Bio-based cyclodextrins(CDs)are a common research object in supramolecular chemistry.The special cavity structure of CDs can form supramolecular self-assemblies such as vesicles and microcrystals through weak interact...Bio-based cyclodextrins(CDs)are a common research object in supramolecular chemistry.The special cavity structure of CDs can form supramolecular self-assemblies such as vesicles and microcrystals through weak interaction with guest molecules.The different forms of supramolecular self-assemblies can be transformed into each other under certain conditions.The regulation of supramolecular self-assembly is not only helpful to understand the self-assembly principle,but also beneficial to its application.In the present study,the self-assembly behavior of epoxy-β-cyclodextrin(EP-β-CD)and mixed anionic and cationic surfactant system(sodium dodecyl sulfate/dodecyltrimethylammonium bromide,SDS/DTAB)in aqueous solution was studied.Morphological and particle size characterization found that the SDS/DTAB@EP-β-CD complex,as the basic building unit,self-assembled into worm-like micelles at lower temperatures and vesicles at higher temperatures.Nuclear magnetic resonance(NMR)and Fourier transform infrared spectroscopy(FT-IR)analysis revealed that the driving force for the formation of vesicles and worm-like micelles was the hydrogen bonds between EP-β-CD molecules,while water molecules played an important role in promoting vesicle formation between SDS/DTAB@EP-β-CD units.Herein,the mechanism of the morphologic transformation of SDS/DTAB@EP-β-CD supramolecular aggregates induced by temperature was elucidated by exploring the self-assembly process,which may provide an excellent basis for the development of delivery carriers.展开更多
In the last two decades,the Yangtze Estuary has undergone significant changes under the influence of reduced sediment inflow and estuary engineering.This study investigates the influence of floods and typhoons on sedi...In the last two decades,the Yangtze Estuary has undergone significant changes under the influence of reduced sediment inflow and estuary engineering.This study investigates the influence of floods and typhoons on sediment concentration and the morphological evolution of shoals and channels in the Yangtze Estuary.The analysis is conducted through the utilization of topographic data measured pre-and post-flood events and observations of hydro-sedimentary changes during typhoons.By using a generalized estuary mathematical model,this study examines the interplay between varying tidal ranges,tidal divisions,runoff volumes,and regulation projects on the erosion and deposition of shoals and channels in bifurcated estuaries.The results show that due to the implementation of river and waterway regulation projects,the impact of the 2020 flood on the main channel and shoal was significantly less than that of the1998 flood.The swing amplitude of the South Branch main channel decreased.However,local river sections such as the Southern Waterway of Baimao Shoal exhibited erosion.During typhoons,sediment concentration in the 20 cm above the bottom increased significantly and was closely related to wave processes,with a weakened correlation to tidal dynamics.After typhoons,high shoals in South Passage above 0 m were silted up,while the terrain on one side of the tail of Jiuduan Shoal in the downstream deep-water area was generally scoured due to strong wave action.The generalized mathematical model of the bifurcated estuary revealed that M2 tidal component contributed most to the ero sion and deposition evolution of estuary shoals and channels,with floods exhibiting characteristics of sedime ntation on shoals and erosion on channels.With the implementation of a branch rectification project,branch resistance increased,diversion decreased,and the riverbed changed from pre-project erosion to post-project sedimentation,with an increase in erosion in non-project branches.展开更多
The morphology of the Modaomen Estuary(ME)has undergone drastic changes in recent decades,and quantifying the contribution of human activities and natural processes is crucial for estuary management.Using Landsat imag...The morphology of the Modaomen Estuary(ME)has undergone drastic changes in recent decades,and quantifying the contribution of human activities and natural processes is crucial for estuary management.Using Landsat images,chart data,and hydrological and meteorological data,this study analyzed the evolution of the shoreline and subaqueous topography of the ME and attempted to quantify the extent of the contributions of human activities.The results show that local human activities dominated morphological evolution in some periods.From 1973 to 2003,the shoreline advanced rapidly seaward,resulting in approximately half of the water area being converted into land.Human activity is critical to this process,with the direct contribution of local land reclamation projects reaching more than 85%.After 2003,the shoreline remained relatively stable,probably due to a decrease in land reclamation projects.Regarding the evolution of subaqueous topography,the shoals in the estuary were heavily silted and gradually disappeared during 1983–2003,and the waterways narrowed and deepened.The average siltation rate decreased from 15.43 mm/a to-1.02 mm/a,indicating that the ME changed from sedimentation to slight erosion.By detecting variations of sediment load,we found that upstream human activities reduced river sediment,while downstream human activities significantly increased sediment input to the ME,leaving little change in the actual sediment input to the ME for a relatively long period.In addition,based on the empirical relationship between the sediment input and siltation rate,local human activities influenced the shift in the siltation state more than upstream and downstream human activities did.These findings suggest that more attention should be paid to local human activities to improve the estuarine management in the ME.展开更多
