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Molar-tooth Carbonate Sequences and Sr Isotopes in the Neoproterozoic for Stratigraphic Correlation: Research in the Jilin-Liaoning-Xuzhou-Huaiyang Area of the Sino-Korean Plate and Its Correlation with the Yangtze Plate 被引量:12
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作者 MENGXianghua GEMing +4 位作者 LIUYanxue KUANGHongwei LIUWeifu FrancoiseG.BOURROUILH-LEJAN RobertBOURROUILH 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2004年第3期775-783,共9页
Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been i... Based on a study of Neoproterozoic carbonates in the Jilin-Liaoning-Xuzhou-Huaiyang area, especially its cyclic sequence stratigraphy and Sr isotopes, two maximum sea flooding events (at 820 Ma and 835 Ma) have been identified. The resulting isochronous stratigraphic correlation proves that these Precambrian strata were connected between the Qingbaikou and the Nanhuan systems with a time range from 750 Ma to 850 Ma. The disappearance of microsparite carbonate and coming of a glacial stage offer important evidence for worldwide stratigraphic correlation and open a window for further correlation of the stratigraphic successions across the Sino-Korean and Yangtze Plates. A new correlation scheme is therefore provided based on our work. 展开更多
关键词 microspar (molar-tooth) carbonates PROTEROZOIC sequence Sr isotopes genetic strata
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Effect of drying-wetting cycles on pore characteristics and mechanical properties of enzyme-induced carbonate precipitation-reinforced sea sand 被引量:3
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作者 Ming Huang Kai Xu +2 位作者 Zijian Liu Chaoshui Xu Mingjuan Cui 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第1期291-302,共12页
Enzyme-induced carbonate precipitation(EICP)is an emanating,eco-friendly and potentially sound technique that has presented promise in various geotechnical applications.However,the durability and microscopic character... Enzyme-induced carbonate precipitation(EICP)is an emanating,eco-friendly and potentially sound technique that has presented promise in various geotechnical applications.However,the durability and microscopic characteristics of EICP-treated specimens against the impact of drying-wetting(D-W)cycles is under-explored yet.This study investigates the evolution of mechanical behavior and pore charac-teristics of EICP-treated sea sand subjected to D-W cycles.The uniaxial compressive strength(UCS)tests,synchrotron radiation micro-computed tomography(micro-CT),and three-dimensional(3D)recon-struction of CT images were performed to study the multiscale evolution characteristics of EICP-reinforced sea sand under the effect of D-W cycles.The potential correlations between microstructure characteristics and macro-mechanical property deterioration were investigated using gray relational analysis(GRA).Results showed that the UCS of EICP-treated specimens decreases by 63.7% after 15 D-W cycles.The proportion of mesopores gradually decreases whereas the proportion of macropores in-creases due to the exfoliated calcium carbonate with increasing number of D-W cycles.The micro-structure in EICP-reinforced sea sand was gradually disintegrated,resulting in increasing pore size and development of pore shape from ellipsoidal to columnar and branched.The gray relational degree suggested that the weight loss rate and UCS deterioration were attributed to the development of branched pores with a size of 100-1000 m m under the action of D-W cycles.Overall,the results in this study provide a useful guidancee for the long-term stability and evolution characteristics of EICP-reinforced sea sand under D-W weathering conditions. 展开更多
关键词 Enzyme-induced carbonate precipitation(EICP) Plant-based urease Drying-wetting(D-W)cycles Microstructure
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Impact of effective stress on permeability for carbonate fractured-vuggy rocks 被引量:1
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作者 Ke Sun Huiqing Liu +5 位作者 Juliana Y.Leung Jing Wang Yabin Feng Renjie Liu Zhijiang Kang Yun Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第3期942-960,共19页
To gain insight into the flow mechanisms and stress sensitivity for fractured-vuggy reservoirs,several core models with different structural characteristics were designed and fabricated to investigate the impact of ef... To gain insight into the flow mechanisms and stress sensitivity for fractured-vuggy reservoirs,several core models with different structural characteristics were designed and fabricated to investigate the impact of effective stress on permeability for carbonate fractured-vuggy rocks(CFVR).It shows that the permeability performance curves under different pore and confining pressures(i.e.altered stress conditions)for the fractured core models and the vuggy core models have similar change patterns.The ranges of permeability variation are significantly wider at high pore pressures,indicating that permeability reduction is the most significant during the early stage of development for fractured-vuggy reservoirs.Since each obtained effective stress coefficient for permeability(ESCP)varies with the changes in confining pressure and pore pressure,the effective stresses for permeability of four representative CFVR show obvious nonlinear