A pilot-scale modified carbon source division anaerobic anoxic oxic(AAO) process with pre-concentration of returned activated sludge(RAS) was proposed in this study for the enhanced biological nutrient removal(BNR) of...A pilot-scale modified carbon source division anaerobic anoxic oxic(AAO) process with pre-concentration of returned activated sludge(RAS) was proposed in this study for the enhanced biological nutrient removal(BNR) of municipal wastewater with limited carbon source. The influent carbon source was fed in step while a novel RAS pre-concentration tank was adopted to improve BNR efficiency, and the effects of an influent carbon source distribution ratio and a RAS pre-concentration ratio were investigated. The results show that the removal efficiency of TN is mainly influenced by the carbon source distribution ratio while the TP removal relies on the RAS pre-concentration ratio. The optimum carbon source distribution ratio and RAS pre-concentration ratio are 60% and 50%, respectively, with an inner recycling ratio of 100% under the optimum steady operation of pilot test, reaching an average effluent TN concentration of 9.8 mg·L-1with a removal efficiency of 63% and an average TP removal efficiency of 94%. The mechanism of nutrient removal is discussed and the kinetics is analyzed. The results reveal that the optimal carbon source distribution ratio provides sufficient denitrifying carbon source to each anoxic phase, reducing nitrate accumulation while the RAS pre-concentration ratio improves the condition of anaerobic zone to ensure the phosphorus release due to less nitrate in the returned sludge. Therefore, nitrifying bacteria, denitrifying bacteria and phosphorus accumulation organisms play an important role under the optimum condition, enhancing the performance of nutrient removal in this test.展开更多
Sorption characteristics of both an organic pollutant (phenol) and a heavy metal (cadmium ion) on the clay layer of a Lou soil (Eum-orthic Anthrosol in Chinese Soil Taxonomy) along with the sorption mechanism were inv...Sorption characteristics of both an organic pollutant (phenol) and a heavy metal (cadmium ion) on the clay layer of a Lou soil (Eum-orthic Anthrosol in Chinese Soil Taxonomy) along with the sorption mechanism were investigated using three soil treatments: modification with a cationic surfactant cetyltrimethylammonium bromide added at an amount equivalent to 50% and 100% of the soil CEC (50%CB and 100%CB), modification with an amphoteric surface-modifying agent dodecyldimethylbetaine (commercially known as BS-12) added at an amount equivalent to 50% and 100% of the soil CEC (50% BS and 100%BS), and an unmodified control (CK). Results showed that the BS soil treatments increased sorption of both the heavy metal Cd2+ and the organic pollutant phenol. The equilibrium sorption amount of Cd2+ decreased in the order: 50%BS > 100%BS > CK > 50%CB > 100%CB, with the BS soil treatments being about 1.3 to 1.8 times higher and the CB soil treatments about 23% to 41% lower than CK. Both the single-site and two-site Langmuir models could be applied to describe the sorption of Cd2+ in each soil treatment. The equilibrium sorption amount of phenol on the soil samples decreased in the order: 100%CB > 50%CB > 100%BS > 50%BS > CK, with the CB soil treatments being 41.0 to 79.6 times higher and the BS soil treatments 4.0 to 8.3 times higher than CK. The Freundlich equation could also be used to describe the sorption characteristics of phenol. In the BS soil treatments, both an organophobic long carbon chain and hydrophilic charged groups resulted in a relatively strong sorption ability for both heavy metals and organic pollutants. In addition, the sorption ratio K, the ratio of phenol sorption amount of the modified soil to that of CK, increased initially and decreased later with the amount of phenol added, and the critical sorption ratio KC, the peak value of the sorption ratio curve plotted against the added phenol concentration, was a good index for evaluating the sorption ability of phenol in the soil.展开更多
Two field experiments were carried out at Akure (7oN, 5o101E) in the rainforest zone of Nigeria in 2006 and 2007 to determine the effectiveness of neem leaf, woodash and modified neem leaf extracts as fertilizer sourc...Two field experiments were carried out at Akure (7oN, 5o101E) in the rainforest zone of Nigeria in 2006 and 2007 to determine the effectiveness of neem leaf, woodash and modified neem leaf extracts as fertilizer sources in improving soil fertility, growth and yield of maize (Zea mays L) and watermelon (Citrulus lanatus) sole and intercrop. There were six treatments namely, poultry manure, neem leaf extract (sole), woodash extract, modified neem leaf (neem leaf + woodash), NPK 15-15-15 and a control (no fertilizer nor extract), replicated three times and arranged in a randomized complete block design (RCB). The extracts (neem leaf, wood ash and modified neem leaf) were applied at 1200 litres per hectare each, NPK 15-15-15 at 300 kg/ha and poultry