Moderately concentrated electrolyte enabling high-performance lithium metal batteries with a wide working temperature range

The electrolyte integrated with lithium metal anodes is subjected to the issues of interfacial compatibility and stability,which strongly influence the performances of high-energy lithium metal batteries.Here,we report a new electrolyte recipe viz.a moderately concentrated electrolyte comprising of 2.4 M lithium bis(fluorosulfonyl)imide(LiFSI)in a cosolvent mixture of fluorinated ethylene carbonate(FEC)and dimethyl carbonate(DMC)with relatively high ion conductivity.Owing to the preferential decomposition of LiFSI and FEC,an inorganic-rich interphase with abundant Li_(2)O and LiF nanocrystals is formed on lithium metal with improved robustness and ion transfer kinetics,enabling lithium plating/stripping with an extremely low overpotential of~8 mV and the average CE of 97%.When tested in Li||LiFePO_(4) cell,this electrolyte provides long-term cycling with a capacity retention of 98.3%after 1000 cycles at 1 C and an excellent rate performance of 20 C,as well as an areal capacity of 1.35 mA h cm^(-2)at the cathode areal loading of 9 mg cm^(-2).Moreover,the Li||LiFePO_(4) cell exhibits excellent wide-temperature performances(-40~60℃),including long-term cycling stability over 2600 cycles without visible capacity fading at 0℃,as well as extremely high average CEs of 99.6%and 99.8% over 400 cycles under-20℃ and 45℃.

Parental Psychological Control and Internet Gaming Disorder Tendency:A Moderated Mediation Model of Core Self-Evaluation and Intentional Self-Regulation

Internet gaming disorder(IGD)among junior high school students is an increasingly prominent mental health concern.It is important to look for influences behind internet gaming disorder tendency(IGDT)in the junior high school student population.The present study aimed to reveal the explanatory mechanisms underlying the association between parental psychological control(PPC)and internet gaming disorder tendency among junior high school students by testing the mediating role of core self-evaluation(CSE)and the moderating role of intentional self-regulation(ISR).Participants in present study were 735 Chinese junior high school students who completed offline self-report questionnaires on parental psychological control,core self-evaluation,intentional self-regulation,and Internet gaming disorder tendency.Analyses were conducted via mediation and moderated mediation.The results showed that:(1)Parental psychological control was positively related to junior high school students’Internet gaming disorder tendency.Core self-evaluation,and intentional self-regulation were negatively related to junior high school students’Internet gaming disorder tendency,respectively.(2)Core self-evaluation partially mediated the relationship between parental psychological control and junior high school students’Internet gaming disorder tendency.(3)Intentional self-regulation moderated the association between parental psychological control and Internet gaming disorder tendency,as well as the relationships between parental psychological control and core self-evaluation and core self-evaluation and Internet gaming disorder tendency in the mediated model.Based on these findings,we believe that there is a need to weaken parental psychological control,strengthen junior high school students’core self-evaluation and intentional self-regulation,and to recognize the important role of parents as well as their children’s personal positive traits in the healthy development of junior high school students.

The Moderating Effect of Organizational Identification on Occupational Stress and Insomnia Among Nurses

Objective:To explore the relationship between organizational identification,occupational stress,and insomnia among nurses and to analyze the moderating role of organizational identification between occupational stress and insomnia.Methods:Through stratified sampling,720 nurses working in a tertiary A-level hospital in Shandong Province from March to May 2021 were surveyed using an effort-reward imbalance questionnaire,an organizational identification questionnaire,and the Athens Insomnia scale.Results:Organizational identification was negatively correlated with occupational stress and insomnia(r_(1)=-0.121,P_(1)<0.01;r_(2)=-0.144,P_(2)<0.01).Occupational stress was positively correlated with insomnia(r=0.379,P<0.01).Organizational identity significantly moderated nurses’occupational stress and insomnia(β=-0.192,t=-2.558,P<0.05).Conclusion:Occupational stress and organizational identification can predict insomnia.Organizational identification could negatively mediate the relationship between occupational stress and insomnia.Improving organizational identification may help alleviate insomnia symptoms by relieving occupational stress.