The tidal flats of the Wanggang area, on the Jiangsu coast, represent the largest continuously distributed coastal wetland in terms of area coverage in China, and the dynamics of tidal flat accretion and erosion is hi...The tidal flats of the Wanggang area, on the Jiangsu coast, represent the largest continuously distributed coastal wetland in terms of area coverage in China, and the dynamics of tidal flat accretion and erosion is highly complicated. The cord-grass Spartina alterniflora, which was introduced artificially into the Jiangsu coast, has significant influences on the regional tidal flat evolution in terms of deposition rate, spacial sediment distribution patterns and tidal creek morphology. On the basis of the data set of bed elevation and accumulation rate for different periods of time, the applicability of the Pethick - Allen model to the Jiangsu tidal salt marshes is discussed. In addition, caesium-137 dating was carried out for sediment samples collected from the salt marsh of the Wangang area. In combination with the caesium-137 analysis and the data collected from literature, the Pethick - Allen model was used to derive the accumulation rate in the Wanggang tidal flat for the various periods. The results show that the pattern of tidal flat accretion has been modified, due to more rapid accretion following the iatroduction of S. alterniflora to the region. Surficial sediment samples were collected from representative profiles and analyzed for grain size with a laser particle analyzer. The result shows that fine-grained sediment has been trapped by the plant, with most of the sediment deposited on the Suaeda salsa and Spartina angelica flats being derived from drainage creeks rather than the from gently sloping tidal flats. Remote sensing analysis and in situ observations indicate that the creeks formed in the S. alterniflora flat have a relatively small ratio of width to depth, a relatively high density, and are more stable than the other tidal flat creek systems in the study area.展开更多
Owing to the intensive human activities, the Modaomen Estuary has been significantly modified since 1950s, which has resulted in considerable changes of hydrodynamics and morphodynamics in the area. In this paper, the...Owing to the intensive human activities, the Modaomen Estuary has been significantly modified since 1950s, which has resulted in considerable changes of hydrodynamics and morphodynamics in the area. In this paper, the effects of the anthropogenic activities on the hydrodynamics and morphological evolution in the estuary at different stages are systematically assessed based on the detailed bathymetric data and field survey. The results show that the human activities have caused the channelization of the enclosed sea area in the Modamen Estuary;fast seaward movement of the mouth bar with high siltation;expansion of the channel volume due to channel deepening. The paper also highlights the main hydrodynamic changes in the estuary, including the rise of the water level;the distinguishing changes of tidal range before and after the 1990s (decrease and increase respectively); as well as the increase of the divided flow ratio. It is found that reclamation is the main factor promoting the transition of nature of the estuary from runoff dominant to runoff and wave dominant, and sand mining activities are mainly to strengthen the tidal dynamic and to low the water level. The results provide useful guidance for better planning of the future developments in the estuary and further research in the area.展开更多
Solid-liquid phase conversion between various sulfur species in lithium-sulfur(Li-S)batteries is a fundamental reaction of the sulfur cathode.Disclosing the morphological evolution of solid sulfur species upon cycling...Solid-liquid phase conversion between various sulfur species in lithium-sulfur(Li-S)batteries is a fundamental reaction of the sulfur cathode.Disclosing the morphological evolution of solid sulfur species upon cycling is of great significance to achieving high energy densities.However,an in-depth investigation of the internal reaction is still lacking.In this work,the evolution process of solid sulfur species on carbon substrates is systematically studied by using an operando light microscope combined with in situ electrochemical impedance spectra technology.The observation of phenomena such as bulk solid sulfur species can form and dissolve independently of the conductive substrates and the transformation of supercooled liquid sulfur to crystalline sulfur.Based on the phenomena mentioned above,a possible mechanism was proposed in which the dissolution reaction of solid sulfur species is a spatially free reaction that involves isotropic physical dissolution,diffusion of molecules,and finally the electrochemical reaction.Correspondingly,the formation of solid sulfur species tends to be a form of crystallization in a saturated solution rather than electrodeposition,as is commonly believed.Our findings offer new insights into the reaction of sulfur cathodes and provide new opportunities to design advanced sulfur cathodes for Li-S batteries.展开更多
A large sand bar develops in the inner Qiantang River Estuary,China.It is a unique sedimentary system,elongating landwards by about 130 km.Based on long-term series of bathymetric data in each April,July,and November ...A large sand bar develops in the inner Qiantang River Estuary,China.It is a unique sedimentary system,elongating landwards by about 130 km.Based on long-term series of bathymetric data in each April,July,and November since the 1960s,this study investigated the morphological behavior of this bar under natural conditions and the influence of a large-scale river narrowing project(LRNP)implemented in the last decades.The results show that three timescales,namely the seasonal,interannual and decadal timescales,can be distinguished for the sand bar evolution.The first two are related to the seasonal and interannual variations of river discharge.During high discharge seasons or years,erosion took place at the upper reach and sedimentation at the lower reach.Consequently,the bar apex shifted seaward.The opposite development took place during low discharge seasons or years.The decadal timescale is related to LRNP.Due to the implementation of LRNP,the upper reach has experienced apparent erosion and currently a new equilibrium state has been reached;whereas the lower reach has been accumulated seriously and the accumulation still continues.Nonlinear relationships for how the bar apex location and elevation depend on the river discharge over various stages of LRNP have been established.Compared with the earlier stage of LRNP,the bar apex at present has shifted seaward by about 12 km and lowered by about 1 m.The sand bar movement has significant feedback on the hydrographic conditions along the estuary and has practical implications for coastal management.展开更多
Micron-sized internal cracks were introduced into rounded bars of pure iron by low cycle fatigue,and the cracks had irregular penny-shaped morphology with the critical diameter of about 30μm and the thickness of 0.5...Micron-sized internal cracks were introduced into rounded bars of pure iron by low cycle fatigue,and the cracks had irregular penny-shaped morphology with the critical diameter of about 30μm and the thickness of 0.5~1.5μm.The initi- ation and propagation of the cracks were investigated quantitatively as well as their location and geometry.After vacuum annealing of the samples fatigued,the mor- phology in a two-dimensional longitudinal section of cracks within grains had evolved from initially elliptical one into arrays of spherical voids controlled by surface diffu- sion.Furthermore,a typical morphology for a broken crack with a center spherical void surrounded by outer doughnut-like cavities was observed along a perpendicu- lar section of the specimen.Subsequently the spherical voids shrink and diminish gradually dominated by bulk diffusion.A physical model to heal an internal micro- crack was proposed,in particular for the various healing stages controlled by the related dominant diffusion mechanism and their dependencies upon the morphology and geometry of an original micro-crack in materials.展开更多
