Application of modified polypropylene （crude） fibers concrete to strengthen the support structures in deep mine roadway

The an thors developed a new composite cement base material by mixing the high tenacity polypropylene （coarse） fiber in plain cement base for the cement-layer-spray technology. By studying the key parameters of the fiber dosage, the spray layer thickness, and the fiber reinforced concrete injection time, etc. It is found that the ideal volume ratio of polypropylene （crude） fiber is 0.8% （V/V）, and the secondary lining fiber concrete spraying should start when the shrinkage rate is lower than 0.5 mm/d, and the optimal thickness of shotcrete is 120 mm. The supporting effects and the economic benefits were studied using a real project practice, and the result obtained can be a good reference for practical applications of this new supporting material in the future.

RELATION BETWEEN DYNAMIC LOSS MODULUS AND DIFFUSION COEFFICIENT IN A MODIFIED PET FIBER

The mobility of polymer chain segments is shown to play a major role in the diffusion ofdisperse dyes in a copolymerization modified PET system, monoepoxy compoundCH_3 (CH_3),OCH_2CH--CH_2 modified PET. The rate of dye diffusion (diffusion coefficient D) hasbeen related to the time-dependent mechanical property, dynamic loss modulus E', which iscontrolled by the mobility of chain segments. In this modified copolyester system, the variance ofamount of modifier in the copolyester fibers causes the change in disperse dye diffusion coefficientto fiber, and in the dynamic loss modulus of the fibers, but the relationship between the diffusionand the dynamic loss modulus is in agreement with the theoretical relation derived by Bell andDumbleton. The relation obtained in this paper is:Ln D=-2. 28Ln E'+26. 81

Toughness of Polymer Modified Steel Fiber Reinforced Concrete

An experimental investigation is carried out to study the toughness of polymer modified steel fiber reinforced concrete. Volume fraction of steel fibers is varied from 0% to 7% at the interval of 1% by weight of cement. 15% SBR latex polymer was used by weight of cement. Cubes of size 150 × 150 × 150 mm for compressive strength, prism specimens of size 150 mm × 150 mm × 700 mm for flexure strength and, specimen of size 150 × 150 × 150 mm with 16 mm diameter tor steel bar of length 650 mm embedded in concrete cube at the center for bond test were prepared. Various specimens were tested after 28 days of curing. Area under curve (toughness) is measured and mentioned in this work.

A 3D graphene/polyimide fiber framework with improved thermal conductivity and mechanical performance

The integration of electronic components and the popularity of flexible devices have come up with higher expectations for the heat dissipation capability and comprehensive mechanical performance of thermal management materials.In this work,after the modification of polyimide(PI)fibers through oxidation and amination,the obtained PDA@OPI fibers(polydopamine(PDA)-modified pre-oxidized PI fibers)with abundant amino groups were mixed into graphene oxide(GO)to form uniform GO-PDA@OPI composites.Followed by evaporation,carbonization,graphitization and mechanical compaction,the G-gPDA@OPI films with a stable three-dimensional(3D)long-range interconnected covalent structure were built.In particular,due to the rich covalent bonds between GO layers and PDI@OPI fibers,the enhanced synergistic graphitization promotes an ordered graphitized structure with less interlayer distance between adjacent graphene sheets in composite film.As a result,the optimized G-gPDA@OPI film displays an improved tensile strength of 78.5 MPa,tensile strain of 19.4%and thermal conductivity of 1028 W/(m·K).Simultaneously,it also shows superior flexibility and high resilience.This work provides an easily-controlled and relatively low-cost route for fabricating multifunctional graphene heat dissipation films.

A Challenging Approach to Improve the Low Affinity of Acrylic Fibres to Be Successfully Dyed with a Bio-Colorant Extracted from Grape Marc

Acrylic fibres are highly crystalline and non-polar polymers,which makes their dyeing a very difficult step that poses real technical challenges.In order to overcome this concern,it is intended in this paper to modify acrylic fibers by different methods namely cationisation using the Crosscolor DRT then amidoximation using hydroxylamine hydrochloride and ammonium acetate.The resulted samples were dyed then with the bio-colorant extracted from grape marc.The effect of the pretreatment on fibers fine structure using X-ray diffraction and the scanning electron microscope(SEM)images and its correlation with the colour strength of the dyed fabrics was investigated.The dyeing parameters,such as dye bath pH and temperature on the performances of this dyeing process were studied.Good dyeing qualities and new shades varying from brown to grey and dark green have been obtained following process optimization,mordanting and modification of acrylic fibers by the technique of cationisation.

