Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply s...Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply soft decision QPSK modulation based on PCSS system,the correlation of superposition PN sequences is discussed. A weighted summation algorithm is adopted in QPSK demodulation to recover the whole orthogonal correlation of the superposition sequences; meanwhile the bit error rate of weighting soft decision QPSK modulation is simulated. The simulation results show that the bit error rate performance of proposed soft decision QPSK modulation based on PCSS system is better than that of hard decision modulation. The method proposed can be widely adopted in engineering application.展开更多
The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant atten...The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant attenuations of turbulence intensities were measured in the farfields, due to small two-phase slip velocities and particle Reynolds number. The gas-phase turbulence is enhanced by particles in the near-fields, but it is significantly attenuated by the small particles in the far-fields. The smaller particles have a more profound effect on the attenuation of turbulence intensities. The enhancements or attenuations of turbulence intensities in the far-fields depends on the energy production, transport and dissipation mechanisms between the two phases, which are determined by the particle prop- erties and two-phase velocity slips. The non-dimensional parameter CTI is introduced to represent the change of turbulence intensity.展开更多
To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the cl...To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the classification of superimposed modulations dedicated to 5G multipleinput multiple-output(MIMO)two-way cognitive relay network in realistic channels modeled with Nakagami-m distribution.Our purpose consists of classifying pairs of users modulations from superimposed signals.To achieve this goal,we apply the higher-order statistics in conjunction with the Multi-BoostAB classifier.We use several efficiency metrics including the true positive(TP)rate,false positive(FP)rate,precision,recall,F-Measure and receiver operating characteristic(ROC)area in order to evaluate the performance of the proposed algorithm in terms of correct superimposed modulations classification.Computer simulations prove that our proposal allows obtaining a good probability of classification for ten superimposed modulations at a low signal-to-noise ratio,including the worst case(i.e.,m=0.5),where the fading distribution follows a one-sided Gaussian distribution.We also carry out a comparative study between our proposal usingMultiBoostAB classifier with the decision tree(J48)classifier.Simulation results show that the performance of MultiBoostAB on the superimposed modulations classifications outperforms the one of J48 classifier.In addition,we study the impact of the symbols number,path loss exponent and relay position on the performance of the proposed automatic classification superimposed modulations in terms of probability of correct classification.展开更多
The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C7...The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C70 >C80 >C90>C100 >C180. Then we compare fullerenes with carbon nanotubes(CNTs) and graphene sheets(GSs) and find that the increase of the HOMO energy of a fullerene is much faster than that of CNTs and graphene sheets with the same number of C atoms. The rising rate rank is fullerene>CNT>GS, which holds no matter what the number of C atoms is or which structure the fullerene isomer is. This work paves a new path for developing all-carbon devices with low-dimensional carbon nanomaterials as different functional elements.展开更多
To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPT...To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPTMMM) and a novel support vector machine fuzzy network (SVMFN) classifier is presented. The WPTMMM feature extraction method has less computational complexity, more stability, and has the preferable advantage of robust with the time parallel moving and white noise. Further, the SVMFN uses a new definition of fuzzy density that incorporates accuracy and uncertainty of the classifiers to improve recognition reliability to classify nine digital modulation types (i.e. 2ASK, 2FSK, 2PSK, 4ASK, 4FSK, 4PSK, 16QAM, MSK, and OQPSK). Computer simulation shows that the proposed scheme has the advantages of high accuracy and reliability (success rates are over 98% when SNR is not lower than 0dB), and it adapts to engineering applications.展开更多
We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger...We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger than the one outside the barriers. It is shown that the transmission exhibits periodicity with the incident angle below the critical transmission angle, and attenuates exponentially in the opposite situation. For both situations, peak splitting occurs in the transmission as the number of the velocity barriers increases, and the characteristics of the transmission suggest an interesting application of an excellent band-pass filter. The dependence of the conductance on the Fermi energy through an identical velocity- modulation structure differs wildly with different Fermi velocities of the barrier. The counterpart of the peak splitting is the sharp oscillations in the conductance profile. Furthermore, some oscillations for the multiple barriers are so sharp that the structure may be used as an excellent sensor.展开更多
Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well ex...Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well explained in terms of condensations of two-coupled phonon modes with wave vectors of q1=0.62a* on the a*-b* plane and q2 = 0.23a* on the a*-c* plane. The atomic displacements occur along the b-axis direction for q1 and along the c-axis direction for q2, respectively. Moreover, the correlation between ql and q2 can be generally written as q1 = (q2 + a*)/2 in the CDW state, suggesting the presence of essential coupling between q1 and q2. A small fraction of Ir doping on the Pt site in Sr(Pt1-xIrx)2As2 (x ≤ 0.06) could moderately change these CDW modulations and also affect their superconductivities.展开更多
Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism a...Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism and multicolor upconversion properties from green,red to near infrared(NIR) emissions with increasing Yb concentrations.Reversible multiband upconversion modulations are achieved by alternating light(365 and 405 nm) or thermal stimuli.After 365 nm irradiation,the luminescence color changes from yellow to red,the luminescent photoswitching contrast reaches up to 86.21%(green),82.12%(red) and 77.38%(NIR) in the Y_(0.83)Er_(0.01)Tm_(0.01)NbO_(4):0.15 Yb sample.Besides,the upconversion emission intensity before and after photochromic reaction shows remarkable change in a wide temperature range of 298-718 K.These results indicate that the Er^(3+)/Tm^(3+)/Yb^(3+) tri-doped YNbO_(4) materials can be a good candidate in optical switching and data storage applications.展开更多
Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from differen...Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from different blocks of the periodic table.Herein,a“rare earth(Ce)-metalloid(Se)”non-bonding heteronuclear diatomic electrocatalyst has been constructed for ORR by rational coordination and carbon support defect engineering.Encouraging,the optimized Ce-Se diatomic catalysts(Ce-Se DAs/NC)displayed a half-wave potential of 0.886 V vs.reversible hydrogen electrode(RHE)and excellent stability,which surpass those of separate Ce or Se single atoms and most single/dual atomic catalysts ever reported.In addition,a primary zinc-air battery constructed using Ce-Se DAs/NC delivers a higher peak power density(209.2 mW·cm^(−2))and specific capacity(786.4 mAh·gZn^(−1))than state-of-the-art noble metal catalysts Pt/C.Theoretical calculations reveal that the Ce-Se DAs/NC has improved the electroactivity of the Ce-N_(4)region due to the electron transfer towards the nearby Se specific activity(SA)sites.Meanwhile,the more electron-rich Se sites promote the adsorptions of key intermediates,which results in the optimal performances of ORR on Ce-Se DAs/NC.This work provides new perspectives on electronic structure modulations via non-bonded long-range coordination micro-environment engineering in DACs for efficient electrocatalysis.展开更多
Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owi...Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.展开更多
Silicon carbide(SiC) power modules play an essential role in the electric vehicle drive system. To improve their performance, reduce their size, and increase production efficiency, this paper proposes a multiple stake...Silicon carbide(SiC) power modules play an essential role in the electric vehicle drive system. To improve their performance, reduce their size, and increase production efficiency, this paper proposes a multiple staked direct bonded copper(DBC) unit based power module packaging method to parallel more chips. This method utilizes mutual inductance cancellation effect to reduce parasitic inductance. Because the conduction area in the new package is doubled, the overall area of power module can be reduced. Entire power module is divided into smaller units to enhance manufacture yield, and improve design freedom. This paper provides a detailed design, analysis and fabrication procedure for the proposed package structure. Additionally, this paper offers several feasible solutions for the connection between power terminals and DBC untis. With the structure, 18dies were paralleled for each phase-leg in a econodual size power module. Both simulation and double pulse test results demonstrate that, compared to conventional layouts, the proposed package method has 74.8% smaller parasitic inductance and 34.9% lower footprint.展开更多
针对在地面站天线对空间站观测任务中,通常基于卫星工具包(satellite tool kit,STK)软件规划出天线对空间站的方位角和俯仰角,实现天线对空间站的自动跟踪.为了保证天线跟踪的准确性和可靠性,需要定期计算出准确的空间站轨道和天线的方...针对在地面站天线对空间站观测任务中,通常基于卫星工具包(satellite tool kit,STK)软件规划出天线对空间站的方位角和俯仰角,实现天线对空间站的自动跟踪.为了保证天线跟踪的准确性和可靠性,需要定期计算出准确的空间站轨道和天线的方位俯仰角,并更新规划任务.因此科学分析与评估空间站两行轨道根数(two line elements,TLE)长期预报精度,对地面站实现空间站的精准跟踪具有重要意义.本文以中国空间站(China Space Station,CSS)梦天实验舱为例,基于TLE数据,利用STK软件提供的简化常规摄动规模型(simplified general perturbations4,SGP4)模型计算空间站轨道以及空间站相对于西安地面站的方位角和俯仰角,并分析不同策略下的精度效果.试验结果表明:在第二天更新空间站的TLE,可以获得较好的轨道结果,从而更好地保障天线的跟踪精度.展开更多
Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be...Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation effects.However,in practical applications,natural hyperbolic materials need to be deposited on the substrate,and the influence of substrate on modulation effect has not been studied yet.In this work,we investigate the influence of substrate effect on near-field radiative modulator based onα-MoO_(3).The results show that compared to the situation without a substrate,the presence of both lossless and lossy substrate will reduce the modulation contrast(MC)for different film thicknesses.When the real or imaginary component of the substrate permittivity increases,the mismatch of hyperbolic phonon polaritons(HPPs)weakens,resulting in a reduction in MC.By reducing the real and imaginary components of substrate permittivity,the MC can be significantly improved,reaching 4.64 forε_(s)=3 at t=10 nm.This work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect,and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.展开更多