Novel Nb2O5 nanorods and polygonal Nb2O5 platelets were generated by a simple solvothermal technique. The geometry evolution of the resultant Nb2O5 from amorphous nanoparticles to crystallized particles, from polygona...Novel Nb2O5 nanorods and polygonal Nb2O5 platelets were generated by a simple solvothermal technique. The geometry evolution of the resultant Nb2O5 from amorphous nanoparticles to crystallized particles, from polygonal platelets to well-elongated nanorods was been studied in detail. The processing parameters, including the reaction temperature, reaction time, concentration of the precursors, and pH value of the solution, which affect the shape and size of the nanorods, were investigated. The Nb2O5 nanorods with different aspect ratios were examined by XRD, SEM and TEM. The experimental results show that Nb2O5 nanorod is the orthorhombic structure and well-crystallized. The growth of the nanorods follows their [001] direction. The successful generation of high quality Nb2O5 nanorods is not only important for transition metal oxide research, but also potentially important for further formation of new Nb-based 1-D nanostructures, such as NbS2 and NbN.展开更多
Since the reform and opening up,Shenzhen has experienced rapid urbanization.Modern urban landscape has replaced the original traditional village landscape,followed by the loss of urban features and the demise of tradi...Since the reform and opening up,Shenzhen has experienced rapid urbanization.Modern urban landscape has replaced the original traditional village landscape,followed by the loss of urban features and the demise of traditional villages.To change the phenomenon,with the help of town plan analysis method,the historical process of urban material form is looked back on.Combining the theory of evolution mechanism of urban spatial structure,and taking Hubei Village which is the only traditional village in the central district of Shenzhen as an example,the characteristics and causes of evolution of traditional villages in Shenzhen in different periods are analyzed,and the evolution characteristics of plane pattern are summarized.Moreover,the power source and characteristics of urban renewal in Shenzhen are pointed out from the perspective of government,market and social force,and the focus of promoting the renewal of traditional villages in the future is explored.展开更多
Effects of the growth temperature on morphological and microstructural evolution of a-plane GaN films grown on r-plane sapphires by metal organic chemical vapor deposition are investigated by atomic force microscopy a...Effects of the growth temperature on morphological and microstructural evolution of a-plane GaN films grown on r-plane sapphires by metal organic chemical vapor deposition are investigated by atomic force microscopy and secondary ion mass spectroscopy (SIMS). Surface morphology, structural quality and related impurity incorpora- tion are very sensitive to the growth temperature. A significant difference of yellow luminescence is observed and attributed to the incorporation of carbon into GaN films, which is confirmed by SIMS analysis. Our results show that the sample with triangular-pit morphology has sample with pentagon-like pit morphology, which is significantly higher concentrations of oxygen than the other induced by the existence of an N-face in triangular pits.展开更多
The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment sourc...The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.展开更多
Zinc-based flow battery is an energy storage technology with good application prospects because of its advantages of abundant raw materials,low cost,and environmental friendliness.The chemical stability of zinc electr...Zinc-based flow battery is an energy storage technology with good application prospects because of its advantages of abundant raw materials,low cost,and environmental friendliness.The chemical stability of zinc electrodes exposed to electrolyte is a very important issue for zinc-based batteries.This paper reports on details of chemical stability of the zinc metal exposed to a series of solutions,as well as the relationship between the morphological evolution of zinc electrodes and their properties in an alkaline medium.Chemical corrosion of zinc electrodes by the electrolyte will change their surface morphology.However,we observed that chemical corrosion is not the main contributor to the evolution of zinc electrode surface morphology,but the main contributor is the Zn/Zn^(2+)electrode process.The morphological evolution of zinc electrodes was controlled by using ionic liquids,1-ethyl-3-methylimidazolium acetate(EMIA),and 1-propylsulfonic-3-methylimidazolium tosylate(PSMIT),and the electrode performance was recorded during the morphological evolution process.It was observed that the reversible change of zinc electrode morphology was accompanied by better electrode performance.展开更多
A petal-like icosahedral quasicrystal with five branches,which is considered to be the representative morphology of the icosahedral quasicrystal,has been observed in the Y-rich Mg-Zn-Y ternary alloys. Moreover,the pol...A petal-like icosahedral quasicrystal with five branches,which is considered to be the representative morphology of the icosahedral quasicrystal,has been observed in the Y-rich Mg-Zn-Y ternary alloys. Moreover,the polygon-like morphology,another pattern of the icosahedral quasicrystal,has also been found in the Y-rich Mg-Zn-Y ternary alloys. The latter morphology results from the evolution of the former one. The growth mechanism of the petal-like morphology of the icosahedral quasicrystal was also discussed. Alloying composition,i.e.,Y element content,is a major factor inducing the morphology evolution of the icosahedral quasicrystal.展开更多