Strength of massive to moderately jointed hard rock masses

The Hoek-Brown (HB) failure criterion and the geological strength index (GSI) were developed for the estimation of rock mass strength in jointed and blocky ground where rock mass failure is dominated by sliding along open joints and rotation of rock blocks. In massive, veined and moderately jointed rock in which rock blocks cannot form without failure of intact rock, the approach to obtain HB parameters must be modified. Typical situations when these modifications are required include the design of pillars, excavation and cavern stability, strainburst potential assessment, and tunnel support in deep underground conditions (around σ1/σci > 0.15, where σ1 is the major principal compressive stress and σci is the unconfined compressive strength of the homogeneous rock) in hard brittle rocks with GSI ≥ 65. In this article, the strength of massive to moderately jointed hard rock masses is investigated, and an approach is presented to estimate the rock mass strength envelope using laboratory data from uniaxial and triaxial compressive strength tests without reliance on the HB-GSI equations. The data from tests on specimens obtained from massive to moderately jointed heterogeneous (veined) rock masses are used to obtain the rock and rock mass strengths at confining stress ranges that are relevant for deep tunnelling and mining;and a methodology is presented for this purpose from laboratory data alone. By directly obtaining the equivalent HB rock mass strength envelope for massive to moderately jointed rock from laboratory tests, the HB-GSI rock mass strength estimation approach is complemented for conditions where the GSIequations are not applicable. Guidance is also provided on how to apply the proposed approach when laboratory test data are not or not yet available.

ELASTIC DYNAMIC ANALYSIS OF MODERATELY THICK PLATE USING MESHLESS LRPIM

A meshless local radial point interpolation method （LRPIM） for solving elastic dy-namic problems of moderately thick plates is presented in this paper. The discretized system equation of the plate is obtained using a locally weighted residual method. It uses a radial basis function （RBF） coupled with a polynomial basis function as a trial function,and uses the quartic spline function as a test function of the weighted residual method. The shape function has the properties of the Kronecker delta function,and no additional treatment is done to impose essen-tial boundary conditions. The Newmark method for solving the dynamic problem is adopted in computation. Effects of sizes of the quadrature sub-domain and influence domain on the dynamic properties are investigated. The numerical results show that the presented method can give quite accurate results for the elastic dynamic problem of the moderately thick plate.

Evaluation of the use of sublevel open stoping in the mining of moderately dipping medium-thick orebodies

The flow of blasted ore during mining of moderately dipping medium-thick orebodies is a challenge.Selecting a suitable mining system for such ore bodies is difficult.This paper proposes a diamond layout sublevel open stoping system using fan blastholes with backfilling to mine such orebodies.To evaluate the performance of system the relationships between ore recovery and stope footwall dip angle,footwall surface roughness,drawpoint spacing and production blast ring burden were investigated.An ore recovery data set from 81 laboratory physical model experiments was established from combinations of the listed factors.Various modules in a back propagation neural network structure were compared,and an optimal network structure identified.An ore recovery backpropagation neural network(BPNN)forecast model was developed.Using the model and sensitivity analysis of the factors affecting the proposed open stope mining system,the significance of each factor on ore recovery was studied.The study results were applied to a case study at the Shandong Gold Group Jiaojia Gold Mine.The results showed that the application of a BPNN and sensitivity analysis models for ore recovery prediction in the proposed mining system and field experimental results confirm that the suggested mining method is feasible.