characteristics,and the variation ranges of ESCP are all between 0 and 1.Meanwhile,a comprehensive ESCP mathematical model considering triple media,including matrix pores,fractures,and dissolved vugs,was proposed.It is proved theoretically that the ESCP of CFVR generally varies between 0 and 1.Additionally,the regression results showed that the power model ranked highest among the four empirical models mainly applied in stress sensitivity characterization,followed by the logarithmic model,exponential model,and binomial model.The concept of“permeability decline rate”was introduced to better evaluate the stress sensitivity performance for CFVR,in which the one-fracture rock is the strongest,followed by the fracture-vug rock and two-horizontalfracture rock;the through-hole rock is the weakest.In general,this study provides a theoretical basis to guide the design of development and adjustment programs for carbonate fractured-vuggy reservoirs. 展开更多
关键词 Effective stress PERMEABILITY carbonate fractured-vuggy rocks Structure characteristics Stress sensitivity
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Hydrocarbon accumulation and orderly distribution of whole petroleum system in marine carbonate rocks of Sichuan Basin,SW China 被引量:1
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作者 GUO Xusheng HUANG Renchun +3 位作者 ZHANG Dianwei LI Shuangjian SHEN Baojian LIU Tianjia 《Petroleum Exploration and Development》 SCIE 2024年第4期852-869,共18页
Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbo... Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbon accumulation elements,especially the source rock.The hydrocarbon accumulation characteristics of each whole petroleum system are analyzed,the patterns of integrated conventional and unconventional hydrocarbon accumulation are summarized,and the favorable exploration targets are proposed.Under the control of multiple extensional-convergent tectonic cycles,the marine carbonate rocks of the Sichuan Basin contain three sets of regional source rocks and three sets of regional cap rocks,and can be divided into the Cambrian,Silurian and Permian whole petroleum systems.These whole petroleum systems present mainly independent hydrocarbon accumulation,containing natural gas of affinity individually.Locally,large fault zones run through multiple whole petroleum systems,forming a fault-controlled complex whole petroleum system.The hydrocarbon accumulation sequence of continental shelf facies shale gas accumulation,marginal platform facies-controlled gas reservoirs,and intra-platform fault-and facies-controlled gas reservoirs is common in the whole petroleum system,with a stereoscopic accumulation and orderly distribution pattern.High-quality source rock is fundamental to the formation of large gas fields,and natural gas in a whole petroleum system is generally enriched near and within the source rocks.The development and maintenance of large-scale reservoirs are essential for natural gas enrichment,multiple sources,oil and gas transformation,and dynamic adjustment are the characteristics of marine petroleum accumulation,and good preservation conditions are critical to natural gas accumulation.Large-scale marginal-platform reef-bank facies zones,deep shale gas,and large-scale lithological complexes related to source-connected faults are future marine hydrocarbon exploration targets in the Sichuan Basin. 展开更多
关键词 Sichuan Basin margin oil/gas whole petroleum system carbonate hydrocarbon accumulation hydrocarbon distribution law hydrocarbon exploration target
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The Response of Carbonate System to Watershed Urbanization Process in a Semi-Arid River
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作者 LI Yunxiao DANG Jiajia +5 位作者 HUANG Xiao YANG Hong WANG Xiao LI Lina BAI Jie CHEN Xi 《Journal of Ocean University of China》 SCIE CAS CSCD 2024年第4期991-1002,共12页
Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the wa... Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the water chemistry and the controls of carbonate system in an urbanized river(the Fenhe River)on the semi-arid Loess Plateau were analyzed.The water chemistry of the river water showed that the high dissolved inorganic carbon(DIC)concentration(about 37 mg L^(-1))in the upstream with a karst land type was mainly sourced from carbonate weathering involved by H_(2)CO_(3) and H_(2)SO_(4),resulting in an oversaturated partial pressure of CO_(2)(pCO_(2))(about 800μatm).In comparison,damming resulted in the widespread appearance of non-free flowing river segments,and aquatic photosynthesis dominated the DIC and pCO_(2) spatiality demonstrated by the enriched stable isotope of DIC(δ^(13)CDIC).Especially in the mid-downstream flowing through major cities in warm and low-runoff August,some river segments even acted as an atmospheric CO_(2) sink.The noteworthy is wastewater input leading to a sudden increase in DIC(>55 mg L^(-1))and pCO_(2)(>4500μatm)in the downstream of Taiyuan City,and in cold November the increased DIC even extended to the outlet of the river.Our results highlight the effects of aquatic production induced by damming and urban sewage input on riverine CO_(2) system in semi-arid areas,and reducing sewage discharge may mitigate CO_(2) emission from the rivers. 展开更多
