Effects of operating parameters on oxidative coupling of methane over Na-W-Mn/SiO_2 catalyst at elevated pressures

The effects of operating parameters on oxidative coupling of methane （OCM） over Na-W-Mn/SiO2 catalyst have been studied at elevated pressures of 0.2, 0.3 and 0.4 MPa under low gaseous hourly space velocity （GHSV） and low temperature conditions. Experimental results show that when the operating pressure is increased, C2＋ yield slightly decreases, while the maximum ratio of ethylene to ethane remains unchanged. Moreover, it has been found empirically that increase of pressure does not affect the catalyst behavior permanently, the catalyst recovers its original low pressure performance without hysteresis behavior by reducing the pressure. Under the investigated conditions, when oxygen is completely consumed, the increase of GHSV leads to improvement in C2 selectivity, while C3＋ and COx selectivities decrease slightly. The C2＋ selectivity increases by increase of nitrogen diluent in the feed, but the C3＋ hydrocarbons selectivities decrease with increase of nitrogen since it is possible that further dilution at high pressure may reduce the probability of collision between CH3 and C2＋ hydrocarbons. During the stability test at high pressure, the catalyst performance remains unchanged throughout the 20 h running. The fresh and used catalysts were characterized using XRD, SEM and N2 adsorption-desorption methods. It was found that the phase transformation of the support from α-cristobalite to tridymite and quartz does not have obvious effect on catalyst performance at high pressure.

Reliability of linear coupling synchronization of hyperchaotic systems with unknown parameters

Complete synchronization could be reached between some chaotic and/or hyperchaotic systems under linear coupling. More generally, the conditional Lyapunov exponents are often calculated to confirm the stability of synchronization and reliability of linear controllers. In this paper, detailed proof and measurement of the reliability of linear controllers are given by constructing a Lyapunov function in the exponential form. It is confirmed that two hyperchaotic systems can reach complete synchronization when two linear controllers are imposed on the driven system unidirectionally and the unknown parameters in the driving systems are estimated completely. Finally, it gives the general guidance to reach complete synchronization under linear coupling for other chaotic and hyperchaotic systems with unknown parameters.

Periodic synchronization of community networks with non-identical nodes uncertain parameters and adaptive coupling strength

In this paper, we propose a novel approach for simultaneously identifying unknown parameters and synchronizing time-delayed complex community networks with nonidentical nodes. Based on the LaSalle＇s invariance principle, a cri- teflon is established by constructing an effective control identification scheme and adjusting automatically the adaptive coupling strength. The proposed control law is applied to a complex community network which is periodically synchro- nized with different chaotic states. Numerical simulations are conducted to demonstrate the feasibility of the proposed method.

Theoretical Study on the Spectroscopic Parameters and Transition Properties of MgH Radical Including Spin-orbit Coupling

An accurate theoretical study on the MgH radical is reported by adopting the high-level relativistic MRCI＋Q method with a quintuple-zeta quality basis set. The reliable potential energy curves of the five A-S states of MgH are derived. Then the associated spectroscopic parameters are determined and found to be in good accordance with the available experimental results. The permanent dipole moments （PDMs） and the spin-orbit （SO） matrix elements of A-S states are computed. The results show that the abrupt changes of PDMs and SO matrix elements are attributed to the variations of electronic configurations at the avoided crossing point. The SOC effect leads to the five A-S states split into ten Ω states and results in the double potential well of （2）1//2 state. Finally, the transition properties from the （2）1//2, （1）3//2 and （3）1//2 states to the ground state X2∑＋1//2 transitions are obtained, including the transition dipole moments, Franck-Condon factors and radiative lifetimes.

NUMERICAL SIMULATION FOR DYNAMIC INITIAL SHOCK PARAMETERS OF COUPLING CHARGE ON BOREHOLE WALL UNDER THE ACTION OF HIGH EXPLOSIVES

According to detonation theory and hydrodynamic principle, a physical model has been set up in this paper. Based on the model a methodology for calculating dynamic initial shock parameters such as shock pressure pm shock wave velosity Dm etc. of coupling charge on borehole wall has ben developed. The shock parameters have been calculated when high explosives works on granite, limestone and marble respectively. The magnitude of every parameter on borehole wall has been obtained from ignited dot to the end of borehole along axial direction. Some important conclusions are also gained.

