YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step mul...YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step multi-compositional oxidation by rapid heating oxidation mode is proposed to reduce the oxidation rate by 3.6 times compared to conventional slow heating oxidation mode.Results show that preferentially formed Y_(2)O_(3) oxide initiates a multi-step oxidation,produces a cracking and porous oxides,and thereby resulting in a fast oxidation with pesting.The one-step multi-compositional oxidation with a compact and dense Y_(2)Si_(2)O_(7)scale contributes to the much better oxidation resistance for rapid heating oxidation mode of YSi alloy.The stable formation of Y_(2)Si_(2)O_(7)scale is comprehensively understood by the energy barrier,charge density and electronic level based on density functional theory.This study demonstrates a promising application of YSi alloy by rapid heating oxidation mode.展开更多
基金financially supported by the Aero En-gine Corporation of China Industry-University-Research Coopera-tion Project(NO.HFZL2019CXY015)the Natural Science Foun-dation of Suzhou(No.SYG202103).
文摘YSi alloy is a promising candidate as oxidation resistant coatings for both the bond coat of environmental barrier coatings(EBCs)and anti-ablation coatings at a high temperature of∼1300℃.In this study,a one-step multi-compositional oxidation by rapid heating oxidation mode is proposed to reduce the oxidation rate by 3.6 times compared to conventional slow heating oxidation mode.Results show that preferentially formed Y_(2)O_(3) oxide initiates a multi-step oxidation,produces a cracking and porous oxides,and thereby resulting in a fast oxidation with pesting.The one-step multi-compositional oxidation with a compact and dense Y_(2)Si_(2)O_(7)scale contributes to the much better oxidation resistance for rapid heating oxidation mode of YSi alloy.The stable formation of Y_(2)Si_(2)O_(7)scale is comprehensively understood by the energy barrier,charge density and electronic level based on density functional theory.This study demonstrates a promising application of YSi alloy by rapid heating oxidation mode.
