Mono(isopropyl maleate-oyloxyl) diisopropoxyl dysprosium(DM) was synthesized by the reaction of dysprosium isopropoxide with maleic anhydride. Dy-containing polymer(PDM) was obtained by the solution polymerization of ...Mono(isopropyl maleate-oyloxyl) diisopropoxyl dysprosium(DM) was synthesized by the reaction of dysprosium isopropoxide with maleic anhydride. Dy-containing polymer(PDM) was obtained by the solution polymerization of DM using 2, 2'-azobisisobutyronitrile (AIBN) as an initiator. The kinetic study on the polymerization shows that the polymerization of DM exhibits high apparent activation energy(96.3 kJ.mol(-1)), indicating that the activity of DM is low for polymerization. The kinetic equation of polymerization can be expressed as R-P = k(P)C(DM)(1.23)c(AIBN)(0.82). The polymeric solid material shows excellent heat-stability and strong characteristic fluorescence of Dy3+, (4)Fg(9/2) --> H-6(15/2) and F-4(9/2) --> H-6(13/2).展开更多
The extraction and stripping of scandium from its sulfate solutions by isopropyl phosphonic acid mono (1-hexyl-4-ethyl) octyl ester (PT-2, HL) diluted with n-hexane are reported. A high efficiency of separation betwee...The extraction and stripping of scandium from its sulfate solutions by isopropyl phosphonic acid mono (1-hexyl-4-ethyl) octyl ester (PT-2, HL) diluted with n-hexane are reported. A high efficiency of separation between scandium, iron and lutetium can be achieved by controlling aqueous acidity. Different mechanisms of Sc3+ with PT-2 in various acid range have been proposed.At lower aqueous acidity, it is a cation exchange reaction, while at higher acidity. a solvation reaction was ascertained. Its IR and NMR spectra have been discussed. The effect of temperature on extraction of Sc3+ was observed and thermodynamic functions were calculated.展开更多
Drought stress is themajor abiotic factor that can seriously affect plant growth and crop production.The functions of flavin-containing monooxygenases(FMOs)are known in animals.They addmolecular oxygen to lipophilic c...Drought stress is themajor abiotic factor that can seriously affect plant growth and crop production.The functions of flavin-containing monooxygenases(FMOs)are known in animals.They addmolecular oxygen to lipophilic compounds or produce reactive oxygen species(ROS).However,little information on FMOs in plants is available.Here,we characterized a tomato drought-responsive gene that showed homology to FMO,and it was designated as FMO1.FMO1 was downregulated promptly by drought and ABA treatments.Transgenic functional analysis indicated that RNAi suppression of the expression of FMO1(FMO1-Ri)improved drought tolerance relative to wild-type(WT)plants,whereas overexpression of FMO1(FMO1-OE)reduced drought tolerance.The FMO1-Ri plants exhibited lower ABA accumulation,higher levels of antioxidant enzyme activities,and less ROS generation comparedwith theWTand FMO1-OE plants under drought stress.RNA-seq transcriptional analysis revealed the differential expression levels of many drought-responsive genes thatwere co-expressed with FMO1,including PP2Cs,PYLs,WRKY,and LEA.Using Y2H screening,we found that FMO1 physically interacted with catalase 2(CAT2),which is an antioxidant enzyme and confers drought resistance.Our findings suggest that tomato FMO1 negatively regulates tomato drought tolerance in the ABA-dependent pathway and modulates ROS homeostasis by directly binding to SlCAT2.展开更多
The filling of rivers generated by carried solid deposit is a factor for the raising of height of rivers and thus activates the floods and inundations. The quantification of carried solid flow charges through their ch...The filling of rivers generated by carried solid deposit is a factor for the raising of height of rivers and thus activates the floods and inundations. The quantification of carried solid flow charges through their characterization and the analysis of hydrosedimentary dynamics is the second step of the investigation of the solid flow transport in the Mono river. This study aims to quantify the volume of trapped sediments in function of the variation of the geometry of the shape of sections of the river depending of the slope and the flow rate therefore to evaluate the capacity of transport of eroded solid flows of a watercourse from upstream to downstream. Consequently, the decreasing percentage of deposited alluvium from upstream to downstream is calculated along Mono river. Thus the drawn granulometric curve of sediments and the determinate granulometric characteristics of sediments permit to quantify the carried sediment charges at each chosen section with Engelund-Hansen model in Mono river.展开更多
文摘Mono(isopropyl maleate-oyloxyl) diisopropoxyl dysprosium(DM) was synthesized by the reaction of dysprosium isopropoxide with maleic anhydride. Dy-containing polymer(PDM) was obtained by the solution polymerization of DM using 2, 2'-azobisisobutyronitrile (AIBN) as an initiator. The kinetic study on the polymerization shows that the polymerization of DM exhibits high apparent activation energy(96.3 kJ.mol(-1)), indicating that the activity of DM is low for polymerization. The kinetic equation of polymerization can be expressed as R-P = k(P)C(DM)(1.23)c(AIBN)(0.82). The polymeric solid material shows excellent heat-stability and strong characteristic fluorescence of Dy3+, (4)Fg(9/2) --> H-6(15/2) and F-4(9/2) --> H-6(13/2).