This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID ...This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID scheme, the information bits conveyed by the signal-domain(SiD) symbols and the spatial-domain(SpD) light emitting diode(LED)-index patterns are coded by a protograph low-density parity-check(P-LDPC) code. Specifically, we propose a signal-domain symbol expanding and re-allocating(SSER) method for constructing a type of novel generalized spatial modulation(GSM) constellations, referred to as SSERGSM constellations, so as to boost the performance of the BICGSM-ID MIMO-VLC systems.Moreover, by applying a modified PEXIT(MPEXIT) algorithm, we further design a family of rate-compatible P-LDPC codes, referred to as enhanced accumulate-repeat-accumulate(EARA) codes,which possess both excellent decoding thresholds and linear-minimum-distance-growth property. Both analysis and simulation results illustrate that the proposed SSERGSM constellations and P-LDPC codes can remarkably improve the convergence and decoding performance of MIMO-VLC systems. Therefore, the proposed P-LDPC-coded SSERGSM-mapped BICGSMID configuration is envisioned as a promising transmission solution to satisfy the high-throughput requirement of MIMO-VLC applications.展开更多
Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufac...Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.展开更多
Is it better to be safe than sorry?This Hamletic dilemma has always stimulated medical-scientific debates in numerous fields of biomedicine.And among these,the preventive-therapeutic approach to the treatment of brain...Is it better to be safe than sorry?This Hamletic dilemma has always stimulated medical-scientific debates in numerous fields of biomedicine.And among these,the preventive-therapeutic approach to the treatment of brain trauma is one of the most striking examples.Traumatic brain injury(TBI)is a leading cause of brain damage among young and elderly populations with a very high hospitalization and death rate.TBI is characterized by two pathologically distinct but strictly consequential phases:a first characterized by an immediate and highly variable mechanical dysfunction of the brain tissue,which involves widespread cell death and tissue degeneration,followed by a second phase which can last from days to even years depending on the severity of the TBI and the patient’s pre-existing health status.Secondary processes,including inflammatory phenomena,oxidative stress associated with metabolic,vascular,and neuro-modulatory deficits,are very often responsible for neuro-motor and psychological deficits leading to long-term disabilities(Kaur and Sharma,2018).展开更多
Nonreciprocity of thermal metamaterials has significant application prospects in isolation protection,unidirectional transmission,and energy harvesting.However,due to the inherent isotropic diffusion law of heat flow,...Nonreciprocity of thermal metamaterials has significant application prospects in isolation protection,unidirectional transmission,and energy harvesting.However,due to the inherent isotropic diffusion law of heat flow,it is extremely difficult to achieve nonreciprocity of heat transfer.This review presents the recent developments in thermal nonreciprocity and explores the fundamental theories,which underpin the design of nonreciprocal thermal metamaterials,i.e.,the Onsager reciprocity theorem.Next,three methods for achieving nonreciprocal metamaterials in the thermal field are elucidated,namely,nonlinearity,spatiotemporal modulation,and angular momentum bias,and the applications of nonreciprocal thermal metamaterials are outlined.We also discuss nonreciprocal thermal radiation.Moreover,the potential applications of nonreciprocity to other Laplacian physical fields are discussed.Finally,the prospects for advancing nonreciprocal thermal metamaterials are highlighted,including developments in device design and manufacturing techniques and machine learning-assisted material design.展开更多
Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to...Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to provide reversible and fast color changes under applied voltage.With the rapid development and increasing demand for flexible electronics,flexible electrochromic devices(FECDs)that offer smarter and more controllable light modulation hold great promise for practical applications.The electrochromic material(ECM)undergoing color changes during the electrochemical reactions is one of the key components in electrochromic devices.Among the ECMs,viologens,a family of organic small molecules with 1,1'-disubstituted-4,4'-dipyridinium salts,have garnered extensive research interest,due to their well-reversible redox reactions,excellent electron acceptance ability,and the ability to produce multiple colors.Notably,viologen-based FECDs demonstrate color changes in the liquid or semisolid electrolyte layer,eliminating the need for two solid electrodes and thus simplifying the device structure.Consequently,viologens offer significant potential for the development of FECDs with high optical contrast,fast response speed,and excellent stability.This review aims to provide a comprehensive overview of the progress and perspectives of viologen-based FECDs.It begins by summarizing the typical structure and recent exciting developments in viologen-based FECDs,along with their advantages and disadvantages.Furthermore,the review discusses recent advancements in FECDs with additional functionalities such as sensing,photochromism,and energy storage.Finally,the remaining challenges and potential research directions for the future of viologen-based FECDs are addressed.展开更多