Modeling Approach and Analysis of the Structural Parameters of an Inductively Coupled Plasma Etcher Based on a Regression Orthogonal Design

The geometry of an inductively coupled plasma （ICP） etcher is usually considered to be an important factor for determining both plasma and process uniformity over a large wafer. During the past few decades, these parameters were determined by the ＂trial and error＂ method, resulting in wastes of time and funds. In this paper, a new approach of regression orthogonal design with plasma simulation experiments is proposed to investigate the sensitivity of the structural parameters on the uniformity of plasma characteristics. The tool for simulating plasma is CFD-ACE＋, which is commercial multi-physical modeling software that has been proven to be accurate for plasma simulation. The simulated experimental results are analyzed to get a regression equation on three structural parameters. Through this equation, engineers can compute the uniformity of the electron number density rapidly without modeling by CFD-ACE＋. An optimization performed at the end produces good results.

Mixed Electric and Magnetic Coupling Design Based on Coupling Matrix Extraction

This paper proposes a design and fine-tuning method for mixed electric and magnetic coupling filters.It derives the quantitative relationship between the coupling coefficients(electric and magnetic coupling,i.e.,EC and MC)and the linear coefficients of frequencydependent coupling for the first time.Different from the parameter extraction technique using the bandpass circuit model,the proposed approach explicitly relatesEC and MC to the coupling matrix model.This paper provides a general theoretic framework for computer-aided design and tuning of a mixed electric and magnetic coupling filter based on coupling matrices.An example of a 7th-order coaxial combline filter design is given in the paper,verifying the practical value of the approach.

Morphological parameters of both surfaces of coupled joint

Twenty one joints were made with Brazilian tests and each surface was scanned by the Talysurf CLI 2000.Morphological characteristics of joint surface were quantified by statistical and textural parameters.By the contrast of these parameters between both sides of each coupled joint,the following conclusions are drawn.The upper and lower surfaces of coupled joints have approximately equal values of Sp(maximum height of joint surface),Sa(arithmetic mean height of joint surface) and Sq(root mean square height of joint surface),but the Ssk(skewness of the height distribution of joint surface) values of the two surfaces of a coupled joint are different,one is positive while the other is negative.The Sal(auto-correlation length) parameter values of both surfaces of each coupled joint are quite close,and the Str(texture aspect ratio) values have the same situation to the S al parameter,but the same parameters of different surfaces have big differences which illustrates its own characteristics of each joint.The two surfaces of each coupled joint have similar values of ■p(mean profile angle) which can be used to deduce the value of ■p each other.

General hybrid projective complete dislocated synchronization with non-derivative and derivative coupling based on parameter identification in several chaotic and hyperchaotic systems

According to the Lyapunov stability theorem, a new general hybrid projective complete dislocated synchronization scheme with non-derivative and derivative coupling based on parameter identification is proposed under the framework of drive-response systems. Every state variable of the response system equals the summation of the hybrid drive systems in the previous hybrid synchronization. However, every state variable of the drive system equals the summation of the hybrid response systems while evolving with time in our method. Complete synchronization, hybrid dislocated synchronization, projective synchronization, non-derivative and derivative coupling, and parameter identification are included as its special item. The Lorenz chaotic system, Rssler chaotic system, memristor chaotic oscillator system, and hyperchaotic Lü system are discussed to show the effectiveness of the proposed methods.

ANALYSIS OF THE THERMOPHYSICAL PARAMETERS OF MOIST WOOD PARTICLE MATERIAL IN A COUPLED HEAT AND MASS TRANSFER PROCESS OF FREEZING BY USING FINITE ELEMENT METHOD

The coupled heat and moisture transfer in a freezing process of wood particle material was mathematically modeled in the paper. The models were interactively solved by using the numerical method(the finite element method and the finite difference method). By matching the theoretical calculation to an experiment, the nonlinear problem was analyzed and the variable thermophysical parameters concerned was evaluated. The analysis procedure and the evaluation of the parameters were presented in detail. The result of the study showed that by using the method as described in the paper, it was possible to determine the variable (with respect to temperature, moisture content and freezing state) thermophysical parameters which were unknown or difficult to measure as long as the governing equations for a considered process were available. The method can significantly reduces the experiment efforts for determining thermophysical parameters which arc very complicated to measure. The determined variable of the effective heat conductivity of wood particle material was given in the paper. The error of the numerical calculation was also estimated by the comparison with a matched experiment.

