such as minerals,metallurgy,material science,environment,biology,...The physicochemical properties of multicomponent systems are involved in all fields of chemistry and have received attention from various related areas such as minerals,metallurgy,material science,environment,biology,and agriculture.At present,the relevant data can be obtained by using two major calculation methods,namely,the first principle method and the empirical method.Though the former has achieved recent great progress,it is still a long way to offer practical data;while the latter has not received progress for almost half a century.Therefore,a new method that is theoretically reasonable and accurate in practical application is necessary to obtain practical and precise physicochemical data for ternary and multicomponent systems.In this paper,a new theoretical model is suggested based on its corresponding binary ones.The feasibility of this theoretical model is discussed in terms of both theoretical analysis and practical performance.展开更多
In orber to calculate the activity coefficients of water in the aqueous solution systems of double electrolytes, HCl and MCln (M=Ni, Cu,Na and Fe), a simplified regular solution model has been derived based on the as...In orber to calculate the activity coefficients of water in the aqueous solution systems of double electrolytes, HCl and MCln (M=Ni, Cu,Na and Fe), a simplified regular solution model has been derived based on the assumption that the electrolytes in the aqueous solution are treated as independent particles instead of their ion forms, and that the interaction of the component pair HCl-MCln in the aqueous solution is very weak as compared with the component pairs HCl-H2O and H2 O-MCln. The interchange energies of the component pairs in the discussed systems, ωWCl-H2o, ωH2o-NiCl2,ωH2o-CuCl2, ωH2o-NaCl and ωH2O-FeCl3, have been evaluated from the experimental data to be-69800, -212600, -90550, -42450 and -198310J·mol-1.展开更多
The fully anisotropic molecular overall tumbling model with methyl conformation jumps internal rotation among three equivalent sites is proposed,the overall tumbling rotation rates and the methyl internal rotation rat...The fully anisotropic molecular overall tumbling model with methyl conformation jumps internal rotation among three equivalent sites is proposed,the overall tumbling rotation rates and the methyl internal rotation rates of ponicidin are computed with this model from ~C relaxation parameters.展开更多
The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these...The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these models.展开更多
In this paper we obtain the existence of the generalized solutions to the Cauchy problem for a model of combustion provided that the function f is of nonconvexity and initial values lie in the bounded, measurable class.
The expressions for calculating the values of the workspace areas of 2-DOF parallel planar manipulators (PPM) is derived. By the aid of computer, the values are calculated and plotted on the physical model o...The expressions for calculating the values of the workspace areas of 2-DOF parallel planar manipulators (PPM) is derived. By the aid of computer, the values are calculated and plotted on the physical model of the solution space of the 2-DOF PPMs,so the workspaee-area-property atlas is obtained. The atlas delineates the relationship between the workspace areas and the link lengths of the 2-DOF PPMs all-sidedly. It is very useful for designers overalI to understand and know welI the relationship.展开更多
Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. Th...Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake.展开更多
Model Investigation is the only feasible way to solve the problem about the component activities in concentrated multicomponent alloys and molten slags at present. The basic characteristic of SELF-SReM model is brief...Model Investigation is the only feasible way to solve the problem about the component activities in concentrated multicomponent alloys and molten slags at present. The basic characteristic of SELF-SReM model is briefly introduced in this paper. It intends to give out the systematical value of component activities in the whole homogeneous region of a concentrated multicomponent melt, then to provide a reliable database for the description of the equilibrium conditions associated with metallurgy processes. For molten slags, the key issue is to distinguish the accuracy of thermodynamic properties in binary systems. The fundamental approach for this task is to link the microscopic bond structure and macroscopic activity based on both of the measurement of high tem- perature Raman spectroscopy and the corresponding computation simulation according to molecular dynamics and quantum chemistry.展开更多