Nano-optics is an emergent research field in physics that appeared in the 1980s,which deals with light–matter optical interactions at the nanometer scale.In early studies of nano-optics,the main concern focus is to o...Nano-optics is an emergent research field in physics that appeared in the 1980s,which deals with light–matter optical interactions at the nanometer scale.In early studies of nano-optics,the main concern focus is to obtain higher optical resolution over the diffraction limit.The researches of near-field imaging and spectroscopy based on scanning near-field optical microscopy(SNOM)are developed.The exploration of improving SNOM probe for near-field detection leads to the emergence of surface plasmons.In the sense of resolution and wider application,there has been a significant transition from seeking higher resolution microscopy to plasmonic near-field modulations in the nano-optics community during the nano-optic development.Nowadays,studies of nano-optics prefer the investigation of plasmonics in different material systems.In this article,the history of the development of near-field optics is briefly reviewed.The difficulties of conventional SNOM to achieve higher resolution are discussed.As an alternative solution,surface plasmons have shown the advantages of higher resolution,wider application,and flexible nano-optical modulation for new devices.The typical studies in different periods are introduced and characteristics of nano-optics in each stage are analyzed.In this way,the evolution progress from near-field optics to plasmonics of nano-optics research is presented.The future development of nano-optics is discussed then.展开更多
基金Sponsored by the National Natural Science Foundation of China(Grant No.61271263)
文摘Recently,soft decision modulations become the highlight of parallel combinatory spread spectrum ( PCSS) system. Existing soft decision BPSK and APK modulations are given and compared in the thesis. In order to apply soft decision QPSK modulation based on PCSS system,the correlation of superposition PN sequences is discussed. A weighted summation algorithm is adopted in QPSK demodulation to recover the whole orthogonal correlation of the superposition sequences; meanwhile the bit error rate of weighting soft decision QPSK modulation is simulated. The simulation results show that the bit error rate performance of proposed soft decision QPSK modulation based on PCSS system is better than that of hard decision modulation. The method proposed can be widely adopted in engineering application.
基金supported by the National Natural Science Foundation of China (50876053 and 50706021).
文摘The particle modulations to turbulence in round jets were experimentally studied by means of two-phase velocity measurements with Phase Doppler Anemometer (PDA). Laden with very large particles, no significant attenuations of turbulence intensities were measured in the farfields, due to small two-phase slip velocities and particle Reynolds number. The gas-phase turbulence is enhanced by particles in the near-fields, but it is significantly attenuated by the small particles in the far-fields. The smaller particles have a more profound effect on the attenuation of turbulence intensities. The enhancements or attenuations of turbulence intensities in the far-fields depends on the energy production, transport and dissipation mechanisms between the two phases, which are determined by the particle prop- erties and two-phase velocity slips. The non-dimensional parameter CTI is introduced to represent the change of turbulence intensity.
文摘To promote reliable and secure communications in the cognitive radio network,the automatic modulation classification algorithms have been mainly proposed to estimate a single modulation.In this paper,we address the classification of superimposed modulations dedicated to 5G multipleinput multiple-output(MIMO)two-way cognitive relay network in realistic channels modeled with Nakagami-m distribution.Our purpose consists of classifying pairs of users modulations from superimposed signals.To achieve this goal,we apply the higher-order statistics in conjunction with the Multi-BoostAB classifier.We use several efficiency metrics including the true positive(TP)rate,false positive(FP)rate,precision,recall,F-Measure and receiver operating characteristic(ROC)area in order to evaluate the performance of the proposed algorithm in terms of correct superimposed modulations classification.Computer simulations prove that our proposal allows obtaining a good probability of classification for ten superimposed modulations at a low signal-to-noise ratio,including the worst case(i.e.,m=0.5),where the fading distribution follows a one-sided Gaussian distribution.We also carry out a comparative study between our proposal usingMultiBoostAB classifier with the decision tree(J48)classifier.Simulation results show that the performance of MultiBoostAB on the superimposed modulations classifications outperforms the one of J48 classifier.In addition,we study the impact of the symbols number,path loss exponent and relay position on the performance of the proposed automatic classification superimposed modulations in terms of probability of correct classification.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11374174,51390471,51527803,and 51701143the National Basic Research Program of China under Grant No 2015CB654902+4 种基金the National Key Research and Development Program under Grant No 2016YFB0700402the Foundation for the Author of National Excellent Doctoral Dissertation under Grant No 201141the National Program for Thousand Young Talents of China,the Tianjin Municipal Education Commissionthe Tianjin Municipal Science and Technology Commissionthe Fundamental Research Fund of Tianjin University of Technology
文摘The highest occupied molecular orbital(HOMO) energies of fullerenes are found by quantitative first-principles calculations to be raised by negative charging, and the rising rate rank of the fullerenes is C60 >C70 >C80 >C90>C100 >C180. Then we compare fullerenes with carbon nanotubes(CNTs) and graphene sheets(GSs) and find that the increase of the HOMO energy of a fullerene is much faster than that of CNTs and graphene sheets with the same number of C atoms. The rising rate rank is fullerene>CNT>GS, which holds no matter what the number of C atoms is or which structure the fullerene isomer is. This work paves a new path for developing all-carbon devices with low-dimensional carbon nanomaterials as different functional elements.