The feedback between morphological evolution and tidal hydrodynamics in a wave-dominated tidal inlet, Xiaohai, China is investigated through data analysis and numerical model experiments. Historically, Xiaohai Inlet h...The feedback between morphological evolution and tidal hydrodynamics in a wave-dominated tidal inlet, Xiaohai, China is investigated through data analysis and numerical model experiments. Historically, Xiaohai Inlet had two openings, located at the north and south of Neizhi Island (a rocky outcrop), respectively. The evolution of Xiaohai Inlet was dominated by the natural process before 1972. In addition to the natural process, human interventions, including the closure of the north opening, 50% of freshwater reduction, and increase of land reclamation, have altered tidal hydrodynamics and morphological evolution since 1972. A series of numerical model simulations were conducted to investigate the influence of morphological changes on the hydrodynamics and the influence of human activities on the inlet evolution. The natural process has caused narrowing and shoaling of the inlet throat, development of the flood-tidal delta, and shoaling of the tidal channel inside the lagoon. Human interventions have accelerated these changes. Consequently, the tidal propagation from the offshore into the lagoon has been impeded and the tidal energy has been dissipated substantially. Tidal current has changed from ebb-dominant to flood-dominant in most parts of the inlet system whereas the inlet throat has remained as ebb-dominant, the tidal prism has decreased consistently, and sediment has continued to deposit inside the inlet. As a result, the changes of morphology, hydrodynamics, and sediment transport show a positive feedback. The human interventions have had both advantageous and adverse influences on the stability of the inlet. The closure of the North Opening has decreased the longshore sediment input to the inlet, and increased the tidal prism, ebb velocity, and sediment transport in the south opening, thus enhancing the inlet's stability. However, reducing the river discharge and landfill of the tidal flats has resulted in a decrease of the tidal prism, the ebb velocity, and the ability to export sediment, thus having the tendency to deteriorate the inlet's stability. A stability analysis based on a closure curve methodology has shown that Xiaohai Inlet is in a state of dynamic equilibrium at present.展开更多
The microstructure, chemical composition and morphology evolution of icosahedral quasicrystalline phase of Mg67.4Zn28.9Y3.7 ternary alloy were investigated in detail at different pouring temperatures by X-ray diffract...The microstructure, chemical composition and morphology evolution of icosahedral quasicrystalline phase of Mg67.4Zn28.9Y3.7 ternary alloy were investigated in detail at different pouring temperatures by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive spectrum (EDS). Low interracial energy favors the formation of l-phase. The experimental results show that the primary l-phase reveals petal-shaped with five and six branches, where each branch has facetted growth morphology with the size ranging from 50 to 100μm. As the temperature decreases, the polygon-shaped l-phase forms, attributed to the decomposition of branch of petal-shaped l-phase, and then it grows bigger and some of the fine polygons join together to form large polygons. Besides these, (α-Mg+l-phase) eutectic structures disappear and the relative amount of Mg7Zn3 phase increases as the pouring temperature decreases. The chemical composition and morphology evolution of l-phase were also discussed.展开更多
The morphology evolution of Al9(Mn,Ni)2 eutectic phase in Al-4 Ni-2 Mn alloy at 350 °C was examined. Two kinds of morphology evolution trends of Al9(Mn, Ni)2 eutectic phase were observed by using scanning electro...The morphology evolution of Al9(Mn,Ni)2 eutectic phase in Al-4 Ni-2 Mn alloy at 350 °C was examined. Two kinds of morphology evolution trends of Al9(Mn, Ni)2 eutectic phase were observed by using scanning electron microscopy and transmission electron microscopy. The ribbon-like Al9(Mn, Ni)2 eutectic phase taking up a small portion of the eutectic structures gradually changes from ribbon-like morphology to rod-like during the heat treatment. The rod-like Al9(Mn, Ni)2 eutectics, primary eutectic structure in the alloy, become unstable at the transverse subboundaries of the eutectic rod when the samples are heat treated at 350 °C, and then split up into short rods with the extension of heat treatment time. Also, the Vickers microhardness test was used to characterize the change of local mechanical properties. The hardness test results indicate that local morphology evolution of eutectic phase has no obvious effect on the local mechanical properties of the alloy. The microhardness of the eutectic area increases slightly when the heat treatment time is extended to 192 h or 360 h.展开更多
Influence of tourism on society,economy and culture of traditional villages is shown gradually by physical form,promoting the evolution of villages into small towns. Based on the perspective of morphology,the changing...Influence of tourism on society,economy and culture of traditional villages is shown gradually by physical form,promoting the evolution of villages into small towns. Based on the perspective of morphology,the changing features of physical and social spatial form of three typical regions(Xizhou Village and its surrounding areas,Zhoucheng Village and its surrounding areas,and Renliyi Village) in Xizhou Town of Dali City during 1985-2010 were analyzed; the roles of tourism during the evolution process of villages into small towns were discussed; the evolution features of villages into small towns were summarized. It is concluded that tourism and economy related to tourism have played important roles in the enhancement of cohesion degree of an aggregation nucleus and have promoted the evolution process of vilages into small towns.展开更多
Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and h...Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and hardness change at the same quenching temperature were investigated. The experimental results show that, with the gradual decrease of the cooling rate from 25 K/min, the morphology of ferrite starts to transform experiencing the dendrite, radial pattern, Widmanstatten-like and wire-net. Sample starts to present the Widmanstatten-like microstructure at 10 K/min which does not exist at higher or lower cooling rates, and this microstructure is detrimental to the mechanical property. Except 10 K/min, the hardness decreases with decreasing cooling rate.展开更多
The hydrodynamic effects of molten surface of titanium alloy on the morphology evolution by intense pulsed ion beam (IPIB) irradiation are studied. It is experimentally revealed that under irradiation of IPIB pulses...The hydrodynamic effects of molten surface of titanium alloy on the morphology evolution by intense pulsed ion beam (IPIB) irradiation are studied. It is experimentally revealed that under irradiation of IPIB pulses, the surface morphology of titanium alloy in a spatial scale of μm exhibits an obvious smoothening trend. The mechanism of this phenomenon is explained by the mass transfer caused by the surface tension of molten metal. Hydrodynamic simulation with a combination of the finite element method and the level set method reveals that the change in curvature on the molten surface leads to uneven distribution of surface tension. Mass transfer is caused by the relief of surface tension, and meanwhile a flattening trend in the surface morphology evolution is achieved.展开更多
基金China Postdoctoral Science Foundation(2020M681125)National Natural Science Foundation of China(32272254,31901618)Collaborative Innovation Center of Fragrance Flavour and Cosmetics.