was applied at 6t/ha. The results showed that there were significant increases (P 2O), K, Ca, Mg, Na, O.M, P and N compared to NPK 15-15-15 and neem leaf extract. For instance, modified neem leaf extract increased soil pH (H2O), K, Ca, Mg, Na, O.M, P and N by 12.4%, 32.8%, 25%, 23.7%, 19.32%, 17.24% and 20% respectively compared to neem leaf extract under intercrop plot. The high soil K/Ca, K/Mg and P/Mg ratios in the NPK 15-15-15 fertilizer treatment led to an imbalance in the supply of P, K, Ca and Mg nutrients to maize and watermelon crops. The least values for growth, yield and soil parameters were recorded under the control treatment. In these experiments, modified neem leaf extract (woodash + neem leaf extracts) applied at 1200 litres/ha was the most effective in improving soil fertility, growth and yield of maize and watermelon (sole and intercrop) and could substitute for 6 tons per hectare of poultry manure and 300kg/ha of NPK 15-15-15 fertilizer.展开更多
A macromer, methoxypolyethylene glycol acrylate (MPEGAA), was synthesized by direct esterification using methoxypolyethylene glycol (MPEG-1200) and acrylic acid (AA) as the main materials. MPEGAA was then used t...A macromer, methoxypolyethylene glycol acrylate (MPEGAA), was synthesized by direct esterification using methoxypolyethylene glycol (MPEG-1200) and acrylic acid (AA) as the main materials. MPEGAA was then used to prepare a polyacrylic acid superplasticizer modified with 2-acrylamido-2- methylpropane sulfonic acid (AMPS). A single-factor test was performed to investigate the effects of the molar ratio of acid to alcohol (n(AA)/n(MPEG)), inhibitor amount, catalyst amount, temperature, and time of esterification on the synthesis of MPEGAA. The experimental results showed that the optimal esterification conditions were as follows: n(AA)/n(MPEG), 3.5:1; amount of hydroquinone (as an inhibitor), 1.2%; amount of para-toluenesulfonic acid (as a catalyst), 5.5%; reaction temperature, 95 ~C; and reaction time, 6 h. The AMPS- modified polyacrylic acid superplasticizer prepared under the optimal esterification conditions enabled the achievement and maintenance of high cement dispersibility. At an admixture amount of 0.15%, the cement paste fluidity was initially as high as 300 mm, and then decreased to 315 mm after 1 h and to 290 mm after 2 h.展开更多
A changepoint in statistical applications refers to an observational time point at which the structure pattern changes during a somewhat long-term experimentation process. In many cases, the change point time and caus...A changepoint in statistical applications refers to an observational time point at which the structure pattern changes during a somewhat long-term experimentation process. In many cases, the change point time and cause are documented and it is reasonably straightforward to statistically adjust (homogenize) the series for the effects of the changepoint. Sadly many changepoint times are undocumented and the changepoint times themselves are the main purpose of study. In this article, the changepoint analysis in two-phrase linear regression models is developed and discussed. Following Liu and Qian (2010)'s idea in the segmented linear regression models, the modified empirical likelihood ratio statistic is proposed to test if there exists a changepoint during the long-term experiment and observation. The modified empirical likelihood ratio statistic is computation-friendly and its ρ-value can be easily approximated based on the large sample properties. The procedure is applied to the Old Faithful geyser eruption data in October 1980.展开更多
A modified one-dimensional transient hygrothermal model for multilayer wall was proposed using air humidity ratio and temperature as the driving potentials.The solution for the governing equations was obtained numeric...A modified one-dimensional transient hygrothermal model for multilayer wall was proposed using air humidity ratio and temperature as the driving potentials.The solution for the governing equations was obtained numerically by implementing the finite-difference scheme.To evaluate the accuracy of the model,a test system was built up to measure relative humidity and temperature within a porous wall and compare with the prediction of the model.The prediction results have good agreement with the experimental results.For the interface close to indoor side,the maximum deviation of temperature between calculated and test data is 1.87 K,and the average deviation is 0.95 K;the maximum deviation of relative humidity is 11.4%,and the average deviation is 5.7%.For the interface close to outdoor side,the maximum deviation of temperature between prediction and measurement is 1.78 K,and the average deviation is 1.1 K;the maximum deviation of relative humidity is 9.9%,and the average deviation is 4.2%.展开更多