关键词 dissolved inorganic carbon stable carbon isotope carbonate weathering aquatic photosynthesis sewage input the Fenhe River
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Mechanical Property and Microstructure of Cement Mortar with Carbonated Recycled Powder
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作者 丁亚红 张美香 +3 位作者 YANG Xiaolin XU Ping SUN Bo GUO Shuqi 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第3期689-697,共9页
Carbonated recycled powder as cementitious auxiliary material can reduce carbon emissions and realize high-quality recycling of recycled concrete.In this paper,microscopic property of recycled powder with three carbon... Carbonated recycled powder as cementitious auxiliary material can reduce carbon emissions and realize high-quality recycling of recycled concrete.In this paper,microscopic property of recycled powder with three carbonation methods was tested through XRD and SEM,the mechanical property and microstructure of recycled powder mortar with three replacement rates were studied by ISO method and SEM,and the strengthening mechanism was analyzed.The results showed that the mechanical property of recycled powder mortar decreased with the increasing of replacement rate.It is suggested that the replacement rate of recycled powder should not exceed 20%.The strength index and activity index of carbonated recycled powder mortar were improved,in which the flexural strength was increased by 27.85%and compressive strength was increased by 20%at the maximum.Recycled powder can be quickly and completely carbonated,and the improvement effect of CH pre-soaking carbonation was the best.The activity index of carbonated recycled powder can meet the requirements of Grade II technical standard for recycled powder.Microscopic results revealed the activation mechanism of carbonated recycled powder such as surplus calcium source effect,alkaline polycondensation effect and carbonation enhancement effect. 展开更多
关键词 recycled powder carbonation activation compound carbonation activity index mechanical property MICROSTRUCTURE
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Carbonation of Dicalcium Silicate Enhanced by Ammonia Bicarbonate and Its Mechanism
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作者 周浩 刘鹏 +1 位作者 WANG Fazhou HU Chuanlin 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第1期69-74,共6页
The strength development law of γ-type dicalcium silicate (γ-C_(2)S) under different carbonation processes was investigated,and the carbonation mechanism of γ-C_(2)S under the action of NH_(4)HCO_(3) was clarified ... The strength development law of γ-type dicalcium silicate (γ-C_(2)S) under different carbonation processes was investigated,and the carbonation mechanism of γ-C_(2)S under the action of NH_(4)HCO_(3) was clarified by using a wide range of test methods,including XRD and SEM.A method of saturated NH_(4)HCO_(3) solution as a curing agent was identified to improve the carbonation efficiency and enhance the carbonation degree of γ-C_(2)S,and then a high-strength carbonated specimen was obtained.Microhardness analysis and SEM morphology analysis were conducted on the carbonised specimens obtained under atmospheric pressure carbonisation conditions using the curing agent.It was found that γ-C_(2)S could perform carbonisation well under atmospheric pressure,which promoted the carbonisation efficiency and decreased the carbonisation cost simultaneously.Therefore,a new carbonisation process solution was proposed for the rapid carbonisation of γ-C_(2)S. 展开更多
关键词 type dicalcium silicate carbonization process curing agent atmospheric carbonization
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Catalytically altering the redox pathway of sulfur in propylene carbonate electrolyte using dual-nitrogen/oxygen-containing carbon
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作者 Linghui Yu Heng Zhang +9 位作者 Luyuan Paul Wang Samuel Jun Hoong Ong Shibo Xi Bo Chen Rui Guo Ting Wang Yonghua Du Wei Chen Ovadia Lev Zhichuan J.Xu 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第8期224-233,共10页
Carbonate electrolytes are one of the most desirable electrolytes for high-energy lithium-sulfur batteries(LSBs)because of their successful implementation in commercial Li-ion batteries.The low-polysulfide-solubility ... Carbonate electrolytes are one of the most desirable electrolytes for high-energy lithium-sulfur batteries(LSBs)because of their successful implementation in commercial Li-ion batteries.The low-polysulfide-solubility feature of some carbonate solvents also makes them very promising for overcoming the shuttle effects of LSBs.However,regular sulfur electrodes experience undesired electrochemical mechanisms in carbonate electrolytes due to side reactions.In this study,we report a catalytic redox mechanism of sulfur in propylene carbonate(PC)electrolyte based on a compari-son study.The catalytic mechanism is characterized by the interactions between polysulfides and dual N/O functional groups on the host carbon,which largely prevents side reactions between polysulfides and the carbonate electrolyte.Such a mechanism coupled with the low-polysulfide-solubility feature leads to stable cycling of LSBs in PC electrolyte.Favorable dual N/O functional groups are identified via a density functional theory study.This work provides an alternative route for enabling LSBs in carbonate electrolytes. 展开更多