Based on six thermodynamic equilibria,a unified retention model of solute in liquid chromatography(LC)is first proposed.The unified model was tested and proved to be valid for a LC sys- tem with mobile phase consistin...Based on six thermodynamic equilibria,a unified retention model of solute in liquid chromatography(LC)is first proposed.The unified model was tested and proved to be valid for a LC sys- tem with mobile phase consisting of a complete range of multiple,ternary or binary components and each kind of LC except size exclusion chromatography.In addition,so long as making some assumptions and mathematical conversions,the expressions of various popular models in LC can be derived by using the unified model.展开更多
A sub-regular solution model SELFSReM4 used to evaluate activities of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Lab of Ferrometallurgy. This paper introduces...A sub-regular solution model SELFSReM4 used to evaluate activities of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Lab of Ferrometallurgy. This paper introduces the application of SELFSReM4 in evaluating activities of the components in C-Mn-Fe-Si system without SiC precipitation.展开更多
A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application ...A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.展开更多
The filling and exhausting processes in a pneumatic system are involved with many factors, and numerical solutions of many partial differential equations are always adapted in the study of those processes, which have ...The filling and exhausting processes in a pneumatic system are involved with many factors, and numerical solutions of many partial differential equations are always adapted in the study of those processes, which have been proved to be troublesome and less intuitive. Analytical solutions based on loss-less tube model and average friction tube model are found respectively by using fluid net theory, and they fit the experimental results well. The research work shows that: Fluid net theory can be used to solve the analytical solution of filling and exhausting processes of pneumatic system, and the result of loss-less tube model is close to that of average friction model, so loss-less tube model is recommended since it is simpler, and the difference between filling time and exhausting time is determined by initial and final pressures, the volume of container and the section area of tube, and has nothing to do with the length of the tube.展开更多
基金The project supported by NSF of Shandong Province
文摘According to the physiological and anatomical characteristics of small intestine,neglecting the effect of its motility on the distribution and absorption of drug and nutrient,Y.Miyamoto et al.proposed a model of two-dimensional laminar flow in a circular porous tube with permeable wall and calculated the concentration profile of drugby numerical analysis.In this paper,we give a steady-state analytical solution of the above model including deactivationterm.The obtained results are in agreement with the results of their numerical analysis. Moreover the analytical solution presented in this paper reveals the relation among the physiological parameters of the model and describes the basic absorption rule of drug and nutrient through the intestinal wall and hence pro- vides a theoretical basis for determining the permeability and reflection coefficient through in situ experiments.
文摘The modified sub regular solution model was used for a calculation of the activity coefficient of immiscible binary alloy systems. The parameters needed for the calculation are the interaction parameters, λ 1 and λ 2, which are represented as a linear function of temperature, T . The molar excess Gibbs free energy, G m E, can be written in the form G m E= x A x B[( λ 11 + λ 12 T )+( λ 21 + λ 22 T ) x B ] The calculation is carried out numerically for three immiscible binary alloy systems, Al Pb, Cu Tl and In V. The agreement between the calculated and experimentally determined values of activity coefficient is excellent.
基金Project supported by the National Basic Research Program of China (Grant No. 2011CB403501)the National Natural Science Foundation of China (GrantNos. 41175058,41275062,and 11202106)
文摘A weak nonlinear model of a two-layer barotropic ocean with Rayleigh dissipation is built.The analytic asymptotic solution is derived in the mid-latitude stationary wind field,and the physical meaning of the corresponding problem is discussed.
文摘A simplified subregular solution model was developed for describing the activities of MgCl 2 in both KCl MgCl 2 LiCl and CaCl 2 MgCl 2 NaCl systems on the assumption that the electrolytes in the solution are treated as independent particles in stead of their ion forms and the interchange energy between the KCl LiCl (or CaCl 2 NaCl) pair is ignored as compared to those of the KCl MgCl 2(or CaCl 2 MgCl 2) and MgCl 2 LiCl (or MgCl 2 NaCl) pairs. The calculating results on the model agree with the observed very well.
