Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been i...Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work.展开更多
Molar tooth structure （MTS） represented by complex ptygmatical shapes is widely distributed in the Proterozoic of the world. MTS filled by fine, equant sparry calcite （or dolomite） displays an abrupt contact with ...Molar tooth structure （MTS） represented by complex ptygmatical shapes is widely distributed in the Proterozoic of the world. MTS filled by fine, equant sparry calcite （or dolomite） displays an abrupt contact with hosting rocks, which are mainly composed of carbonaceous micrites and fine-grained carbonates with local silts and stormdominated deposits with graded, cross or wave beddings, numerous erosional surfaces and truncated and fills or guttered bases. Occurrence of MTS suggests a result of the constraint of sedimentary facies, and the storm-base in ramp settings is the maximum depth for the formation of MTS. Vertical succession of MTS-bearing carbonates shows a deposition stacked by high-frequency shallow subtidal and peritidal cycles. An individual cyclic MTS-bearing sequence is characterized by thinning, shallowing and dynamic decreasing-upward, and peritidal caps of purple red iron and organic carbonaceous sediments with more complicated shapes of MTS are common on the top of individual MTS-bearing sequences.展开更多
Both the macroscopic feature and the sequence-stratigraphic position of the molar-tooth structure developed in the third member of the Gaoyuzhuang （高于庄） Formation at the Jixian （蓟县） Section in Tianjin （天津...Both the macroscopic feature and the sequence-stratigraphic position of the molar-tooth structure developed in the third member of the Gaoyuzhuang （高于庄） Formation at the Jixian （蓟县） Section in Tianjin （天津） can provide some useful information about its origin and can reveal some problems to be further researched in the future. The Mesoproterozoic Gaoyuzhuang Formation is a set of 1 600 m thick carbonate strata. This formation can be divided into four members. The first member is mainly made up of stromatolitic dolomites; the second is marked by a set of manganese dolomites; the third is mainly composed of lamina limestones with the development of molar-tooth strcutures; the fourth is a set of stromatolitic-lithoherm dolomites. According to lithofacies and its succession, several types of meter-scale cycles can be discerned in the Gaoyuzhuang Formation： the L-M type, the subtidal type and the peritidal type. There is a regularly vertical stacking pattern for meter-scale cycles in the third-order sequence. Therefore, the Mesoproterozoic Gaoyuzhuang Formation can be divided into 13 third-order sequences （SQ1 to SQ13 ） and can further be grouped into 4 second-order sequences. The third member is marked by lamina limestones and can be grouped into three third-order sequences （SQ9 to SQ11 ）. The molar-tooth structure is developed in the middle part of the third sequence, i.e. SQH , in the third member. Several features of this kind of molar-tooth structure reflect some features of carbonate sedimentation in the Precambrian, such as the particular configuration, abundant organic matter, and easy silication. Stromatolites are chiefly formed in a shallow tidal-flat environment; lamina are mainly formed in the shallow ramp and molar-tooth structures are mainly generated in a relatively more deep-water environment from the middle to the deep ramp. Therefore, similar to stromatolite and lamina, the molartooth structure might also be a kind of bio-sedimentation structure. This suggestion is based on macroscopic observation and the sedimentary-facies analysis of the molar-tooth structures from the sequencestratigraphic position. These features of Precambrian sedimentation also reveal the problem of Precambrian carbonate sedimentation. With more detailed study, a more practical solution for these problems may be obtained in the future.展开更多
Although its origin has not yet reached a consensus so far, MTS （Molar-Tooth Structure） has been documented for more than 100 years. Current study reports a discovery of MTS from the Mesoproterozoic Wumishan Formati...Although its origin has not yet reached a consensus so far, MTS （Molar-Tooth Structure） has been documented for more than 100 years. Current study reports a discovery of MTS from the Mesoproterozoic Wumishan Formation, Lingyuan, Yanshan Region, North China, and the features and geological implications of MTS are further discussed. Here, straitigraphic horizons of MTS＇s occurrences show that it was mainly located within the top part of the Wumishan Formation, i.e., limestone unit. Four kinds of morphology of MTS, i.e., fine fusiform, debris, ribbon, ptigmatic and nodular （irregular）, were recognized and thought to be highly related to the sedimentary environments and facies. Geochemistry of MTS including oxides, trace elements and C, O and Sr isotopes indicates that the horizons of MTS-bearing is of higher Sr/Ba and Ca/Mg ratios, lower positive ~13C and highly negative 3180 values than the adjacent stratigraphic levels of rare MTS. Lithology, morphology and geochemistry of MTS in the Wumishan Formation suggest that MTS occurs mainly in shallow subtidal near the storm wave base, which is typically characterized by warm temperature, oversaturated calcium carbonate seawater and high organic productivity. Furthermore, occasional enrichment of algae bacteria here is more favorable for the calcification of calcium oozes and catalytic for MTS. C isotope composition of the Wumishan Formation and MTS of this study is well correlated with that of the Mesoproterozoic Belt Supergroup, North America and Riphean, Siberia, suggesting that MTS acts as a sedimentary record responding to global changes and is a perfect indicator in Precambrian stratigraphic correlation worldwide.展开更多
