A new lignanoside, （7R,8S）-7,8-dihydro-7-（4-hydroxy-3,5-dimethoxyphenyl）-1＇-formyl-3＇-y-methoxyl-8-hydroxymethylbenzo- furan-4-O-β-D-glucopyranoside （moellenoside A）, was isolated from Selaginella moellendorf...A new lignanoside, （7R,8S）-7,8-dihydro-7-（4-hydroxy-3,5-dimethoxyphenyl）-1＇-formyl-3＇-y-methoxyl-8-hydroxymethylbenzo- furan-4-O-β-D-glucopyranoside （moellenoside A）, was isolated from Selaginella moellendorffii Hieron. Its structure was determined by spectroscopic evidences. 2007 Wei Sheng Feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.展开更多
Two new neolignans selaginellol(1)and selaginellol 4'-O-β-D-glucopyranoside(2),together with seven known compounds(3–9),were isolated from the whole plant of Selaginella moellendorffii.The structures of the new ...Two new neolignans selaginellol(1)and selaginellol 4'-O-β-D-glucopyranoside(2),together with seven known compounds(3–9),were isolated from the whole plant of Selaginella moellendorffii.The structures of the new isolates were determined through spectroscopic data analysis.Compounds 1–9,as well as compounds 10–18 previously isolated from the species,were measured for the activity against platelet aggregation induced by ADP or collagen.Three neoligans(8,11,and 12),one flavanone(14),and one alkaloid(16)showed inhibitory activity against ADP-or collagen-induced platelet aggregation as compared with tirofiban.The dihydrobenzofuran neolignans(8,11,and 12)are more potent than the benzofuran neolignan(13)and other types of neolignans(1–7).Glucosidation of the dihydrobenzofuran neolignans(11 and 12)is helpful for the activity.Graphical Abstract Two new neolignans selaginellol(1)and selaginellol 40-O-b-D-glucopyranoside(2)were isolated from the whole plant of Selaginella moellendorffii.Several compounds from this plant showed the activity against platelet aggregation induced by ADP or collagen.展开更多
作者对窄膜棘豆 (OxytropismoellendorffiiBunge)的分类学处理提出了新的观点 :通过对原产地标本、资料的研究 ,认为五台山棘豆 (O .wutaiensisTatewakietHurusawa )实际上是窄膜棘豆 (O .moellendorffiiBunge) ,对其变种 (O .wu taiens...作者对窄膜棘豆 (OxytropismoellendorffiiBunge)的分类学处理提出了新的观点 :通过对原产地标本、资料的研究 ,认为五台山棘豆 (O .wutaiensisTatewakietHurusawa )实际上是窄膜棘豆 (O .moellendorffiiBunge) ,对其变种 (O .wu taiensisTatewakietHurusawavar.glabrataTatewakietHurusawa )也进行了归并 ;另外本文中发表一个新等级———西灵山棘豆 (O .moellendorffiiBungevar.sylin chanensis (Franch .)G .Z .Qian)。展开更多
Taking annual Heracl'eum moellendorffii Hance as the material,this research studied the epidemic dynamics of H.moellendorffii Hance powdery mildew and plant growth by using the interactive methods of soil moisture...Taking annual Heracl'eum moellendorffii Hance as the material,this research studied the epidemic dynamics of H.moellendorffii Hance powdery mildew and plant growth by using the interactive methods of soil moisture and soil organic matter.The results showed that the interaction of higher soil moisture content(60%-80%)and soil organic matter content(75-100 g•kg^(-1))had few diseases,dosease index and area under disease progression curve(AUDPC)compared with those of other treatments,thus could effectivley control powdery mildew disease.Moreover,higher soil moisture and organic matter content increased the yield,contents of soluble sugar,soluble protein,vitamin C and coumarin in H.moellendorffii Hance.展开更多