Influence of simulating deep-sea environmental factors on cathodic performance of seawater battery

A metal-dissolved oxygen seawater battery(SWB)uses metal and dissolved oxygen as the reactants,and it is ideal for use as a long-time low-power distributed power supply in deep sea,due to its advantages of open structure in service without electrolyte.However,several simulating deep-sea environmental factors,such as flow rate,dissolved oxygen concentration,and temperature of seawater may af fect the oxygen reduction reaction(ORR)rate and the stability of electrochemically modified polyacrylonitrile-based carbon fiber brush(MPAN-CFB)cathode,which was studied by steady-state polarization and galvanostatic discharge methods.In addition,the scales formed on MPAN-CFB surface were characterized by SEM and XRD.Results show that the ORR rate increased quickly with the increase of the seawater flow rate up to 3 cm/s,and then gradually stabilized.Moreover,the ORR rate was largely af fected by dissolved oxygen concentration,and the concentration of>3 mg/L was favorable.Compared with surface layer temperature of 15℃,the low temperature of deep sea(4℃)has a negligible ef fect on ORR rate.When the working current is too high,it will lead to the formation of CaCO_3 scales(aragonite)of at the cathodic surface,resulting in the decrease of ORR rate,and consequently the damage to the long-time stability of MPAN-CFB.

Fast removal of heavy metal ions and phytic acids from water using new modified chelating fiber

The graft copolymerization of acrylic acid（AA） onto polyethylene glycol terephthalate（PET） fiber initialed by benzoy peroxide （BPO） was carried out in heterogeneous media.Moreover,modification of the grafted PET fiber（PET-AA） was done by changing the carboxyl group into acylamino group through the reaction with dimethylamine.The modified chelating fiber（NDWJN1） was characterized using elementary analysis,SEM and FT-IR spectroscopy.Adsorption kinetic curves indicated that NDWJNl could fast remove heavy metal ions and phytic acids from water effectively.Furthermore,batch kinetic studies indicated that heavy metal ions adsorbed to NDWJNl could be filted well by both pseudo-first-order and pseudo-second-order adsorption equations,but the intra-particle diffusion played a dominant role in the adsorption of phytic acids.

Liquid modified photonic crystal fiber for simultaneous temperature and strain measurement

A liquid modified photonic crystal fiber(PCF)integrated with an embedded directional coupler and multi-mode interferometer is fabricated by infiltrating three adjacent air holes of the innermost layer with standard 1.48 refractive index liquids.The refractive index of the filled liquid is higher than that of background silica,which can not only support the transmitting rod modes but also the"liquid modified core"modes propagating between the PCF core and the liquid rods.Hence,the light propagating in the liquid modified core can be efficiently coupled into the satellite waveguides under the phase-matching conditions,resulting in a dramatic decrease of the resonant wavelength intensity.Furthermore,there is a multi-mode interference produced by modified core modes and rod modes.Such a compact(~0.91 cm)device integrated with an embedded coupler and interferometer is demonstrated for high-sensitivity simultaneous temperature(~14.72 nm∕℃)and strain(~13.01 pm∕με)measurement.

Low-noise and highly stable optical fiber temperature sensor using modified pulse-reference-based compensation technique

We modify the pulse-reference-based compensation technique and propose a low-noise and highly stable optical fiber temperature sensor based on a zinc telluride film-coated fiber tip. The system noise is measured to be 0.0005 dB, which makes it possible for the detection of the minor reflectivity change of the film at different temperatures. The temperature sensitivity is 0.0034 d B/℃, so the resolution can achieve 0.2℃. The maximum difference of the temperature output values of the sensor at 20℃ at different points in time is 0.39℃. The low cost, ultra-small size, high stability, and good repeatability of the sensor make it a promising temperature sensing device for practical application.