Along with the progress in research on the Precambrian, Molar-tooth carbonates (simplified as MT, or microsparite carbonates or MT structure) which were formed in the Middle-Late Proterozoic have become a hot subject ...Along with the progress in research on the Precambrian, Molar-tooth carbonates (simplified as MT, or microsparite carbonates or MT structure) which were formed in the Middle-Late Proterozoic have become a hot subject recently. The Proterozoic Molar-tooth (MT) carbonate rocks refer to those Meso- to Neoproterozoic (1600-650 Ma) carbonates with MT structure, i.e., a series of peculiar, ptygmatically folded and spar-filled cracks in fine-grained carbonates of Precambrian age, located in the environment of mid- to inner ramp and shallow platform. MTS, like a bridge connecting the inorganic world with the organic one, are closely related to the evolution of paleo-oceans, atmosphere and biosphere. Their development and/or recession are/is related to the origin of life and the abruption of sedimentary geochemistry events of marine carbonates. By using modern instruments and testing methods adequately, the contents of oxides in sandstones were measured and the REE distribution pattern curves were established; an accurate value of isotopic ratio of 87Sr/86Sr was obtained, that is, the age of MT formation is about 750-900 Ma; C and O isotopes of some fresh micrite limestone samples were analyzed; the energy spectrum analysis revealed that the MT consists mainly of microspar calcite, while as for its chemical composition, the matrix shows outstanding peaks of Ca, Mg, Al, Si, and K. The geochemical indicators proved that Neoproterozoic MT carbonates in the Jilin-Liaoning region were developed at the margin of a stable continent, in the torrid zone where the paleo-temperature was about 50℃, the seawater had normal salinity when MT was formed during the Wanlong period in southern Jilin and during the Yingchengzi and Xingmincun periods in eastern Liaoning. The sedimentary environment was located in the inner ramp. In summary, it is of great importance to understand the origin of MT, ascertain the paleo-climate and paleo-environment characteristics, constrain the age and the stratigraphic division and comparison of the Proterozoic so as to study the geochemical characteristics of MT carbonates and their formation environment.展开更多
文摘Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work.
文摘Molar tooth structure （MTS） represented by complex ptygmatical shapes is widely distributed in the Proterozoic of the world. MTS filled by fine, equant sparry calcite （or dolomite） displays an abrupt contact with hosting rocks, which are mainly composed of carbonaceous micrites and fine-grained carbonates with local silts and stormdominated deposits with graded, cross or wave beddings, numerous erosional surfaces and truncated and fills or guttered bases. Occurrence of MTS suggests a result of the constraint of sedimentary facies, and the storm-base in ramp settings is the maximum depth for the formation of MTS. Vertical succession of MTS-bearing carbonates shows a deposition stacked by high-frequency shallow subtidal and peritidal cycles. An individual cyclic MTS-bearing sequence is characterized by thinning, shallowing and dynamic decreasing-upward, and peritidal caps of purple red iron and organic carbonaceous sediments with more complicated shapes of MTS are common on the top of individual MTS-bearing sequences.
基金This paper is financially supported by the National Natural Science Foundation of China (Nos .49802012 ,40472065) .
文摘Both the macroscopic feature and the sequence-stratigraphic position of the molar-tooth structure developed in the third member of the Gaoyuzhuang （高于庄） Formation at the Jixian （蓟县） Section in Tianjin （天津） can provide some useful information about its origin and can reveal some problems to be further researched in the future. The Mesoproterozoic Gaoyuzhuang Formation is a set of 1 600 m thick carbonate strata. This formation can be divided into four members. The first member is mainly made up of stromatolitic dolomites; the second is marked by a set of manganese dolomites; the third is mainly composed of lamina limestones with the development of molar-tooth strcutures; the fourth is a set of stromatolitic-lithoherm dolomites. According to lithofacies and its succession, several types of meter-scale cycles can be discerned in the Gaoyuzhuang Formation： the L-M type, the subtidal type and the peritidal type. There is a regularly vertical stacking pattern for meter-scale cycles in the third-order sequence. Therefore, the Mesoproterozoic Gaoyuzhuang Formation can be divided into 13 third-order sequences （SQ1 to SQ13 ） and can further be grouped into 4 second-order sequences. The third member is marked by lamina limestones and can be grouped into three third-order sequences （SQ9 to SQ11 ）. The molar-tooth structure is developed in the middle part of the third sequence, i.e. SQH , in the third member. Several features of this kind of molar-tooth structure reflect some features of carbonate sedimentation in the Precambrian, such as the particular configuration, abundant organic matter, and easy silication. Stromatolites are chiefly formed in a shallow tidal-flat environment; lamina are mainly formed in the shallow ramp and molar-tooth structures are mainly generated in a relatively more deep-water environment from the middle to the deep ramp. Therefore, similar to stromatolite and lamina, the molartooth structure might also be a kind of bio-sedimentation structure. This suggestion is based on macroscopic observation and the sedimentary-facies analysis of the molar-tooth structures from the sequencestratigraphic position. These features of Precambrian sedimentation also reveal the problem of Precambrian carbonate sedimentation. With more detailed study, a more practical solution for these problems may be obtained in the future.