关键词 Energy storage Lithium-sulfur battery Catalytic redox reaction Porous carbon carbonate electrolyte
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Highly dispersed MgInCe-mixed metal oxides catalyzed direct carbonylation of glycerol and CO_(2)into glycerol carbonate
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作者 Xufang Chen Xin Shu +5 位作者 Yanru Zhu Jian Zhang Zhigang Chai Hongyan Song Zhe An Jing He 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第8期153-163,共11页
Glycerol carbonate,an important glycerol value-added product,has been widely used as an active intermediate and inert solvent in the synthesis of cosmetics,detergents,chemical intermediates,polymers,and so on.The dire... Glycerol carbonate,an important glycerol value-added product,has been widely used as an active intermediate and inert solvent in the synthesis of cosmetics,detergents,chemical intermediates,polymers,and so on.The direct carbonylation from glycerol with CO_(2)is considered a promising route,but still tough work due to the thermodynamic stability and the kinetic inertness of CO_(2).In this work,highlyselective direct carbonylation of glycerol and CO_(2)into glycerol carbonate has been achieved over highly dispersed MgInCe-mixed metal oxides(MgInCe-MMO),which were prepared through the topological transformation derived from the MgInCe-layered double hydroxides(MgInCe-LDHs).By precisely modulating the surface basic-acidic properties and the oxygen vacancies,an efficient carbonylation of glycerol with CO_(2)has been achieved with a selectivity of up to>99%to glycerol carbonate.Deep investigation into the synergistic catalysis of base-acid sites and oxygen vacancies has been clarified. 展开更多
关键词 Catalytic reaction engineering Glycerol carbonate Direct carbonylation from glycerol carbon dioxide Mixed metal oxides Synergistic catalysis
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A general descriptor for guiding the electrolysis of CO_(2)in molten carbonate
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作者 Zhengshan Yang Bowen Deng +2 位作者 Kaifa Du Huayi Yin Dihua Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第4期748-757,共10页
Molten carbonate is an excellent electrolyte for the electrochemical reduction of CO_(2)to carbonaceous materials.However,the electrolyte–electrode-reaction relationship has not been well understood.Herein,we propose... Molten carbonate is an excellent electrolyte for the electrochemical reduction of CO_(2)to carbonaceous materials.However,the electrolyte–electrode-reaction relationship has not been well understood.Herein,we propose a general descriptor,the CO_(2)activity,to reveal the electrolyte–electrode-reaction relationship by thermodynamic calculations and experimental studies.Experimental studies agree well with theoretical predictions that both cations(Li^(+),Ca^(2+),Sr^(2+)and Ba^(2+))and anions(BO_(2)^(-),Ti_(5)O_(14)^(8-),SiO_(3)^(2-))can modulate the CO_(2)activity to control both cathode and anode reactions in a typical molten carbonate electrolyzer in terms of tuning reaction products and overpotentials.In this regard,the reduction of CO_(3)^(2-)can be interpreted as the direct reduction of CO_(2)generated from the dissociated CO_(3)^(2-),and the CO_(2)activity can be used as a general descriptor to predict the electrode reaction in molten carbonate.Overall,the CO_(2)activity descriptor unlocks the electrolyte–electrode-reaction relationship,thereby providing fundamental insights into guiding molten carbonate CO_(2)electrolysis. 展开更多
关键词 Molten carbonate CO_(2)activity CO_(2)RR Electrolyte engineering carbon
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Preparation of high-purity fluorite and nanoscale calcium carbonate from low-grade fluorite
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作者 Qianqian Lu Haisheng Han +5 位作者 Wenjuan Sun Xingfei Zhang Weiwei Wang Bilan Zhang Wensheng Chen Qin Zou 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第6期1198-1207,共10页
Flotation separation of calcite from fluorite is a challenge on low-grade fluorite flotation that limits the recovery and purity of fluorite concentrate.A new acid leaching–flotation process for fluorite is proposed ... Flotation separation of calcite from fluorite is a challenge on low-grade fluorite flotation that limits the recovery and purity of fluorite concentrate.A new acid leaching–flotation process for fluorite is proposed in this work.This innovative process raised the fluor-ite’s grade to 97.26wt%while producing nanoscale calcium carbonate from its leachate,which contained plenty of calcium ions.On the production of nanoscale calcium carbonate,the impacts of concentration,temperature,and titration rate were examined.By modifying the process conditions and utilizing crystal conditioning agents,calcite-type and amorphous calcium carbonates with corresponding particle sizes of 1.823 and 1.511μm were produced.The influence of the impurity ions Mn^(2+),Mg^(2+),and Fe^(3+)was demonstrated to reduce the particle size of nanoscale calcium carbonate and make crystal shape easier to manage in the fluorite leach solution system compared with the calcium chloride solution.The combination of the acid leaching–flotation process and the nanoscale calcium carbonate preparation method improved the grade of fluorite while recovering calcite resources,thus presenting a novel idea for the effective and clean usage of low-quality fluorite resources with embedded microfine particles. 展开更多