基金Project supported by the National Natural Science Foundation of China(No.11972112)the Fundamental Research Funds for the Central Universities of China(Nos.N2103024 and N2103002)the Major Projects of Aero-Engines and Gasturbines(No.J2019-I-0008-0008)。
文摘The dynamic characteristics of a single liquid-filled pipe have been broadly studied in the previous literature.The parallel liquid-filled pipe(PLFP)system is also widely used in engineering,and its structure is more complex than that of a single pipe.However,there are few reports about the dynamic characteristics of the PLFPs.Therefore,this paper proposes improved frequency modeling and solution for the PLFPs,involving the logical alignment principle and coupled matrix processing.The established model incorporates both the fluid-structure interaction(FSI)and the structural coupling of the PLFPs.The validity of the established model is verified by modal experiments.The effects of some unique parameters on the dynamic characteristics of the PLFPs are discussed.This work provides a feasible method for solving the FSI of multiple pipes in parallel and potential theoretical guidance for the dynamic analysis of the PLFPs in engineering.
文摘This survey is concerned with the new developments on existence and uniqueness of solutions of some basic models in atmospheric dynamics, such as two-and three-dimensional quasi-geostrophic models and three-dimensional balanced model. The main aim of this paper is to introduce some results about the global and local (with respect to time) existence of solutions given by the authors in recent years, but others' important contributions and the literature on this subject are also quoted. We discuss briefly the relationships among the existence and uniqueness, physical instability and computational instability. In the appendixes, some key mathematical techniques in obtaining our results are presented, which are of vital importance to other problems in geophysical fluid dynamics as well.
文摘In this paper, the interaction parameters in the subregular solution model, λ1 and λ2, are regarded as a linear function of temperature, T. Therefore, the molar excess Gibbs energy of A-B binary system may be reexpressed as follows:Gm^E=xAxB[(λ11+λ12T)+(λ21+λ22T)xB]The calculation of the model parameters, λ11, λ12, λ21and λ22, was carried out numerically from the phase diagrams for 11 alkali metal-alkali halide or alkali earth metal-halide systems. In addition, artificial neural network trained by known data has been used to predict the values of these model parameters. The predicted results are in good agreement with the .calculated ones. The applicability of the subregular solution model to the alkali metal-alkali halide or alkali earth metal-halide systems were tested by comparing the available experimental composition along the boundary of miscibility gap with the calculated ones which were obtained by using genetic algorithm. The good agreement between the calculated and experimental results across the entire liquidus is valid evidence in support of the model.
文摘In the present paper the authors prove that all the generalised entropy,solutions of the CJ-model, which for the given Riemann initial data are a oneparameter family u(eta) characterised by weak detonation discontinuity point eta, are just the limits of the admissible solutions u(ek) Of the selfsimilar combustion model. In fact, the authors prove that for any possible eta, there exists a constant B>0 s.t.
基金financially supported by the National Natural Science Foundation of China(No.51734002)Zhejiang Phenomenological Materials Technology Co.,Ltd.,China。
文摘The physicochemical properties of multicomponent systems are involved in all fields of chemistry and have received attention from various related areas such as minerals,metallurgy,material science,environment,biology,and agriculture.At present,the relevant data can be obtained by using two major calculation methods,namely,the first principle method and the empirical method.Though the former has achieved recent great progress,it is still a long way to offer practical data;while the latter has not received progress for almost half a century.Therefore,a new method that is theoretically reasonable and accurate in practical application is necessary to obtain practical and precise physicochemical data for ternary and multicomponent systems.In this paper,a new theoretical model is suggested based on its corresponding binary ones.The feasibility of this theoretical model is discussed in terms of both theoretical analysis and practical performance.
文摘In orber to calculate the activity coefficients of water in the aqueous solution systems of double electrolytes, HCl and MCln (M=Ni, Cu,Na and Fe), a simplified regular solution model has been derived based on the assumption that the electrolytes in the aqueous solution are treated as independent particles instead of their ion forms, and that the interaction of the component pair HCl-MCln in the aqueous solution is very weak as compared with the component pairs HCl-H2O and H2 O-MCln. The interchange energies of the component pairs in the discussed systems, ωWCl-H2o, ωH2o-NiCl2,ωH2o-CuCl2, ωH2o-NaCl and ωH2O-FeCl3, have been evaluated from the experimental data to be-69800, -212600, -90550, -42450 and -198310J·mol-1.