The WENO method, RKDG method, RKDG method with original ghost fluid method, and RKDG method with modified ghost fluid method are applied to singlemedium and two-medium air-air, air-liquid compressible flows with high ...The WENO method, RKDG method, RKDG method with original ghost fluid method, and RKDG method with modified ghost fluid method are applied to singlemedium and two-medium air-air, air-liquid compressible flows with high density and pressure ratios: We also provide a numerical comparison and analysis for the above methods. Numerical results show that, compared with the other methods, the RKDG method with modified ghost fluid method can obtain high resolution results and the correct position of the shock, and the computed solutions are converged to the physical solutions as themesh is refined.展开更多
Inference for the difference of two independent normal means has been widely studied in staitstical literature. In this paper, we consider the case that the variances are unknown but with a known relationship between ...Inference for the difference of two independent normal means has been widely studied in staitstical literature. In this paper, we consider the case that the variances are unknown but with a known relationship between them. This situation arises frequently in practice, for example, when two instruments report averaged responses of the same object based on a different number of replicates, the ratio of the variances of the response is then known, and is the ratio of the number of replicates going into each response. A likelihood based method is proposed. Simulation results show that the proposed method is very accurate even when the sample sizes are small. Moreover, the proposed method can be extended to the case that the ratio of the variances is unknown.展开更多
A novel technology,modified roasting in CO-CO2 mixed gas and magnetic separation,was presented to recover iron from copper slag.The effects of various parameters such as dosage of flux(CaO),gas flowrate of CO and CO2,...A novel technology,modified roasting in CO-CO2 mixed gas and magnetic separation,was presented to recover iron from copper slag.The effects of various parameters such as dosage of flux(CaO),gas flowrate of CO and CO2,roasting temperature,roasting time,particle size of modified slag and magnetic flux density on the oxidized modification and magnetic separation were investigated by comparison of the X-ray diffraction patterns and iron recovery ratio.The optimum conditions for recovering iron by oxidizing roasting and magnetic separation are as follows:calcium oxide content of 25 wt.%,mixed gas flow rates of CO2 and CO of 180 and 20 mL/min,oxidizing roasting at 1323 K for 2 h,grinding the modified slag to 38.5-25.0μm and magnetic separation at 170 mT.The mineralogical and microstructural characteristics of modified slag revealed that the iron-bearing minerals in the copper slag were oxidized,the generated magnetite grew into large particles,and the silicate in copper slag was combined with calcium oxide to form calcium silicate.Finally,the iron-bearing concentrate with an iron grade of 54.79%and iron recovery ratio of 80.14%was effectively obtained.展开更多
基金Supported by the Major Science and Technology Program for Water Pollution Contro and Treatment-Crucial Technology Research and Engineering Sample Subject on Municipa Wastewater Treatment Process Updated to Higher Drainage Standard(2008ZX07317-02)Wuhan Water Pollution Control and the Water Environment Administer Technology and Synthetic Sample Project in Cities and Towns(2008ZX07317)
文摘A pilot-scale modified carbon source division anaerobic anoxic oxic(AAO) process with pre-concentration of returned activated sludge(RAS) was proposed in this study for the enhanced biological nutrient removal(BNR) of municipal wastewater with limited carbon source. The influent carbon source was fed in step while a novel RAS pre-concentration tank was adopted to improve BNR efficiency, and the effects of an influent carbon source distribution ratio and a RAS pre-concentration ratio were investigated. The results show that the removal efficiency of TN is mainly influenced by the carbon source distribution ratio while the TP removal relies on the RAS pre-concentration ratio. The optimum carbon source distribution ratio and RAS pre-concentration ratio are 60% and 50%, respectively, with an inner recycling ratio of 100% under the optimum steady operation of pilot test, reaching an average effluent TN concentration of 9.8 mg·L-1with a removal efficiency of 63% and an average TP removal efficiency of 94%. The mechanism of nutrient removal is discussed and the kinetics is analyzed. The results reveal that the optimal carbon source distribution ratio provides sufficient denitrifying carbon source to each anoxic phase, reducing nitrate accumulation while the RAS pre-concentration ratio improves the condition of anaerobic zone to ensure the phosphorus release due to less nitrate in the returned sludge. Therefore, nitrifying bacteria, denitrifying bacteria and phosphorus accumulation organisms play an important role under the optimum condition, enhancing the performance of nutrient removal in this test.
基金Project supported by the National Natural Science Foundation of China (No. 40301021).
