The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate...The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing fillers.The interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW materials.Compared to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded steel.And 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of propellants.Despite the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic activity.This strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.展开更多
Gradiently denitrated gun propellant(GDGP)prepared by a“gradient denitration”strategy is obviously superior in progressive burning performance to the traditional deterred gun propellant.Currently,the preparation of ...Gradiently denitrated gun propellant(GDGP)prepared by a“gradient denitration”strategy is obviously superior in progressive burning performance to the traditional deterred gun propellant.Currently,the preparation of GDGP employed a tedious two-step method involving organic solvents,which hinders the large-scale preparation of GDGP.In this paper,GDGP was successfully prepared via a novelty and environmentally friendly one-step method.The obtained samples were characterized by FT-IR,Raman,SEM and XPS.The results showed that the content of nitrate groups gradiently increased from the surface to the core in the surface layer of GDGP and the surface layer of GDGP exhibited a higher compaction than that of raw gun propellant,with a well-preserved nitrocellulose structure.The denitration process enabled the propellant surface with regressive energy density and good progressive burning performance,as confirmed by oxygen bomb and closed bomb test.At the same time,the effects of different solvents on the component loss of propellant were compared.The result showed that water caused the least component loss.Finally,the stability of GDGP was confirmed by methyl-violet test.This work not only provided environmentally friendly,simple and economic preparation of GDGP,but also confirmed the stability of GDGP prepared by this method.展开更多
Smart materials,which exhibit shape memory behavior in response to external stimuli,have shown great potential for use in biomedical applications.In this study,an energetic composite was fabricated using a UV-assisted...Smart materials,which exhibit shape memory behavior in response to external stimuli,have shown great potential for use in biomedical applications.In this study,an energetic composite was fabricated using a UV-assisted DIW 3D printing technique and a shape memory material(SMP)as the binder.This composite has the ability to reduce the impact of external factors and adjust gun propellant combustion behavior.The composition and 3D printing process were delineated,while the internal structure and shape memory performance of the composite material were studied.The energetic SMP composite exhibits an angle of reversal of 18 s at 70°,with a maximum elongation typically reaching up to 280% of the original length and a recovery length of approximately 105%during ten cycles.Additionally,thermal decomposition and combustion behavior were also demonstrated for the energetic SMP composite.展开更多
The simulation of compression and fracture of charge bed in chamber is one of the key problems in the study of launch safety of gun propellant charge. A new kind of experimental device that can be used for simulation ...The simulation of compression and fracture of charge bed in chamber is one of the key problems in the study of launch safety of gun propellant charge. A new kind of experimental device that can be used for simulation is given. Its structure and operational principle are introduced. Using a semi-closed vessel as a source of compression force, the device can simulate any kind of dynamic environment in a gun propellant charge. Using the low temperature inert gas （N2） as the compression medium, the device can not only ensure that the simulation is real, but also protect the fragmentized propellant from combustion after experiment. Using the device, many simulation experiments have been accomplished, and dynamic environment of propellant fracture is acquired. With the experiments, fragmentized propellant for the compression and fracture of charge bed is obtained. Results of experiments show that the new device can be used to study the principle of the compression and fracture of charge bed.展开更多