Structural Parameter Analyses on Rotor Airloads with New Type Blade-Tip Based on CFD/CSD Coupling Method

For accurate aeroelastic analysis,the unsteady rotor flowfield is solved by computational fluid dynamics(CFD)module based on RANS/Euler equations and moving-embedded grid system,while computational structural dynamics(CSD)module is introduced to handle blade flexibility.In CFD module,dual time-stepping algorithm is employed in temporal discretization,Jameson two-order central difference(JST)scheme is adopted in spatial discretization and B-L turbulent model is used to illustrate the viscous effect.The CSD module is developed based on Hamilton′s variational principles and moderate deflection beam theory.Grid deformation is implemented using algebraic method through coordinate transformations to achieve deflections with high quality and efficiency.A CFD/CSD loose coupling strategy is developed to transfer information between rotor flowfield and blade structure.The CFD and the CSD modules are verified seperately.Then the CFD/CSD loose coupling is adopted in airloads prediction of UH-60A rotor under high speed forward flight condition.The calculated results agree well with test data.Finally,effects of torsional stiffness properties on airloads of rotors with different tip swept angles(from 10° forward to 30° backward)are investigated.The results are evaluated through pressure distribution and airloads variation,and some meaningful conclusions are drawn the moderated shock wave strength and pressure gradient caused by varied tip swept angle and structural properties.

Beam Parameter Product Optimization for High Power SWIR Laser Diode Stack Fiber Coupling

An optimized setup for fiber optic injection of a kilowatt peak power laser diode stack emitting in the SWIR spectral range is proposed. Starting from a fast axis collimated (FAC) and slow axis collimated (SAC) 15 bars, 19 emitters off the shelf laser diode stack, the beam is transformed using spatial beam combining and polarization coupling. Both techniques integrated in a compact design enable to couple the kilowatt level beam into a standard 600 μm core, 0.22 numerical aperture (NA) multimode optical fiber. An application in the field of long range SWIR laser illuminator for gated viewing is presented. A comparison between two illuminators is realized both based on the same laser diode stack but one using beam parameter product (BPP) reduction and one without. It could be demonstrated that BPP reduction is the best way for efficient, narrow divergence and compact semi-conductor based laser illuminators design and realization. The global laser illuminator efficiency could be improved by 75% for the narrowest divergences thanks to this approach.

Influence of multiple structural parameters on interior ballistics based on orthogonal test methods

Influence of multiple structural parameters on the performance of a gun launch system driven by highpressure reactive gases is important for structural design and performance adjustment.A coupled lumped parameter model was utilized to predict the propellant combustion,and a dynamic finite element method was applied to approximate the mechanical interactions between the projectile and the barrel.The combustion and the mechanical interactions were coupled through a user subroutine interface in ABAQUS.The correctness and the capability of the finite element approximations in capturing small structural changes were validated by comparing predicted resistance with experiments.Based on the coupled model,the influence of structural parameters of a medium-caliber gun on the system performance was investigated.In order to reduce the research costs,orthogonal tests were designed to investigate the comprehensive effects of the parameters.According to statistical analysis,the important order of the structural parameters on the launching process was obtained.The results indicate that the influence of the width of the rotating band stands out among the studied parameters in the gun.The work provides a method to investigate the influence of multiple parameters on system performance and gives guidance for controlling the system performance.

Multi-target localization for bistatic MIMO radar in the presence of unknown mutual coupling

A decoupling-estimation signal parameters via rotarional invariance technique（ESPRIT） method is presented for multi-target localization with unknown mutual coupling in bistatic multiple-input multiple-output（MIMO） radar.Two steps are carried out in this method.The decoupling operation between angle and mutual coupling estimates is realized by choosing the auxiliary elements on both sides of the transmit and receive uniform linear arrays（ULAs）.Then the ESPRIT method is resilient against the unknown mutual coupling matrix（MCM） and can be directly utilized to estimate the direction of departure（DOD） and the direction of arrival（DOA）.Moreover,the mutual coupling coefficient is estimated by finding the solution of the linear constrained optimization problem.The proposed method allows an efficient DOD and DOA estimates with automatic pairing.Simulation results are presented to verify the effectiveness of the proposed method.

