Chemical dehydration coupling multi-effect evaporation to treat waste sulfuric acid in titanium dioxide production process

In order to concentrate the diluted sulfuric acid from the titanium dioxide(TiO2)production of sulphate process,a new concentration process was proposed by coupling chemical dehydration and multi-effect evaporation.The ferrous sulfate monohydrate(FeSO4·H2O),as the dehydrant,was added to the diluted sulfuric acid to form ferrous sulfate heptahydrate(FeSO4·7H2O)according to the H2SO4-FeSO4-H2O phase diagrams,which partially removes the water.This process was named as Chemical Dehydration Process.The residual water was further removed by two-effect evaporation and finally 70 wt%sulfuric acid was obtained.The FeSO4·H2O can be regenerated through drying and dehydration of FeSO4·7H2O.The results show that FeSO4·H2O is the most suitable dehydrant,the optimal reaction time of chemical dehydration process is 30 min,and low temperature is favorable for the dehydration reaction.45.17%of the entire removed water can be removed by chemical dehydration from the diluted sulfuric acid.This chemical dehydration process is also energy efficient with 24.76%saving compared with the direct evaporation process.Furthermore,51.21%of the FeSO4 dissolved originally in the diluted sulfuric acid are precipitated out during the chemical dehydration,which greatly reduces the solid precipitation and effectively alleviates the scaling in the subsequent multi-effect evaporation process.

Study on Multi-effect Time Parameters of Ergonomic Validity Index in Low-carbon Residential Kitchen

In the study on functional low-carbon ergonomic validity in buildings,ergonomic validity is different from resource validity which is easy for quantitative analysis. To eliminate the complexity and uncertainty impacts of human factors on quantitative study,it proposes a method of building a parameter of ergonomic validity—multi-effect time by using cardiotachometer to record heart rate change,being used to evaluate the functional low-carbon ergonomic validity targeting at the ontological characteristics of kitchen. This method is used to determine the physical consumption intensity( multi-effect) through heart rate incremental relation based on the principles of physiology and ergonomics,and to confirm the ergonomic validity of environmental factors by the time to complete standard work as well as multi-effect quantitative analysis. The test results show that,under the kitchen operating conditions,the multi-effect( ME) can properly reflect the real-time status of the operator and is easily operated; the parameters obtained are not significantly related to the physiological status of the operator,and multi-effect time( MT) is sensitive to the physical consumption brought about to the operator due to kitchen environmental factors; thus,it can be taken as an objective index,which is simple and easy to operate in residential kitchen functional low-carbon evaluation.

Multi-effects and Mechanism of Broad Beau M_1 Root-tip Cells Implanted by Low Energy N^+ Beam

Broad beans were divided into six groups and implanted with N+ beam of 30 KeV, 8 × 1016/cm2 per time for various radiating times respectively. Besides the statistics of its vigor of germination, the M1 root-tip cells of these broad beans were systematically analyzed on their changes in mitotic percentage, morphology and behavior of chromosomes, along with the structure o f cytoskeletons, including microtubule and intermediate filament. Based on all results of these studies, our opinions have been expressed in the report on the mechanism of low-energy N+ beams effecting on higher dicotyledons such as broad beau.

Simulation of Countercurrent Multi-Effect Drying System

The paper bulids a countercurrent multi-effect drying process model which can be expressed as a linear programming(LP) problem with the minimum total energy consumption as target function. Based on the model it can be conventient to solve the heat load , degree of drying and other drying parameters of each effect. And it realizes the mathematical simulation an analysis of multi-effect drying process. Such process not only reuses the secondary steam but also utilizes the high energy grade. Drying silica sand using 1-effect drying to 5-effect drying is presented as an example. The energy consumption and energy saving rate are compared by using co-current multi-effect drying and countercurrent multi-effect drying. As a summary, the countercurrent multi-effect drying is better than co-current drying. Considered the equipment investment and energy conservation, the study also concluded that the countercurrent 4-effect drying is the optimum selection, and it can save 57.6% energy compared to countercurrent 1-effect drying.

