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From concept to commercialization:A review of tubular solid oxide fuel cell technology 被引量:1
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作者 Ruyan Chen Yuan Gao +4 位作者 Jiutao Gao Huiyu Zhang Martin Motola Muhammad Bilal Hanif Cheng-Xin Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期79-109,I0003,共32页
The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the st... The reduced sealing difficulty of tubular solid oxide fuel cells(SOFCs)makes the stacking of tubular cell groups relatively easy,and the thermal stress constraints during stack operation are smaller,which helps the stack to operate stably for a long time.The special design of tubular SOFC structures can completely solve the problem of high-temperature sealing,especially in the design of multiple single-cell series integrated into one tube,where each cell tube is equivalent to a small electric stack,with unique characteristics of high voltage and low current output,which can significantly reduce the ohmic polarization loss of tubular cells.This paper provides an overview of typical tubular SOFC structural designs both domestically and internationally.Based on the geometric structure of tubular SOFCs,they can be divided into bamboo tubes,bamboo flat tubes,single-section tubes,and single-section flat tube structures.Meanwhile,this article provides an overview of commonly used materials and preparation methods for tubular SOFCs,including commonly used materials and preparation methods for support and functional layers,as well as a comparison of commonly used preparation methods for microtubule SOFCs,It introduced the three most important parts of building a fuel cell stack:manifold,current collector,and ceramic adhesive,and also provided a detailed introduction to the power generation systems of different tubular SOFCs,Finally,the development prospects of tubular SOFCs were discussed. 展开更多
关键词 Tubular solid oxide fuel cell Support material Geometric structure Preparation methods stack
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Dynamic Thermal Model and Temperature Control of Proton Exchange Membrane Fuel Cell Stack 被引量:5
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作者 邵庆龙 卫东 +1 位作者 曹广益 朱新坚 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第2期218-224,共7页
A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain p... A dynamic thermal transfer model of a proton exchange membrane fuel cell (PEMFC) stack is developed based on energy conservation in order to reach better temperature control of PEMFC stack. Considering its uncertain parameters and disturbance, we propose a robust adaptive controller based on backstepping algorithm of Lyaponov function. Numerical simulations indicate the validity of the proposed controller. 展开更多
关键词 proton exchange membrane fuel cell stack dynamic thermal transfer model temperature control
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Evaluation of 1-kW Class PEM Fuel Cell Stack under In-Situ Conditions Considering Individual Cells 被引量:1
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作者 Keiichi Okajima Takumi Nasu Seunghyuk Choi 《Journal of Energy and Power Engineering》 2014年第9期1543-1551,共9页
Focusing on the stack performance is important for practical use of PEM (proton exchange membrane) fuel cells. This paper describes the experiments and evaluation on the performance of 1-kW class PEM FC (fuel cell... Focusing on the stack performance is important for practical use of PEM (proton exchange membrane) fuel cells. This paper describes the experiments and evaluation on the performance of 1-kW class PEM FC (fuel cell) stacks for reliability improvement. We investigated the stack performance, voltage distributions, and internal resistance of the single cells of a PEMFC stack. The standard deviation of individual cell voltages increased almost linearly with the current load by 2.5 times that in the case of an open-circuit voltage, with a standard deviation of 33 A. From the results of the current-interrupt tests, the internal resistance of the FC stack was calculated to be 43.53 mΩ. The internal resistances of each individual cell were not uniform. The average internal resistance was 0.505 mΩ at 18 A, which was less than that calculated from the stack current-interrupt test. We also investigated the current distribution in the PEM FC stack under in-situ conditions using a triaxial magnetic sensor probe. From the results, the current distribution tended to concentrate on the underside of the cell. Each I-V curve at the divided plane can be obtained using the developed method. 展开更多
关键词 Proton exchange membrane fuel cell PEM stack current distribution magnetic field magnetic sensor probe diagnostics.