文摘The extraction and stripping of scandium from its sulfate solutions by isopropyl phosphonic acid mono (1-hexyl-4-ethyl) octyl ester (PT-2, HL) diluted with n-hexane are reported. A high efficiency of separation between scandium, iron and lutetium can be achieved by controlling aqueous acidity. Different mechanisms of Sc3+ with PT-2 in various acid range have been proposed.At lower aqueous acidity, it is a cation exchange reaction, while at higher acidity. a solvation reaction was ascertained. Its IR and NMR spectra have been discussed. The effect of temperature on extraction of Sc3+ was observed and thermodynamic functions were calculated.
基金supported by grants from the National Natural Science Foundation of China(No.31872123)Natural Science Foundation of Chongqing,China(No.cstc2019jcyj-msxmX0333)the Fundamental Research Funds for the Central Universities(No.XDJK2020B060).
文摘Drought stress is themajor abiotic factor that can seriously affect plant growth and crop production.The functions of flavin-containing monooxygenases(FMOs)are known in animals.They addmolecular oxygen to lipophilic compounds or produce reactive oxygen species(ROS).However,little information on FMOs in plants is available.Here,we characterized a tomato drought-responsive gene that showed homology to FMO,and it was designated as FMO1.FMO1 was downregulated promptly by drought and ABA treatments.Transgenic functional analysis indicated that RNAi suppression of the expression of FMO1(FMO1-Ri)improved drought tolerance relative to wild-type(WT)plants,whereas overexpression of FMO1(FMO1-OE)reduced drought tolerance.The FMO1-Ri plants exhibited lower ABA accumulation,higher levels of antioxidant enzyme activities,and less ROS generation comparedwith theWTand FMO1-OE plants under drought stress.RNA-seq transcriptional analysis revealed the differential expression levels of many drought-responsive genes thatwere co-expressed with FMO1,including PP2Cs,PYLs,WRKY,and LEA.Using Y2H screening,we found that FMO1 physically interacted with catalase 2(CAT2),which is an antioxidant enzyme and confers drought resistance.Our findings suggest that tomato FMO1 negatively regulates tomato drought tolerance in the ABA-dependent pathway and modulates ROS homeostasis by directly binding to SlCAT2.
文摘The filling of rivers generated by carried solid deposit is a factor for the raising of height of rivers and thus activates the floods and inundations. The quantification of carried solid flow charges through their characterization and the analysis of hydrosedimentary dynamics is the second step of the investigation of the solid flow transport in the Mono river. This study aims to quantify the volume of trapped sediments in function of the variation of the geometry of the shape of sections of the river depending of the slope and the flow rate therefore to evaluate the capacity of transport of eroded solid flows of a watercourse from upstream to downstream. Consequently, the decreasing percentage of deposited alluvium from upstream to downstream is calculated along Mono river. Thus the drawn granulometric curve of sediments and the determinate granulometric characteristics of sediments permit to quantify the carried sediment charges at each chosen section with Engelund-Hansen model in Mono river.