文摘Bio-based cyclodextrins(CDs)are a common research object in supramolecular chemistry.The special cavity structure of CDs can form supramolecular self-assemblies such as vesicles and microcrystals through weak interaction with guest molecules.The different forms of supramolecular self-assemblies can be transformed into each other under certain conditions.The regulation of supramolecular self-assembly is not only helpful to understand the self-assembly principle,but also beneficial to its application.In the present study,the self-assembly behavior of epoxy-β-cyclodextrin(EP-β-CD)and mixed anionic and cationic surfactant system(sodium dodecyl sulfate/dodecyltrimethylammonium bromide,SDS/DTAB)in aqueous solution was studied.Morphological and particle size characterization found that the SDS/DTAB@EP-β-CD complex,as the basic building unit,self-assembled into worm-like micelles at lower temperatures and vesicles at higher temperatures.Nuclear magnetic resonance(NMR)and Fourier transform infrared spectroscopy(FT-IR)analysis revealed that the driving force for the formation of vesicles and worm-like micelles was the hydrogen bonds between EP-β-CD molecules,while water molecules played an important role in promoting vesicle formation between SDS/DTAB@EP-β-CD units.Herein,the mechanism of the morphologic transformation of SDS/DTAB@EP-β-CD supramolecular aggregates induced by temperature was elucidated by exploring the self-assembly process,which may provide an excellent basis for the development of delivery carriers.
基金financially supported by the CRSRI Open Research Program (Grant No.CKWV20221007/KY)the National Natural Science Foundation of China (Grant No.51979172)+3 种基金Jiangsu Provincial Water Conservancy Technology Project (Grant Nos.2020002,2021025,and 2021029)Fundamental Research Funds for Central Public Welfare Research Institutes (Y223002)Innovation Team Project of Estuarine and Coastal Protection and Management (Grant No.Y220013)the Major Scientific Projects of the Ministry of Water Resources (Grant No.SKS-2022087)。
文摘In the last two decades,the Yangtze Estuary has undergone significant changes under the influence of reduced sediment inflow and estuary engineering.This study investigates the influence of floods and typhoons on sediment concentration and the morphological evolution of shoals and channels in the Yangtze Estuary.The analysis is conducted through the utilization of topographic data measured pre-and post-flood events and observations of hydro-sedimentary changes during typhoons.By using a generalized estuary mathematical model,this study examines the interplay between varying tidal ranges,tidal divisions,runoff volumes,and regulation projects on the erosion and deposition of shoals and channels in bifurcated estuaries.The results show that due to the implementation of river and waterway regulation projects,the impact of the 2020 flood on the main channel and shoal was significantly less than that of the1998 flood.The swing amplitude of the South Branch main channel decreased.However,local river sections such as the Southern Waterway of Baimao Shoal exhibited erosion.During typhoons,sediment concentration in the 20 cm above the bottom increased significantly and was closely related to wave processes,with a weakened correlation to tidal dynamics.After typhoons,high shoals in South Passage above 0 m were silted up,while the terrain on one side of the tail of Jiuduan Shoal in the downstream deep-water area was generally scoured due to strong wave action.The generalized mathematical model of the bifurcated estuary revealed that M2 tidal component contributed most to the ero sion and deposition evolution of estuary shoals and channels,with floods exhibiting characteristics of sedime ntation on shoals and erosion on channels.With the implementation of a branch rectification project,branch resistance increased,diversion decreased,and the riverbed changed from pre-project erosion to post-project sedimentation,with an increase in erosion in non-project branches.
基金The National Natural Science Foundation of China under contract Nos 41876205,42106169 and 41890851the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)under contract Nos GML2019ZD0305 and GML2019ZD0303the Project of State Key Laboratory of Tropical Oceanography under contract Nos LTOZZ2102 and LTOZZ2202.
文摘The morphology of the Modaomen Estuary(ME)has undergone drastic changes in recent decades,and quantifying the contribution of human activities and natural processes is crucial for estuary management.Using Landsat images,chart data,and hydrological and meteorological data,this study analyzed the evolution of the shoreline and subaqueous topography of the ME and attempted to quantify the extent of the contributions of human activities.The results show that local human activities dominated morphological evolution in some periods.From 1973 to 2003,the shoreline advanced rapidly seaward,resulting in approximately half of the water area being converted into land.Human activity is critical to this process,with the direct contribution of local land reclamation projects reaching more than 85%.After 2003,the shoreline remained relatively stable,probably due to a decrease in land reclamation projects.Regarding the evolution of subaqueous topography,the shoals in the estuary were heavily silted and gradually disappeared during 1983–2003,and the waterways narrowed and deepened.The average siltation rate decreased from 15.43 mm/a to-1.02 mm/a,indicating that the ME changed from sedimentation to slight erosion.By detecting variations of sediment load,we found that upstream human activities reduced river sediment,while downstream human activities significantly increased sediment input to the ME,leaving little change in the actual sediment input to the ME for a relatively long period.In addition,based on the empirical relationship between the sediment input and siltation rate,local human activities influenced the shift in the siltation state more than upstream and downstream human activities did.These findings suggest that more attention should be paid to local human activities to improve the estuarine management in the ME.
基金supported financially by the National Natural Science Foundation of China under contract Nos 40231010 and 40476041the Marine Science Youth Fund of State 0ceanic Administration of China under contract No.2006312.
文摘The tidal flats of the Wanggang area, on the Jiangsu coast, represent the largest continuously distributed coastal wetland in terms of area coverage in China, and the dynamics of tidal flat accretion and erosion is highly complicated. The cord-grass Spartina alterniflora, which was introduced artificially into the Jiangsu coast, has significant influences on the regional tidal flat evolution in terms of deposition rate, spacial sediment distribution patterns and tidal creek morphology. On the basis of the data set of bed elevation and accumulation rate for different periods of time, the applicability of the Pethick - Allen model to the Jiangsu tidal salt marshes is discussed. In addition, caesium-137 dating was carried out for sediment samples collected from the salt marsh of the Wangang area. In combination with the caesium-137 analysis and the data collected from literature, the Pethick - Allen model was used to derive the accumulation rate in the Wanggang tidal flat for the various periods. The results show that the pattern of tidal flat accretion has been modified, due to more rapid accretion following the iatroduction of S. alterniflora to the region. Surficial sediment samples were collected from representative profiles and analyzed for grain size with a laser particle analyzer. The result shows that fine-grained sediment has been trapped by the plant, with most of the sediment deposited on the Suaeda salsa and Spartina angelica flats being derived from drainage creeks rather than the from gently sloping tidal flats. Remote sensing analysis and in situ observations indicate that the creeks formed in the S. alterniflora flat have a relatively small ratio of width to depth, a relatively high density, and are more stable than the other tidal flat creek systems in the study area.
