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Design and Engineering of Urban Interchange Ramp Bridge Structure
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作者 Yuxiao Zhang Maode Yang 《Journal of Architectural Research and Development》 2024年第2期62-67,共6页
This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural de... This paper analyzes the structural design of an urban interchange ramp bridge from four aspects,which are the superstructure,pier structure,foundation structure,and deck structure design to summarize the structural design ideas of this urban interchange ramp bridge,which can be used as a reference for future construction of the same bridge. 展开更多
关键词 Interchange ramp bridge structure design Pier structure Foundation structure bridge deck structure
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Technical Analysis of Safety Monitoring and Evaluation of Existing Bridge Structures
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作者 Jiang Feng Qing Yang 《Journal of World Architecture》 2024年第2期17-24,共8页
Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.I... Bridge structure safety monitoring and assessment has been a great concern for the government and the public,and bridge structure safety monitoring and assessment technology has also developed rapidly over the years.Its goal is to equip relevant organizations and professionals with a deep understanding of the principles and practical applications of these technologies.By doing so,it seeks to facilitate the effective implementation of safety monitoring and assessment practices in bridge management.Ultimately,the aim is to foster the constructive development of road and bridge construction and operational management at a broader level. 展开更多
关键词 bridge structure Safety monitoring Defect diagnosis Theoretical modeling method
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Design of foundation structures of sea-crossing bridges on serviceability limit state
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作者 金伟良 胡琦忠 +2 位作者 帅长斌 于群力 鲁征 《Journal of Southeast University(English Edition)》 EI CAS 2008年第1期74-79,共6页
The target reliability indices of the foundation structures of sea-crossing bridges on the serviceability limit state (SLS) are different from those of common bridges due to their different surroundings. Consequentl... The target reliability indices of the foundation structures of sea-crossing bridges on the serviceability limit state (SLS) are different from those of common bridges due to their different surroundings. Consequently, three levels of the target reliability indices, which are 1.5, 2. 0 and 2. 3, respectively, for those structures on the SLS are suggested based on the Joint Committee on Structural Safety (JCSS) model code, and a new method of calibrating factors of live loads, which is based on the contribution ratio of tensile stresses of reinforcing bars produced by various loads to the maximum crack width of concrete, is proposed. Finally, the calibration of the reliability-based factors of the frequent value and the quasi-permanent value of live loads is conducted by the Joint Committee (JC) method through an actual design, and the indices are proved to be reasonable and the new method is proved to be feasible. 展开更多
关键词 sea-crossing bridges target reliability JC (Joint Committee) method frequent value quasi-permanent value foundation structures
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Big Model Strategy for Bridge Structural Health Monitoring Based on Data-Driven, Adaptive Method and Convolutional Neural Network (CNN) Group
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作者 Yadong Xu Weixing Hong +3 位作者 Mohammad Noori Wael A.Altabey Ahmed Silik Nabeel S.D.Farhan 《Structural Durability & Health Monitoring》 EI 2024年第6期763-783,共21页
This study introduces an innovative“Big Model”strategy to enhance Bridge Structural Health Monitoring(SHM)using a Convolutional Neural Network(CNN),time-frequency analysis,and fine element analysis.Leveraging ensemb... This study introduces an innovative“Big Model”strategy to enhance Bridge Structural Health Monitoring(SHM)using a Convolutional Neural Network(CNN),time-frequency analysis,and fine element analysis.Leveraging ensemble methods,collaborative learning,and distributed computing,the approach effectively manages the complexity and scale of large-scale bridge data.The CNN employs transfer learning,fine-tuning,and continuous monitoring to optimize models for adaptive and accurate structural health assessments,focusing on extracting meaningful features through time-frequency analysis.By integrating Finite Element Analysis,time-frequency analysis,and CNNs,the strategy provides a comprehensive understanding of bridge health.Utilizing diverse sensor data,sophisticated feature extraction,and advanced CNN architecture,the model is optimized through rigorous preprocessing and hyperparameter tuning.This approach significantly enhances the ability to make accurate predictions,monitor structural health,and support proactive maintenance practices,thereby ensuring the safety and longevity of critical infrastructure. 展开更多
关键词 structural Health Monitoring(SHM) bridgeS big model Convolutional Neural Network(CNN) Finite Element Method(FEM)