关键词 FLUORITE CALCITE nanoscale calcium carbonate waste recovery
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Sedimentary build-ups of pre-salt isolated carbonate platforms and formation of deep-water giant oil fields in Santos Basin,Brazil
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作者 DOU Lirong WEN Zhixin +7 位作者 WANG Zhaoming HE Zhengjun SONG Chengpeng CHEN Ruiyin YANG Xiaofa LIU Xiaobing LIU Zuodong CHEN Yanyan 《Petroleum Exploration and Development》 SCIE 2024年第4期949-962,共14页
In response to the problems of unclear distribution of deep-water pre-salt carbonate reservoirs and formation conditions of large oil fields in the Santos passive continental margin basin,based on comprehensive utiliz... In response to the problems of unclear distribution of deep-water pre-salt carbonate reservoirs and formation conditions of large oil fields in the Santos passive continental margin basin,based on comprehensive utilization of geological,seismic,and core data,and reconstruction of Early Cretaceous prototype basin and lithofacies paleogeography,it is proposed for the first time that the construction of pre-salt carbonate build-ups was controlled by two types of isolated platforms:inter-depression fault-uplift and intra-depression fault-high.The inter-depression fault-uplift isolated platforms are distributed on the present-day pre-salt uplifted zones between depressions,and are built on half-and fault-horst blocks that were inherited and developed in the early intra-continental and inter-continental rift stages.The late intra-continental rift coquinas of the ITP Formation and the early inter-continental rift microbial limestones of the BVE Formation are continuously constructed;intra-depression fault-high isolated platforms are distributed in the current pre-salt depression zones,built on the uplifted zones formed by volcanic rock build-ups in the early prototype stage of intra-continental rifts,and only the BVE microbial limestones are developed.Both types of limestones formed into mound-shoal bodies,that have the characteristics of large reservoir thickness and good physical properties.Based on the dissection of large pre-salt oil fields discovered in the Santos Basin,it has been found that both types of platforms could form large-scale combined structural-stratigraphic traps,surrounded by high-quality lacustrine and lagoon source rocks at the periphery,and efficiently sealed by thick high-quality evaporite rocks above,forming the optimal combination of source,reservoir and cap in the form of“lower generation,middle storage,and upper cap”,with a high degree of oil and gas enrichment.It has been found that the large oil fields are all bottom water massive oil fields with a unified pressure system,and they are all filled to the spill-point.The future exploration is recommended to focus on the inter-depression fault-uplift isolated platforms in the western uplift zone and the southern section of eastern uplift zones,as well as intra-depression fault-high isolated platforms in the central depression zone.The result not only provides an important basis for the advanced selection of potential play fairways,bidding of new blocks,and deployment of awarded exploration blocks in the Santos Basin,but also provides a reference for the global selection of deep-water exploration blocks in passive continental margin basins. 展开更多
关键词 Santos Basin passive continental marginal basin deep water inter-depression fault-uplift isolated carbonate platform intra-depression fault-high carbonate isolated platform giant oil fields
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Effects of Different Concentrations of Sulfate Ions on Carbonate Crude Oil Desorption:Experimental Analysis and Molecular Simulation
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作者 Nannan Liu Hengchen Qi +1 位作者 Hui Xu Yanfeng He 《Fluid Dynamics & Materials Processing》 EI 2024年第8期1731-1741,共11页
Low salinity water containing sulfate ions can significantly alter the surface wettability of carbonate rocks.Nevertheless,the impact of sulfate concentration on the desorption of oil film on the surface of carbonate ... Low salinity water containing sulfate ions can significantly alter the surface wettability of carbonate rocks.Nevertheless,the impact of sulfate concentration on the desorption of oil film on the surface of carbonate rock is still unknown.This study examines the variations in the wettability of the surface of carbonate rocks in solutions containing varying amounts of sodium sulfate and pure water.The problem is addressed in the framework of molecular dynamics simulation(Material Studio software)and experiments.The experiment’s findings demonstrate that sodium sulfate can increase the rate at which oil moisture is turned into water moisture.The final contact angle is smaller than that of pure water.The results of the simulations show that many water molecules travel down the water channel under the influence of several powerful forces,including the electrostatic force,the van der Waals force and hydrogen bond,crowding out the oil molecules on the calcite’s surface and causing the oil film to separate.The relative concentration curve of water and oil molecules indicates that the separation rate of the oil film on the surface of calcite increases with the number of sulfate ions. 展开更多