文摘To make the modulation classification system more suitable for signals in a wide range of signal to noise rate (SNR), a feature extraction method based on signal wavelet packet transform modulus maxima matrix (WPTMMM) and a novel support vector machine fuzzy network (SVMFN) classifier is presented. The WPTMMM feature extraction method has less computational complexity, more stability, and has the preferable advantage of robust with the time parallel moving and white noise. Further, the SVMFN uses a new definition of fuzzy density that incorporates accuracy and uncertainty of the classifiers to improve recognition reliability to classify nine digital modulation types (i.e. 2ASK, 2FSK, 2PSK, 4ASK, 4FSK, 4PSK, 16QAM, MSK, and OQPSK). Computer simulation shows that the proposed scheme has the advantages of high accuracy and reliability (success rates are over 98% when SNR is not lower than 0dB), and it adapts to engineering applications.
基金Project supported by the National Natural Science Foundation of China (Grant No. 11104156)the Postdoctoral Science Foundation of China (CPSF) (Grant No. 2012M510405)+1 种基金the Independent Research and Development Fund of Tsinghua University (Grant No. 20121087948)Beijing Key Laboratory of Fine Ceramics Opening Fund (Grant No. 2012200110)
文摘We compare the transport properties of electrons in monolayer graphene by modulating the Fermi velocity inside the barrier. A critical transmission angle is found only when the Fermi velocity in the barriers is larger than the one outside the barriers. It is shown that the transmission exhibits periodicity with the incident angle below the critical transmission angle, and attenuates exponentially in the opposite situation. For both situations, peak splitting occurs in the transmission as the number of the velocity barriers increases, and the characteristics of the transmission suggest an interesting application of an excellent band-pass filter. The dependence of the conductance on the Fermi energy through an identical velocity- modulation structure differs wildly with different Fermi velocities of the barrier. The counterpart of the peak splitting is the sharp oscillations in the conductance profile. Furthermore, some oscillations for the multiple barriers are so sharp that the structure may be used as an excellent sensor.
基金Project supported by the National Basic Research Program of China(Grant Nos.2011CBA00101,2010CB923002,2012CB821404,and 2011CB921703)the National Natural Science Foundation of China(Grant Nos.11190022,11274368,and 51272277)the Funds from the Chinese Academy of Sciences
文摘Transmission electron microscopy (TEM) study of SrPt2As2 reveals two incommensurate modulations appearing in the charge-density-wave (CDW) state below TCDW ≈ 470 K. These two structural modulations can be well explained in terms of condensations of two-coupled phonon modes with wave vectors of q1=0.62a* on the a*-b* plane and q2 = 0.23a* on the a*-c* plane. The atomic displacements occur along the b-axis direction for q1 and along the c-axis direction for q2, respectively. Moreover, the correlation between ql and q2 can be generally written as q1 = (q2 + a*)/2 in the CDW state, suggesting the presence of essential coupling between q1 and q2. A small fraction of Ir doping on the Pt site in Sr(Pt1-xIrx)2As2 (x ≤ 0.06) could moderately change these CDW modulations and also affect their superconductivities.
基金Project supported by the National Natural Science Foundation of China(52062042,51802164)the Natural Science Foundation of Inner Mongolia(2020MS05044)。
文摘Photochromic materials with multicolor upconversion reversible modulations are attractive in optical switching devices.Herein,the fabricated YNbO_(4):Er^(3+)/Tm^(3+)/Yb^(3+) materials exhibit excellent photochromism and multicolor upconversion properties from green,red to near infrared(NIR) emissions with increasing Yb concentrations.Reversible multiband upconversion modulations are achieved by alternating light(365 and 405 nm) or thermal stimuli.After 365 nm irradiation,the luminescence color changes from yellow to red,the luminescent photoswitching contrast reaches up to 86.21%(green),82.12%(red) and 77.38%(NIR) in the Y_(0.83)Er_(0.01)Tm_(0.01)NbO_(4):0.15 Yb sample.Besides,the upconversion emission intensity before and after photochromic reaction shows remarkable change in a wide temperature range of 298-718 K.These results indicate that the Er^(3+)/Tm^(3+)/Yb^(3+) tri-doped YNbO_(4) materials can be a good candidate in optical switching and data storage applications.
基金the support from the National Key R&D Program of China(No.2021YFA1501101)the National Natural Science Foundation of China(No.21971117)+12 种基金the National Natural Science Foundation of China/Research Grant Council of Hong Kong Joint Research Scheme(No.N_PolyU502/21)the National Natural Science Foundation of China/Research Grants Council(RGC)of Hong Kong Collaborative Research Scheme(No.CRS_PolyU504/22)the Functional Research Funds for the Central Nankai University(No.63186005)the Tianjin Key Lab for Rare Earth Materials and Applications(No.ZB19500202)the Open Funds(No.RERU2019001)the State Key Laboratory of Rare Earth Resource Utilization,the 111 Project(No.B18030)from Chinathe Beijing-Tianjin-Hebei Collaborative Innovation Project(No.19YFSLQY00030)the Outstanding Youth Project of Tianjin 21 Natural Science Foundation(No.20JCJQJC00130)the Key Project of Tianjin Natural Science Foundation(No.20JCZDJC00650)the funding for Projects of Strategic Importance of The Hong Kong Polytechnic University(Project Code:1-ZE2V)the Shenzhen Fundamental Research Scheme-General Program(No.JCYJ20220531090807017)the Natural Science Foundation of Guangdong Province(No.2023A1515012219)the Departmental General Research Fund(Project Code:ZVUL)from The Hong Kong Polytechnic University.