文摘The fully anisotropic molecular overall tumbling model with methyl conformation jumps internal rotation among three equivalent sites is proposed,the overall tumbling rotation rates and the methyl internal rotation rates of ponicidin are computed with this model from ~C relaxation parameters.
文摘The existing geometrical solution models for predicting ternary thermodynamic properties from relevant binary ones have been analysed,and a general representation was proposed in an integral form on the bases of these models.
文摘In this paper we obtain the existence of the generalized solutions to the Cauchy problem for a model of combustion provided that the function f is of nonconvexity and initial values lie in the bounded, measurable class.
文摘The expressions for calculating the values of the workspace areas of 2-DOF parallel planar manipulators (PPM) is derived. By the aid of computer, the values are calculated and plotted on the physical model of the solution space of the 2-DOF PPMs,so the workspaee-area-property atlas is obtained. The atlas delineates the relationship between the workspace areas and the link lengths of the 2-DOF PPMs all-sidedly. It is very useful for designers overalI to understand and know welI the relationship.
基金the National Natural Science Foundation of China
文摘Firstly, the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory. The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented, which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake. And secondly, with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference, a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile, the model was applied to model potassium/magnesium transport in Qarhan Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarhan Salt Lake.
文摘Model Investigation is the only feasible way to solve the problem about the component activities in concentrated multicomponent alloys and molten slags at present. The basic characteristic of SELF-SReM model is briefly introduced in this paper. It intends to give out the systematical value of component activities in the whole homogeneous region of a concentrated multicomponent melt, then to provide a reliable database for the description of the equilibrium conditions associated with metallurgy processes. For molten slags, the key issue is to distinguish the accuracy of thermodynamic properties in binary systems. The fundamental approach for this task is to link the microscopic bond structure and macroscopic activity based on both of the measurement of high tem- perature Raman spectroscopy and the corresponding computation simulation according to molecular dynamics and quantum chemistry.
基金This work was supported by the Excellent Young Faculty Foundation of the State Education Committee of China
文摘Based on six thermodynamic equilibria,a unified retention model of solute in liquid chromatography(LC)is first proposed.The unified model was tested and proved to be valid for a LC sys- tem with mobile phase consisting of a complete range of multiple,ternary or binary components and each kind of LC except size exclusion chromatography.In addition,so long as making some assumptions and mathematical conversions,the expressions of various popular models in LC can be derived by using the unified model.
文摘A sub-regular solution model SELFSReM4 used to evaluate activities of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Lab of Ferrometallurgy. This paper introduces the application of SELFSReM4 in evaluating activities of the components in C-Mn-Fe-Si system without SiC precipitation.
文摘A sub-regular solution model SELF-SReM4 used to evaluate activity of the components in a homogeneous region of a quaternary system has been developed in Shanghai Enhanced Laboratory of Ferrometallurgy.The application of SELF-SReM4 in C-Mn-Fe-Si system without the SiC formation has been introduced in previous paper.It’s application for molten slag of MnO-SiO2-Al2O3-CaO was introduced in this paper.They provide a basis for the prediction of the metal-slag equilibrium conditions.
基金This project is supported by National Natural Science Foundation of China(No.50575209).
文摘The filling and exhausting processes in a pneumatic system are involved with many factors, and numerical solutions of many partial differential equations are always adapted in the study of those processes, which have been proved to be troublesome and less intuitive. Analytical solutions based on loss-less tube model and average friction tube model are found respectively by using fluid net theory, and they fit the experimental results well. The research work shows that: Fluid net theory can be used to solve the analytical solution of filling and exhausting processes of pneumatic system, and the result of loss-less tube model is close to that of average friction model, so loss-less tube model is recommended since it is simpler, and the difference between filling time and exhausting time is determined by initial and final pressures, the volume of container and the section area of tube, and has nothing to do with the length of the tube.