基金funded by the Program of International S&T Cooperation(Grant No.2010DFA24470)the Non-profitable Special Scientific Research Project from the Ministry of Water Resources,China(Grant No.200901034–01)
文摘Owing to the intensive human activities, the Modaomen Estuary has been significantly modified since 1950s, which has resulted in considerable changes of hydrodynamics and morphodynamics in the area. In this paper, the effects of the anthropogenic activities on the hydrodynamics and morphological evolution in the estuary at different stages are systematically assessed based on the detailed bathymetric data and field survey. The results show that the human activities have caused the channelization of the enclosed sea area in the Modamen Estuary;fast seaward movement of the mouth bar with high siltation;expansion of the channel volume due to channel deepening. The paper also highlights the main hydrodynamic changes in the estuary, including the rise of the water level;the distinguishing changes of tidal range before and after the 1990s (decrease and increase respectively); as well as the increase of the divided flow ratio. It is found that reclamation is the main factor promoting the transition of nature of the estuary from runoff dominant to runoff and wave dominant, and sand mining activities are mainly to strengthen the tidal dynamic and to low the water level. The results provide useful guidance for better planning of the future developments in the estuary and further research in the area.
基金the financial support from The National Key Research and Development Program of China(2018YFB0104200)。
文摘Solid-liquid phase conversion between various sulfur species in lithium-sulfur(Li-S)batteries is a fundamental reaction of the sulfur cathode.Disclosing the morphological evolution of solid sulfur species upon cycling is of great significance to achieving high energy densities.However,an in-depth investigation of the internal reaction is still lacking.In this work,the evolution process of solid sulfur species on carbon substrates is systematically studied by using an operando light microscope combined with in situ electrochemical impedance spectra technology.The observation of phenomena such as bulk solid sulfur species can form and dissolve independently of the conductive substrates and the transformation of supercooled liquid sulfur to crystalline sulfur.Based on the phenomena mentioned above,a possible mechanism was proposed in which the dissolution reaction of solid sulfur species is a spatially free reaction that involves isotropic physical dissolution,diffusion of molecules,and finally the electrochemical reaction.Correspondingly,the formation of solid sulfur species tends to be a form of crystallization in a saturated solution rather than electrodeposition,as is commonly believed.Our findings offer new insights into the reaction of sulfur cathodes and provide new opportunities to design advanced sulfur cathodes for Li-S batteries.
基金The National Natural Science Foundation of China under contract Nos 41676085 and 42176170the Zhejiang Provincial Hydraulic Science and Technology Planning Project under contract No.RB2033the Zhejiang Provincial Natural Science Foundation of China under contract No.LY16D060004.
文摘A large sand bar develops in the inner Qiantang River Estuary,China.It is a unique sedimentary system,elongating landwards by about 130 km.Based on long-term series of bathymetric data in each April,July,and November since the 1960s,this study investigated the morphological behavior of this bar under natural conditions and the influence of a large-scale river narrowing project(LRNP)implemented in the last decades.The results show that three timescales,namely the seasonal,interannual and decadal timescales,can be distinguished for the sand bar evolution.The first two are related to the seasonal and interannual variations of river discharge.During high discharge seasons or years,erosion took place at the upper reach and sedimentation at the lower reach.Consequently,the bar apex shifted seaward.The opposite development took place during low discharge seasons or years.The decadal timescale is related to LRNP.Due to the implementation of LRNP,the upper reach has experienced apparent erosion and currently a new equilibrium state has been reached;whereas the lower reach has been accumulated seriously and the accumulation still continues.Nonlinear relationships for how the bar apex location and elevation depend on the river discharge over various stages of LRNP have been established.Compared with the earlier stage of LRNP,the bar apex at present has shifted seaward by about 12 km and lowered by about 1 m.The sand bar movement has significant feedback on the hydrographic conditions along the estuary and has practical implications for coastal management.
基金The project supported by the National Outstanding Young Investigator Grant of China (59925104)the National Natural Science Foundation of China (59889101)
文摘Micron-sized internal cracks were introduced into rounded bars of pure iron by low cycle fatigue,and the cracks had irregular penny-shaped morphology with the critical diameter of about 30μm and the thickness of 0.5~1.5μm.The initi- ation and propagation of the cracks were investigated quantitatively as well as their location and geometry.After vacuum annealing of the samples fatigued,the mor- phology in a two-dimensional longitudinal section of cracks within grains had evolved from initially elliptical one into arrays of spherical voids controlled by surface diffu- sion.Furthermore,a typical morphology for a broken crack with a center spherical void surrounded by outer doughnut-like cavities was observed along a perpendicu- lar section of the specimen.Subsequently the spherical voids shrink and diminish gradually dominated by bulk diffusion.A physical model to heal an internal micro- crack was proposed,in particular for the various healing stages controlled by the related dominant diffusion mechanism and their dependencies upon the morphology and geometry of an original micro-crack in materials.
基金Funded by the International Cooperation Project of Hubei Province (2006CA014)
文摘Novel Nb2O5 nanorods and polygonal Nb2O5 platelets were generated by a simple solvothermal technique. The geometry evolution of the resultant Nb2O5 from amorphous nanoparticles to crystallized particles, from polygonal platelets to well-elongated nanorods was been studied in detail. The processing parameters, including the reaction temperature, reaction time, concentration of the precursors, and pH value of the solution, which affect the shape and size of the nanorods, were investigated. The Nb2O5 nanorods with different aspect ratios were examined by XRD, SEM and TEM. The experimental results show that Nb2O5 nanorod is the orthorhombic structure and well-crystallized. The growth of the nanorods follows their [001] direction. The successful generation of high quality Nb2O5 nanorods is not only important for transition metal oxide research, but also potentially important for further formation of new Nb-based 1-D nanostructures, such as NbS2 and NbN.