The thermal decomposition behavior and nonisothermal reaction kinetics of the double-base gun propellants containing the mixed ester of triethyleneglycol dinitrate（TEGDN） and nitroglycerin（NG） were investigated by...The thermal decomposition behavior and nonisothermal reaction kinetics of the double-base gun propellants containing the mixed ester of triethyleneglycol dinitrate（TEGDN） and nitroglycerin（NG） were investigated by thermogravimetry（TG） and differential thermogravimetry（DTG）, and differential scanning calorimetry（DSC） under the high-pressure dynamic ambience. The results show that the thermal decomposition processes of the mixed nitric ester gun propellants have two mass-loss stages. Nitric ester evaporates and decomposes in the first stage, and nitrocellulose and centralite II（C2） decompose in the second stage. The mass loss, the DTG peak points, and the terminated temperatures of the two stages are changeable with the difference of the mass ratio of TEGDN to NG. There is only one obvious exothermic peak in the DSC curves under the different pressures. With the increase in the furnace pressure, the peak temperature decreases, and the decomposition heat increases. With the increase in the content of TEGDN, the decomposition heat decreases at 0.1 MPa and rises at high pressure. The variety of mass ratio of TEGDN to NG makes few effect on the exothermic peak temperatures in the DSC curves at different pressures. The kinetic equation of the main exothermal decomposition reaction of the gun propellant TG0601 was determined as： dα/dt=1021.59（1-α）3e-2.60×104/T. The reaction mechanism of the process can be classified as chemical reaction. The critical temperatures of the thermal explosion（Tbe and Tbp） obtained from the onset temperature（Te） and the peak temperature（Tp） are 456.46 and 473.40 K, respectively. ΔS≠, ΔH≠, and ΔG≠ of the decomposition reaction are 163.57 J·mol^-1·K^-1, 209.54 kJ·mol^-1, and 133.55 kJ·mol^-1, respectively.展开更多
Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the pr...Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the propellant should not influence the ballistic properties of the round. Nevertheless, constant initial temperature coefficients can not be achieved easily. This work focuses on the influence of the firing temperature on the ballistic properties, the mechanical integrity and the sensitivity to impact of nitrocellulose based propellants. Combustion rates have been determined by closed vessel tests. Ballistic properties have been investigated by firing 5.56 cartridges. The propellants have been conditioned at temperatures ranging from -54 ℃ to ＋71 ℃ before firing. The largest temperature coefficient is observed at high temperatures. The temperature sensitivity of the peak pressure in the combustion chamber can not be fully explained by the results from the closed vessel test. The authors speculated that the mechanical behaviour of the propellant grains at low temperatures influences also the overall ballistic properties of the round. Impact tests with propellants conditioned at low and high temperatures permit to investigate their mechanical strength under extreme temperatures and to better understand the propellant performance during firing. Tests on aged propellants have been conducted as well.展开更多
Cellulose acetate nitrate(CAN) was used as an insensitive energetic binder to improve the insensitive munitions(IM) properties of gun propellants to replace the M1 propellant used in 105 mm artillery charges.CAN conta...Cellulose acetate nitrate(CAN) was used as an insensitive energetic binder to improve the insensitive munitions(IM) properties of gun propellants to replace the M1 propellant used in 105 mm artillery charges.CAN contains the energetic nitro groups found in nitrocellulose(NC),but also acetyl functionalities,which lowered the polymer's sensitivity to heat and shock,and therefore improved its IM properties relative to NC.The formulation,development and small-scale characterization testing of several CAN-based propellants were done.The formulations,using insensitive energetic solid fillers and high-nitrogen modifiers in place of nitramine were completed.The small scale characterization testing,such as closed bomb testing,small scale sensitivity,thermal stability,and chemical compatibility were done.The mechanical response of the propellants under high-rate uni-axial compression at,hot,cold,and ambient temperatures were also completed.Critical diameter testing,hot fragment conductive ignition(HFCI) tests were done to evaluate the propellants' responses to thermal and shock stimuli.Utilizing the propellant chemical composition,theoretical predictions of erosivity were completed.All the small scale test results were utilized to down-select the promising CAN based formulations for large scale demonstration testing such as the ballistic performance and fragment impact testing in the105 mm M67 artillery charge configurations.The test results completed in the small and large scale testing are discussed.展开更多
