Machine learning(ML)integrated with density functional theory(DFT)calculations have recently been used to accelerate the design and discovery of single-atom catalysts(SACs)by establishing deep structure–activity rela...Machine learning(ML)integrated with density functional theory(DFT)calculations have recently been used to accelerate the design and discovery of single-atom catalysts(SACs)by establishing deep structure–activity relationships.The traditional ML models are always difficult to identify the structural differences among the single-atom systems with different modification methods,leading to the limitation of the potential application range.Aiming to the structural properties of several typical two-dimensional MA_(2)Z_(4)-based single-atom systems(bare MA_(2)Z_(4)and metal single-atom doped/supported MA_(2)Z_(4)),an improved crystal graph convolutional neural network(CGCNN)classification model was employed,instead of the traditional machine learning regression model,to address the challenge of incompatibility in the studied systems.The CGCNN model was optimized using crystal graph representation in which the geometric configuration was divided into active layer,surface layer,and bulk layer(ASB-GCNN).Through ML and DFT calculations,five potential single-atom hydrogen evolution reaction(HER)catalysts were screened from chemical space of 600 MA_(2)Z_(4)-based materials,especially V_(1)/HfSn_(2)N_(4)(S)with high stability and activity(Δ_(GH*)is 0.06 eV).Further projected density of states(pDOS)analysis in combination with the wave function analysis of the SAC-H bond revealed that the SAC-dz^(2)orbital coincided with the H-s orbital around the energy level of−2.50 eV,and orbital analysis confirmed the formation ofσbonds.This study provides an efficient multistep screening design framework of metal single-atom catalyst for HER systems with similar two-dimensional supports but different geometric configurations.展开更多
To address the issues of reduced performance and shortened lifespan during the low-carbonizating process of Al_(2)O_(3)-C refractories,nano-crystalline ZrC modified graphite was prepared using Zr powder and flake grap...To address the issues of reduced performance and shortened lifespan during the low-carbonizating process of Al_(2)O_(3)-C refractories,nano-crystalline ZrC modified graphite was prepared using Zr powder and flake graphite as raw materials,with NaCl and NaF mixed salt serving as the medium.The flake graphite was gradually replaced by ZrC modified graphite in the preparation of Al_(2)O_(3)-C refractories,and its impact on the material’s structure and properties was investigated.The results indicate that,compared to samples with only flake graphite,the introduction of 1 mass%to 5 mass%nano-crystalline ZrC modified graphite can significantly enhance the mechanical performance of low-carbon Al_(2)O_(3)-C refractories.When 5 mass%ZrC modified graphite is added,the mechanical properties of the samples are optimal,with the cold modulus of rupture and elastic modulus reaching 22.5 MPa and 65.0 GPa,respectively.展开更多
Nafion as a universal polymer ionomer was widely applied for nanocatalysts electrode preparation.However,the effect of Nafion on electrocatalytic performance was often overlooked,especially for CO_(2)electrolysis.Here...Nafion as a universal polymer ionomer was widely applied for nanocatalysts electrode preparation.However,the effect of Nafion on electrocatalytic performance was often overlooked,especially for CO_(2)electrolysis.Herein,the key roles of Nafion for CO_(2)RR were systematically studied on Cu nanoparticles(NPs)electrocatalyst.We found that Nafion modifier not only inhibit hydrogen evolution reaction(HER)by decreasing the accessibility of H_(2)O from electrolyte to Cu NPs,and increase the CO_(2)concentration at electrocatalyst interface for enhancing the CO_(2)mass transfer process,but also activate CO_(2)molecule by Lewis acid-base interaction between Nafion and CO_(2)to accelerate the formation of^(*)CO,which favor of C–C coupling for boosting C_(2)product generation.Owing to these features,the HER selectivity was suppressed from 40.6%to 16.8%on optimal Cu@Nafion electrode at-1.2 V versus reversible hydrogen electrode(RHE),and as high as 73.5%faradaic efficiencies(FEs)of C_(2)products were achieved at the same applied potential,which was 2.6 times higher than that on bare Cu electrode(~28.3%).In addition,Nafion also contributed to the long-term stability by hinder Cu NPs morphology reconstruction.Thus,this work provides insights into the impact of Nafion on electrocatalytic CO_(2)RR performance.展开更多
