New construction of mutually unbiased bases for odd-dimensional state space

We study the construction of mutually unbiased bases in Hilbert space for composite dimensions d which are not prime powers.We explore the results for composite dimensions which are true for prime power dimensions.We then provide a method for selecting mutually unbiased vectors from the eigenvectors of generalized Pauli matrices to construct mutually unbiased bases.In particular,we present four mutually unbiased bases in C^(15).

Research on the Construction and Development of Aesthetic Education Bases in Higher Education Institutions

In order to implement the national aesthetic education policy,it is essential to organically integrate relevant aesthetic education resources,promote interdisciplinary education,and carry out extracurricular practical activities centered on aesthetic education.Strengthening the foundation of aesthetic education theory,addressing practical challenges in the teaching process,and closely linking research with teaching will create a feedback loop that benefits drama education.This article provides an in-depth analysis of the construction strategies,resource advantages and disadvantages,and development of aesthetic education bases,offering countermeasures and suggestions for their construction in universities.It aims to provide a solid research foundation for the growth and development of aesthetic education bases in higher education institutions.

Homogenization Construction of Three-Level Teaching Bases for General Practice Medicine Under the Internet+Model

With the continuous expansion of medical student enrollment,the number of clinical teaching bases is gradually increasing.However,there are significant differences in clinical teaching management models and teaching levels among different bases.Most clinical teaching bases have incomplete teaching management systems,inadequate teaching management institutions,insufficient teaching personnel,and inadequate implementation of teaching rules and regulations.This article combines the construction practice of three-level clinical teaching base of the General Medicine College and the First Affiliated Hospital of Xi’an Medical University.We establish a standardized management system for the three-level clinical teaching base;implement a teaching supervision system and strengthen the monitoring of teaching quality;adopt multiple evaluations to test the effectiveness of clinical teaching implementation;explore the path of homogenization construction of teaching bases in terms of unified teacher training,promoting the development of teacher teaching abilities with equal quality and excellence,and providing a reference for improving the quality of medical talent training.

Schiff bases及配合物的研究进展

希夫碱配体及与后过渡金属元素所形成的配合物,以其多样的结构和广泛的用途愈来愈受到人们的重视。文章综述了Schiff base配体及配合物的发展状况以及在生物化学、催化化学、分析化学、材料化学等方面的研究与应用,并指出了它的美好前景。

5-硝基水杨醛氨基酸Schiff-bases铜配合物与DNA相互作用的研究

用电子光谱、荧光淬灭光谱和循环伏安的方法,研究了(苯丙氨酸缩5-硝基水杨醛)铜(1)和(组氨酸缩5-硝基水杨醛)铜(2)与 DNA 的作用.结果表明,配合物均以插入模式与 DNA 作用;配合物与 DNA 作用强弱为:配合物(2)>配合物(1).

脱氢枞胺水杨醛类席夫碱(Schiff Bases)对铜离子萃取性能的研究

合成5种脱氢枞胺水杨醛类Schiff碱,对其萃取铜离子的影响因素进行研究,并与萃取剂N902对电镀废水中铜离子的萃取性能进行了比较。结果表明:萃取温度和萃取时间对铜离子萃取率的影响不明显,萃取温度在20～30℃、萃取时间为2 h就能达到萃取平衡;大部分Schiff碱在低pH范围内对铜离子的萃取效果不理想,在高pH范围内有较好的萃取性能。DHAA 2,3,4-三羟基苯甲醛的萃取效果与N902相当。

Spaces with σ-locally Countable Weak Bases

In this paper, by msss_mappings, the relations between metric spaces and spaces with σ _locally countable cs_networks or spaces with σ _locally countable weak bases are established. These are some answers to Alexandroff’s problems.