The U.S. military has a need for more powerful propellants with balanced/stoichiometric amounts of fuel and oxidants. However, balanced and more powerful propellants lead to accelerated gun barrel erosion and markedly...The U.S. military has a need for more powerful propellants with balanced/stoichiometric amounts of fuel and oxidants. However, balanced and more powerful propellants lead to accelerated gun barrel erosion and markedly shortened useful barrel life. Boron nitride(BN) is an interesting potential additive for propellants that could reduce gun wear effects in advanced propellants(US patent pending 2015-026P). Hexagonal boron nitride is a good lubricant that can provide wear resistance and lower flame temperatures for gun barrels. Further, boron can dope steel, which drastically improves its strength and wear resistance, and can block the formation of softer carbides. A scalable synthesis method for producing boron nitride nano-particles that can be readily dispersed into propellants has been developed. Even dispersion of the nano-particles in a double-base propellant has been demonstrated using a solvent-based processing approach. Stability of a composite propellant with the BN additive was verified. In this paper, results from propellant testing of boron nitride nano-composite propellants are presented, including closed bomb and wear and erosion testing. Detailed characterization of the erosion tester substrates before and after firing was obtained by electron microscopy,inductively coupled plasma and x-ray photoelectron spectroscopy. This promising boron nitride additive shows the ability to improve gun wear and erosion resistance without any destabilizing effects to the propellant. Potential applications could include less erosive propellants in propellant ammunition for large, medium and small diameter fire arms.展开更多
The experimental modal analysis of the selected self-propelled gun was completed to obtain its modal frequency distribution and modes by using an operational modal analysis experimental technique.The result obtained b...The experimental modal analysis of the selected self-propelled gun was completed to obtain its modal frequency distribution and modes by using an operational modal analysis experimental technique.The result obtained by the method was compared with that obtained by the traditional method.It indicates that the two results are in good agreement.展开更多
From the view point of launch safety caused by fracture of propellant charge,this paper points out that the safety criterion of pressure wave is inadequate to evaluate the launch safety of propellant charge based on t...From the view point of launch safety caused by fracture of propellant charge,this paper points out that the safety criterion of pressure wave is inadequate to evaluate the launch safety of propellant charge based on the initial negative differential pressure and sensitivity tests.Generally,the maximum barrel pressure does not depend upon the intensity of pressure wave correspondingly.The pressure wave intensity can not describe the fracture degree of propellant charge in chamber and reflect the mechanical environment of propellant charge fracturing exactly and wholly.The evaluation criterion for launch safety of propellant charge should be built on the basis of depicting the fracture degree of propellant bed.展开更多
基金the support of the instrument and equipment fund of the Key Laboratory of Special Energy,Ministry of Education,Nanjing University of Science and Technology,China.
文摘The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun propellants.To address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing fillers.The interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW materials.Compared to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded steel.And 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of propellants.Despite the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic activity.This strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.
文摘Gradiently denitrated gun propellant(GDGP)prepared by a“gradient denitration”strategy is obviously superior in progressive burning performance to the traditional deterred gun propellant.Currently,the preparation of GDGP employed a tedious two-step method involving organic solvents,which hinders the large-scale preparation of GDGP.In this paper,GDGP was successfully prepared via a novelty and environmentally friendly one-step method.The obtained samples were characterized by FT-IR,Raman,SEM and XPS.The results showed that the content of nitrate groups gradiently increased from the surface to the core in the surface layer of GDGP and the surface layer of GDGP exhibited a higher compaction than that of raw gun propellant,with a well-preserved nitrocellulose structure.The denitration process enabled the propellant surface with regressive energy density and good progressive burning performance,as confirmed by oxygen bomb and closed bomb test.At the same time,the effects of different solvents on the component loss of propellant were compared.The result showed that water caused the least component loss.Finally,the stability of GDGP was confirmed by methyl-violet test.This work not only provided environmentally friendly,simple and economic preparation of GDGP,but also confirmed the stability of GDGP prepared by this method.