In this study, we will introduce the modified (G'/G<sup>2</sup>)-expansion method to explore some of the exact traveling wave solutions of some nonlinear partial differential equations namely, Phi-4 eq...In this study, we will introduce the modified (G'/G<sup>2</sup>)-expansion method to explore some of the exact traveling wave solutions of some nonlinear partial differential equations namely, Phi-4 equation, Joseph-Egri (TRLW) equation, and Calogro-Degasperis (CD) equation. As a result, we have obtained solutions for the equations expressed in terms of trigonometric, hyperbolic and rational functions. Moreover, some selected solutions are plotted using some specific values for the parameters.展开更多
A carbon paste electrode (CPE) modified with ferrocene carboxylic acid (FcCA) and TiO2 nanoparticles was constructed by incorporating TiO2 nanoparticles and ferrocene carboxylic acid into the carbon paste matrix. The ...A carbon paste electrode (CPE) modified with ferrocene carboxylic acid (FcCA) and TiO2 nanoparticles was constructed by incorporating TiO2 nanoparticles and ferrocene carboxylic acid into the carbon paste matrix. The electrochemical behavior of captopril (CAP) at the surface of the modified electrode was investigated using electroanalytical methods. The modified electrode showed excellent electrocatalytic activity for the oxidation of CAP in aqueous solutions at physiological pH values. Cyclic voltammetric curves showed that the oxidation of CAP at the surface of the modified electrode reduced its overpotential by more than 290 mV. The modified electrode was used for detecting captopril using cyclic voltammetry and square wave voltammetry techniques. A calibration curve in the range of 0.03 to 2400 μmol/L was obtained that had a detection limit of 0.0096 μmol/L (3?) under the optimized conditions. The modified electrode was successfully used for the determination of captopril in pharmaceutical and biological samples.展开更多
On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For stu...On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For study of the dynamical mechanism, which causes the pattern of summer circulation in the SCS, the diagnostic model (Yuan et al. 1982. Acta Oceanologica Sinica,4(1):1-11; Yuan and Su. 1992. Numerical Computation of Physical Oceanography.474-542) is used to simulate numerically the summer circulation in the SCS. The following results have been obtained. (1) The central and southwestern SCSs are dominated mainly by anticy-clonic circulation systems. They are mainly as follows. 1) There is strong anticyclonic eddy southeast of Vietnam (W1). Its horizontal scale is about 300 km, and it extends vertically from the surface to the about 1 000 m level. 2) There are a warm eddy W2 southeast of Zhongsha Islands and the anticyclonic circulation system W3 west off the Luzon Island. 3) There is a stronger cyclonic eddy C1 between the anticyclonic eddies W1 and W2.4) A strong northward coastal jet is present near the coast of Vietnam, and separates from the coast of Vietnam at about 12° N to the northeast.(2)The northern SCS is dominated mainly by a cyclonic circulation system. There is a cyclonic circulation system near and north of Section N2. (3) The southeastern SCS is dominated mainly by the cyclonic circulation system. (4) Comparing the results of circulation in the SCS during the summer of 2000 with those during the summer of 1998, it is found that they agree qualitatively, but there is the some difference between them in quantity.This shows that the circulation in the SCS has obviously seasonal feature. (5) The dynamical mechanism which products the basic pattern of summer circulation is because the following two reasons: 1) the joint effect of the baroclinity and relief (JEBAR) is essential dynamical cause; and 2) it is next important dynamical cause that the interaction between the wind stress and bottom topography under the southerly monsoon. (6) Comparing the hydrographic structure and distribution of stream functions with the SSH data from TOPEX/ERS-2 analysis in the SCS during August of 2000, they agree qualitatively.展开更多