文摘Currently,dual atomic catalysts(DACs)with neighboring active sites for oxygen reduction reaction(ORR)still meet lots of challenges in the synthesis,especially the construction of atomic pairs of elements from different blocks of the periodic table.Herein,a“rare earth(Ce)-metalloid(Se)”non-bonding heteronuclear diatomic electrocatalyst has been constructed for ORR by rational coordination and carbon support defect engineering.Encouraging,the optimized Ce-Se diatomic catalysts(Ce-Se DAs/NC)displayed a half-wave potential of 0.886 V vs.reversible hydrogen electrode(RHE)and excellent stability,which surpass those of separate Ce or Se single atoms and most single/dual atomic catalysts ever reported.In addition,a primary zinc-air battery constructed using Ce-Se DAs/NC delivers a higher peak power density(209.2 mW·cm^(−2))and specific capacity(786.4 mAh·gZn^(−1))than state-of-the-art noble metal catalysts Pt/C.Theoretical calculations reveal that the Ce-Se DAs/NC has improved the electroactivity of the Ce-N_(4)region due to the electron transfer towards the nearby Se specific activity(SA)sites.Meanwhile,the more electron-rich Se sites promote the adsorptions of key intermediates,which results in the optimal performances of ORR on Ce-Se DAs/NC.This work provides new perspectives on electronic structure modulations via non-bonded long-range coordination micro-environment engineering in DACs for efficient electrocatalysis.
基金The authors acknowledge the micro-fabrication center of National Laboratory of Solid State Microstructures(NLSSM)for technique supportProf.Jia Zhu acknowledges the support from the XPLORER PRIZE+3 种基金This work is jointly supported by the National Key Research and Development Program of China(No.2021YFA140070)the National Natural Science Foundation of China(Nos.61735008,51925204,12022403)Excellent Research Program of Nanjing University(ZYJH005)Carbon Peaking and Carbon Neutrality Science and Technology Innovation Fund of Jiangsu Province(BK20220035).
文摘Two-dimensional(2D)materials have attracted considerable research interest,leading to significant advances in energy applications in recent years,such as lithium batteries,catalysis,electronics,and thermoelectrics,owing to their rich controllable properties and excellent performances.Recently,pressure has been successfully employed as an effective method for property modulation of 2D materials,through tuning electronic orbitals and bonding patterns.In this review,we summarize recent progresses in the pressure-driven property modulations and elucidate the underlying mechanism of the pressure modulation of 2D materials.Further,we identify the remaining challenges and opportunities in this new,vibrant area of research for energy conversion and utilization.Among the different property modulation strategies,the in situ application of high pressure is systematically identified as a promising knob for 2D materials.This review is expected to inspire further research on the fundamental understanding and practical applications of high-pressure modulation in 2D materials.
基金supported in part by National Key R&D Program of China (2021YFB2500600)CAS Youth multi-discipline project (JCTD-2021-09)Strategic Piority Research Program of Chinese Academy of Sciences (XDA28040100)。
文摘Silicon carbide(SiC) power modules play an essential role in the electric vehicle drive system. To improve their performance, reduce their size, and increase production efficiency, this paper proposes a multiple staked direct bonded copper(DBC) unit based power module packaging method to parallel more chips. This method utilizes mutual inductance cancellation effect to reduce parasitic inductance. Because the conduction area in the new package is doubled, the overall area of power module can be reduced. Entire power module is divided into smaller units to enhance manufacture yield, and improve design freedom. This paper provides a detailed design, analysis and fabrication procedure for the proposed package structure. Additionally, this paper offers several feasible solutions for the connection between power terminals and DBC untis. With the structure, 18dies were paralleled for each phase-leg in a econodual size power module. Both simulation and double pulse test results demonstrate that, compared to conventional layouts, the proposed package method has 74.8% smaller parasitic inductance and 34.9% lower footprint.
文摘针对在地面站天线对空间站观测任务中,通常基于卫星工具包(satellite tool kit,STK)软件规划出天线对空间站的方位角和俯仰角,实现天线对空间站的自动跟踪.为了保证天线跟踪的准确性和可靠性,需要定期计算出准确的空间站轨道和天线的方位俯仰角,并更新规划任务.因此科学分析与评估空间站两行轨道根数(two line elements,TLE)长期预报精度,对地面站实现空间站的精准跟踪具有重要意义.本文以中国空间站(China Space Station,CSS)梦天实验舱为例,基于TLE数据,利用STK软件提供的简化常规摄动规模型(simplified general perturbations4,SGP4)模型计算空间站轨道以及空间站相对于西安地面站的方位角和俯仰角,并分析不同策略下的精度效果.试验结果表明:在第二天更新空间站的TLE,可以获得较好的轨道结果,从而更好地保障天线的跟踪精度.