文摘Smart materials,which exhibit shape memory behavior in response to external stimuli,have shown great potential for use in biomedical applications.In this study,an energetic composite was fabricated using a UV-assisted DIW 3D printing technique and a shape memory material(SMP)as the binder.This composite has the ability to reduce the impact of external factors and adjust gun propellant combustion behavior.The composition and 3D printing process were delineated,while the internal structure and shape memory performance of the composite material were studied.The energetic SMP composite exhibits an angle of reversal of 18 s at 70°,with a maximum elongation typically reaching up to 280% of the original length and a recovery length of approximately 105%during ten cycles.Additionally,thermal decomposition and combustion behavior were also demonstrated for the energetic SMP composite.
文摘The simulation of compression and fracture of charge bed in chamber is one of the key problems in the study of launch safety of gun propellant charge. A new kind of experimental device that can be used for simulation is given. Its structure and operational principle are introduced. Using a semi-closed vessel as a source of compression force, the device can simulate any kind of dynamic environment in a gun propellant charge. Using the low temperature inert gas （N2） as the compression medium, the device can not only ensure that the simulation is real, but also protect the fragmentized propellant from combustion after experiment. Using the device, many simulation experiments have been accomplished, and dynamic environment of propellant fracture is acquired. With the experiments, fragmentized propellant for the compression and fracture of charge bed is obtained. Results of experiments show that the new device can be used to study the principle of the compression and fracture of charge bed.
基金the National Natural Science Foundation of China(No.20573098)the Foundation of Key Laboratory of Science and Technology for National Defence of Propellant and Explosive of China(No.9140C3503020605).
文摘The thermal decomposition behavior and nonisothermal reaction kinetics of the double-base gun propellants containing the mixed ester of triethyleneglycol dinitrate（TEGDN） and nitroglycerin（NG） were investigated by thermogravimetry（TG） and differential thermogravimetry（DTG）, and differential scanning calorimetry（DSC） under the high-pressure dynamic ambience. The results show that the thermal decomposition processes of the mixed nitric ester gun propellants have two mass-loss stages. Nitric ester evaporates and decomposes in the first stage, and nitrocellulose and centralite II（C2） decompose in the second stage. The mass loss, the DTG peak points, and the terminated temperatures of the two stages are changeable with the difference of the mass ratio of TEGDN to NG. There is only one obvious exothermic peak in the DSC curves under the different pressures. With the increase in the furnace pressure, the peak temperature decreases, and the decomposition heat increases. With the increase in the content of TEGDN, the decomposition heat decreases at 0.1 MPa and rises at high pressure. The variety of mass ratio of TEGDN to NG makes few effect on the exothermic peak temperatures in the DSC curves at different pressures. The kinetic equation of the main exothermal decomposition reaction of the gun propellant TG0601 was determined as： dα/dt=1021.59（1-α）3e-2.60×104/T. The reaction mechanism of the process can be classified as chemical reaction. The critical temperatures of the thermal explosion（Tbe and Tbp） obtained from the onset temperature（Te） and the peak temperature（Tp） are 456.46 and 473.40 K, respectively. ΔS≠, ΔH≠, and ΔG≠ of the decomposition reaction are 163.57 J·mol^-1·K^-1, 209.54 kJ·mol^-1, and 133.55 kJ·mol^-1, respectively.
文摘Initial firing temperatures play an important role on the combustion rate of propellant. In gun propellants, initial temperature is a key factor for both accuracy and safety. Ideally, the initial temperature of the propellant should not influence the ballistic properties of the round. Nevertheless, constant initial temperature coefficients can not be achieved easily. This work focuses on the influence of the firing temperature on the ballistic properties, the mechanical integrity and the sensitivity to impact of nitrocellulose based propellants. Combustion rates have been determined by closed vessel tests. Ballistic properties have been investigated by firing 5.56 cartridges. The propellants have been conditioned at temperatures ranging from -54 ℃ to ＋71 ℃ before firing. The largest temperature coefficient is observed at high temperatures. The temperature sensitivity of the peak pressure in the combustion chamber can not be fully explained by the results from the closed vessel test. The authors speculated that the mechanical behaviour of the propellant grains at low temperatures influences also the overall ballistic properties of the round. Impact tests with propellants conditioned at low and high temperatures permit to investigate their mechanical strength under extreme temperatures and to better understand the propellant performance during firing. Tests on aged propellants have been conducted as well.