Study on Variation of Fitting Goodness of Relation Between Earthquake Frequency and Magnitude before Moderately Strong Earthquakes (Ms≥5.0)

In this paper,characteristics of spatial and temporal variation of linear fitting goodness before some moderately strong earthquakes(Ms≥5.0)in the eastern part of China(east of longitude 180)are studied according to the famous Gutenberg-Richter’s relation expressed as lgN=a-bM,by using the moderate and small events that occurred in and around the source area.The results show that the linear goodness of fitting varies abnormally prior to these moderately strong earthquakes.In the early stage of the earthquake preparatory process,distribution of the energy released through small events in and around the source area is isostatic and the fitting goodness approximates 1,while the distribution of the energy turns to be isostatic before moderately strong earthquakes,leading to the obvious decrease of the linear goodness of fitting.This phenomenon could be a medium term anomaly and a medium term criterion for moderately strong earthquake prediction.

Ustekinumab versus adalimumab for induction and maintenance therapy in biologic-naive patients with moderately to severely active Crohn's disease:a multicentre,randomised,double-blind,parallel-group,phase 3b trial

Background:Active-comparator trials are important to inform patient and physician choice.We aimed to evaluate the efficacy and safety of monotherapy with either ustekinumab or adalimumab in biologic-naive patients with moderately to severely active Crohn's disease.

Effect of mixed moderately thermophilic adaptation on leachability and mechanism of high arsenic gold concentrate in an airlift bioreactor

A refractory gold concentrate with 19% arsenic was treated by a mixed moderately thermophiles in an airlift bioreactor through an adaptation protocol. The moderately thermophiles could respond well to 20%(w/v) pulp density with less than 10% loss of productivity, and resist arsenic up to 15 g/L. There were a lot of jarosite, arsenolite and sulfur, but not scorodite and ferric arsenate in the bioleached residue. Jarosite passivation and lower sulfur-oxidizing activity of the cells due to the toxicity of the high concentrations of soluble arsenic and iron ions at low p H value should mainly response for the incomplete extraction at high pulp density. The initial bacterial community did not change in nature except for new found P aeruginosa ANSC, but sulfur-oxidizing microorganisms have been dominant microorganisms after a long time of adaptation. Pseudomonas aeruginosa originating from the gold concentrate should be closely relative to the metabolism of the organic matters contained in the refractory gold concentrate.

Marmatite bioleaching with moderately thermoacidophilic bacterial strain and mineral analyses of solid residues

The bioleaching of a marmatite flotation concentrate with a moderately thermoacidophilic iron-oxidizing bacterial strain (MLY) is influenced significantly by temperature, pH, particle size, pulp density of ores and bacterial strains. Under such leaching conditions as the initial pH value of 1.5, temperature of 50℃, pulp density of 5%, particle size less than 35.5μm (over 90%) and inoculating the adapted strains of MLY, the leached Zn is over 95% after 10d of bioleaching. SEM observations show the cell attachment and the surface features of solid residues under different leaching conditions. XRD and EDX analyses show that a mass of elemental sulfur form during the bioleaching process. The technological feasibility of a microbiological process using MLY for extracting zinc from the marmatite concentrate is demonstrated.

Halomonas Erhaiensis sp. nov.,a Moderately Halotolerant Bacterium Isolated from Erhai Lake,Qinghai Province,China

The strain CUG00003T was isolated from the sediment of Erhai Lake of Qing Hai Province,China.Results of 16S r RNA gene sequence analyses indicated a close relationship(97%similarity)of the isolate to

Isolation and identification of moderately thermophilic acidophilic iron-oxidizing bacterium and its bioleaching characterization

A moderately thermophilic acidophilic iron-oxidizing bacterium ZW-1 was isolated from Dexing mine, Jiangxi Province, China. The morphological, biochemical and physiological characteristics, 16S rRNA sequence and bioleaching characterization of strain ZW-1 were studied. The optimum growth temperature is 48 ℃, and the optimum initial pH is 1.9. The strain can grow autotrophically by using ferrous iron or elemental sulfur as sole energy sources. The strain is also able to grow heterotrophically by using peptone and yeast extract powder, but not glucose. The cell density of strain ZW-1 can reach up to 1.02×108 /mL with addition of 0.4 g/L peptone. A phylogenetic tree was constructed by comparing with the published 16S rRNA sequences of the relative bacteria species. In the phylogenetic tree, strain ZW-1 is closely relative to Sulfobacilus acidophilus with more than 99% sequence similarity. The results of bioleaching experiments indicate that the strain could oxidize Fe2+ efficiently, and the maximum oxidizing rate is 0.295 g/(L·h). It could tolerate high concentration of Fe3+ and Cu2+ (35 g/L and 25 g/L, respectively). After 20 d, 44.6% of copper is extracted from chalcopyrite by using strain ZW-1 as inocula.