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Efficient Power Conditioner for a Fuel Cell Stack-Ripple Current Reduction Using Multiphase Converter
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作者 Sampath Naveen Kumar Natarajan Rajalakshmi Kaveripatnam Samban Dhathathreyan 《Smart Grid and Renewable Energy》 2013年第1期53-56,共4页
Integration of fuel cell stack with an inverter is complex in nature. A number of factors have to be taken into account in designing the inverter as well as during the integration. One of these factors is ripple curre... Integration of fuel cell stack with an inverter is complex in nature. A number of factors have to be taken into account in designing the inverter as well as during the integration. One of these factors is ripple current which could affect the life of the fuel cell stack if there is fuel and/or oxidant starvation. In this paper an inverter topology is investigated which significantly reduces or even nullifies the ripple content in the fuel cell system. The investigations have been carried out using indigenously developed 1 KW PEMFC stack and a 4 kW PEMFC stack with single and multi phase inverter. The results are presented here. 展开更多
关键词 fuel cell stack RIPPLE Current REDUCTION MULTIPHASE INVERTER
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Influence of PTFE on Electrode Structure for Performance of PEMFC and 10-Cells Stack 被引量:1
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作者 LIN Rui ZHAO Tiantian +3 位作者 ZHANG Haiyan CAO Chunhui LI Bing MA Jianxin 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2012年第6期1171-1175,共5页
Water plays a critical role on the performance, stability and lifetime of proton exchange membrane fuel cells(PEMFCs). The addition of poly tetrafluoroethylene(PTFE) to the gas diffusion layer, especially, the cat... Water plays a critical role on the performance, stability and lifetime of proton exchange membrane fuel cells(PEMFCs). The addition of poly tetrafluoroethylene(PTFE) to the gas diffusion layer, especially, the cathode side, would optimize the transportation of water, electron and gas and thus improve the performance of the fuel cell. But until now, the studies about directly applying the PTFE to the catalyst layer are rarely reported. In this paper, the membrane electrode is fabricated by using directly coating catalyst to the membrane method(CCM) and applying PTFE directly to the cathode electrode catalyst layer. The performance of the single cell is determined by polarization curves and durability tests. Electrochemical impedance spectroscopy(EIS) and scanning electron microscopy(SEM) techniques are used to characterize the electrochemical properties of PEMFC. Also the performance of a 10-cells stack is detected. Combining the performance and the physical-chemistry characterization of PEMFC shows that addition of appropriate content of PTFE to the electrode enhances the performance of the fuel cell, which may be due to the improved water management. Addition of appropriate content of PTFE enhances the interaction between the membrane and the catalyst layer, and bigger pores and highly textured structure form in the MEA, which favors the oxygen mass transfer and protons transfer in the fuel cell. While superfluous addition of PTFE covers the surface of catalysts and hindered the contact of catalyst with Nation, which leads to the reduction of electrochemical active area and the decay of the fuel cell performance. The proposed research would optimize the water management of the fuel cell and thus improve the performance of the fuel cell. 展开更多