关键词 carbonate rocks WETTABILITY sulfate ions CONCENTRATION molecular simulation DESORPTION
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Efficient C-N coupling in electrocatalytic urea generation on copper carbonate hydroxide electrocatalysts
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作者 Yinuo Wang Yian Wang +11 位作者 Qinglan Zhao Hongming Xu Shangqian Zhu Fei Yang Ernest P.Delmo Xiaoyi Qiu Chi Song Juhee Jang Tiehuai Li Ping Gao MDanny Gu Minhua Shao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期289-298,I0008,共11页
Urea generation through electrochemical CO_(2) and NO_(3)~-co-reduction reaction(CO_(2)NO_(3)RR)is still limited by either the low selectivity or yield rate of urea.Herein,we report copper carbonate hydroxide(Cu_2(OH)... Urea generation through electrochemical CO_(2) and NO_(3)~-co-reduction reaction(CO_(2)NO_(3)RR)is still limited by either the low selectivity or yield rate of urea.Herein,we report copper carbonate hydroxide(Cu_2(OH)_2CO_(3))as an efficient CO_(2)NO_(3)RR electrocatalyst with an impressive urea Faradaic efficiency of45.2%±2.1%and a high yield rate of 1564.5±145.2μg h~(-1)mg_(cat)~(-1).More importantly,H_(2) evolution is fully inhibited on this electrocatalyst over a wide potential range between-0.3 and-0.8 V versus reversible hydrogen electrode.Our thermodynamic simulation reveals that the first C-N coupling follows a unique pathway on Cu_2(OH)_2CO_(3) by combining the two intermediates,~*COOH and~*NHO.This work demonstrates that high selectivity and yield rate of urea can be simultaneously achieved on simple Cu-based electrocatalysts in CO_(2)NO_(3)RR,and provide guidance for rational design of more advanced catalysts. 展开更多
关键词 Copper carbonate hydroxide Co-reduction Urea generation C-N coupling DFT calculation
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Experimental investigation into the salinity effect on the physicomechanical properties of carbonate saline soil
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作者 Jiejie Shen Qing Wang +3 位作者 Yating Chen Xuefei Zhang Yan Han Yaowu Liu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第5期1883-1895,共13页
For engineering structures with saline soil as a filling material,such as channel slope,road subgrade,etc.,the rich soluble salt in the soil is an important potential factor affecting their safety performance.This stu... For engineering structures with saline soil as a filling material,such as channel slope,road subgrade,etc.,the rich soluble salt in the soil is an important potential factor affecting their safety performance.This study examines the Atterberg limits,shear strength,and compressibility of carbonate saline soil samples with different NaHCO3 contents in Northeast China.The mechanism underlying the influence of salt content on soil macroscopic properties was investigated based on a volumetric flask test,a mercury intrusion porosimetry(MIP)test,and a scanning electron microscopic(SEM)test.The results demonstrated that when NaHCO3 contents were lower than the threshold value of 1.5%,the bound water film adsorbed on the surface of clay particles thickened continuously,and correspondingly,the Atterberg limits and plasticity index increased rapidly as the increase of sodium ion content.Meanwhile,the bonding force between particles was weakened,the dispersion of large aggregates was enhanced,and the soil structure became looser.Macroscopically,the compressibility increased and the shear strength(mainly cohesion)decreased by 28.64%.However,when the NaHCO3 content exceeded the threshold value of 1.5%,the salt gradually approached solubility and filled the pores between particles in the form of crystals,resulting in a decrease in soil porosity.The cementation effect generated by salt crystals increased the bonding force between soil particles,leading to a decrease in plasticity index and an improvement in soil mechanical properties.Moreover,this work provides valuable suggestions and theoretical guidance for the scientific utilization of carbonate saline soil in backfill engineering projects. 展开更多
关键词 carbonate saline soil Salt content Physicomechanical properties Bound water MICROSTRUCTURE
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Retaining the self-released chalcogenate at reconstructed cobalt sites by self-transformed carbonate regulation for boosted oxygen evolution
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作者 Jingxuan Zhao Zhe Xue +3 位作者 Qing Wang Xiangyang Li Shoujie Liu Xu Zhao 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期46-54,I0002,共10页