Selecting Suitable Heat Source in Refinery for Multi-effect Distillation Based on Grey System Theory

For dealing with high-salinity wastewater in the refinery, the high cost of driving heat source is the disadvantage of multi-effect distillation (MED) so it is of great importance to evaluate the performance of low-temperature heat source for conducting MED and select the optimal temperature for it. Both the MED and the low-temperature heat sources studied in this paper were from a typical refinery located in northwestern China. Besides, a new methodology to evaluate heat sources as the optimal candidate was proposed for MED based on the grey system theory. Five process units, which included 18 fluids of the refinery, were named as the evaluation projects. Three factors, which included safety effects, total costs and characteristics of low-temperature heat sources were determined as the evaluation indexes, the values of which were established through the analyses. The results obtained through the grey correlation analyses have revealed that the grey correlation degrees of these units were 0.661(AVDU), 0.732 (#1 FCCU), 0.618 (#2 FCCU), 0.535 (#1 DCU), and 0.572 (#2 DCU), respectively. Thus, the optimal heat source was provided from #1 FCCU. Through further analyses of the fluids from #1 FCCU, the grey correlation degrees of the fluids were 0.597 (oil and gas at top of tower), 0.714 (recycle oil and gas), and 0.512 (diesel), respectively. Thus, the optimal heat source was the oil and gas recycle stream.

Multi-effect anthraquinone-based polyimide enclosed SnO_(2)/reduced graphene oxide composite as high-performance anode for lithium-ion battery

The cycling stability of SnO_(2)anode as lithium-ion battery is poor due to volume expansion.Polyimide coatings can effectively confine the expansion of SnO_(2).However,linear polyimides are easily dissolved in ester electrolytes and their carbonyls is not fully utilized during charging/discharging process.Herein,the SnO_(2)enclosed with anthraquinone-based polyimide/reduced graphene oxide composite was prepared by self-assembly.Carbonyls from the anthraquinone unit provide fully available active sites to react with Li^(+),improving the utilization of carbonyl in the polyimide.More exposed carbonyl active sites promote the conversion of Sn to SnO_(2)with electrode gradual activation,leading to an increase in reversible capacity during the charge/discharge cycle.In addition,the introduction of reduced graphene oxide cannot only improve the stability of polyimide in the electrolyte,but also build fast ion and electron transport channels for composite electrodes.Due to the multiple effects of anthraquinone-based polyimide and the synergistic effect of reducing graphene oxide,the composite anode exhibits a maximum reversible capacity of 1266 mAh·g^(−1) at 0.25 A·g^(−1),and maintains an excellent specific capacity of 983 mAh·g^(−1) after 200 cycles.This work provides a new strategy for the synergistic modification of SnO_(2).

天线整流罩对GNSS观测值与定位精度影响研究

当前大部分城市为保护卫星连续运行参考站(CORS)系统基准站天线安装了整流罩,但天线整流罩对观测值以及基准站坐标影响的研究仍显不足。为解决基于广州CORS(GZCORS)的网络RTK高程测量存在较大偏差的问题,基于2016—2021年观测站数据,以及拆除基准站天线罩前后的观测数据质量与定位效果相关分析,对天线整流罩对GNSS观测值与高程定位精度的影响进行了深入探究,并分别进行了静态仿动态和城市车载动态定位测试验证。研究结果显示,天线整流罩在一定程度上会增加原始观测值的多路径效应影响,降低约10%的数据可用率,并对基准站高程定位结果产生1~14 cm的系统性偏差,进而影响用户RTK高程定位效果。定位结果显示,拆除基准站天线罩后,基于GZCORS的RTK水平定位均方根误差(RMS)为1 cm左右,高程定位精度RMS为2 cm左右;城市场景下车辆动态定位精度RMS为15~20 cm,满足车道级定位性能。

炼化企业中低温多效蒸馏海水淡化技术的应用

低温多效蒸馏海水淡化技术是一种利用水平管降膜蒸发器或竖直管蒸发器串联并划分为若干效组,以一定量的输入蒸汽作为热源,经多次蒸发、冷凝,利用二次蒸汽潜热,得到多倍加热蒸汽量的蒸馏海水的海水淡化技术。该技术具有传热效率高、产品水质好、负荷调节范围大、工艺温度低等特点,可用于发电厂、化工厂、低温核反应堆等领域,是国际主流海水淡化技术之一。文章结合某炼化企业节能降耗中低温多效蒸馏海水淡化技术创新应用,分析了该技术应用经济效益,并对技术应用前景进行展望,以期促进该技术推广应用和创新发展。