基金supported by the National Natural Science Foundation(No.40772078)the marineoil and gases exploration progress project of SINOPIC'Petroleum Geology Research and Oil Potential Prospect of the Precambrian stratigraphy of the North China Platform(No.GB0800-06-ZS-350)Foundation of Geology Institute of CAGS(No.J0903,No.J1106)
文摘Although its origin has not yet reached a consensus so far, MTS （Molar-Tooth Structure） has been documented for more than 100 years. Current study reports a discovery of MTS from the Mesoproterozoic Wumishan Formation, Lingyuan, Yanshan Region, North China, and the features and geological implications of MTS are further discussed. Here, straitigraphic horizons of MTS＇s occurrences show that it was mainly located within the top part of the Wumishan Formation, i.e., limestone unit. Four kinds of morphology of MTS, i.e., fine fusiform, debris, ribbon, ptigmatic and nodular （irregular）, were recognized and thought to be highly related to the sedimentary environments and facies. Geochemistry of MTS including oxides, trace elements and C, O and Sr isotopes indicates that the horizons of MTS-bearing is of higher Sr/Ba and Ca/Mg ratios, lower positive ~13C and highly negative 3180 values than the adjacent stratigraphic levels of rare MTS. Lithology, morphology and geochemistry of MTS in the Wumishan Formation suggest that MTS occurs mainly in shallow subtidal near the storm wave base, which is typically characterized by warm temperature, oversaturated calcium carbonate seawater and high organic productivity. Furthermore, occasional enrichment of algae bacteria here is more favorable for the calcification of calcium oozes and catalytic for MTS. C isotope composition of the Wumishan Formation and MTS of this study is well correlated with that of the Mesoproterozoic Belt Supergroup, North America and Riphean, Siberia, suggesting that MTS acts as a sedimentary record responding to global changes and is a perfect indicator in Precambrian stratigraphic correlation worldwide.
基金This Project was funded by the International Geological Comparative Program 447 （IGCP447） （No. SC/GE0/546/447）；the National Natural Science Foundation of China （Grant No. 40172043）；the Natural Science Developmental Fund of the Yangtze University.
文摘Along with the progress in research on the Precambrian, Molar-tooth carbonates (simplified as MT, or microsparite carbonates or MT structure) which were formed in the Middle-Late Proterozoic have become a hot subject recently. The Proterozoic Molar-tooth (MT) carbonate rocks refer to those Meso- to Neoproterozoic (1600-650 Ma) carbonates with MT structure, i.e., a series of peculiar, ptygmatically folded and spar-filled cracks in fine-grained carbonates of Precambrian age, located in the environment of mid- to inner ramp and shallow platform. MTS, like a bridge connecting the inorganic world with the organic one, are closely related to the evolution of paleo-oceans, atmosphere and biosphere. Their development and/or recession are/is related to the origin of life and the abruption of sedimentary geochemistry events of marine carbonates. By using modern instruments and testing methods adequately, the contents of oxides in sandstones were measured and the REE distribution pattern curves were established; an accurate value of isotopic ratio of 87Sr/86Sr was obtained, that is, the age of MT formation is about 750-900 Ma; C and O isotopes of some fresh micrite limestone samples were analyzed; the energy spectrum analysis revealed that the MT consists mainly of microspar calcite, while as for its chemical composition, the matrix shows outstanding peaks of Ca, Mg, Al, Si, and K. The geochemical indicators proved that Neoproterozoic MT carbonates in the Jilin-Liaoning region were developed at the margin of a stable continent, in the torrid zone where the paleo-temperature was about 50℃, the seawater had normal salinity when MT was formed during the Wanlong period in southern Jilin and during the Yingchengzi and Xingmincun periods in eastern Liaoning. The sedimentary environment was located in the inner ramp. In summary, it is of great importance to understand the origin of MT, ascertain the paleo-climate and paleo-environment characteristics, constrain the age and the stratigraphic division and comparison of the Proterozoic so as to study the geochemical characteristics of MT carbonates and their formation environment.