The in-situ generated oxyanions at electrochemically reconstructed catalysts from metal-based nonoxide compounds have been proven to significantly accelerate oxygen evolution reaction(OER)kinetics.However,it remains a... The in-situ generated oxyanions at electrochemically reconstructed catalysts from metal-based nonoxide compounds have been proven to significantly accelerate oxygen evolution reaction(OER)kinetics.However,it remains a challenge to retain these self-released oxyanions at reconstructed catalysts,hindering its utilization as a tool to develop efficient OER catalysts.Here,we demonstrate a versatile selftransformed carbonate regulation strategy to efficiently retain the self-released chalcogenate at Co oxyhydroxides reconstructed from carbon-incorporated Co selenides under OER conditions.These selftransformed CO_(3)^(2-)can induce electron accumulation and narrow d bond at Co sites to facilitate the Co3d-O 2p orbital hybridization between Co sites and SeO_(x)^(2-)for enhanced SeO_(x)^(2-)retention,which can accelerate the rate-limiting step for^(*)OOH formation during OER.Relative to CoOOH-SeO_(x)^(2-)with limited SeO_(x)^(2-)residues,CoOOH-CO_(3)^(2-)/SeO_(x)^(2-)with elevated SeO_(x)^(2-)retention by CO_(3)^(2-)regulation exhibited a 5.6-fold increase in current density and a remarkable lower Tafel slope towards OER.This strategy paves a rational avenue to design efficient catalysts for electrooxidation reactions through finely regulating self-released oxyanions at reconstructed structures. 展开更多
关键词 Electrochemical reconstruction Chalcogenate retention carbonate regulation Orbital hybridization Oxygen evolution reaction
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Impacts of interactions with low-mineralized water on permeability and pore behavior of carbonate reservoirs
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作者 Dmitriy A.Martyushev Inna N.Ponomareva +3 位作者 Vasiliy I.Chernykh Shadfar Davoodi Yousef Kazemzadeh Tianshou Ma 《Energy Geoscience》 EI 2024年第4期278-290,共13页
Laboratory filtration experiments are employed to investigate effective well killing while minimizing its impacts on surrounding rocks.The novelty of this experimental study lies in the prolonged exposure of rock samp... Laboratory filtration experiments are employed to investigate effective well killing while minimizing its impacts on surrounding rocks.The novelty of this experimental study lies in the prolonged exposure of rock samples to the killing fluid for seven days,corresponding to the average duration of well workovers in the oilfields in Perm Krai,Russia.Our findings indicate that critical factors influencing the interactions between rocks and the killing fluid include the chemical composition of the killing fluid,the mineralogical composition of the carbonate rocks,reservoir pressure and temperature,and the contact time.Petrophysical analyses using multi-scale X-ray computed tomography,field emission scanning electron microscopy,and X-ray diffraction were conducted on samples both before and after the well killing simulation.The experiments were performed using real samples of cores,crude oil,and the killing fluid.The results from this study indicate that low-mineralized water(practically fresh water)is a carbonate rock solvent.Such water causes the dissolution of rock components,the formation of new calcite crystals and amoeba-like secretions,and the migration of small particles(clay,quartz,and carbonates).The formation of deep channels was also recorded.The assessment reveals that the change in the pH of the killing fluid indicates that the observed mineral reactions were caused by carbonate dissolution.These combined phenomena led to a decrease in the total number of voids in the core samples,which was 25%on average,predominantly among voids measuring between 45 and 70μm in size.The change in the pore distribution in the bulk of the samples resulted in decreases in porosity of 1.8%and permeability of 67.0%in the studied core samples.The results from this study indicate the unsuitability of low-mineralized water as a well killing fluid in carbonate reservoirs.The composition of the killing fluid should be optimized,for example,in terms of the ionic composition of water,which we intend to investigate in future research. 展开更多
关键词 Fine particle Clay mineral Low-mineralized water Geochemical dissolution carbonate reservoir
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Tuning the cross-linked structure of basic poly(ionic liquid)to develop an efficient catalyst for the conversion of vinyl carbonate to dimethyl carbonate
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作者 Zhaoyang Qi Shiquan Zhong +4 位作者 Huiyun Su Changshen Ye Limei Ren Ting Qiu Jie Chen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第8期106-116,共11页
Dimethyl carbonate(DMC)is a crucial chemical raw material widely used in organic synthesis,lithiumion battery electrolytes,and various other fields.The current primary industrial process employs a conventional sodium ... Dimethyl carbonate(DMC)is a crucial chemical raw material widely used in organic synthesis,lithiumion battery electrolytes,and various other fields.The current primary industrial process employs a conventional sodium methoxide basic catalyst to produce DMC through the transesterification reaction between vinyl carbonate and methanol.However,the utilization of this catalyst presents several challenges during the process,including equipment corrosion,the generation of solid waste,susceptibility to deactivation,and complexities in separation and recovery.To address these limitations,a series of alkaline poly(ionic liquid)s,i.e.[DVBPIL][PHO],[DVCPIL][PHO],and[TBVPIL][PHO],with different crosslinking degrees and structures,were synthesized through the construction of cross-linked polymeric monomers and functionalization.These poly(ionic liquid)s exhibit cross-linked structures and controllable cationic and anionic characteristics.Research was conducted to investigate the effect of the cross-linking degree and structure on the catalytic performance of transesterification in synthesizing DMC.It was discovered that the appropriate cross-linking degree and structure of the[DVCPIL][PHO]catalyst resulted in a DMC yield of up to 80.6%.Furthermore,this catalyst material exhibited good stability,maintaining its catalytic activity after repeated use five times without significant changes.The results of this study demonstrate the potential for using alkaline poly(ionic liquid)s as a highly efficient and sustainable alternative to traditional catalysts for the transesterification synthesis of DMC. 展开更多