Recently, a new （2＋1）-dimensional shallow water wave system, the （2＋1）-dlmenslonal displacement shallow water wave system （2DDSWWS）, was constructed by applying the variational principle of the analytic mechan...Recently, a new （2＋1）-dimensional shallow water wave system, the （2＋1）-dlmenslonal displacement shallow water wave system （2DDSWWS）, was constructed by applying the variational principle of the analytic mechanics in the Lagrange coordinates. The disadvantage is that fluid viscidity is not considered in the 2DDSWWS, which is the same as the famous Kadomtsev-Petviashvili equation and Korteweg-de Vries equation. Applying dimensional analysis, we modify the 2DDSWWS and add the term related to the fluid viscidity to the 2DDSWWS. The approximate similarity solutions of the modified 2DDSWWS （M2DDSWWS） is studied and four similarity solutions are obtained. For the perfect fluids, the coefficient of kinematic viscosity is zero, then the M2DDSWWS will degenerate to the 2DDSWWS.展开更多
The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were charact...The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were characterized byFT-IR spectra,TEM and TG analysis.It was convinced from FT-IR studies that both methyl methacrylate(MMA)and butyl-methacrylate(BMA)were co-grafted onto the surface of nano-TiO_2 particles.TEM images show that the surface of nano-TiO_2 particles was successfully modified by a thick layer of film-like polymer.TG results demonstrate that the decompositiontemperature of HPMC-g-PMMA/PBMA,which has been grafted onto the surface of nano-TiO_2,is 56.9 K higher than that ofHPMC-g-PMMA/PBMA.展开更多
In this paper,the truncated Painlev′e analysis,nonlocal symmetry,Bcklund transformation of the（2＋1）-dimensional modified Bogoyavlenskii–Schiff equation are presented.Then the nonlocal symmetry is localized to the...In this paper,the truncated Painlev′e analysis,nonlocal symmetry,Bcklund transformation of the（2＋1）-dimensional modified Bogoyavlenskii–Schiff equation are presented.Then the nonlocal symmetry is localized to the corresponding nonlocal group by the prolonged system.In addition,the（2＋1）-dimensional modified Bogoyavlenskii–Schiff is proved consistent Riccati expansion（CRE） solvable.As a result,the soliton–cnoidal wave interaction solutions of the equation are explicitly given,which are difficult to find by other traditional methods.Moreover figures are given out to show the properties of the explicit analytic interaction solutions.展开更多
A novel nano crystalline Ag2O2-PbO2 film chemically modified electrode (CME) was prepared and the CME was characterized by X-ray diffractometer (XRD) and atomic force microscope (AFM). By chronoamperometry, the nano A...A novel nano crystalline Ag2O2-PbO2 film chemically modified electrode (CME) was prepared and the CME was characterized by X-ray diffractometer (XRD) and atomic force microscope (AFM). By chronoamperometry, the nano Ag2O2-PbO2 CME was used as bioelectro- chemical sensor to determine the population of Escherichia coli (E. coli) in water. Compared with conventional methods, it is found that the technique we used is fast and convenient in counting E. coli.展开更多
The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modifi...The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40（40%）/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40（40%）/SiO2.展开更多