关键词 proton exchange membrane fuel cell poly-tetrafluoroethylene electrochemical impedance spectroscopy scanning electron microscopy fuel cell stack
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Study and performance test of 10 kW molten carbonate fuel cell power generation system 被引量:1
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作者 Chengzhuang Lu Ruiyun Zhang +3 位作者 Guanjun Yang Hua Huang Jian Cheng Shisen Xu 《International Journal of Coal Science & Technology》 EI CAS CSCD 2021年第3期368-376,共9页
The use of high-temperature fuel cells as a power technology can improve the efficiency of electricity generation and achieve near-zero emissions of carbon dioxide.This work explores the performance of a 10 kW high-te... The use of high-temperature fuel cells as a power technology can improve the efficiency of electricity generation and achieve near-zero emissions of carbon dioxide.This work explores the performance of a 10 kW high-temperature molten carbonate fuel cell.The key materials of a single cell were characterized and analyzed using X-ray diffraction and scanning electron microscopy.The results show that the pore size of the key electrode material is 6.5 lm and the matrix material is a-LiAlO_(2).Experimentally,the open circuit voltage of the single cell was found to be 1.23 V.The current density was greater than 100 mA/cm^(2)at an operating voltage of 0.7 V.The 10 kW fuel cell stack comprised 80 single fuel cells with a total area of 2000 cm^(2)and achieved an open circuit voltage of greater than 85 V.The fuel cell stack power and current density could reach 11.7 kW and 104.5 mA/cm2 at an operating voltage of 56 V.The influence and long-term stable operation of the stack were also analyzed and discussed.The successful operation of a 10 kW high-temperature fuel cell promotes the large-scale use of fuel cells and provides a research basis for future investigations of fuel cell capacity enhancement and distributed generation in China. 展开更多
关键词 fuel cell stack Key materials Molten carbonate fuel cell Power generation test
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Status of an MWth integrated gasification fuel cell powergeneration system in China
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作者 Chang Wei Zhien Liu +8 位作者 Chufu Li Surinder Singh Haoren Lu Yudong Gong Pingping Li Hanlin Wang Xia Yang Ming Xu Shujun Mu 《International Journal of Coal Science & Technology》 EI CAS CSCD 2021年第3期401-411,共11页
Abstract Here,we provide a status update of an integrated gasification fuel cell(IGFC)power-generation system being developed at the National Institute of Clean-and-Low-Carbon in China at the megawatt thermal(MWth)sca... Abstract Here,we provide a status update of an integrated gasification fuel cell(IGFC)power-generation system being developed at the National Institute of Clean-and-Low-Carbon in China at the megawatt thermal(MWth)scale.This system is designed to use coal as fuel to produce syngas as a first step,similar to that employed for the integrated gasification combined cycle.Subsequently,the solid-oxide fuel-cell(SOFC)system is used to convert chemical energy to electricity directly through an electrochemical reaction without combustion.This system leads to higher efficiency as compared with that from a traditional coal-fired power plant.The unreacted fuel in the SOFC system is transported to an oxygencombustor to be converted to steam and carbon dioxide(CO_(2)).Through a heat-recovery system,the steam is condensed and removed,and CO_(2) is enriched and captured for sequestration