Synthesis and Biological Activities of Some Mannich Bases of 5-(4-Hydroxyphenyl)-1,3,4-Oxadiazole-2-Thione

以对羟基苯甲酸乙酯为原料，经肼解、环化合成５（４羟基苯基）１，３，４二唑２硫酮，继而经Ｍａｎｎｉｃｈ反应合成了四种新曼尼希碱，其结构经红外光谱、核磁共振和元素分析证实。初步抑菌活性试验表明，显示弱的抑菌活性。

Synthesis of New Schiff Bases Containing Thiophene Moiety

Seven new Schiff bases, which are 4,4,4-trifluo-ro-1-(2-thienyl)-1-butanone-3-Z, Z =-thioseraicarbazone (a); -thiocarbohydrazone (b),-benzoic hydrazone (c), -( o-hydroxyphenyl) imine (d) ,-nicotinic hydrazone (e),-salicylic hydrazone (f), and -(p-fluoro-m-chlorophenyl) imine (g), have been synthesized by reaction of 4, 4, 4-trifluoro-1-(2-thienyl)-1,3-butanedione (TFTBD) with corresponding hy-drazides or anilines, acetic acid or p-toluence sulfonic acid as catalyst, and characterized by Elemental analysis, IR, UV-Vis,1H NMR and MS. The MS spectra confirmed that the -C3=O condensed with primary amino group. Tauto-merism of the compounds is discussed.

The Evolution of Regional Economic Resilience in the Old Industrial Bases in China: A Case Study of Liaoning Province, China

The economic transformation of the old industrial bases is a key research topic among geographers in China.In this paper,we propose that the concept of regional economic resilience(RER)has unique theoretical value in analyzing the economic transformation of the old industrial bases.We constructed an analytical framework and an index system and applied the conceptual tools to study the evolution of RER in the old industrial base of Liaoning Province in China,which is currently subjected to not only sudden shocks but‘slow burn’—longer term processes of change that may nevertheless affect the regional economy.There are four main findings:first,the evolution of RER in Liaoning can be divided into four stages from 2000 to 2015.Liaoning is currently in its conservation-release period,and the next stage will be a release-reorganization period.Second,the RER of the majority of the studied cities is lower than the average value for Liaoning,and this is mainly attributed to the relatively weak vulnerability-resistance and adaptability-transformation capacity of these cities.Third,the RER levels of the 14 cities in Liaoning differ significantly.At the first level is Shenyang and Dalian,at the second level is Dandong and Yingkou,and the third level comprises the remaining cities.Fourth,regional economic resilience is mainly determined by vulnerability-resistance,which indirectly reflects Liaoning’s lack of adaptability-transformation capacity,and the ability of the region to renew or create a new development path is weak.

Reaction of Nitrosonium (NO^+) with Schiff Bases

The reaction of nitrosonium (NO+) with Schiff bases produced diazonium salts and aldehydes in good yield. The reaction is assumed to be an electrophilic reaction of nitrosonium with imines via a four-member ring intermediate.

Dioxygen Affinity and Catalytic Performance of Bis-(furaldehyde) Schiff Bases Co(II) Complexes in Cyclohexene Oxidation

Oxygenation constants and thermodynamic parameters DeltaH degrees and DeltaS degrees of cobalt (II) complexes with bis-(furaldehyde) Schiff bases (1, 2, 3, 4)were obtained by mearsuring saturated dioxygen uptake of these complexes in pyridine at different temperature. These complexes could activate molecular oxygen and were used as catalysts in cyclohexene oxidation. The influence of ligand structure on the dioxygen affinity and catalytic activity of the complexes were discussed.

Synthesis, Structural Features and Evaluation of Antibacterial Activities of Two Schiff Bases Derived from 3,4-Dihydroxybenzhydrazide

A new Schiff base compound （I）, （E）-N＇-（2-hydroxy-3-methoxybenzylidene）-3,4-dihydroxybenzohydrazide-ethanol-water （1/1/1）, has been synthesized and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 7.459（4）, b = 18.316（10）, c = 13.638（7）, β = 101.585（9）o, V = 1825.2（17）3, Z = 4, μ = 0.104 mm-1, Dc = 1.333 g/cm3, F（000） = 776, the final R = 0.0635 and wR = 0.1302 for 3216 observed reflections with I 〉 2σ（I）. Another compound （Ⅱ）, （E）-N＇-（2,5-dimethoxybenzylidene）-3,4-dihydroxybenzohydrazide-ethanol-water （1/1/1）, has been synthesized and reported before. The antibacterial activities of these two compounds against seven bacteria were first evaluated, and one compound showed considerable antibacterial activity against S. aureus.