文摘Cellulose acetate nitrate(CAN) was used as an insensitive energetic binder to improve the insensitive munitions(IM) properties of gun propellants to replace the M1 propellant used in 105 mm artillery charges.CAN contains the energetic nitro groups found in nitrocellulose(NC),but also acetyl functionalities,which lowered the polymer's sensitivity to heat and shock,and therefore improved its IM properties relative to NC.The formulation,development and small-scale characterization testing of several CAN-based propellants were done.The formulations,using insensitive energetic solid fillers and high-nitrogen modifiers in place of nitramine were completed.The small scale characterization testing,such as closed bomb testing,small scale sensitivity,thermal stability,and chemical compatibility were done.The mechanical response of the propellants under high-rate uni-axial compression at,hot,cold,and ambient temperatures were also completed.Critical diameter testing,hot fragment conductive ignition(HFCI) tests were done to evaluate the propellants' responses to thermal and shock stimuli.Utilizing the propellant chemical composition,theoretical predictions of erosivity were completed.All the small scale test results were utilized to down-select the promising CAN based formulations for large scale demonstration testing such as the ballistic performance and fragment impact testing in the105 mm M67 artillery charge configurations.The test results completed in the small and large scale testing are discussed.
基金supported by the US ARMY RDECOM Tech Base ProgramSmall Business Innovation Research (SBIR) Army Contract Number W15QKN-12-C-0041
文摘The U.S. military has a need for more powerful propellants with balanced/stoichiometric amounts of fuel and oxidants. However, balanced and more powerful propellants lead to accelerated gun barrel erosion and markedly shortened useful barrel life. Boron nitride(BN) is an interesting potential additive for propellants that could reduce gun wear effects in advanced propellants(US patent pending 2015-026P). Hexagonal boron nitride is a good lubricant that can provide wear resistance and lower flame temperatures for gun barrels. Further, boron can dope steel, which drastically improves its strength and wear resistance, and can block the formation of softer carbides. A scalable synthesis method for producing boron nitride nano-particles that can be readily dispersed into propellants has been developed. Even dispersion of the nano-particles in a double-base propellant has been demonstrated using a solvent-based processing approach. Stability of a composite propellant with the BN additive was verified. In this paper, results from propellant testing of boron nitride nano-composite propellants are presented, including closed bomb and wear and erosion testing. Detailed characterization of the erosion tester substrates before and after firing was obtained by electron microscopy,inductively coupled plasma and x-ray photoelectron spectroscopy. This promising boron nitride additive shows the ability to improve gun wear and erosion resistance without any destabilizing effects to the propellant. Potential applications could include less erosive propellants in propellant ammunition for large, medium and small diameter fire arms.
文摘The experimental modal analysis of the selected self-propelled gun was completed to obtain its modal frequency distribution and modes by using an operational modal analysis experimental technique.The result obtained by the method was compared with that obtained by the traditional method.It indicates that the two results are in good agreement.
基金Sponsored by National Defence Prestudy Foundation of China(40406010401)
文摘From the view point of launch safety caused by fracture of propellant charge,this paper points out that the safety criterion of pressure wave is inadequate to evaluate the launch safety of propellant charge based on the initial negative differential pressure and sensitivity tests.Generally,the maximum barrel pressure does not depend upon the intensity of pressure wave correspondingly.The pressure wave intensity can not describe the fracture degree of propellant charge in chamber and reflect the mechanical environment of propellant charge fracturing exactly and wholly.The evaluation criterion for launch safety of propellant charge should be built on the basis of depicting the fracture degree of propellant bed.
