Cathode activity plays an important role in the improvement of the microbial fuel cells on ocean floor （BMFCs）. A comparison study between Rayon-based （CF-R） and PAN-based carbon fiber （CF-P） cathodes is conduct...Cathode activity plays an important role in the improvement of the microbial fuel cells on ocean floor （BMFCs）. A comparison study between Rayon-based （CF-R） and PAN-based carbon fiber （CF-P） cathodes is conducted in the paper. The two carbon fibers were heat treated to improve cell performance （CF-R-H ＆ CF-P-H）, and were used to build a new BMFCs structure with a foamy carbon anode. The maximum power density was 112.4mWm-2 for CF-R-H, followed by 66.6mWm-2 for CF-R, 49.7 mWm-2 for CF-P-H and 21.6mWm-2 for CF-P respectively. The higher specific area and deep groove make CF-R have a better power output than with CF-P. Meanwhile, heat treatment of carbon fiber can improve cell power, nearly two-fold higher than heat treatment of plain fiber. This improvement may be due to the quinones group formation to accelerate the reduction of oxygen and electron transfer on the fiber surface in the three phase boundary after heat treatment. Compared to PAN-based carbon fiber, Rayon-based carbon fiber would be preferentially selected as cathode in novel BMFCs design due to its high surface area, low cost and higher power. The comparison research is significant for cathode material selection and cell design.展开更多
Microbial fuel cell(MFC) on the ocean floor is a kind of novel energy-harvesting device that can be developed to drive small instruments to work continuously.The shape of electrode has a great effect on the performanc...Microbial fuel cell(MFC) on the ocean floor is a kind of novel energy-harvesting device that can be developed to drive small instruments to work continuously.The shape of electrode has a great effect on the performance of the MFC.In this paper,several shapes of electrode and cell structure were designed,and their performance in MFC were compared in pairs:Mesh(cell-1) vs.flat plate(cell-2),branch(cell-3) vs.cylinder(cell-4),and forest(cell-5) vs.disk(cell-6) FC.Our results showed that the maximum power densities were 16.50,14.20,19.30,15.00,14.64,and 9.95 mWm-2 for cell-1,2,3,4,5 and 6 respectively.And the corre-sponding diffusion-limited currents were 7.16,2.80,18.86,10.50,18.00,and 6.900 mA.The mesh and branch anodes showed higher power densities and much higher diffusion-limited currents than the flat plate and the cylinder anodes respectively due to the low diffusion hindrance with the former anodes.The forest cathode improved by 47% of the power density and by 161% of diffusion-limited current than the disk cathode due to the former's extended solid/liquid/gas three-phase boundary.These results indicated that the shape of electrode is a major parameter that determining the diffusion-limited current of an MFC,and the differences in the elec-trode shape lead to the differences in cell performance.These results would be useful for MFC structure design in practical applica-tions.展开更多
Extensive oedometer tests and physical tests have been conducted on remolded and reconstituted marine soils with different initial water contents and liquid limits. The oedometer test data can be well fitted with a st...Extensive oedometer tests and physical tests have been conducted on remolded and reconstituted marine soils with different initial water contents and liquid limits. The oedometer test data can be well fitted with a straight line in the bilogarithmic ln(1+ e ) ～ lg p plot. The initial effective stress corresponding to the initial void ratio is determined by extrapolation of the bilogarithmic compression line. This new way of extrapolating oedometer test data to the initial void ratio overcomes the difficulty of measuring the residual effective stress of soils in the remolded state. The initial stable compression line of ocean floor deposits under different deposition environments corresponds to the compression line at the sensitivity equal to one. This initial stable compression line obtained in this study is consistent with the available compression line at the sensitivity equal to one which is proposed based on the experimental data of remolded undrained strength and the theoretical concept of Cam clay critical state line.展开更多