Preservation of moderately thermophilic culture by freeze drying and frozen preservation way and effect on subsequent bioleaching of chalcopyrite

Freeze drying and frozen preservation way was used to preserve a moderately thermophilic culture for bioleaching of chalcopyrite concentrate.After preservation of 15 months,the cell viability rate decreases to 22% with a cell density of 7×107 mL-1.When the growth time was extended from 8 days to 14 days,cell density would increase in a large scale to about 3×108 mL-1.In the bioleaching experiments,unpreserved and preserved cultures were compared for dissolving chalcopyrite concentrate.Before 44 days,the unpreserved culture can reach a high copper extraction of about 17.4 g/L.While the preserved culture shows a rather low copper extraction,which is only 9.7 g/L.When the bioleaching time was extended to 80 days,copper extraction by preserved culture increases remarkably,and the concentration of copper finally achieves up to 18.3 g/L.On the other hand,copper extraction by the unpreserved culture does not show remarkable increase from 44th to the 80th day,and finally the total copper extraction is 19.8 g/L.As a result,total copper extraction in 80 days by preserved culture approaches that by unpreserved culture and freeze drying and frozen preservation even after 15 months does not bring much decrease of bioleaching ability.

Biodiversity and Screening of Moderately Halophilic Bacteria with Hydrolytic and Antimicrobial Activities from Yuncheng Salt Lake,China

1 Introduction Yuncheng Salt Lake is an old lake with a history of more than 5000 years,which locates in the margins of the central plains of China,with an area of about 130 km.It was an important resource of salt for human consumption from early times.Major chemicals in Yuncheng Salt Lake contain Na Cl,Na2SO4 and Mg SO4(Gao et al.2007).In recent years,some halophilic bacteria and archaea were

Bioleaching of chalcopyrite by mixed culture of moderately thermophilic microorganisms

A mixed culture of moderately thermophilic microorganisms was enriched from acid mine drainages(AMDs)samples collected from several sulphide mines in China,and the bioleaching of chalcopyrite was conducted both in shake flask and bioreactor.The results show that in the shake flask,the mixture can tolerate 50 g/L chalcopyrite after being acclimated to gradually increased concentrations of chalcopyrite.The copper extraction increases obviously in bioleaching of chalcopyrite with moderately thermophilic microorganisms supplemented with 0.4 g/L yeast extract at 180 r/min,74% copper can be extracted in the pulp of 50 g/L chalcopyrite after 20 d.Compared with copper extractions of mesophilic culture,unacclimated culture and acclimated culture without addition of yeast extract,that of accliniated culture with addition of yeast extract is increased by 53%,44% and 16%,respectively.In a completely stirred tank reactor,the mass fraction of copper and total iron extraction reach up to 81% and 56%,respectively.The results also indicate that it is necessary to add a large amount of acid to the pulp to extract copper from chalcopyrite effectively.

THE STOCHASTIC BOUNDARY ELEMENT METHOD IN STATISTICAL ANALYSIS OF MODERATELY THICK PLATES

In this paper a stochastic boundary element method (SEEM) is developed to analyze moderately thick plates with random material parameters and random thickness. Based on the Taylor series expansion, the boundary integration equations concerning the mean and deviation of the generalized displacements are derived, respectively. It is found that the randomness of material parameters is equivalent to a random load, so the mean and covariance matrices of unknown generalized boundary displacements and tractions can be obtained. Furthermore, the mean and covariance of generalized displacements and forces at internal points can also be obtained. A numerical example has been worked out with the method proposed and necessary analysis is made for the results.