文摘Since the reform and opening up,Shenzhen has experienced rapid urbanization.Modern urban landscape has replaced the original traditional village landscape,followed by the loss of urban features and the demise of traditional villages.To change the phenomenon,with the help of town plan analysis method,the historical process of urban material form is looked back on.Combining the theory of evolution mechanism of urban spatial structure,and taking Hubei Village which is the only traditional village in the central district of Shenzhen as an example,the characteristics and causes of evolution of traditional villages in Shenzhen in different periods are analyzed,and the evolution characteristics of plane pattern are summarized.Moreover,the power source and characteristics of urban renewal in Shenzhen are pointed out from the perspective of government,market and social force,and the focus of promoting the renewal of traditional villages in the future is explored.
基金Supported by the National Natural Science Foundation of China under Grant No 61204006the Fundamental Research Funds for the Central Universities under Grant No K50511250002
文摘Effects of the growth temperature on morphological and microstructural evolution of a-plane GaN films grown on r-plane sapphires by metal organic chemical vapor deposition are investigated by atomic force microscopy and secondary ion mass spectroscopy (SIMS). Surface morphology, structural quality and related impurity incorpora- tion are very sensitive to the growth temperature. A significant difference of yellow luminescence is observed and attributed to the incorporation of carbon into GaN films, which is confirmed by SIMS analysis. Our results show that the sample with triangular-pit morphology has sample with pentagon-like pit morphology, which is significantly higher concentrations of oxygen than the other induced by the existence of an N-face in triangular pits.
基金The National Natural Science Foundation of China under contract Nos 41930538,42076211 and 42076058the Scientific Research Foundation of the Third Institute of Oceanography,Ministry of Natural Resources under contract Nos 2022017 and 2019006the China Postdoctoral Science Foundation under contract No.2019M652248.
文摘The clay mineralogy of 28 sandy-muddy transitional beach(SMT-Beach)sediments and surrounding mountain river sediments along the coasts of southeastern China was systematically investigated to reveal the sediment source-to-sink process variations of such beaches and their morphological indications.The results show that the clay mineral assemblages of these SMT-Beaches mainly comprise of almost equal illite(~30%),kaolinite(~28%),chlorite(~22%),and smectite(~20%)contents.From the surrounding mountain rivers to the SMT-Beaches,clay mineral assemblages show distinct spatial changes characterized by a large decrease(~40%)in kaolinite,whereas the other three clay minerals present relative increases,especially clear for smectite.The muddy sediment sources of SMT-Beaches inferred from the clay mineralogy are mainly derived from nearby mountain rivers coupled with long-distance transport and penetration of the Changjiang River.The sandy sediments of these beaches are predominantly sourced from nearby mountain rivers,the weathering products of surrounding rocks in both mainland and island environments,and erosion of the“Old Red Sand”and“Red Soil Platform”.However,the sandy sediment sources of the SMT-Beaches are largely reduced because of the remarkable decrease in the river fluvial supply associated with intensive human activities such as dam construction and coastal reclamation.Subsequently,the sandy sections of SMT-Beaches present clear erosion and have revealed by both time series remote sensing images and a compilation of published literature.In contrast,the muddy sediment supply of SMT-Beaches is temporarily stable and relatively constant,resulting in the landward migration of the mudflats with relative transgression or accumulation.These findings highlight that the natural evolution processes of SMT-Beaches have been greatly reshaped by intensive human activities.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.21361010 and 22065014)the National Innovation Training Program(Grant No.202210407024)+1 种基金the Natural Science Foundation of Jiangxi Province(Grant No.20171BAB206001)the Education Department of Jiangxi Province(Grant No.GJJ190433).
文摘Zinc-based flow battery is an energy storage technology with good application prospects because of its advantages of abundant raw materials,low cost,and environmental friendliness.The chemical stability of zinc electrodes exposed to electrolyte is a very important issue for zinc-based batteries.This paper reports on details of chemical stability of the zinc metal exposed to a series of solutions,as well as the relationship between the morphological evolution of zinc electrodes and their properties in an alkaline medium.Chemical corrosion of zinc electrodes by the electrolyte will change their surface morphology.However,we observed that chemical corrosion is not the main contributor to the evolution of zinc electrode surface morphology,but the main contributor is the Zn/Zn^(2+)electrode process.The morphological evolution of zinc electrodes was controlled by using ionic liquids,1-ethyl-3-methylimidazolium acetate(EMIA),and 1-propylsulfonic-3-methylimidazolium tosylate(PSMIT),and the electrode performance was recorded during the morphological evolution process.It was observed that the reversible change of zinc electrode morphology was accompanied by better electrode performance.
基金the National Natural Science Foundation of China (No. 50571081)the Aviation Foundation of China (No. 04G53024).
文摘A petal-like icosahedral quasicrystal with five branches,which is considered to be the representative morphology of the icosahedral quasicrystal,has been observed in the Y-rich Mg-Zn-Y ternary alloys. Moreover,the polygon-like morphology,another pattern of the icosahedral quasicrystal,has also been found in the Y-rich Mg-Zn-Y ternary alloys. The latter morphology results from the evolution of the former one. The growth mechanism of the petal-like morphology of the icosahedral quasicrystal was also discussed. Alloying composition,i.e.,Y element content,is a major factor inducing the morphology evolution of the icosahedral quasicrystal.
