Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water whe...Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water when the low temperature was 20 ℃. The following results were obtained: the highest temperature at the condenser outlet reached about 85 ℃; when the difference between the water temperatures at the condenser outlet and the evaporator inlet was less than 40 ℃, the coefficient of performance (COP) was larger than 4; when the difference reached 55 ℃, the COP still kept 3; the discharge temperature of BY-3 was lower than 100 ℃, and the refrigerant vapor pressure kept lower than 1.8 MPa. When the water temperature at the condenser outlet reached over 85 ℃, nearly a 5 ℃ superheating temperature was maintained.展开更多
In China, directly dropping high temperature refrigerant into conventional compressor is considered as a dominant technical route for development of moderately high temperature heat pump. Based on this route, selectio...In China, directly dropping high temperature refrigerant into conventional compressor is considered as a dominant technical route for development of moderately high temperature heat pump. Based on this route, selection criteria for high temperature refrigerant were presented with consideration of several influencing factors. Moreover, a set of research methods were built including theoretical calculations and experimental tests. Four high temperature refrigerants from HTR01 to HTR04 were compared and analyzed. In results, firstly, HTR03 and HTR04 belonging to non-ozone depleting refrigerants could bring outstanding environmental benefits; secondly, the condenser outlet water efficiently generated by heat pump using high temperature refrigerants could cover 60°C–90°C;; finally, the feasibility of the technical route and the research methods were proved.展开更多
With the increasing environmental concern on global warming, hydrofluoro-olefin (HFOs), possessing low GWP, has attracted great attention of many researchers recently. In this study, non-azeotropic mixtures composed o...With the increasing environmental concern on global warming, hydrofluoro-olefin (HFOs), possessing low GWP, has attracted great attention of many researchers recently. In this study, non-azeotropic mixtures composed of HFOs (HFO-1234yf, HFO-1234ze(z), HFO-1234ze(e) and HFO-1234zf) are developed to substitute for HFC-134a and CFC-114 in air-conditioning and high-temperature heat pump systems, respectively. The cycle performances were evaluated by an improved theoretical cy-cle evaluation methodology. The results showed that all the mixtures proposed herein were favorable refrigerants with excel-lent thermodynamic cycle performances. M1A presented lower discharge temperature and pressure ratio and higher COPc than that of HFC-134a. The volumetric cooling capacity was similar to HFC-134a. It can be served as a good environmentally friendly alternative to replace HFC-134a. M3H delivered similar discharge temperature as CFC-114 did. And the COPh was 3% higher. It exhibits excellent cycle performance in high-temperature heat pump and is a promising refrigerant to substitute for CFC-114. And the gliding temperature differences enable them to exhibit better coefficient of performance by matching the sink/source temperature in practice. Because the toxicity, flammability and other properties are not investigated in detail, ex-tensive toxicity and flammability testing needs to be conducted before they are used in a particular application.展开更多