The electrochemical behavior of vitamin C（ascorbic acid or AA） is investigated on the surface of a carbon-paste electrode modified with TiO2 nanoparticles and 2,2＇-（1,2 butanediylbis（nitriloethylidyne））-bis-hyd...The electrochemical behavior of vitamin C（ascorbic acid or AA） is investigated on the surface of a carbon-paste electrode modified with TiO2 nanoparticles and 2,2＇-（1,2 butanediylbis（nitriloethylidyne））-bis-hydroquinone（BBNBH）.The prepared modified electrode showed an efficient catalytic role in the electrochemical oxidation of AA,leading to remarkable decrease in oxidation overpotential and enhancement of the kinetics of the electrode reaction.This modified electrode exhibits well-separated oxidation peaks for AA and uric acid（UA）.The modified electrode is successfully applied for the accurate determination of AA in pharmaceutical preparations.展开更多
A novel chelating resin with sulfonic group was synthesized by chemical modification of D401 resin with sulphonation reaction and characterized by FT-IR spectrometry. The adsorption properties of the novel chelating r...A novel chelating resin with sulfonic group was synthesized by chemical modification of D401 resin with sulphonation reaction and characterized by FT-IR spectrometry. The adsorption properties of the novel chelating resin for Pb2+ were studied by batch adsorption, and the adsorption process was analyzed from thermodynamics and kinetics aspects. The adsorption mechanism of Pb2+ on the modified D401 chelating resin was discussed by FT-IR spectrometry. Experimental results show that in the Pb2+ concentration range of 200-400 mg/L, the adsorption capacities of the modified D401 chelating resin for Pb2+ increase by 77%-129%, and Langmuir isothermal adsorption model is more suitable for the equilibrium adsorption data. Adsorption is an endothermic process that runs spontaneously. Kinetic analysis shows that the adsorption rate is mainly governed by liquid film diffusion. The best pH value under adsorption condition is 4-5. The saturated resin can be regenerated by 3 mol/L nitric acid, and the adsorption capacity remains stable after five consecutive adsorption-desorption cycles. The maximal static saturated adsorption capacity of the resin is 206 mg/g at 333 K in the Pb2+ concentration range of 200-400 mg/L. The modified D401 chelating resin is an efficient adsorbent for the removal of Pb2+ from its single-metal ion solution.展开更多
Artificial zeolite was modified by nano-Fe3O4 for development of functional adsorbents.Subsequently,adsorbents such as calcium cross-linked nano-Fe3O4 microspheres (Ca-MS),calcium cross-linked nano-Fe3O4 modified zeol...Artificial zeolite was modified by nano-Fe3O4 for development of functional adsorbents.Subsequently,adsorbents such as calcium cross-linked nano-Fe3O4 microspheres (Ca-MS),calcium cross-linked nano-Fe3O4 modified zeolite microspheres (Ca-MZS) and iron cross-linked nano-Fe3O4 modified zeolite microspheres (Fe-MZS) were prepared and compared for their adsorption performance.The effects of adsorbent dosage,solution pH,initial concentration and ion content on the removal of Cu^2+ from wastewater are investigated,and the adsorption kinetics and isotherms for the adsorbent materials were analyzed.The experimental results indicate that for the initial concentration of Cu^2+ of 30 mg/L,the adsorption is noted to be most stable.The optimal initial pH for adsorbing Cu^2+ is observed to be 5.5.At an optimal dosage of Ca-MZS of 900 mg/L,the adsorption capacity is measured to be 28.25 mg/g,along with the removal rate of 72.49%.The addition of Na+ and K+ affects the adsorption of Cu^2+.For the Na^+ and K^+ concentration of 0.2 mmol/L,the Cu^2+ removal rate by Ca-MZS drops to 11.94% and 22.12%,respectively.As compared with the adsorbents such as Natural Zeolite (NZ),Ca-MS and Fe-MZS,Ca-MZS demonstrates the best removal effect in solution,where the removal rate reaches 84.27%,with the maximum adsorption capacity of 28.09 mg/g.The Cu^2+ adsorption kinetics of Ca-MZS is observed to follow the Elovich kinetic model,with the adsorption isotherm data fitting the Freundlich isotherm model by using the non-linear method.展开更多
基金supported by the National Key R&D Program of China(2021YFA1500900)National Natural Science Foundation of China(U21A20298,22141001).