基金The National Natural Science Foundation of China under contract No.40266001
文摘The feedback between morphological evolution and tidal hydrodynamics in a wave-dominated tidal inlet, Xiaohai, China is investigated through data analysis and numerical model experiments. Historically, Xiaohai Inlet had two openings, located at the north and south of Neizhi Island (a rocky outcrop), respectively. The evolution of Xiaohai Inlet was dominated by the natural process before 1972. In addition to the natural process, human interventions, including the closure of the north opening, 50% of freshwater reduction, and increase of land reclamation, have altered tidal hydrodynamics and morphological evolution since 1972. A series of numerical model simulations were conducted to investigate the influence of morphological changes on the hydrodynamics and the influence of human activities on the inlet evolution. The natural process has caused narrowing and shoaling of the inlet throat, development of the flood-tidal delta, and shoaling of the tidal channel inside the lagoon. Human interventions have accelerated these changes. Consequently, the tidal propagation from the offshore into the lagoon has been impeded and the tidal energy has been dissipated substantially. Tidal current has changed from ebb-dominant to flood-dominant in most parts of the inlet system whereas the inlet throat has remained as ebb-dominant, the tidal prism has decreased consistently, and sediment has continued to deposit inside the inlet. As a result, the changes of morphology, hydrodynamics, and sediment transport show a positive feedback. The human interventions have had both advantageous and adverse influences on the stability of the inlet. The closure of the North Opening has decreased the longshore sediment input to the inlet, and increased the tidal prism, ebb velocity, and sediment transport in the south opening, thus enhancing the inlet's stability. However, reducing the river discharge and landfill of the tidal flats has resulted in a decrease of the tidal prism, the ebb velocity, and the ability to export sediment, thus having the tendency to deteriorate the inlet's stability. A stability analysis based on a closure curve methodology has shown that Xiaohai Inlet is in a state of dynamic equilibrium at present.
基金supported by the National Natural Science Foundation of China (Grant No.50571081)the Aeronautical Science Foundation of China (Grant No.04G53042)
文摘The microstructure, chemical composition and morphology evolution of icosahedral quasicrystalline phase of Mg67.4Zn28.9Y3.7 ternary alloy were investigated in detail at different pouring temperatures by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy-dispersive spectrum (EDS). Low interracial energy favors the formation of l-phase. The experimental results show that the primary l-phase reveals petal-shaped with five and six branches, where each branch has facetted growth morphology with the size ranging from 50 to 100μm. As the temperature decreases, the polygon-shaped l-phase forms, attributed to the decomposition of branch of petal-shaped l-phase, and then it grows bigger and some of the fine polygons join together to form large polygons. Besides these, (α-Mg+l-phase) eutectic structures disappear and the relative amount of Mg7Zn3 phase increases as the pouring temperature decreases. The chemical composition and morphology evolution of l-phase were also discussed.
文摘The morphology evolution of Al9(Mn,Ni)2 eutectic phase in Al-4 Ni-2 Mn alloy at 350 °C was examined. Two kinds of morphology evolution trends of Al9(Mn, Ni)2 eutectic phase were observed by using scanning electron microscopy and transmission electron microscopy. The ribbon-like Al9(Mn, Ni)2 eutectic phase taking up a small portion of the eutectic structures gradually changes from ribbon-like morphology to rod-like during the heat treatment. The rod-like Al9(Mn, Ni)2 eutectics, primary eutectic structure in the alloy, become unstable at the transverse subboundaries of the eutectic rod when the samples are heat treated at 350 °C, and then split up into short rods with the extension of heat treatment time. Also, the Vickers microhardness test was used to characterize the change of local mechanical properties. The hardness test results indicate that local morphology evolution of eutectic phase has no obvious effect on the local mechanical properties of the alloy. The microhardness of the eutectic area increases slightly when the heat treatment time is extended to 192 h or 360 h.
基金Sponsored by National Natural Science Foundation of China(51368023)
文摘Influence of tourism on society,economy and culture of traditional villages is shown gradually by physical form,promoting the evolution of villages into small towns. Based on the perspective of morphology,the changing features of physical and social spatial form of three typical regions(Xizhou Village and its surrounding areas,Zhoucheng Village and its surrounding areas,and Renliyi Village) in Xizhou Town of Dali City during 1985-2010 were analyzed; the roles of tourism during the evolution process of villages into small towns were discussed; the evolution features of villages into small towns were summarized. It is concluded that tourism and economy related to tourism have played important roles in the enhancement of cohesion degree of an aggregation nucleus and have promoted the evolution process of vilages into small towns.
基金Funded by the National Natural Science Foundation of China(No.2010DFB70630)
文摘Quenching experiments were performed at different cooling rates under non-directional solidification by differential thermal analysis, and the morphologic variation of primary phase, phase transition temperature and hardness change at the same quenching temperature were investigated. The experimental results show that, with the gradual decrease of the cooling rate from 25 K/min, the morphology of ferrite starts to transform experiencing the dendrite, radial pattern, Widmanstatten-like and wire-net. Sample starts to present the Widmanstatten-like microstructure at 10 K/min which does not exist at higher or lower cooling rates, and this microstructure is detrimental to the mechanical property. Except 10 K/min, the hardness decreases with decreasing cooling rate.
基金Supported by the National Natural Science Foundation of China under Grant No 1175012the China Postdoctoral Science Foundation under Grant No 2016M600897the National Science and Technology Major Project of the Ministry of Science and Technology of China under Grant No 2013ZX04001-071
文摘The hydrodynamic effects of molten surface of titanium alloy on the morphology evolution by intense pulsed ion beam (IPIB) irradiation are studied. It is experimentally revealed that under irradiation of IPIB pulses, the surface morphology of titanium alloy in a spatial scale of μm exhibits an obvious smoothening trend. The mechanism of this phenomenon is explained by the mass transfer caused by the surface tension of molten metal. Hydrodynamic simulation with a combination of the finite element method and the level set method reveals that the change in curvature on the molten surface leads to uneven distribution of surface tension. Mass transfer is caused by the relief of surface tension, and meanwhile a flattening trend in the surface morphology evolution is achieved.