Synthesis of Schiff bases of naphtha[1,2-d]thiazol-2-amine and metal complexes of 2-(2'-hydroxy)benzylideneaminonaphthothiazole as potential antimicrobial agents

Objective： A series of 2-benzylideneaminonaphthothiazoles were designed and synthesized incorporating the lipophilic naphthalene ring to render them more capable of penetrating various biomembranes. Methods： Schiff bases were synthesized by the reaction of naphtha[1,2-d]thiazol-2-amine with various substituted aromatic aldehydes. 2-（2＇-Hydroxy）ben- zylideneaminonaphthothiazole was converted to its Co（Ⅱ）, Ni（Ⅱ） and Cu（Ⅱ） metal complexes upon treatment with metal salts in ethanol. All the compounds were evaluated for their antibacterial activities by paper disc diffusion method with Gram positive Staphylococcus aureus and Staphylococcus epidermidis and Gram negative Escherichia coli and Pseudomonas aeruginosa bacteria. The minimum inhibitory concentrations of all the Schiff bases and metal complexes were determined by agar streak dilution method. Results： All the compounds moderately inhibited the growth of Cram positive and Gram negative bacteria. In the present study among all Schiff bases 2-（2＇-hydroxy）benzylideneaminonaphthothiazole showed maximum inhibitory activity and among metal complexes Cu（Ⅱ） metal complex was found to be most potent. Conclusion： The results obtained validate the hypothesis that Schiff bases having substitution with halogens, hydroxyl group and nitro group at phenyl ring are required for the antibacterial activity while methoxy group at different positions in the aromatic ring has minimal role in the inhibitory activity. The results also indicated that the metal complexes are better antibacterial agents as compared to the Schiff bases.

Canonical Transformations, Quantization, Mutually Unbiased and Other Complete Bases

Using ideas based on supersymmetric quantum mechanics, we design canonical transformations of the usual position and momentum to create generalized “Cartesian-like” positions, W, and momenta, Pw , with unit Poisson brackets. These are quantized by the usual replacement of the classical , x Px by quantum operators, leading to an infinite family of potential “operator observables”. However, all but one of the resulting operators are not Hermitian (formally self-adjoint) in the original position representation. Using either the chain rule or Dirac quantization, we show that the resulting operators are “quasi-Hermitian” relative to the x-representation and that all are Hermitian in the W-representation. Depending on how one treats the Jacobian of the canonical transformation in the expression for the classical momentum, Pw , quantization yields a) continuous mutually unbiased bases (MUB), b) orthogonal bases (with Dirac delta normalization), c) biorthogonal bases (with Dirac delta normalization), d) new W-harmonic oscillators yielding standard orthonormal bases (as functions of W) and associated coherent states and Wigner distributions. The MUB lead to W-generalized Fourier transform kernels whose eigenvectors are the W-harmonic oscillator eigenstates, with the spectrum (±1,±i) , as well as “W-linear chirps”. As expected, W,?Pw satisfy the uncertainty product relation: ΔWΔPw ≥1/2 , h=1.

Agricultural Ecological Zoning Plan of Old Industrial Bases in Liaoning Province, China

On the basis of brief description of current situation of old industrial bases and primary industry of Liaoning Province, the paper introduces the general situation of agriculture-ecological zoning plan in Liaoning Province. First, the ecological bases of agricultural zoning plan are introduced through various topographic and geomorphic types, regional climate differences and imbalanced distribution of natural resources; Second, in accordance with the theory of comparative advantage, distribution of production and resource economics, on the basis of comprehensive evaluation of agricultural natural resources, with the principle of fully excavating economic function of different natural resources, and in order to improve allocation efficiency of the two resources of market and government, the formation of ecological zoning plan of agriculture in Liaoning Province is analyzed; Third, according to Regional Layout Planning of Characteristic Agricultural Products of Liaoning Province (2006-2010), the paper describes basic layout of agriculture-ecological zoning plan in Liaoning Province. The policy support of agriculture-ecological zoning plan in Liaoning Province is analyzed from three aspects-support policy of functional zone major in producing grain, support policy of other characteristic agriculture-ecological zone and support measures of development of agriculture-ecological zone. The paper also analyzes experiences of agricultural development of old industrial bases in ecological zoning plan: First, agriculture-ecological zoning plan is a effective way of the revitalization of old industrial bases; Second, scientificity of plan is the basis of improving competitiveness of regional agriculture; Third, multi-input mechanism guiding by government is the key of agricultural packing effect; Fourth, integrated agricultural industrial chain is guarantee of realizing industrialization in ecological zone.