[Objectives]This study was conducted to investigate the quality standard of Heracleum moellendorffii Hance.,so as to provide data support for the 2003 version of Quality Standards for Chinese Medicinal Materials and E...[Objectives]This study was conducted to investigate the quality standard of Heracleum moellendorffii Hance.,so as to provide data support for the 2003 version of Quality Standards for Chinese Medicinal Materials and Ethnic Medicinal Materials in Guizhou Province.[Methods]H.moellendorffii was subjected to character identification and microscopic identification.Referring to Chinese Pharmacopoeia,TCL thin-layer identification and extract determination were carried out on 10 batches of H.moellendorffii from 6 habitats in Guizhou.[Results]The characters and microscopic characteristics of H.moellendorffii were described in detail.The TLC thin-layer identification spots were clear,with strong specificity.The limit of the medicinal material extract was determined to be not less than 22.0%.[Conclusions]This study can provide data support for the quality evaluation and standard improvement of the medicinal material H.moellendorffii.展开更多
为深入探索老山芹种子休眠机理,以老山芹层积前后种子为研究对象,采用气相色谱-飞行时间质谱联用技术(gas chromatography-time of flight mass spectrometry,GC-TOF/MS)对其非层积种子(non-lamellarized seeds,NS)和层积后达到发芽状...为深入探索老山芹种子休眠机理,以老山芹层积前后种子为研究对象,采用气相色谱-飞行时间质谱联用技术(gas chromatography-time of flight mass spectrometry,GC-TOF/MS)对其非层积种子(non-lamellarized seeds,NS)和层积后达到发芽状态种子(germination seeds,GS)的差异代谢物进行分析。结果表明,共检测到995种代谢产物,NS和GS的代谢物存在明显分离,差异代谢物有126种,其中极显著差异代谢物75种,包括35种上调,40种下调。对极显著差异代谢物所在代谢通路分析表明,涉及10条关键代谢通路。和弦图分析表明,差异代谢物中脂质类化合物(含类脂分子)与苯类化合物呈极显著正相关;苯丙烷类化合物(含聚酮类化合物)与有机氧类化合物呈极显著负相关。以上研究结果为探索老山芹种子成熟后萌发提供了代谢组学理论基础,为更好地研究老山芹种子后成熟及休眠机制提供了依据和支撑。展开更多
This study reports an investigation into the chemical constituents of the whole plant of Selaginella moellendorffii Hieron.Ten compounds,isolated and purified by column chromatography,were identified on the basis of s...This study reports an investigation into the chemical constituents of the whole plant of Selaginella moellendorffii Hieron.Ten compounds,isolated and purified by column chromatography,were identified on the basis of spectral analysis and their physicochemical properties to be:(8R)-3,5-dimethoxy-4-hydroxyphenylpropylalcohol-8-(1-acetyl-3-methoxy-4-hydroxyphenyl)-9-O-b-D-glucopyranoside(moellenoside B)(1),amentoflavone(2),hinokiflavone(3),apigenin-7-O-bneohesperidoside(4),apigenin-8-C-b-D-glucopyranoside(5),adenosine(6),uridine(7),2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylic acid(8),vanillic acid(9),and lariciresinol(10).Compound 1 is a new norlignan lignanoside and compounds 4–10 were isolated from this plant for the first time.展开更多
文摘A new lignanoside, （7R,8S）-7,8-dihydro-7-（4-hydroxy-3,5-dimethoxyphenyl）-1＇-formyl-3＇-y-methoxyl-8-hydroxymethylbenzo- furan-4-O-β-D-glucopyranoside （moellenoside A）, was isolated from Selaginella moellendorffii Hieron. Its structure was determined by spectroscopic evidences. 2007 Wei Sheng Feng. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
基金This work was funded by the Ministry of Science&Technology of China(2012FY110300)the National Natural Science Foundation of China(3116140345)the Minzu University of China(YLDX01013,2015MDTD16C).
文摘Two new neolignans selaginellol(1)and selaginellol 4'-O-β-D-glucopyranoside(2),together with seven known compounds(3–9),were isolated from the whole plant of Selaginella moellendorffii.The structures of the new isolates were determined through spectroscopic data analysis.Compounds 1–9,as well as compounds 10–18 previously isolated from the species,were measured for the activity against platelet aggregation induced by ADP or collagen.Three neoligans(8,11,and 12),one flavanone(14),and one alkaloid(16)showed inhibitory activity against ADP-or collagen-induced platelet aggregation as compared with tirofiban.The dihydrobenzofuran neolignans(8,11,and 12)are more potent than the benzofuran neolignan(13)and other types of neolignans(1–7).Glucosidation of the dihydrobenzofuran neolignans(11 and 12)is helpful for the activity.Graphical Abstract Two new neolignans selaginellol(1)and selaginellol 40-O-b-D-glucopyranoside(2)were isolated from the whole plant of Selaginella moellendorffii.Several compounds from this plant showed the activity against platelet aggregation induced by ADP or collagen.