多向加权Tsallis熵最大化导向的自动阈值分割方法

受噪声或随机细节、目标和背景的大小比例、成像时的点扩散等不同因素的影响,许多图像的灰度直方图呈现为无模态、单模态、双模态或者多模态样式.为了在统一框架内处理这4种不同模态情形下的自动阈值选择问题,本文提出了一种多向加权Tsallis熵最大化导向的自动阈值分割方法(Multi-directional Weighted Tsallis Entropy,MWTE).基于新设计的反正切方向性卷积核的多尺度乘积效应,该方法将不同模态的灰度直方图转化为统一的单模态右偏灰度直方图.在4个不同方向上提取出这种特殊的单模态右偏灰度直方图后,通过多向加权策略构建出与原始图像灰度值紧密相关的加权Tsallis熵目标函数,并以该目标函数取最大值时对应的灰度值作为最终分割阈值.本文将提出的方法和3个阈值分割方法、1个软分割方法、1个活动轮廓分割方法以及1个自动聚类分割方法进行了比较.在4种不同模态情形下的4幅合成图像和50幅真实世界图像上的实验结果表明,本文提出的方法虽然在计算效率方面不占有优势,但它对不同模态的测试图像具有更稳健的分割适应性,且在量化分割精度所用的马修斯相关系数方面优于其他6个分割方法.

“一带一路”倡议与全球价值链升级——基于沿线国家的实证数据

基于2007—2020年“一带一路”沿线国家的样本数据,利用多期双重差分模型实证检验了“一带一路”倡议对沿线国家的价值链升级作用。研究结果证实:“一带一路”倡议对于沿线国家全球价值链发展具有显著正向影响。机制分析表明:“一带一路”倡议对沿线国家存在“虹吸效应”,有利于沿线国家的发展。此外,政策沟通对于倡议的推行具有积极的促进作用。研究结果不仅证实了倡议对于沿线国家价值链升级的正向影响,也论证了其中存在的影响机制,为未来进一步的研究提供了理论支撑和有益探索。

为什么国家严控撤县设区:基于粮食安全的新解释

撤县设区是我国推进新型城镇化建设的重要行政区划调整政策。但2021年以来,国家多次表态要严控撤县设区。将撤县设区政策视为准自然实验,基于2000—2019年县域经济社会数据,运用多期DID、PSM-DID、CMP模型、中介效应模型等分析了撤县设区政策对粮食生产和粮食安全的影响及作用机制,从粮食安全视角对国家严控撤县设区的合理性进行了论证。研究发现:首先,撤县设区政策不利于粮食生产和粮食安全,这一结论在更换回归模型、更换被解释变量、调整样本量等检验后仍然稳健,而且这种负面影响存在长期性;其次,撤县设区政策通过农业生产要素重新配置和“政府注意力”转移两个方面对粮食安全产生负面影响;最后,这种负面影响还存在地区异质性,撤县设区对非粮食生产核心区的负面影响更加显著,导致粮食安全责任进一步失衡。建议谨慎推进撤县设区,平衡不同省份粮食安全责任,有序推进县域粮食综合生产能力提升。

贸易便利化、三元边际效应与中国农产品贸易出口的关系——基于上合组织成员国的实证分析

贸易便利化对于中国农产品贸易出口、深化与其他国家的贸易合作有着深刻的战略意义。文章在三元边际分解框架下,借助多重中介模型研究上合组织成员国贸易便利化对中国农产品出口的影响机制。实证结果表明:(1)上合组织成员国贸易便利化水平提高会促进中国农产品出口数量增长和种类多元化,进而扩大农产品出口规模;(2)基础设施、海关环境、规制环境、电子商务4个指标对中国农产品出口均有积极影响,其中电子商务的促进作用最强,同时四者对中国农产品出口三元边际的影响呈现差异性;(3)农产品异质性检验表明,上合组织成员国贸易便利化水平的提升对中国动物类产品的出口促进作用最大,其次是食品类产品,对植物类产品和油类产品出口无显著影响。鉴于此,提出了相应的建议。

考虑质量传导的项目调度与人员配置集成优化

研究表明,质量问题是项目返工的主要原因之一,而人员技能水平是影响项目活动完成质量的关键因素。基于一般性的多技能资源受限项目调度问题,综合考虑人员技能水平以及活动间质量传导作用对活动完成质量的影响,进一步数学表达级联作用下的返工子网以及重构的项目网络,并结合一个大型船舶制造项目案例进行实验分析。对比实验结果表明:所提出的模型可有效平衡有限人力资源在不同活动间的分配,有利于减少返工风险的级联,缩短项目总工期。进一步,通过质量评估区间和人员技能水平参数波动的随机实验,验证模型对两类参数波动具有一定的鲁棒性。