文摘Sorption characteristics of both an organic pollutant (phenol) and a heavy metal (cadmium ion) on the clay layer of a Lou soil (Eum-orthic Anthrosol in Chinese Soil Taxonomy) along with the sorption mechanism were investigated using three soil treatments: modification with a cationic surfactant cetyltrimethylammonium bromide added at an amount equivalent to 50% and 100% of the soil CEC (50%CB and 100%CB), modification with an amphoteric surface-modifying agent dodecyldimethylbetaine (commercially known as BS-12) added at an amount equivalent to 50% and 100% of the soil CEC (50% BS and 100%BS), and an unmodified control (CK). Results showed that the BS soil treatments increased sorption of both the heavy metal Cd2+ and the organic pollutant phenol. The equilibrium sorption amount of Cd2+ decreased in the order: 50%BS > 100%BS > CK > 50%CB > 100%CB, with the BS soil treatments being about 1.3 to 1.8 times higher and the CB soil treatments about 23% to 41% lower than CK. Both the single-site and two-site Langmuir models could be applied to describe the sorption of Cd2+ in each soil treatment. The equilibrium sorption amount of phenol on the soil samples decreased in the order: 100%CB > 50%CB > 100%BS > 50%BS > CK, with the CB soil treatments being 41.0 to 79.6 times higher and the BS soil treatments 4.0 to 8.3 times higher than CK. The Freundlich equation could also be used to describe the sorption characteristics of phenol. In the BS soil treatments, both an organophobic long carbon chain and hydrophilic charged groups resulted in a relatively strong sorption ability for both heavy metals and organic pollutants. In addition, the sorption ratio K, the ratio of phenol sorption amount of the modified soil to that of CK, increased initially and decreased later with the amount of phenol added, and the critical sorption ratio KC, the peak value of the sorption ratio curve plotted against the added phenol concentration, was a good index for evaluating the sorption ability of phenol in the soil.
文摘Two field experiments were carried out at Akure (7oN, 5o101E) in the rainforest zone of Nigeria in 2006 and 2007 to determine the effectiveness of neem leaf, woodash and modified neem leaf extracts as fertilizer sources in improving soil fertility, growth and yield of maize (Zea mays L) and watermelon (Citrulus lanatus) sole and intercrop. There were six treatments namely, poultry manure, neem leaf extract (sole), woodash extract, modified neem leaf (neem leaf + woodash), NPK 15-15-15 and a control (no fertilizer nor extract), replicated three times and arranged in a randomized complete block design (RCB). The extracts (neem leaf, wood ash and modified neem leaf) were applied at 1200 litres per hectare each, NPK 15-15-15 at 300 kg/ha and poultry was applied at 6t/ha. The results showed that there were significant increases (P 2O), K, Ca, Mg, Na, O.M, P and N compared to NPK 15-15-15 and neem leaf extract. For instance, modified neem leaf extract increased soil pH (H2O), K, Ca, Mg, Na, O.M, P and N by 12.4%, 32.8%, 25%, 23.7%, 19.32%, 17.24% and 20% respectively compared to neem leaf extract under intercrop plot. The high soil K/Ca, K/Mg and P/Mg ratios in the NPK 15-15-15 fertilizer treatment led to an imbalance in the supply of P, K, Ca and Mg nutrients to maize and watermelon crops. The least values for growth, yield and soil parameters were recorded under the control treatment. In these experiments, modified neem leaf extract (woodash + neem leaf extracts) applied at 1200 litres/ha was the most effective in improving soil fertility, growth and yield of maize and watermelon (sole and intercrop) and could substitute for 6 tons per hectare of poultry manure and 300kg/ha of NPK 15-15-15 fertilizer.
基金Funded by the Fujian Education Department(Nos.JA11329,JA12412)the Quanzhou(Fujian)Technology Research and Development Program(No.2010G7)
文摘A macromer, methoxypolyethylene glycol acrylate (MPEGAA), was synthesized by direct esterification using methoxypolyethylene glycol (MPEG-1200) and acrylic acid (AA) as the main materials. MPEGAA was then used to prepare a polyacrylic acid superplasticizer modified with 2-acrylamido-2- methylpropane sulfonic acid (AMPS). A single-factor test was performed to investigate the effects of the molar ratio of acid to alcohol (n(AA)/n(MPEG)), inhibitor amount, catalyst amount, temperature, and time of esterification on the synthesis of MPEGAA. The experimental results showed that the optimal esterification conditions were as follows: n(AA)/n(MPEG), 3.5:1; amount of hydroquinone (as an inhibitor), 1.2%; amount of para-toluenesulfonic acid (as a catalyst), 5.5%; reaction temperature, 95 ~C; and reaction time, 6 h. The AMPS- modified polyacrylic acid superplasticizer prepared under the optimal esterification conditions enabled the achievement and maintenance of high cement dispersibility. At an admixture amount of 0.15%, the cement paste fluidity was initially as high as 300 mm, and then decreased to 315 mm after 1 h and to 290 mm after 2 h.