or utilization.Comprehensive economic analyses for a typical IGFC system was performed and the results were compared with those for a supercritical pulverized coal-fired power plant.The SOFC stacks selected for IGFC development were tested and qualified under hydrogen and simulated coal syngas fuel.Experimental results using SOFC stacks and thermodynamic analyses indicated that the control of hydrogen/CO ratio of syngas and steam/CO ratio is important to avoid carbon deposition with the fuel pipe.A 20-kW SOFC unit is under development with design power output of 20 kW and DC efficiency of 50.41%.A 100 kW-level subsystem will consist of 6920-kW power-generation units,and the MWth IGFC system will consist of 59100 kWlevel subsystems. 展开更多
关键词 Integrated gasification fuel cell(IGFC) Solid oxide fuel cell stack module Carbon dioxide capture Oxygen-combustor
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Performance test of a 5 kW solid oxide fuel cell system under high fuel utilization with industrial fuel gas feeding
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作者 Ming Xu Hanlin Wang +7 位作者 Mingxian Liu Jianning Zhao Yuqiong Zhang Pingping Li Mingliang Shi Siqi Gong Zhaohuan Zhang Chufu Li 《International Journal of Coal Science & Technology》 EI CAS CSCD 2021年第3期394-400,共7页
As the demand for green energy with high efficiency and low carbon dioxide(CO2)emissions has increased,solid oxide fuel cells(SOFCs)have been intensively developed in recent years.Integrated gasification fuel cells(IG... As the demand for green energy with high efficiency and low carbon dioxide(CO2)emissions has increased,solid oxide fuel cells(SOFCs)have been intensively developed in recent years.Integrated gasification fuel cells(IGFCs)in particular show potential for large-scale power generation to further increase system efficiency.Thus,for commercial application of IGFCs,it is important to design reliable multi-stacks for large systems that show long-term stability and practical fuel gas for application to industrial equipment.In this work,a test rig(of a 5 kW SOFC system,with syngas from industrial gasifiers as fuel)was fabricated and subjected to long-term tests under high fuel utilization to investigate its performance.The maximum steady output power of the system was 5700 W using hydrogen and 5660 W using syngas and the maximum steady electrical efficiency was 61.24%while the fuel utilization efficiency was 89.25%.The test lasted for more than 500 h as the fuel utilization efficiency was larger than 83%.The performances of each stack tower were almost identical at both the initial stage and after long-term operation.After 500 h operation,the performances of the stack towers decreased only slightly under lower current and showed almost no change under high current.These results demonstrate the reliability of the multi-stack design and the prospect of this SOFC power-generation system for further enlarging its application in a MWth demonstration. 展开更多
关键词 Solid oxide fuel cell(SOFC) Integration gasification with fuel cell(IGFC) GASIFICATION stack tower
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Dynamic Performance of Fuel Cell Power Module for Mobility Applications
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作者 Bouziane Mahmah Ghania Morsli +4 位作者 Mounia Belacel Hocine Benmoussa Soulef Achachera Amina Benhamou Maiouf Belhamel 《Engineering(科研)》 2013年第2期219-229,共11页