基金Project supported by the National Natural Science Foundation of China (Grant No.52106099)the Natural Science Foundation of Shandong Province of China (Grant No.ZR2022YQ57)the Taishan Scholars Program。
文摘Relative rotation between the emitter and receiver could effectively modulate the near-field radiative heat transfer(NFRHT)in anisotropic media.Due to the strong in-plane anisotropy,natural hyperbolic materials can be used to construct near-field radiative modulators with excellent modulation effects.However,in practical applications,natural hyperbolic materials need to be deposited on the substrate,and the influence of substrate on modulation effect has not been studied yet.In this work,we investigate the influence of substrate effect on near-field radiative modulator based onα-MoO_(3).The results show that compared to the situation without a substrate,the presence of both lossless and lossy substrate will reduce the modulation contrast(MC)for different film thicknesses.When the real or imaginary component of the substrate permittivity increases,the mismatch of hyperbolic phonon polaritons(HPPs)weakens,resulting in a reduction in MC.By reducing the real and imaginary components of substrate permittivity,the MC can be significantly improved,reaching 4.64 forε_(s)=3 at t=10 nm.This work indicates that choosing a substrate with a smaller permittivity helps to achieve a better modulation effect,and provides guidance for the application of natural hyperbolic materials in the near-field radiative modulator.
基金supported in part by the NSF of China under Grant 62322106,62071131the Guangdong Basic and Applied Basic Research Foundation under Grant 2022B1515020086+2 种基金the International Collaborative Research Program of Guangdong Science and Technology Department under Grant 2022A0505050070in part by the Open Research Fund of the State Key Laboratory of Integrated Services Networks under Grant ISN22-23the National Research Foundation,Singapore University of Technology Design under its Future Communications Research&Development Programme“Advanced Error Control Coding for 6G URLLC and mMTC”Grant No.FCP-NTU-RG-2022-020.
文摘This paper investigates the bit-interleaved coded generalized spatial modulation(BICGSM) with iterative decoding(BICGSM-ID) for multiple-input multiple-output(MIMO) visible light communications(VLC). In the BICGSM-ID scheme, the information bits conveyed by the signal-domain(SiD) symbols and the spatial-domain(SpD) light emitting diode(LED)-index patterns are coded by a protograph low-density parity-check(P-LDPC) code. Specifically, we propose a signal-domain symbol expanding and re-allocating(SSER) method for constructing a type of novel generalized spatial modulation(GSM) constellations, referred to as SSERGSM constellations, so as to boost the performance of the BICGSM-ID MIMO-VLC systems.Moreover, by applying a modified PEXIT(MPEXIT) algorithm, we further design a family of rate-compatible P-LDPC codes, referred to as enhanced accumulate-repeat-accumulate(EARA) codes,which possess both excellent decoding thresholds and linear-minimum-distance-growth property. Both analysis and simulation results illustrate that the proposed SSERGSM constellations and P-LDPC codes can remarkably improve the convergence and decoding performance of MIMO-VLC systems. Therefore, the proposed P-LDPC-coded SSERGSM-mapped BICGSMID configuration is envisioned as a promising transmission solution to satisfy the high-throughput requirement of MIMO-VLC applications.
基金supported by the National Natural Science Foundation of China(U1930117,12204445)。
文摘Active control of terahertz(THz)waves is attracting tremendous attentions in terahertz communications and active photonic devices.Perovskite,due to its excellent photoelectric conversion performance and simple manufacturing process,has emerged as a promising candidate for optoelectronic applications.However,the exploration of perovskites in optically controlled THz modulators is still limited.In this work,the photoelectric properties and carrier dynamics of FA_(0.4)MA_(0.6)PbI_(3)perovskite films were investigated by optical pumped terahertz probe(OPTP)system.The ultrafast carrier dynamics reveal that FA_(0.4)MA_(0.6)PbI_(3)thin film exhibits rapid switching and relaxation time within picosecond level,suggesting that FA_(0.4)MA_(0.6)PbI_(3)is an ideal candidate for active THz devices with ultrafast response.Furthermore,as a proof of concept,a FA_(0.4)MA_(0.6)PbI_(3)-based metadevice with integrating plasma-induced transparency(PIT)effect was fabricated to achieve ultrafast modulation of THz wave.The experimental results demonstrated that the switching time of FA_(0.4)MA_(0.6)PbI_(3)-based THz modulator is near to 3.5 ps,and the threshold of optical pump is as low as 12.7μJ cm^(-2).The simulation results attribute the mechanism of ultrafast THz modulation to photo-induced free carriers in the FA_(0.4)MA_(0.6)PbI_(3)layer,which progressively shorten the capacitive gap of PIT resonator.This study not only illuminates the potential of FA_(0.4)MA_(0.6)PbI_(3)in THz modulation,but also contributes to the field of ultrafast photonic devices.