文摘A changepoint in statistical applications refers to an observational time point at which the structure pattern changes during a somewhat long-term experimentation process. In many cases, the change point time and cause are documented and it is reasonably straightforward to statistically adjust (homogenize) the series for the effects of the changepoint. Sadly many changepoint times are undocumented and the changepoint times themselves are the main purpose of study. In this article, the changepoint analysis in two-phrase linear regression models is developed and discussed. Following Liu and Qian (2010)'s idea in the segmented linear regression models, the modified empirical likelihood ratio statistic is proposed to test if there exists a changepoint during the long-term experiment and observation. The modified empirical likelihood ratio statistic is computation-friendly and its ρ-value can be easily approximated based on the large sample properties. The procedure is applied to the Old Faithful geyser eruption data in October 1980.
基金Project(51078127) supported by the National Natural Science Foundation of ChinaProject(JJ201109091631) supported by the Foundation for Young Scientists of Jiangxi Education Department, China
文摘A modified one-dimensional transient hygrothermal model for multilayer wall was proposed using air humidity ratio and temperature as the driving potentials.The solution for the governing equations was obtained numerically by implementing the finite-difference scheme.To evaluate the accuracy of the model,a test system was built up to measure relative humidity and temperature within a porous wall and compare with the prediction of the model.The prediction results have good agreement with the experimental results.For the interface close to indoor side,the maximum deviation of temperature between calculated and test data is 1.87 K,and the average deviation is 0.95 K;the maximum deviation of relative humidity is 11.4%,and the average deviation is 5.7%.For the interface close to outdoor side,the maximum deviation of temperature between prediction and measurement is 1.78 K,and the average deviation is 1.1 K;the maximum deviation of relative humidity is 9.9%,and the average deviation is 4.2%.
基金the National Natural Science Foundation of China(No.10671120)
文摘The WENO method, RKDG method, RKDG method with original ghost fluid method, and RKDG method with modified ghost fluid method are applied to singlemedium and two-medium air-air, air-liquid compressible flows with high density and pressure ratios: We also provide a numerical comparison and analysis for the above methods. Numerical results show that, compared with the other methods, the RKDG method with modified ghost fluid method can obtain high resolution results and the correct position of the shock, and the computed solutions are converged to the physical solutions as themesh is refined.
文摘Inference for the difference of two independent normal means has been widely studied in staitstical literature. In this paper, we consider the case that the variances are unknown but with a known relationship between them. This situation arises frequently in practice, for example, when two instruments report averaged responses of the same object based on a different number of replicates, the ratio of the variances of the response is then known, and is the ratio of the number of replicates going into each response. A likelihood based method is proposed. Simulation results show that the proposed method is very accurate even when the sample sizes are small. Moreover, the proposed method can be extended to the case that the ratio of the variances is unknown.
基金The authors wish to express thanks to National Natural Science Foundation of China(Grant No.51774154)the Jiangxi Natural Science Foundation(Grant No.20151BAB206029)for the financial support for this research。
文摘A novel technology,modified roasting in CO-CO2 mixed gas and magnetic separation,was presented to recover iron from copper slag.The effects of various parameters such as dosage of flux(CaO),gas flowrate of CO and CO2,roasting temperature,roasting time,particle size of modified slag and magnetic flux density on the oxidized modification and magnetic separation were investigated by comparison of the X-ray diffraction patterns and iron recovery ratio.The optimum conditions for recovering iron by oxidizing roasting and magnetic separation are as follows:calcium oxide content of 25 wt.%,mixed gas flow rates of CO2 and CO of 180 and 20 mL/min,oxidizing roasting at 1323 K for 2 h,grinding the modified slag to 38.5-25.0μm and magnetic separation at 170 mT.The mineralogical and microstructural characteristics of modified slag revealed that the iron-bearing minerals in the copper slag were oxidized,the generated magnetite grew into large particles,and the silicate in copper slag was combined with calcium oxide to form calcium silicate.Finally,the iron-bearing concentrate with an iron grade of 54.79%and iron recovery ratio of 80.14%was effectively obtained.