Fuel cell powered vehicles have been developed as another alternative to internal combustion engine powered vehicles for some applications including passenger cars, buses, trains, motorcycles, forklifts, electric whee... Fuel cell powered vehicles have been developed as another alternative to internal combustion engine powered vehicles for some applications including passenger cars, buses, trains, motorcycles, forklifts, electric wheelchairs, electric trolleybuses, medical carts, military engines, personal sports craft, mobility devices and other self propelled equipment. Up to now, many researches have focused on the development of the power module in the Fuel cell vehicles (FCVs) and the components of these systems such as membranes, bipolar plates, and electrodes. However, our work in this study focuses on operating the integrated fuel cell power module system efficiently for various operating conditions such as pressure, relative humidity and operating modes. In our validation we have utilized PEMFC single cell, with active area geometry 16 cm2 and of 120 cm2. Some results obtained in our study shown significant performance indicators for PEMFC stack (composed of 2 cells and 4 cells in a series) at different humidification levels. 展开更多
关键词 fuel cell Power Module Mobility Applications PEMFC stack Voltage Experimental Validation
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基于运行数据时空特征和Stacking集成学习的质子交换膜燃料电池故障诊断 被引量:2
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作者 袁铁江 郭泽林 方彤 《中国电机工程学报》 EI CSCD 北大核心 2023年第14期5461-5470,共10页
为实现质子交换膜燃料电池(proton exchange membrane fuel cell,PEMFC)故障诊断的快速性和准确性,提出基于运行数据时空特征和Stacking集成学习的故障诊断方法。首先,采用客观赋权法为反映PEMFC运行状态的电压、电流、温度和压力等变... 为实现质子交换膜燃料电池(proton exchange membrane fuel cell,PEMFC)故障诊断的快速性和准确性,提出基于运行数据时空特征和Stacking集成学习的故障诊断方法。首先,采用客观赋权法为反映PEMFC运行状态的电压、电流、温度和压力等变量进行赋权,基于核主成分分析和长短时记忆神经网络提取其空间、时间特征,基于add思想融合空间、时间特征,构建时空特征集。然后,建立以卷积神经网络(convolutional neural network,CNN)、随机森林、K最近邻算法、极端梯度提升树(extreme gradient boosting,XGBoost)为基分类器,XGBoost为元分类器的Stacking集成学习框架,实现了对PEMFC系统正常、水淹、膜干和氢气泄漏四种运行状态的诊断。最后,算例结果表明,所构建的时空特征集在5种单一分类模型的平均诊断准确率为99.23%,相比空间特征集提升2.83%,在Stacking模型的诊断准确率为99.99%。同时,在满足相同损失函数的前提下,使CNN的运算时间减少28s。因此,所提方法能够实现对PEMFC系统故障的快速准确诊断。 展开更多
关键词 质子交换膜燃料电池 特征加权 时空特征 stacking集成学习 故障诊断
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Research on the technical scheme of multi-stack common rail fuel cell engine based on the demand of commercial vehicle
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作者 Bo Li Qianya Xie +4 位作者 Jun Li Ziliang Zhao Junming Lai Kang Li Fojin Zhou 《Energy and AI》 EI 2024年第2期241-255,共15页
At present,most fuel cell engines are single-stack systems,and high-power single-stack systems have bottlenecks in meeting the power requirements of heavy-duty trucks,mainly because the increase in the single active a... At present,most fuel cell engines are single-stack systems,and high-power single-stack systems have bottlenecks in meeting the power requirements of heavy-duty trucks,mainly because the increase in the single active area and the excessive number of cells will lead to poor distribution uniformity of water,gas and heat in the stack,which will cause local attenuation and reduce the performance of the stack.This paper introduces the design concept of internal combustion engine,takes three-stack fuel cell engine as an example,designs multi-stack fuel cell system scheme and serialized high-voltage scheme.Through Intelligent control technology of independent hydrogen injection based on multi-stack coupling,the hydrogen injection inflow of each stack is controlled online according to the real-time anode pressure to achieve accurate fuel injection of a single stack and ensure the consistency between multiple stacks.proves the performance advantage of multi-stack fuel cell engine through theoretical design,intelligent control and test verification,and focuses on analyzing the key technical problems that may exist in multi-stack consistency.The research results provide a reference for the design of multi-stack fuel cell engines,and have important reference value for the powertrain design of long-distance heavy-duty and high-power fuel cell trucks. 展开更多