文摘Is it better to be safe than sorry?This Hamletic dilemma has always stimulated medical-scientific debates in numerous fields of biomedicine.And among these,the preventive-therapeutic approach to the treatment of brain trauma is one of the most striking examples.Traumatic brain injury(TBI)is a leading cause of brain damage among young and elderly populations with a very high hospitalization and death rate.TBI is characterized by two pathologically distinct but strictly consequential phases:a first characterized by an immediate and highly variable mechanical dysfunction of the brain tissue,which involves widespread cell death and tissue degeneration,followed by a second phase which can last from days to even years depending on the severity of the TBI and the patient’s pre-existing health status.Secondary processes,including inflammatory phenomena,oxidative stress associated with metabolic,vascular,and neuro-modulatory deficits,are very often responsible for neuro-motor and psychological deficits leading to long-term disabilities(Kaur and Sharma,2018).
基金the National Natural Science Foundation of China(No.52325208)the Fundamental Research Funds for the Central Universities(No.06500174)National Key Research and Development Program of China(No.2022YFB3807401)。
文摘Nonreciprocity of thermal metamaterials has significant application prospects in isolation protection,unidirectional transmission,and energy harvesting.However,due to the inherent isotropic diffusion law of heat flow,it is extremely difficult to achieve nonreciprocity of heat transfer.This review presents the recent developments in thermal nonreciprocity and explores the fundamental theories,which underpin the design of nonreciprocal thermal metamaterials,i.e.,the Onsager reciprocity theorem.Next,three methods for achieving nonreciprocal metamaterials in the thermal field are elucidated,namely,nonlinearity,spatiotemporal modulation,and angular momentum bias,and the applications of nonreciprocal thermal metamaterials are outlined.We also discuss nonreciprocal thermal radiation.Moreover,the potential applications of nonreciprocity to other Laplacian physical fields are discussed.Finally,the prospects for advancing nonreciprocal thermal metamaterials are highlighted,including developments in device design and manufacturing techniques and machine learning-assisted material design.
基金financial support from the National Natural Science Foundation of China(22105106)the Natural Science Foundation of Jiangsu Province of China(BK20210603)+1 种基金the Nanjing Science and Technology Innovation Project for overseas Students(NJKCZYZZ2022–05)the Start-up Funding from NUPTSF(NY221003)。
文摘Electrochromic technology has gained significant attention in various fields such as displays,smart windows,biomedical monitoring,military camouflage,human-machine interaction,and electronic skin due to its ability to provide reversible and fast color changes under applied voltage.With the rapid development and increasing demand for flexible electronics,flexible electrochromic devices(FECDs)that offer smarter and more controllable light modulation hold great promise for practical applications.The electrochromic material(ECM)undergoing color changes during the electrochemical reactions is one of the key components in electrochromic devices.Among the ECMs,viologens,a family of organic small molecules with 1,1'-disubstituted-4,4'-dipyridinium salts,have garnered extensive research interest,due to their well-reversible redox reactions,excellent electron acceptance ability,and the ability to produce multiple colors.Notably,viologen-based FECDs demonstrate color changes in the liquid or semisolid electrolyte layer,eliminating the need for two solid electrodes and thus simplifying the device structure.Consequently,viologens offer significant potential for the development of FECDs with high optical contrast,fast response speed,and excellent stability.This review aims to provide a comprehensive overview of the progress and perspectives of viologen-based FECDs.It begins by summarizing the typical structure and recent exciting developments in viologen-based FECDs,along with their advantages and disadvantages.Furthermore,the review discusses recent advancements in FECDs with additional functionalities such as sensing,photochromism,and energy storage.Finally,the remaining challenges and potential research directions for the future of viologen-based FECDs are addressed.
文摘Nano-optics is an emergent research field in physics that appeared in the 1980s,which deals with light–matter optical interactions at the nanometer scale.In early studies of nano-optics,the main concern focus is to obtain higher optical resolution over the diffraction limit.The researches of near-field imaging and spectroscopy based on scanning near-field optical microscopy(SNOM)are developed.The exploration of improving SNOM probe for near-field detection leads to the emergence of surface plasmons.In the sense of resolution and wider application,there has been a significant transition from seeking higher resolution microscopy to plasmonic near-field modulations in the nano-optics community during the nano-optic development.Nowadays,studies of nano-optics prefer the investigation of plasmonics in different material systems.In this article,the history of the development of near-field optics is briefly reviewed.The difficulties of conventional SNOM to achieve higher resolution are discussed.As an alternative solution,surface plasmons have shown the advantages of higher resolution,wider application,and flexible nano-optical modulation for new devices.The typical studies in different periods are introduced and characteristics of nano-optics in each stage are analyzed.In this way,the evolution progress from near-field optics to plasmonics of nano-optics research is presented.The future development of nano-optics is discussed then.