多边平台模式应对突发公共卫生事件的治理效能评价--基于海南省案例的实证研究

以海南省的实证案例,探讨多边平台治理模式在突发公共卫生事件中的应用及其效能。借助因子分析和主成分分析,通过信息沟通效率、资源整合能力、协同行动能力和实际治理成果4个维度的指标评价体系,对海南省18个市县运用多边平台模式防控突发公共卫生事件的治理效能进行量化评价与排名。采用多元回归分析,选取社会参与度作为因变量,分析经济实力支持、社会动员支持、医疗救助支持、信息技术支持等多个公共因子的影响。研究显示,多边平台模式应对突发公共卫生事件的治理效能具有显著优势,能够增强信息共享,提高资源在公共领域的配置效率,实现社会治理的精细化和智能化,进而激发创新活力,提升公共服务水平。

基于阵列声波测井的井下多尺度压裂效果评价方法

为有效监测水力压裂效果、提高储层压裂效果评价精度,基于阵列声波测井资料的井下压裂效果评价方法,采用反射斯通利波提取和成像技术定量表征近井筒压裂缝,建立适用于测井观测系统的叠前深度偏移成像算法,以实现远井压裂缝的高精度成像,形成了基于阵列声波测井的井下多尺度压裂效果评价方法,并在中国西部某油田X1水平井成功应用。研究表明,基于阵列声波测井资料评价的压裂缝发育程度与压裂液注入量呈正相关关系,并且压裂缝最为发育层段与地震蚂蚁体属性图中天然裂缝发育位置一致。基于阵列声波测井的井下压裂效果评价方法的提出,对表征井周数十米范围内不同尺度压裂缝的发育情况具有重要意义,对更好地发挥水力压裂技术对能源勘探开发行业的支撑作用具有一定指导意义。

中药滋阴补阳方剂治疗肾气亏虚型多囊卵巢综合征不孕症对患者超声动态多参数的影响评价

目的评价中药滋阴补阳方剂治疗肾气亏虚型多囊卵巢综合征不孕症对患者超声动态多参数的影响。方法选取2022年1月至2023年1月江西省妇幼保健院收治的80例肾气亏虚型多囊卵巢综合征患者作为研究对象,按照随机数字法将其分为观察组(40例)与对照组(40例)。对照组采用枸橼酸氯米芬片治疗,观察组在对照组方法的基础上联合中药滋阴补阳方剂治疗。比较两组患者的治疗效果、卵泡发育情况、激素水平、子宫动脉血流灌注情况及子宫内膜厚度。结果观察组的有效率高于对照组,差异有统计学意义(P<0.05);观察组治疗后的卵泡及优势卵泡数目多于对照组,差异有统计学意义(P<0.05);观察组治疗后的黄体生成素(LH)、促卵泡激素(FSH)、睾酮(T)均低于对照组,雌二醇(E2)高于对照组,差异有统计学意义(P<0.05);观察组治疗后的搏动指数(PI)、阻力指数(RI)均低于对照组,差异有统计学意义(P<0.05);观察组治疗后的子宫内膜厚度高于对照组,差异有统计学意义(P<0.05)。结论将中药滋阴补阳方剂应用于肾气亏虚型多囊卵巢综合征不孕症患者治疗中,可积极改善患者的激素水平及子宫动脉血流灌注情况,同时能够促进卵泡发育,增加子宫内膜厚度,改善症状,值得推广。

小净距隧道掘进爆破及其振动响应规律研究

为了研究爆破荷载作用下小净距隧道中夹岩区的动力稳定性问题,依托小龙门隧道爆破工程,开展了现场爆破振动监测试验。通过改进的变分模态分解(variational mode decomposition,VMD)与多尺度排列熵(multi-scale permutation entropy,MPE)算法对爆破振动信号进行消噪处理,基于此分析了掏槽孔与周边孔爆破在后行洞左拱腰(非中夹岩区)、右拱腰(中夹岩区)中产生的振动特征差异。结果表明:采用改进的自适应VMD-MPE算法可以有效消除振动信号中的噪声,并降低了主观决策的影响;此外,相对于非中夹岩区,中夹岩对爆破振动具有明显的放大效应,其质点峰值振速明显大于非中夹岩区,但中夹岩区的振动衰减速度更快;同时,通过对比非中夹岩区与中夹岩区各测点振动频率特征可以发现,中夹岩区小于40 Hz的低频振动能量占比较大,更易引起支护结构的共振,发生损伤与破坏的风险更高,应重点关注;受“转角削弱”作用以及地震波传播路径的影响,在比例距离SD小于等于11.57 m·kg^(1/3)范围内,周边孔爆破在掌子面后方围岩中产生的振速大于掏槽孔。