基金support by the Key Project of Nature Science Fund of Shandong Province, China (ZR2011B Z008)the Special Fund of Marine Renewable Energy from China’s State Oceanic Administration (GHME 2011GD04)
文摘Cathode activity plays an important role in the improvement of the microbial fuel cells on ocean floor （BMFCs）. A comparison study between Rayon-based （CF-R） and PAN-based carbon fiber （CF-P） cathodes is conducted in the paper. The two carbon fibers were heat treated to improve cell performance （CF-R-H ＆ CF-P-H）, and were used to build a new BMFCs structure with a foamy carbon anode. The maximum power density was 112.4mWm-2 for CF-R-H, followed by 66.6mWm-2 for CF-R, 49.7 mWm-2 for CF-P-H and 21.6mWm-2 for CF-P respectively. The higher specific area and deep groove make CF-R have a better power output than with CF-P. Meanwhile, heat treatment of carbon fiber can improve cell power, nearly two-fold higher than heat treatment of plain fiber. This improvement may be due to the quinones group formation to accelerate the reduction of oxygen and electron transfer on the fiber surface in the three phase boundary after heat treatment. Compared to PAN-based carbon fiber, Rayon-based carbon fiber would be preferentially selected as cathode in novel BMFCs design due to its high surface area, low cost and higher power. The comparison research is significant for cathode material selection and cell design.
基金supported by the Key Project of Natural Science Fund of Shandong Province (ZR2011BZ008)the Marine Renewable Energy Special Fund Project from the State Oceanic Administration PRC (GHME2011GD04)+2 种基金the Scientific and Technology Development Plan Project of Shandong Province,China (2008GG10007003)the Key Laboratory of Submarine Geoscience and Exploring Technology of the Ministry of Education,Ocean University of China (Grant No. 2008-01)the Key Laboratory of Marine Environment & Ecology,Ministry of Education (Grant No. 2008010)
文摘Microbial fuel cell(MFC) on the ocean floor is a kind of novel energy-harvesting device that can be developed to drive small instruments to work continuously.The shape of electrode has a great effect on the performance of the MFC.In this paper,several shapes of electrode and cell structure were designed,and their performance in MFC were compared in pairs:Mesh(cell-1) vs.flat plate(cell-2),branch(cell-3) vs.cylinder(cell-4),and forest(cell-5) vs.disk(cell-6) FC.Our results showed that the maximum power densities were 16.50,14.20,19.30,15.00,14.64,and 9.95 mWm-2 for cell-1,2,3,4,5 and 6 respectively.And the corre-sponding diffusion-limited currents were 7.16,2.80,18.86,10.50,18.00,and 6.900 mA.The mesh and branch anodes showed higher power densities and much higher diffusion-limited currents than the flat plate and the cylinder anodes respectively due to the low diffusion hindrance with the former anodes.The forest cathode improved by 47% of the power density and by 161% of diffusion-limited current than the disk cathode due to the former's extended solid/liquid/gas three-phase boundary.These results indicated that the shape of electrode is a major parameter that determining the diffusion-limited current of an MFC,and the differences in the elec-trode shape lead to the differences in cell performance.These results would be useful for MFC structure design in practical applica-tions.
文摘Extensive oedometer tests and physical tests have been conducted on remolded and reconstituted marine soils with different initial water contents and liquid limits. The oedometer test data can be well fitted with a straight line in the bilogarithmic ln(1+ e ) ～ lg p plot. The initial effective stress corresponding to the initial void ratio is determined by extrapolation of the bilogarithmic compression line. This new way of extrapolating oedometer test data to the initial void ratio overcomes the difficulty of measuring the residual effective stress of soils in the remolded state. The initial stable compression line of ocean floor deposits under different deposition environments corresponds to the compression line at the sensitivity equal to one. This initial stable compression line obtained in this study is consistent with the available compression line at the sensitivity equal to one which is proposed based on the experimental data of remolded undrained strength and the theoretical concept of Cam clay critical state line.