关键词 Poly(ionic liquid) Cross-linking degree Dimethyl carbonate production Transesterification reaction Mechanism
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Identification of reservoir types in deep carbonates based on mixedkernel machine learning using geophysical logging data
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作者 Jin-Xiong Shi Xiang-Yuan Zhao +3 位作者 Lian-Bo Zeng Yun-Zhao Zhang Zheng-Ping Zhu Shao-Qun Dong 《Petroleum Science》 SCIE EI CAS CSCD 2024年第3期1632-1648,共17页
Identification of reservoir types in deep carbonates has always been a great challenge due to complex logging responses caused by the heterogeneous scale and distribution of storage spaces.Traditional cross-plot analy... Identification of reservoir types in deep carbonates has always been a great challenge due to complex logging responses caused by the heterogeneous scale and distribution of storage spaces.Traditional cross-plot analysis and empirical formula methods for identifying reservoir types using geophysical logging data have high uncertainty and low efficiency,which cannot accurately reflect the nonlinear relationship between reservoir types and logging data.Recently,the kernel Fisher discriminant analysis(KFD),a kernel-based machine learning technique,attracts attention in many fields because of its strong nonlinear processing ability.However,the overall performance of KFD model may be limited as a single kernel function cannot simultaneously extrapolate and interpolate well,especially for highly complex data cases.To address this issue,in this study,a mixed kernel Fisher discriminant analysis(MKFD)model was established and applied to identify reservoir types of the deep Sinian carbonates in central Sichuan Basin,China.The MKFD model was trained and tested with 453 datasets from 7 coring wells,utilizing GR,CAL,DEN,AC,CNL and RT logs as input variables.The particle swarm optimization(PSO)was adopted for hyper-parameter optimization of MKFD model.To evaluate the model performance,prediction results of MKFD were compared with those of basic-kernel based KFD,RF and SVM models.Subsequently,the built MKFD model was applied in a blind well test,and a variable importance analysis was conducted.The comparison and blind test results demonstrated that MKFD outperformed traditional KFD,RF and SVM in the identification of reservoir types,which provided higher accuracy and stronger generalization.The MKFD can therefore be a reliable method for identifying reservoir types of deep carbonates. 展开更多
关键词 Reservoir type identification Geophysical logging data Kernel Fisher discriminantanalysis Mixedkernel function Deep carbonates
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Fracture identification of carbonate reservoirs by deep forest model:An example from the D oilfield in Zagros Basin
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作者 Chunqiu Ji Shaoqun Dong +3 位作者 Lianbo Zeng Yuanyuan Liu Jingru Hao Ziyi Yang 《Energy Geoscience》 EI 2024年第3期339-350,共12页
Identifying fractures along a well trajectory is of immense significance in determining the subsurface fracture network distribution.Typically,conventional logs exhibit responses in fracture zones,and almost all wells... Identifying fractures along a well trajectory is of immense significance in determining the subsurface fracture network distribution.Typically,conventional logs exhibit responses in fracture zones,and almost all wells have such logs.However,detecting fractures through logging responses can be challenging since the log response intensity is weak and complex.To address this problem,we propose a deep learning model for fracture identification using deep forest,which is based on a cascade structure comprising multi-layer random forests.Deep forest can extract complex nonlinear features of fractures in conventional logs through ensemble learning and deep learning.The proposed approach is tested using a dataset from the Oligocene to Miocene tight carbonate reservoirs in D oilfield,Zagros Basin,Middle East,and eight logs are selected to construct the fracture identification model based on sensitivity analysis of logging curves against fractures.The log package includes the gamma-ray,caliper,density,compensated neutron,acoustic transit time,and shallow,deep,and flushed zone resistivity logs.Experiments have shown that the deep forest obtains high recall and accuracy(>92%).In a blind well test,results from the deep forest learning model have a good correlation with fracture observation from cores.Compared to the random forest method,a widely used ensemble learning method,the proposed deep forest model improves accuracy by approximately 4.6%. 展开更多
关键词 Fracture identification Conventional log Deep forest Deep learning Tight carbonate reservoir
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