文摘Machine learning(ML)integrated with density functional theory(DFT)calculations have recently been used to accelerate the design and discovery of single-atom catalysts(SACs)by establishing deep structure–activity relationships.The traditional ML models are always difficult to identify the structural differences among the single-atom systems with different modification methods,leading to the limitation of the potential application range.Aiming to the structural properties of several typical two-dimensional MA_(2)Z_(4)-based single-atom systems(bare MA_(2)Z_(4)and metal single-atom doped/supported MA_(2)Z_(4)),an improved crystal graph convolutional neural network(CGCNN)classification model was employed,instead of the traditional machine learning regression model,to address the challenge of incompatibility in the studied systems.The CGCNN model was optimized using crystal graph representation in which the geometric configuration was divided into active layer,surface layer,and bulk layer(ASB-GCNN).Through ML and DFT calculations,five potential single-atom hydrogen evolution reaction(HER)catalysts were screened from chemical space of 600 MA_(2)Z_(4)-based materials,especially V_(1)/HfSn_(2)N_(4)(S)with high stability and activity(Δ_(GH*)is 0.06 eV).Further projected density of states(pDOS)analysis in combination with the wave function analysis of the SAC-H bond revealed that the SAC-dz^(2)orbital coincided with the H-s orbital around the energy level of−2.50 eV,and orbital analysis confirmed the formation ofσbonds.This study provides an efficient multistep screening design framework of metal single-atom catalyst for HER systems with similar two-dimensional supports but different geometric configurations.
文摘To address the issues of reduced performance and shortened lifespan during the low-carbonizating process of Al_(2)O_(3)-C refractories,nano-crystalline ZrC modified graphite was prepared using Zr powder and flake graphite as raw materials,with NaCl and NaF mixed salt serving as the medium.The flake graphite was gradually replaced by ZrC modified graphite in the preparation of Al_(2)O_(3)-C refractories,and its impact on the material’s structure and properties was investigated.The results indicate that,compared to samples with only flake graphite,the introduction of 1 mass%to 5 mass%nano-crystalline ZrC modified graphite can significantly enhance the mechanical performance of low-carbon Al_(2)O_(3)-C refractories.When 5 mass%ZrC modified graphite is added,the mechanical properties of the samples are optimal,with the cold modulus of rupture and elastic modulus reaching 22.5 MPa and 65.0 GPa,respectively.
基金financially supported by the Natural Science Foundation of Guangdong Province (2022A1515012359)the National Natural Science Foundation of China (21902121)+1 种基金the STU Scientific Research Foundation for Talents (NTF21020)the 2020 Li Ka Shing Foundation Cross-Disciplinary Research Grant (2020LKSFG09A)。
文摘Nafion as a universal polymer ionomer was widely applied for nanocatalysts electrode preparation.However,the effect of Nafion on electrocatalytic performance was often overlooked,especially for CO_(2)electrolysis.Herein,the key roles of Nafion for CO_(2)RR were systematically studied on Cu nanoparticles(NPs)electrocatalyst.We found that Nafion modifier not only inhibit hydrogen evolution reaction(HER)by decreasing the accessibility of H_(2)O from electrolyte to Cu NPs,and increase the CO_(2)concentration at electrocatalyst interface for enhancing the CO_(2)mass transfer process,but also activate CO_(2)molecule by Lewis acid-base interaction between Nafion and CO_(2)to accelerate the formation of^(*)CO,which favor of C–C coupling for boosting C_(2)product generation.Owing to these features,the HER selectivity was suppressed from 40.6%to 16.8%on optimal Cu@Nafion electrode at-1.2 V versus reversible hydrogen electrode(RHE),and as high as 73.5%faradaic efficiencies(FEs)of C_(2)products were achieved at the same applied potential,which was 2.6 times higher than that on bare Cu electrode(~28.3%).In addition,Nafion also contributed to the long-term stability by hinder Cu NPs morphology reconstruction.Thus,this work provides insights into the impact of Nafion on electrocatalytic CO_(2)RR performance.