Synthesis of Pyridyl Polyheterocyclic Oxime-ether Schiff Bases Containing s-Triazole and Oxadiazole Subunits

4-Amino-5-pyridin-4-yl-s-triazole-3-thiol （1） was sequentally reacted with 3-chloro-1- phenylpropan-1-one to afford 3-（4-amino-5-pyridin-4-yl-s-triazole-3-sulfanyl）-1-phenylpropan-1- one （2） followed by oximation with hydroxylamine hydrochloride and etherification with 5-aryl-[13,4]oxadiazole-2-cbloromethanes to the corresponding oxime （3） and oxime-ethers （4a-e）, respectively. The condensation of compounds 4 with salicylaldehyde gave the title compounds （5a-e）. The antibacterial activity in vitro against Gram-postive （G^＋） and Gram negative （G） bacteria was primarily evaluated.

Acylhydrazide and Isatin Schiff Bases as Alternate UV-Laser Desorption Ionization (LDI) Matrices for Low Molecular Weight (LMW) Peptides Analysis

Matrix-assisted laser desorption/ionization (MALDI) is a preferred and widely used mass spectrometric technique for the analysis of macromolecules. Limited UV-LDI matrices are available for the analysis of biomolecules due to the restricted structural features to serve in the laser desorption/ionization mechanism with a problem of background signals appearing in the low mass region. This paper describes the application of Schiff base derivatives of acylhydrazide and isatin as alternate UV-LDI matrices for the analysis of peptides with significantly low background signals. Thirty one compounds have been successfully employed as matrices for the analysis of low molecular weight (LMW) peptides (α-Cyano-4-hydroxycinnamic acid (HCCA), a preferred choice for peptide analysis.

Synthesis and Characterization of New Schiff Bases Formed by Condensation of 2,9-Phenathroline-1,10-dialdehyde with Sulfur-Containing Amines

Four new Schiff bases of 1,10-phenanthroline-2,9-dicarboxaldehyde with sulfur-containing amines such as 2-mercaptoaniline, S-alkyl/aryl dithiocarbazates and thiosemicarbazide have been synthesized and characterized by spectroscopic and X-ray crystallographic techniques. A comparative study of the methods of synthesis has been made using both traditional and microwave techniques. A significant reduction in reaction time has been observed when the microwave method was used. In some of the reactions, the yields also increased significantly.

Antioxidative Effect of Schiff Bases with o-Hydroxybenzylidene Groupon Free Radical Induced Hemolysis of Human Red Blood Cell

The hemolysis of human red blood cells was initiated by a water soluble free radical initiator, 2,2′ azobis (2 amidinopropane hydrochloride)(AAPH), at 37 ℃ in phosphate buffered saline(pH=7.4). The respective addition of 1 [ N (o hydroxybenzylidene)amino]tetradecane(TDCA), 1,2 di[ N (o hydroxybenzylidene)amino]cyclohexane(DACH), 4 [ N (o hydroxybenzylidene)amino]benzoic acid(PABA), 4 nitro[ N (o hydroxybenzylidene)]aniline(APNA) or N (o hydroxybenzylidene)aniline(APA) can all prolong the inhibition period of hemolysis, indicating that the above Schiff bases play an antioxidative role in free radical induced hemolysis. It can be concluded that Schiff base with an alkyl group or a conjugated system in the molecule protect red blood cells against free radical induced hemolysis efficiently. This information may be useful for antioxidant drug design.