Stepsize Selection in Explicit Runge-Kutta Methods for Moderately Stiff Problems

We present an algorithm for determining the stepsize in an explicit Runge-Kutta method that is suitable when solving moderately stiff differential equations. The algorithm has a geometric character, and is based on a pair of semicircles that enclose the boundary of the stability region in the left half of the complex plane. The algorithm includes an error control device. We describe a vectorized form of the algorithm, and present a corresponding MATLAB code. Numerical examples for Runge-Kutta methods of third and fourth order demonstrate the properties and capabilities of the algorithm.

GENERAL SOLUTION OF THE OVERALL BENDING OF FLEXIBLE CIRCULAR RING SHELLS WITH MODERATELY SLENDER RATIO AND APPLICATIONS TO THE BELLOWS (Ⅰ)-GOVERNING EQUATION AND GENERAL SOLUTION

The overall bending of circular ring shells subjected to bending moments and lateral forces is discussed. The derivation of the equations was based upon the theory of flexible shells generalized by E.L. Axelrad and the assumption of the moderately slender ratio less than 1/3 (i.e., ratio between curvature radius of the meridian and distance from the meridional curvature center to the axis of revolution). The present general solution is an analytical one convergent in the whole domain of the shell and with the necessary integral constants for the boundary value problems. It can be used to calculate the stresses and displacements of the related bellows. The whole work is arranged into four parts: (Ⅰ) Governing equation and general solution; (Ⅱ) Calculation for Omega_shaped bellows; (Ⅲ) Calculation for C_shaped bellows; (Ⅳ) Calculation for U_shaped bellows. This paper is the first part.

Relationships between Features of EmergingAdulthood, Situated Decisions toward PhysicalActivity, and Physical Activity among CollegeStudents: The Moderating Role of ExerciseIntensity Tolerance

A significant portion of emerging adults do not achieve recommended levels of physical activity (PA). Previous studies observedassociations between features of emerging adulthood and PA levels, while the potential psychological mechanisms that mightexplain this phenomenon are not fully understood. In this context, there is some evidence that situated decisions towardphysical activity (SDPA) and exercise-intensity tolerance might influence PA level. To provide empirical support for thisassumption, the current study investigated whether (i) features of emerging adulthood are linked to SDPA, which, in turn,might affect PA engagement;(ii) exercise-intensity tolerance moderate the relationship between SDPA and PA level;and (iii)SDPA is a mediator of the relationship between features of emerging adulthood and PA levels under the prerequisite thatexercise-intensity tolerance moderates the link between SDPA and PA engagement. In this study a group of 1,706 Chinesecollege students was recruited and asked to complete a set of questionnaires assessing their SDPA, PA levels, exercise-intensitytolerance, and features associated with emerging adulthood, namely Self-exploration, Instability, and Possibility. Our resultsindicated that SDPA positively predicted PA levels and this relationship became stronger when exercise-intensity tolerance wasused as a moderator. Furthermore, it was observed that individuals with a higher level of Instability and a lower level ofPossibility during emerging adulthood exhibited a lower level of SDPA. Taken together, the results of our study providefurther insights on a potential psychological mechanism linking features of emerging adulthood and physical activity.

The Principles and Methods of Division of Potential Seismic Regions for Moderately Strong Earthquakes in Northeast and North China

The uncertainty of potential seismic regions for moderately strong earthquakes has a great effect on the results of seismic hazard analysis in weak seismicity regions,so it is the basement of seismic zoning and seismic hazard assessment for engineering sites by correctly dividing the potential seismic regions for moderately strong earthquakes.By taking Northeast and North China as examples,the authors compiled and systematically analyzed a large amount of basic data and then suggest the principles and methods of potential seismic regions for moderately strong earthquakes based on a great number of case studies.The practical division of potential seismic regions in the Changchun and Jilin areas shows that these principles and methods show better suitability.Moreover,the authors also discuss in this paper the progress obtained and put forward some problems that should be solved in the future.