关键词 Heavy truck Multi-stack fuel cell engine Three stack PERFORMANCE CONSISTENCY
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Nonlinear modeling based on RBF neural networks identification and adaptive fuzzy control of DMFC stack 被引量:1
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作者 苗青 曹广益 朱新坚 《Journal of Shanghai University(English Edition)》 CAS 2006年第4期346-351,共6页
The temperature models of anode and cathode of direct methanol fuel cell (DMFC) stack were established by using radial basis function (RBF) neural networks identification technique to deal with the modeling and co... The temperature models of anode and cathode of direct methanol fuel cell (DMFC) stack were established by using radial basis function (RBF) neural networks identification technique to deal with the modeling and control problem of DMFC stack. An adaptive fuzzy neural networks temperature controller was designed based on the identification models established, and parameters of the controller were regulated by novel back propagation (BP) algorithm. Simulation results show that the RBF neural networks identification modeling method is correct, effective and the models established have good accuracy. Moreover, performance of the adaptive fuzzy neural networks temperature controller designed is superior. 展开更多
关键词 direct methanol fuel cell (DMFC) stack radial basis function (RBF) neural networks contxoller.
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加长加宽的PEMFC电堆应力分布一致性仿真与优化
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作者 张智明 黄刚强 +2 位作者 任辉 陈志浩 章桐 《湖南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第8期127-134,共8页
质子交换膜燃料电池可以通过扩大电堆的活性区域反应面积来获得更高的功率,但电堆反应面积扩大后,容易导致膜电极应力分布的不均匀性增加,从而引起燃料电池电化学性能的下降.为此,本研究设计了4种不同结构尺寸的燃料电池电堆,结合等效... 质子交换膜燃料电池可以通过扩大电堆的活性区域反应面积来获得更高的功率,但电堆反应面积扩大后,容易导致膜电极应力分布的不均匀性增加,从而引起燃料电池电化学性能的下降.为此,本研究设计了4种不同结构尺寸的燃料电池电堆,结合等效刚度模型法和有限元软件,分析了扩大反应面积的电堆结构对膜电极应力分布均匀性的影响,并进一步优化电堆内钢带的安装位置,以提升电堆内部接触压力分布均匀性.研究结果表明,膜电极接触压力分布的均匀性对反应区域宽度的变化较为敏感,当活性区域尺寸加宽,电堆内部活性区域的平均应力标准差增加了23.2%.而当活性区域加长,或同时加长和加宽时,相应增加一根捆扎钢带使电堆内部活性区域的平均应力标准差分别减小了8.6%和8.7%,表明适当增加捆扎钢带的数量可以提高电堆内部接触压力分布的均匀性.此外,钢带位置优化结果显示,电堆外侧钢带越靠近端板侧面时,电堆内部活性区域的应力分布越均匀. 展开更多
关键词 质子交换膜燃料电池 钢带捆扎 电堆放大 膜电极 压力分布一致性
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功率分配方式对船用双堆燃料电池热管理效果分析
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作者 刘志恩 程博源 +3 位作者 刘昌伟 周辉 李永超 卢炽华 《舰船科学技术》 北大核心 2024年第18期111-117,共7页
为研究船用双堆质子交换膜燃料电池(PEMFC)功率分配方式、热管理系统布置形式对热管理系统性能影响,基于AMESim软件建立了船用双堆PEMFC系统仿真模型,根据试验数据验证了仿真模型的可靠性。在此基础上,以串联式、并联式与旁通式热管理... 为研究船用双堆质子交换膜燃料电池(PEMFC)功率分配方式、热管理系统布置形式对热管理系统性能影响,基于AMESim软件建立了船用双堆PEMFC系统仿真模型,根据试验数据验证了仿真模型的可靠性。在此基础上,以串联式、并联式与旁通式热管理系统模型为研究对象,研究在变载工况下采用功率平均分配、逐级分配策略对电堆进出口冷却水温差的影响规律,最后比较在功率平均分配策略下3种热管理系统布置形式的性能。结果表明,3种热管理系统中电堆进出口冷却水温差均会在不同程度上受到功率分配策略的影响,在功率平均分配策略下,采用串联式热管理系统布置形式更有利于提高电堆内部温度一致性。 展开更多
关键词 质子交换膜燃料电池 热管理 功率分配 双堆 热管理系统布置形式
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浅析氢燃料电池发动机及其辅助系统状态监测与故障诊断
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作者 董琪 张伟 《时代汽车》 2024年第13期152-154,共3页