Gas Pool Coupled Activating TIG Welding Method with Coupling Arc Electrode

Gas pool coupled activating TIG(GPCA?TIG) welding put forward in?house can dramatically enhance weld penetration of TIG welding through introducing active element oxygen to reverse the Marangoni convection flow in the molten pool. In order to further improve the welding productivity, the normal solid tungsten electrode is replaced by a kind of coupling arc electrode. The changes of arc pressure distribution along anode surface and the weld appearance were evaluated. On this basis, the dependences of weld shape characterized with weld depth, width and undercut on the main welding parameters were discussed. The results indicate, the substitution of coupling arc electrode can lead to an obvious decrease of arc pressure. Compared to hollow tungsten electrode and twin tungsten electrodes, the coupling arc electrode is much easier to manufacture and has more compacter structure. Combined with the symmetric distribution of arc pressure in di erent directions, this electrode has extensive adaptability. In the GPCA?TIG welding with coupling arc electrode, both the substitution of coupling arc electrode and the introduction of outer active gas oxygen can reduce the possibilities of producing humping bead and undercut. Their joint action makes this welding method have the capability of realizing high travel speed and deep penetration welding.

CHARACTERISTICS OF STRENGTH CONTROL OF ADAPTIVE STRUCTURE WITH ELECTROMECHANICAL COUPLING

Based on the programming method, an electromechanical coupling adaptive statically indeterminate truss structure is controlled for increasing its load capacity. Several main parameters during the process of design of the adaptive structure are selected for a study of its characteristic during the control stage. The curves of each parameter for the effect of control results are plotted and corresponding conclusions are drawn. Thus, the theoretical basis is presented for optimal design, manufacture and control of the adaptive structure.

Impact of the Time Scale of Model Sensitivity Response on Coupled Model Parameter Estimation

That a model has sensitivity responses to parameter uncertainties is a key concept in implementing model parameter es- timation using filtering theory and methodology. Depending on the nature of associated physics and characteristic variability of the fluid in a coupled system, the response time scales of a model to parameters can be different, from hourly to decadal. Unlike state estimation, where the update frequency is usually linked with observational frequency, the update frequency for parameter estimation must be associated with the time scale of the model sensitivity response to the parameter being esti- mated. Here, with a simple coupled model, the impact of model sensitivity response time scales on coupled model parameter estimation is studied. The model includes characteristic synoptic to decadal scales by coupling a long-term varying deep ocean with a slow-varying upper ocean forced by a chaotic atmosphere. Results show that, using the update frequency deter- mined by the model sensitivity response time scale, both the reliability and quality of parameter estimation can be improved significantly, and thus the estimated parameters make the model more consistent with the observation. These simple model results provide a guideline for when real observations are used to optimize the parameters in a coupled general circulation model for improving climate analysis and prediction initialization.

Friction coupling vibration characteristics analysis of aviation hydraulic pipelines considering multi factors

As the power transmission system of an aircraft,a hydraulic pipeline system is equivalent to the " blood vessel" of the aircraft. With the development of aircraft hydraulic system to high pressure,high speed and high power ratio,the fluid-structure interaction vibration mechanism of hydraulic pipeline is more complex and the influence of friction coupling on vibration cannot be ignored. The fluid-structure interaction of hydraulic pipeline will lead to system vibration,lower reliability of system operation and even pipeline rupture. Taking a hydraulic pipeline of C919 aircraft wingtip as the research object,a 14-equation model of fluid-structure interaction vibration considering friction coupling effect is established in this paper. The effects of friction and fluid parameters on the pipeline fluid-structure interaction vibration characteristics are studied and verified by experiments. The research results will provide theoretical guidance for the analysis of the pipeline fluid-structure interaction vibration and have important theoretical significance and great engineering value for promoting the localization process of large aircraft.

The Generalized f(R) Model with Coupling in 5D Spacetime

The generalized f(R)gravity with coupling in five-dimensional(5D)spacetime is studied on the basis of both the 4D generalized f(R)gravity with coupling and the pure f(R)gravity without coupling in 5D spacetime.Specifically,by assuming a hypersurface-orthogonal space-like Killing vector field in 5D spacetime,the generalization of the 4D generalized f(R)gravity to 5D can be realized,which can give the reduced 4-metric coupled with two scalar fields.In particular,we discuss a special class of models,i.e.,f_(1)(R)=f_(2)(R)=αRm(m≠1),and choose B(L_(m))=Lm=-ρin the homogeneous and isotropic cosmology with the 4D Friedmann–Robertson–Walker metric.The numerical analysis shows that the parameter m can be constrained by means of the current observations for the deceleration parameter,which implies that this generalized f(R)model with coupling in 5D spacetime can account for the present accelerated expansion of the universe.