基金Supported by the National Key Research and Development Program of China(2016YFC0500307-06)。
文摘Taking annual Heracl'eum moellendorffii Hance as the material,this research studied the epidemic dynamics of H.moellendorffii Hance powdery mildew and plant growth by using the interactive methods of soil moisture and soil organic matter.The results showed that the interaction of higher soil moisture content(60%-80%)and soil organic matter content(75-100 g•kg^(-1))had few diseases,dosease index and area under disease progression curve(AUDPC)compared with those of other treatments,thus could effectivley control powdery mildew disease.Moreover,higher soil moisture and organic matter content increased the yield,contents of soluble sugar,soluble protein,vitamin C and coumarin in H.moellendorffii Hance.
基金Science and Technology Innovation Platform Construction Project of Anshun City(ASKP[2017]03).
文摘[Objectives]This study was conducted to investigate the quality standard of Heracleum moellendorffii Hance.,so as to provide data support for the 2003 version of Quality Standards for Chinese Medicinal Materials and Ethnic Medicinal Materials in Guizhou Province.[Methods]H.moellendorffii was subjected to character identification and microscopic identification.Referring to Chinese Pharmacopoeia,TCL thin-layer identification and extract determination were carried out on 10 batches of H.moellendorffii from 6 habitats in Guizhou.[Results]The characters and microscopic characteristics of H.moellendorffii were described in detail.The TLC thin-layer identification spots were clear,with strong specificity.The limit of the medicinal material extract was determined to be not less than 22.0%.[Conclusions]This study can provide data support for the quality evaluation and standard improvement of the medicinal material H.moellendorffii.
文摘为深入探索老山芹种子休眠机理,以老山芹层积前后种子为研究对象,采用气相色谱-飞行时间质谱联用技术(gas chromatography-time of flight mass spectrometry,GC-TOF/MS)对其非层积种子(non-lamellarized seeds,NS)和层积后达到发芽状态种子(germination seeds,GS)的差异代谢物进行分析。结果表明,共检测到995种代谢产物,NS和GS的代谢物存在明显分离,差异代谢物有126种,其中极显著差异代谢物75种,包括35种上调,40种下调。对极显著差异代谢物所在代谢通路分析表明,涉及10条关键代谢通路。和弦图分析表明,差异代谢物中脂质类化合物(含类脂分子)与苯类化合物呈极显著正相关;苯丙烷类化合物(含聚酮类化合物)与有机氧类化合物呈极显著负相关。以上研究结果为探索老山芹种子成熟后萌发提供了代谢组学理论基础,为更好地研究老山芹种子后成熟及休眠机制提供了依据和支撑。
基金supported by the National Natural Science Foundation of China(81073034)National Key Technologies R&D Program of China(2009ZX09103-440)Major Public Research Project of Henan Province(081100910800)。
文摘This study reports an investigation into the chemical constituents of the whole plant of Selaginella moellendorffii Hieron.Ten compounds,isolated and purified by column chromatography,were identified on the basis of spectral analysis and their physicochemical properties to be:(8R)-3,5-dimethoxy-4-hydroxyphenylpropylalcohol-8-(1-acetyl-3-methoxy-4-hydroxyphenyl)-9-O-b-D-glucopyranoside(moellenoside B)(1),amentoflavone(2),hinokiflavone(3),apigenin-7-O-bneohesperidoside(4),apigenin-8-C-b-D-glucopyranoside(5),adenosine(6),uridine(7),2,3,4,9-tetrahydro-1H-pyrido[3,4-b]indole-3-carboxylic acid(8),vanillic acid(9),and lariciresinol(10).Compound 1 is a new norlignan lignanoside and compounds 4–10 were isolated from this plant for the first time.