文摘In this study, we will introduce the modified (G'/G<sup>2</sup>)-expansion method to explore some of the exact traveling wave solutions of some nonlinear partial differential equations namely, Phi-4 equation, Joseph-Egri (TRLW) equation, and Calogro-Degasperis (CD) equation. As a result, we have obtained solutions for the equations expressed in terms of trigonometric, hyperbolic and rational functions. Moreover, some selected solutions are plotted using some specific values for the parameters.
文摘A carbon paste electrode (CPE) modified with ferrocene carboxylic acid (FcCA) and TiO2 nanoparticles was constructed by incorporating TiO2 nanoparticles and ferrocene carboxylic acid into the carbon paste matrix. The electrochemical behavior of captopril (CAP) at the surface of the modified electrode was investigated using electroanalytical methods. The modified electrode showed excellent electrocatalytic activity for the oxidation of CAP in aqueous solutions at physiological pH values. Cyclic voltammetric curves showed that the oxidation of CAP at the surface of the modified electrode reduced its overpotential by more than 290 mV. The modified electrode was used for detecting captopril using cyclic voltammetry and square wave voltammetry techniques. A calibration curve in the range of 0.03 to 2400 μmol/L was obtained that had a detection limit of 0.0096 μmol/L (3?) under the optimized conditions. The modified electrode was successfully used for the determination of captopril in pharmaceutical and biological samples.
基金the Major State Basic Research Program of China un der contract No.G1999043805.
文摘On the basis of hydrographic data obtained in August 2000 cruise, the circulation in the South China Sea (SCS) is computed by the modified inverse method in combination with SSH data from TOPEX/ERS-2 analysis. For study of the dynamical mechanism, which causes the pattern of summer circulation in the SCS, the diagnostic model (Yuan et al. 1982. Acta Oceanologica Sinica,4(1):1-11; Yuan and Su. 1992. Numerical Computation of Physical Oceanography.474-542) is used to simulate numerically the summer circulation in the SCS. The following results have been obtained. (1) The central and southwestern SCSs are dominated mainly by anticy-clonic circulation systems. They are mainly as follows. 1) There is strong anticyclonic eddy southeast of Vietnam (W1). Its horizontal scale is about 300 km, and it extends vertically from the surface to the about 1 000 m level. 2) There are a warm eddy W2 southeast of Zhongsha Islands and the anticyclonic circulation system W3 west off the Luzon Island. 3) There is a stronger cyclonic eddy C1 between the anticyclonic eddies W1 and W2.4) A strong northward coastal jet is present near the coast of Vietnam, and separates from the coast of Vietnam at about 12° N to the northeast.(2)The northern SCS is dominated mainly by a cyclonic circulation system. There is a cyclonic circulation system near and north of Section N2. (3) The southeastern SCS is dominated mainly by the cyclonic circulation system. (4) Comparing the results of circulation in the SCS during the summer of 2000 with those during the summer of 1998, it is found that they agree qualitatively, but there is the some difference between them in quantity.This shows that the circulation in the SCS has obviously seasonal feature. (5) The dynamical mechanism which products the basic pattern of summer circulation is because the following two reasons: 1) the joint effect of the baroclinity and relief (JEBAR) is essential dynamical cause; and 2) it is next important dynamical cause that the interaction between the wind stress and bottom topography under the southerly monsoon. (6) Comparing the hydrographic structure and distribution of stream functions with the SSH data from TOPEX/ERS-2 analysis in the SCS during August of 2000, they agree qualitatively.
