Generalized two-dimensional correlation spectroscopy （2DCOS） and its derivate technique, perturbation correlation moving window （PCMW）, have found great potential in studying a series of physico-chemical phenomena...Generalized two-dimensional correlation spectroscopy （2DCOS） and its derivate technique, perturbation correlation moving window （PCMW）, have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension, 2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes, especially in infrared （IR）, near-infrared （NIR） and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing, PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers, mainly focused on liquid crystalline polymers and lower critical solution temperature （LCST）-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level, which contribute to the understanding of their phase transition nature.展开更多
应用太赫兹时域光谱技术结合移动窗口相关系数法筛选与种子老化密切相关的太赫兹特征波段。选取3个不同品种的玉米种子,并制备人工老化0、1、2、3、4 d的实验样本,采用衰减全反射(Attenuated total reflection,ATR)附件采集从样本分离...应用太赫兹时域光谱技术结合移动窗口相关系数法筛选与种子老化密切相关的太赫兹特征波段。选取3个不同品种的玉米种子,并制备人工老化0、1、2、3、4 d的实验样本,采用衰减全反射(Attenuated total reflection,ATR)附件采集从样本分离得到的种胚和胚乳粉末的太赫兹吸光度谱(0.2~80 cm^-1),应用移动窗口相关系数法(窗口宽度为10,阈值为0.3)筛选样本种胚和胚乳特征谱区。结果表明,不同品种样本筛选得到的老化特征谱区差异显著,说明种子老化进程受品种影响较大;在相同的老化阶段,不同品种样本的特征谱区也存在部分共同区间,且主要集中在60~80 cm^-1,说明老化进程中有些成分的变化相近;种胚和胚乳在相同老化阶段筛选的特征谱区不同,说明两者在老化进程中生理变化存在差异。本研究表明太赫兹时域光谱结合化学计量学方法可用于快速表征并探测玉米种子老化的动态变化过程。展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.21274030,51473038 and 21604024)the Natural Science Foundation of Shanghai(No.17ZR1440400)+1 种基金the Open Project of State Key Laboratory of Chemical Engineering(No.SKL-Ch E-16C02)“Chenguang Plan”
文摘Generalized two-dimensional correlation spectroscopy （2DCOS） and its derivate technique, perturbation correlation moving window （PCMW）, have found great potential in studying a series of physico-chemical phenomena in stimuli-responsive polymeric systems. By spreading peaks along a second dimension, 2DCOS can significantly enhance spectral resolution and discern the sequence of group dynamics applicable to various external perturbation-induced spectroscopic changes, especially in infrared （IR）, near-infrared （NIR） and Raman spectroscopy. On the basis of 2DCOS synchronous power spectra changing, PCMW proves to be a powerful tool to monitor complicated spectral variations and to find transition points and ranges. This article reviews the recent work of our research group in the application of 2DCOS and PCMW in thermoresponsive polymers, mainly focused on liquid crystalline polymers and lower critical solution temperature （LCST）-type polymers. Details of group motions and chain conformational changes upon temperature perturbation can thus be elucidated at the molecular level, which contribute to the understanding of their phase transition nature.