A moderate pressure/high temperature zonal metamorphic complex in the Tongulack Mountain Ridge, Altai, Russia, is described, and the applicability of the models of magmatic intrusion and fluid flow to explanation of i...A moderate pressure/high temperature zonal metamorphic complex in the Tongulack Mountain Ridge, Altai, Russia, is described, and the applicability of the models of magmatic intrusion and fluid flow to explanation of its origin discussed. The Precambrian complex was formed at 500–700°C and 3.0–5.5 kbars; it is a linear, 25–30 km wide, thermal anticline with a curved axis showing symmetric metamorphic zoning. The metamorphism was isochemical by its nature, as is corroborated by the chemical compositions of the rocks. Four zones can be recognized within the metamorphic complex: chloritic (on the peripheries), cordieritic, sillimanitic and staurolite-out (in the centre). The zones are separated by successive isograds: cordierite, staurolite-in or sillimanite and staurolite-out. It is argued that the origin of the metamorphic zoning can be explained best by a combined fluid-magmatic model; conductive heat flow from the intrusion predominated considerably over the fluid flux in heat transfer: the fluid flow rate was estimated as about 3 ? 10?9 g/cm2, ? s. The modern position of the axial region of the metamorphic belt is predicted to be lying roughly about 1.5 km above the roof of the intrusive body.展开更多
目前中国仍有部分工业园区采用供电、供热、供气等各种能源供应系统单独规划和运行的方式,导致大量工业余热被浪费,系统能效低、碳排放高。为了充分利用工业余热并提高系统运行能效,提出一种含高温蒸汽热泵(high temperature heat pump,...目前中国仍有部分工业园区采用供电、供热、供气等各种能源供应系统单独规划和运行的方式,导致大量工业余热被浪费,系统能效低、碳排放高。为了充分利用工业余热并提高系统运行能效,提出一种含高温蒸汽热泵(high temperature heat pump,HTHP)的工业园区综合能源系统(integrated energy system,IES)双层优化模型。首先,构建含HTHP的工业园区综合能源系统架构。其次,针对IES能效较低的问题,利用余热的梯级利用原则与多能协同原则,建立含HTHP的综合能源系统调度策略。再次,建立包含设备容量规划优化与运行优化的双层优化模型,并提出优化模型的求解方法。最后,通过西北地区一个化工园区的实例分析,验证了所提方法的有效性。展开更多
为解决低温余热资源过剩与高温用热需求紧缺之间的矛盾,设计了一套基于准二级压缩的高温热泵机组,理论分析循环流程并进行优化设计,采用闪蒸器与回热器组合提高机组性能,开展了机组的性能实验,以制热量、制热COP、[火用]效率、冷凝压力...为解决低温余热资源过剩与高温用热需求紧缺之间的矛盾,设计了一套基于准二级压缩的高温热泵机组,理论分析循环流程并进行优化设计,采用闪蒸器与回热器组合提高机组性能,开展了机组的性能实验,以制热量、制热COP、[火用]效率、冷凝压力、排气温度为性能指标,在冷凝器出水温度为85~120℃,蒸发器进水温度为50、60、70℃工况下,对机组性能进行分析。实测机组性能与理论计算结果吻合,蒸发器进水温度为49.8℃,冷凝器出水温度为118.1℃,机组制热量可达916.3 k W,制热COP为2.51,[火用]效率为46.3%,机组冷凝压力为1.8 MPa,排气温度为137℃,符合机组安全运行的要求。展开更多
文章提出了一种利用高温热泵回收冷却水余热制备中、高温热水的方案。通过建立简化的热力学模型,分析冷、热源温度对热泵单位制热量、单位压缩功及COP(Coefficient of Performance,能效比)值的影响。并从经济节能和环境保护两个方面进...文章提出了一种利用高温热泵回收冷却水余热制备中、高温热水的方案。通过建立简化的热力学模型,分析冷、热源温度对热泵单位制热量、单位压缩功及COP(Coefficient of Performance,能效比)值的影响。并从经济节能和环境保护两个方面进行了效益分析,结果表明:与传统的蒸汽加热制备热水相比,高温热泵回收冷却水余热制备中、高温热水的方案具有经济效益和环境效益,更符合节能减排要求。展开更多
基金Supported by Major State Basic Research Development Program of China ("973" Program, No. 2009CB219907)the Program for Changjiang Scholars and Innovative Research Team in University (No. IRT0936)
文摘Theoretical and experimental analysis of a new refrigerant mixture BY-3 was conducted based on a single-stage vapor compression refrigeration system. The water-water heat pump system used BY-3 to produce hot water when the low temperature was 20 ℃. The following results were obtained: the highest temperature at the condenser outlet reached about 85 ℃; when the difference between the water temperatures at the condenser outlet and the evaporator inlet was less than 40 ℃, the coefficient of performance (COP) was larger than 4; when the difference reached 55 ℃, the COP still kept 3; the discharge temperature of BY-3 was lower than 100 ℃, and the refrigerant vapor pressure kept lower than 1.8 MPa. When the water temperature at the condenser outlet reached over 85 ℃, nearly a 5 ℃ superheating temperature was maintained.
基金Supported by Program for New Century Excellent Talents in University (Grand No. NCET-04-0078)
文摘In China, directly dropping high temperature refrigerant into conventional compressor is considered as a dominant technical route for development of moderately high temperature heat pump. Based on this route, selection criteria for high temperature refrigerant were presented with consideration of several influencing factors. Moreover, a set of research methods were built including theoretical calculations and experimental tests. Four high temperature refrigerants from HTR01 to HTR04 were compared and analyzed. In results, firstly, HTR03 and HTR04 belonging to non-ozone depleting refrigerants could bring outstanding environmental benefits; secondly, the condenser outlet water efficiently generated by heat pump using high temperature refrigerants could cover 60°C–90°C;; finally, the feasibility of the technical route and the research methods were proved.