Screening the emission sources of volatile organic compounds （VOCs） in China by multi-effects evaluation

Volatile organic compounds （VOCs） play important roles in the atmosphere via three main pathways： photochemical ozone formation, secondary organic aerosol production, and direct toxicity to humans. Fewstudies have integrated these effect, s to prioritize control measures for VOC.s sources. In this study,we developed a multi-effects evaluation methodology based on updated emission inventories and source profiles, by combining the ozone formation potential （OFP）, secondary organic aerosol potential （SOAP）, and VOC toxicity data. We derived species-specific emission inventories for 152 sources. The OFPs, SOAPs, and toxicity of each source were estimated, the contribution and sharing of source to each of these adverse effects were calculated. Weightings were given to the three adverse effects by expert scoring, and then the integrated effect was determined. Taking 2012 as the base year,solvent use and industrial process were found to be the most important anthropogenic sources, accounting for 24.2% and 23.1% of the integrated effect, respectively, followed by biomass burning, transportation, and fossil fuel combustion, each had a similar contribution ranging from 16.7% to 18.6%. The top five industrial sources, including plastic products, rubber products, chemical fiberproducts, the chemical industry, and oil refining, accounted for nearly 70.0% of industrial emissions. Beijing, Chongqing, Shanghai, Jiangsu, and Guangdong were the five provinces contributing the largest integrated effects. For the VOC species from emissions showed the largest contributions were styrene, toluene, ethylene, benzene, and m/p-xylene.

页岩储层应力敏感性的时间效应

有效应力及其作用时间是控制岩石孔隙和裂缝变形的重要外部因素。页岩储层的多尺度孔隙结构特征及孔缝配置关系使得其应力敏感时间效应具有特殊性,然而,以往研究尚未考虑有效应力加载及卸载时间对页岩应力敏感行为的影响。以川南威荣气田龙马溪组页岩气藏为研究对象,钻取不同孔缝发育程度的页岩样品,设计并测试了变有效应力状态下变加载及卸载持续稳定时间对岩样渗透率的影响实验。结果表明:1)有效应力从5 MPa升至35 MPa时,微裂缝岩样和基块岩样渗透率分别降低了66.82%和27.19%,卸载过程中渗透率恢复率为74.73%和79.82%。页岩渗透率越低,有效应力滞后效应越显著;2)恒定有效应力加载持续稳定时间从2.5 h延长至10.0 h,应力敏感系数增加3.76%∼80.17%,且当有效应力较小时的时间效应更显著。研究认为,页岩组分及多尺度孔缝结构是导致其孔缝变形行为差异性的主因。基于实验研究结果,推荐页岩样品老化处理为6.0 h,提出了优化页岩储层敏感性评价实验方案和优化气井工作制度的建议。

深层-超深层致密储层天然裂缝分布特征及发育规律

天然裂缝是深层-超深层致密储层的有效储集空间和主要渗流通道,影响着致密储层油气的运移、富集、单井产能、开发方式及开发效果。通过对近年来致密储层裂缝研究成果总结和文献综述,分析了深层-超深层致密储层天然裂缝分布特征及发育规律。将致密储层天然裂缝分为大尺度裂缝、中尺度裂缝、小尺度裂缝和微尺度裂缝4个级别。不同尺度裂缝分布具有幂律分布的特点,裂缝尺度越大,数量越少;裂缝尺度越小,数量越多。大、中尺度裂缝主要起渗流作用,小尺度裂缝主要起渗流和储集作用,而微尺度裂缝主要起储集作用。在地层埋藏过程中的应力体制演化决定了不同时期天然裂缝的类型、产状及其力学性质;构造应力大小、岩石力学层的力学性质和厚度差异控制了多尺度裂缝的形成分布及其发育程度。构造变形导致不同构造部位的局部应力和应变分布产生差异,增强了裂缝发育的非均质性。逆冲断层通过控制其上盘地层变形控制了“裂缝域”的分布规律;走滑断层的组合样式、活动方式和岩石力学层共同控制了相关裂缝的三维空间展布。裂缝形成演化过程中的开启-闭合规律决定了裂缝的储集空间,记录了裂缝有效性的演化历史。