基金Project supported by the Natural Science Foundation of Guangdong Province of China (Grant No.10452840301004616)the National Natural Science Foundation of China (Grant No.61001018)the Scientific Research Foundation for the Doctors of University of Electronic Science and Technology of China Zhongshan Institute (Grant No.408YKQ09)
文摘Recently, a new （2＋1）-dimensional shallow water wave system, the （2＋1）-dlmenslonal displacement shallow water wave system （2DDSWWS）, was constructed by applying the variational principle of the analytic mechanics in the Lagrange coordinates. The disadvantage is that fluid viscidity is not considered in the 2DDSWWS, which is the same as the famous Kadomtsev-Petviashvili equation and Korteweg-de Vries equation. Applying dimensional analysis, we modify the 2DDSWWS and add the term related to the fluid viscidity to the 2DDSWWS. The approximate similarity solutions of the modified 2DDSWWS （M2DDSWWS） is studied and four similarity solutions are obtained. For the perfect fluids, the coefficient of kinematic viscosity is zero, then the M2DDSWWS will degenerate to the 2DDSWWS.
基金This work was funded by the Natural Science Fund of Anhui Educational Committeethe Youth Fund of Anhui Normal University.
文摘The surface of nano-TiO_2 was encapsulated with hydroxyl-propyl-methyl cellulose(HPMC),and then cograftedwith acrylates.Conditions of absorbing and grafting have been studied.Modified nano-TiO_2 particles were characterized byFT-IR spectra,TEM and TG analysis.It was convinced from FT-IR studies that both methyl methacrylate(MMA)and butyl-methacrylate(BMA)were co-grafted onto the surface of nano-TiO_2 particles.TEM images show that the surface of nano-TiO_2 particles was successfully modified by a thick layer of film-like polymer.TG results demonstrate that the decompositiontemperature of HPMC-g-PMMA/PBMA,which has been grafted onto the surface of nano-TiO_2,is 56.9 K higher than that ofHPMC-g-PMMA/PBMA.
基金Project supported by the Global Change Research Program of China(Grant No.2015CB953904)the National Natural Science Foundation of China(Grant Nos.11275072 and 11435005)+2 种基金the Doctoral Program of Higher Education of China(Grant No.20120076110024)the Network Information Physics Calculation of Basic Research Innovation Research Group of China(Grant No.61321064)the Fund from Shanghai Collaborative Innovation Center of Trustworthy Software for Internet of Things(Grant No.ZF1213)
文摘In this paper,the truncated Painlev′e analysis,nonlocal symmetry,Bcklund transformation of the（2＋1）-dimensional modified Bogoyavlenskii–Schiff equation are presented.Then the nonlocal symmetry is localized to the corresponding nonlocal group by the prolonged system.In addition,the（2＋1）-dimensional modified Bogoyavlenskii–Schiff is proved consistent Riccati expansion（CRE） solvable.As a result,the soliton–cnoidal wave interaction solutions of the equation are explicitly given,which are difficult to find by other traditional methods.Moreover figures are given out to show the properties of the explicit analytic interaction solutions.
基金We are greateful to the National Narural Science Foundation of China(No.20455017)Science and Technology Committee of Shanghai Municipal(No.0452nm084).
文摘A novel nano crystalline Ag2O2-PbO2 film chemically modified electrode (CME) was prepared and the CME was characterized by X-ray diffractometer (XRD) and atomic force microscope (AFM). By chronoamperometry, the nano Ag2O2-PbO2 CME was used as bioelectro- chemical sensor to determine the population of Escherichia coli (E. coli) in water. Compared with conventional methods, it is found that the technique we used is fast and convenient in counting E. coli.
基金Foundation items:the National Natural Science Foundation of China(No.20373085)the Natural Science Foundation of Shanxi Province(No.20051023)
文摘The attractive utilization route for one-step catalytic oxidation of dimethyl ether to dimethoxymethane was successfully carried out over the H3PW12O40（40%）/SiO2 catalyst, modified by Cs, K, Ni, and V. The Cs modification of H3PW12O40（40%）/SiO2 gave the most promising result of 20% dimethyl ether conversion and 34.8% dimethoxymethane selectivity. Dimethoxymethane could be synthe- sized via methoxy groups decomposed from dimethyl ether through the synergistic effect between the acid sites and the redox sites of Cs modified H3PW12O40（40%）/SiO2.