基金supported by the National Natural Science Foundation of China (Grant No. 50976079)Science and Technology Support Key Project of Tianjin (Grant No. 10ZCKFGX01700)
文摘With the increasing environmental concern on global warming, hydrofluoro-olefin (HFOs), possessing low GWP, has attracted great attention of many researchers recently. In this study, non-azeotropic mixtures composed of HFOs (HFO-1234yf, HFO-1234ze(z), HFO-1234ze(e) and HFO-1234zf) are developed to substitute for HFC-134a and CFC-114 in air-conditioning and high-temperature heat pump systems, respectively. The cycle performances were evaluated by an improved theoretical cy-cle evaluation methodology. The results showed that all the mixtures proposed herein were favorable refrigerants with excel-lent thermodynamic cycle performances. M1A presented lower discharge temperature and pressure ratio and higher COPc than that of HFC-134a. The volumetric cooling capacity was similar to HFC-134a. It can be served as a good environmentally friendly alternative to replace HFC-134a. M3H delivered similar discharge temperature as CFC-114 did. And the COPh was 3% higher. It exhibits excellent cycle performance in high-temperature heat pump and is a promising refrigerant to substitute for CFC-114. And the gliding temperature differences enable them to exhibit better coefficient of performance by matching the sink/source temperature in practice. Because the toxicity, flammability and other properties are not investigated in detail, ex-tensive toxicity and flammability testing needs to be conducted before they are used in a particular application.
文摘A moderate pressure/high temperature zonal metamorphic complex in the Tongulack Mountain Ridge, Altai, Russia, is described, and the applicability of the models of magmatic intrusion and fluid flow to explanation of its origin discussed. The Precambrian complex was formed at 500–700°C and 3.0–5.5 kbars; it is a linear, 25–30 km wide, thermal anticline with a curved axis showing symmetric metamorphic zoning. The metamorphism was isochemical by its nature, as is corroborated by the chemical compositions of the rocks. Four zones can be recognized within the metamorphic complex: chloritic (on the peripheries), cordieritic, sillimanitic and staurolite-out (in the centre). The zones are separated by successive isograds: cordierite, staurolite-in or sillimanite and staurolite-out. It is argued that the origin of the metamorphic zoning can be explained best by a combined fluid-magmatic model; conductive heat flow from the intrusion predominated considerably over the fluid flux in heat transfer: the fluid flow rate was estimated as about 3 ? 10?9 g/cm2, ? s. The modern position of the axial region of the metamorphic belt is predicted to be lying roughly about 1.5 km above the roof of the intrusive body.
文摘目前中国仍有部分工业园区采用供电、供热、供气等各种能源供应系统单独规划和运行的方式,导致大量工业余热被浪费,系统能效低、碳排放高。为了充分利用工业余热并提高系统运行能效,提出一种含高温蒸汽热泵(high temperature heat pump,HTHP)的工业园区综合能源系统(integrated energy system,IES)双层优化模型。首先,构建含HTHP的工业园区综合能源系统架构。其次,针对IES能效较低的问题,利用余热的梯级利用原则与多能协同原则,建立含HTHP的综合能源系统调度策略。再次,建立包含设备容量规划优化与运行优化的双层优化模型,并提出优化模型的求解方法。最后,通过西北地区一个化工园区的实例分析,验证了所提方法的有效性。
文摘为解决低温余热资源过剩与高温用热需求紧缺之间的矛盾,设计了一套基于准二级压缩的高温热泵机组,理论分析循环流程并进行优化设计,采用闪蒸器与回热器组合提高机组性能,开展了机组的性能实验,以制热量、制热COP、[火用]效率、冷凝压力、排气温度为性能指标,在冷凝器出水温度为85~120℃,蒸发器进水温度为50、60、70℃工况下,对机组性能进行分析。实测机组性能与理论计算结果吻合,蒸发器进水温度为49.8℃,冷凝器出水温度为118.1℃,机组制热量可达916.3 k W,制热COP为2.51,[火用]效率为46.3%,机组冷凝压力为1.8 MPa,排气温度为137℃,符合机组安全运行的要求。
文摘文章提出了一种利用高温热泵回收冷却水余热制备中、高温热水的方案。通过建立简化的热力学模型,分析冷、热源温度对热泵单位制热量、单位压缩功及COP(Coefficient of Performance,能效比)值的影响。并从经济节能和环境保护两个方面进行了效益分析,结果表明:与传统的蒸汽加热制备热水相比,高温热泵回收冷却水余热制备中、高温热水的方案具有经济效益和环境效益,更符合节能减排要求。