氢燃料电池发动机作为氢能车辆核心动力单元,其电堆运行状态健康监测和故障诊断直接影响车辆使用和电堆的寿命。当前采用的监测手段主要是对电堆电流和电堆单片电压的监控,通过判断电堆各个单体的电压一致性,以及是否有出现个别单体电... 氢燃料电池发动机作为氢能车辆核心动力单元,其电堆运行状态健康监测和故障诊断直接影响车辆使用和电堆的寿命。当前采用的监测手段主要是对电堆电流和电堆单片电压的监控,通过判断电堆各个单体的电压一致性,以及是否有出现个别单体电压低的问题来判断电堆的健康状态。存在的问题是没有对先期机械故障即早期零部件失效进行监控,电堆能否正常工作也受制于提供空气和冷却的主要零件空压机和水泵的影响,当前仅通过电压巡检器对电堆单体电压的监测被动的报警,当报警时已经出现零件机械结构问题需要车辆进站维修更换零部件,影响车辆的正常出勤。所以有必要通过振动信号进行空压机、水泵等零部件故障的先期诊断评估,并在车辆保养或者闲时进行维修,可避免影响车辆正常营运,减少客户抱怨。 展开更多
关键词 氢燃料电池发动机 故障诊断 电堆
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质子交换膜燃料电池在线监测方法研究进展 被引量:1
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作者 李兰心 潘牧 郭伟 《材料导报》 EI CAS CSCD 北大核心 2024年第6期103-116,共14页
质子交换膜燃料电池作为一种高效、无污染的新一代发电技术在近年来得到广泛关注,但是其寿命问题依然严重制约其商业应用。通过对燃料电池状态进行在线监测来实现电池的快速故障诊断,是延长电池寿命的极有效的途径之一。本文对近年来质... 质子交换膜燃料电池作为一种高效、无污染的新一代发电技术在近年来得到广泛关注,但是其寿命问题依然严重制约其商业应用。通过对燃料电池状态进行在线监测来实现电池的快速故障诊断,是延长电池寿命的极有效的途径之一。本文对近年来质子交换膜燃料电池在线监测方向的文章进行了总结,并按照故障检测方法(包括极化曲线、循环伏安法、电化学阻抗谱等)进行分类讨论。同时,根据实际应用情况将单一检测方法和多种结合检测方法进行文献综述。另外,在总结现有的在线监测方法的基础上,本文提出了未来燃料电池在线监测需要解决的问题并进行展望。 展开更多
关键词 质子交换膜燃料电池 燃料电池电堆 在线监测 故障诊断 电化学阻抗谱
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以掺氢天然气为燃料直接内重整固体氧化物电池堆的稳定性 被引量:1
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作者 汤亚飞 武安祺 +6 位作者 韩贝贝 刘华 包善军 林王林 陈铭 官万兵 Subhash C.Singhal 《电化学(中英文)》 CAS 北大核心 2024年第1期46-54,共9页
本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验,结果显示,电堆的总体衰减率为2.3%·kh^(-1),电堆中三个金属连接板的面积比电阻分别增加了0.276Ω·cm^(2)、0.254... 本文研究了掺氢天然气直接内重整平管型固体氧化物电池短堆的长期稳定性和衰减机理。通过约3000小时的实测实验,结果显示,电堆的总体衰减率为2.3%·kh^(-1),电堆中三个金属连接板的面积比电阻分别增加了0.276Ω·cm^(2)、0.254Ω·cm^(2)和0.249Ω·cm^(2),但电堆中两个电池的电压反而分别增加了3.38 m V·kh^(-1)和3.78 m V·kh^(-1)。电堆衰减主要由金属连接件表层氧化及其与阴极集流层材料反应生成Sr CrO_(4)物质,两者共同作用增大了电池与金属连接体间的界面电阻所致。结果表明,以掺氢天然气为燃料直接内重整平管型固体氧化物燃料电池电堆具有良好的稳定性。本文工作为掺氢天然气在固体氧化物燃料电池堆中的直接内重整应用提供了理论参考与实验依据。 展开更多
关键词 掺氢天然气 内重整 稳定性 固体氧化物电堆
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进气相对湿度对变载工况下PEMFC电堆性能的影响
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作者 胡超 罗马吉 +1 位作者 陈云 张锐明 《江苏大学学报(自然科学版)》 CAS 北大核心 2024年第2期154-159,共6页
为了探究进气相对湿度对质子交换膜燃料电池电堆变载工况性能的影响,设计了一个动态循环工况,包括电流密度从0.10到0.35 A/cm^(2)、从0.10到1.00 A/cm^(2)的2种阶跃工况和电流密度分别为0.10、0.35、1.00 A/cm^(2)的稳定工况,进行了相... 为了探究进气相对湿度对质子交换膜燃料电池电堆变载工况性能的影响,设计了一个动态循环工况,包括电流密度从0.10到0.35 A/cm^(2)、从0.10到1.00 A/cm^(2)的2种阶跃工况和电流密度分别为0.10、0.35、1.00 A/cm^(2)的稳定工况,进行了相对湿度分别为20%、30%、50%、70%、80%的5组试验.结果表明:恒流状态时,电堆在不同电流密度下对相对湿度的敏感性不同,在大电流密度下相对湿度对电堆性能影响较大;变载过程中,电堆电压出现下冲和过冲现象,加载过程的电压下冲量与变载幅度和相对湿度有关,电堆单电池电压一致性变差,电压一致性与进气相对湿度有关. 展开更多
关键词 燃料电池 相对湿度 变载工况 电压一致性 电堆性能
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基于专利的固体氧化物燃料电池技术趋势分析
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作者 隋依言 姚辉超 +2 位作者 王秀林 张雨晴 卢璐 《现代化工》 CAS CSCD 北大核心 2024年第3期5-9,共5页
固体氧化物燃料电池(SOFC)作为一种在高温下将燃料中的化学能直接转化为电能的发电装置,具有能量转化效率高、燃料适应性强且来源广泛、对环境友好等优点。通过分析1990年以来国内外高温固体燃料电池专利情况,从专利申请趋势、专利申请... 固体氧化物燃料电池(SOFC)作为一种在高温下将燃料中的化学能直接转化为电能的发电装置,具有能量转化效率高、燃料适应性强且来源广泛、对环境友好等优点。通过分析1990年以来国内外高温固体燃料电池专利情况,从专利申请趋势、专利申请人及专利地域布局等角度,研究了SOFC领域的技术关注重点、应用情况及技术发展趋势。现阶段高温固体燃料电池技术开发已进入快速发展期,国外固体氧化物燃料电池的研发方向主要聚焦于降低成本和提高稳定性,国内则主要集中在突破电堆关键技术、核心部件国产化及示范工程建设。 展开更多
关键词 固体氧化物燃料电池 SOFC 电堆 专利分析
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基于经验小波变换的SOFC泄漏故障诊断
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作者 杨瑞志 武鑫 +1 位作者 熊星宇 胡亮 《电池》 CAS 北大核心 2024年第2期170-174,共5页
固体氧化物燃料电池(SOFC)电堆通常在700℃以上的高温下工作。电堆所用密封剂在高温下易退化失效,导致泄漏故障,引发电堆的热失控和损坏,影响系统运行稳定性。提出一种基于电堆温度和电压信号的经验小波变换(EWT)诊断方法。通过EWT分解... 固体氧化物燃料电池(SOFC)电堆通常在700℃以上的高温下工作。电堆所用密封剂在高温下易退化失效,导致泄漏故障,引发电堆的热失控和损坏,影响系统运行稳定性。提出一种基于电堆温度和电压信号的经验小波变换(EWT)诊断方法。通过EWT分解温度和电压信号,得到多分辨率分析(MRA),分析其中故障特征明显的MRA信号,求出时域特征,通过设定的阈值判断是否发生泄漏。通过千瓦级电堆实验平台数据,验证EWT诊断方法可较好地检测电堆泄漏故障,且相较于电压信号,温度信号的诊断更迅速。与集合经验模态分解诊断方法相比,EWT方法可更快地诊断出泄漏故障。 展开更多
关键词 系统建模 固体氧化物燃料电池(SOFC) 电堆泄漏 经验小波变换(EWT)
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