文摘The electrochemical behavior of vitamin C（ascorbic acid or AA） is investigated on the surface of a carbon-paste electrode modified with TiO2 nanoparticles and 2,2＇-（1,2 butanediylbis（nitriloethylidyne））-bis-hydroquinone（BBNBH）.The prepared modified electrode showed an efficient catalytic role in the electrochemical oxidation of AA,leading to remarkable decrease in oxidation overpotential and enhancement of the kinetics of the electrode reaction.This modified electrode exhibits well-separated oxidation peaks for AA and uric acid（UA）.The modified electrode is successfully applied for the accurate determination of AA in pharmaceutical preparations.
基金Project(708049) supported by the Important Item Cultivation Foundation of Scientific Innovation Project of Colleges and Universities of China
文摘A novel chelating resin with sulfonic group was synthesized by chemical modification of D401 resin with sulphonation reaction and characterized by FT-IR spectrometry. The adsorption properties of the novel chelating resin for Pb2+ were studied by batch adsorption, and the adsorption process was analyzed from thermodynamics and kinetics aspects. The adsorption mechanism of Pb2+ on the modified D401 chelating resin was discussed by FT-IR spectrometry. Experimental results show that in the Pb2+ concentration range of 200-400 mg/L, the adsorption capacities of the modified D401 chelating resin for Pb2+ increase by 77%-129%, and Langmuir isothermal adsorption model is more suitable for the equilibrium adsorption data. Adsorption is an endothermic process that runs spontaneously. Kinetic analysis shows that the adsorption rate is mainly governed by liquid film diffusion. The best pH value under adsorption condition is 4-5. The saturated resin can be regenerated by 3 mol/L nitric acid, and the adsorption capacity remains stable after five consecutive adsorption-desorption cycles. The maximal static saturated adsorption capacity of the resin is 206 mg/g at 333 K in the Pb2+ concentration range of 200-400 mg/L. The modified D401 chelating resin is an efficient adsorbent for the removal of Pb2+ from its single-metal ion solution.
基金Funded by the Science Foundation of Hubei Province of China(2015CFB706)。
文摘Artificial zeolite was modified by nano-Fe3O4 for development of functional adsorbents.Subsequently,adsorbents such as calcium cross-linked nano-Fe3O4 microspheres (Ca-MS),calcium cross-linked nano-Fe3O4 modified zeolite microspheres (Ca-MZS) and iron cross-linked nano-Fe3O4 modified zeolite microspheres (Fe-MZS) were prepared and compared for their adsorption performance.The effects of adsorbent dosage,solution pH,initial concentration and ion content on the removal of Cu^2+ from wastewater are investigated,and the adsorption kinetics and isotherms for the adsorbent materials were analyzed.The experimental results indicate that for the initial concentration of Cu^2+ of 30 mg/L,the adsorption is noted to be most stable.The optimal initial pH for adsorbing Cu^2+ is observed to be 5.5.At an optimal dosage of Ca-MZS of 900 mg/L,the adsorption capacity is measured to be 28.25 mg/g,along with the removal rate of 72.49%.The addition of Na+ and K+ affects the adsorption of Cu^2+.For the Na^+ and K^+ concentration of 0.2 mmol/L,the Cu^2+ removal rate by Ca-MZS drops to 11.94% and 22.12%,respectively.As compared with the adsorbents such as Natural Zeolite (NZ),Ca-MS and Fe-MZS,Ca-MZS demonstrates the best removal effect in solution,where the removal rate reaches 84.27%,with the maximum adsorption capacity of 28.09 mg/g.The Cu^2+ adsorption kinetics of Ca-MZS is observed to follow the Elovich kinetic model,with the adsorption isotherm data fitting the Freundlich isotherm model by using the non-linear method.