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Review and Prospect of Research on Structural Health Monitoring Technology for Bridges
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作者 Guoyi Liu 《Journal of Architectural Research and Development》 2024年第3期156-161,共6页
As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its a... As a crucial infrastructure in the transport system,the safe operation of bridges is directly related to all aspects of people’s daily lives.The development of bridge structural health monitoring technology and its application play an important role in ensuring the safety and extending the service life of bridges.This paper carries out in-depth research and analysis on the related technology of bridge structural health monitoring.Firstly,the existing monitoring technologies at home and abroad are sorted out,and the advantages and problems of various methods are compared and analyzed,including nondestructive testing,stress measurement,vibration characteristic identification,and other commonly used monitoring technologies.Secondly,the key technologies and equipment in the bridge health monitoring system,such as sensor technology,data acquisition,and processing technology,are introduced in detail.Finally,the development trend in the field of bridge health monitoring is prospected from both theoretical research and technical application.In the future,with the development of emerging technologies such as big data,cloud computing,and the Internet of Things,it is expected that bridge health monitoring with intelligent and systematic features will be more widely applied to provide a stronger guarantee for the safe and efficient operation of bridges. 展开更多
关键词 bridge structural health monitoring Safe operation Monitoring technology
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Vector-intensity measure based seismic vulnerability analysis of bridge structures 被引量:8
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作者 Li Zhongxian Li Yang Li Ning 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2014年第4期695-705,共11页
This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measure... This paper presents a method for seismic vulnerability analysis of bridge structures based on vector-valued intensity measure (viM), which predicts the limit-state capacities efficiently with multi-intensity measures of seismic event. Accounting for the uncertainties of the bridge model, ten single-bent overpass bridge structures are taken as samples statistically using Latin hypercube sampling approach. 200 earthquake records are chosen randomly for the uncertainties of ground motions according to the site condition of the bridges. The uncertainties of structural capacity and seismic demand are evaluated with the ratios of demand to capacity in different damage state. By comparing the relative importance of different intensity measures, Sa(T1) and Sa(T2) are chosen as viM. Then, the vector-valued fragility functions of different bridge components are developed. Finally, the system-level vulnerability of the bridge based on viM is studied with Duunett- Sobel class correlation matrix which can consider the correlation effects of different bridge components. The study indicates that an increment IMs from a scalar IM to viM results in a significant reduction in the dispersion of fragility functions and in the uncertainties in evaluating earthquake risk. The feasibility and validity of the proposed vulnerability analysis method is validated and the bridge is more vulnerable than any components. 展开更多
关键词 bridge structure seismic vulnerability analysis vector-valued intensity measure components' correlation system vulnerability
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Finite Element Model Updating of Bridge Structures Based on Sensitivity Analysis and Optimization Algorithm 被引量:6
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作者 HUANG Minshui ZHU Hongping 《Wuhan University Journal of Natural Sciences》 CAS 2008年第1期87-92,共6页
The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structur... The dynamic characteristics of bridge structures, such as the natural frequencies, mode shapes and model damping ratio, are the basis of structural dynamic computation, seismic analysis, vibration control and structural health condition monitoring. In this paper, a three-dimensional finite-element model is established for a highway bridge over a railway on No.312 National Highway and the ambient test is carried out in site, the dynamic characteristics of the bridge are studied using the finite-element analysis and ambient vibration measurements. Comparison between the theoretical and experimental results shows that the frequency differences of the modes range between 0.44% and 8.77%. If the measurement is more reliable, the finite element model updating is necessary. Thus, a set of design variables is selected based on sensitivity analysis, then the finite element model of the bridge is updated based on optimization algorithm. The results of model updating show that the proposed updating method in this paper is more simple and effective, the updated finite element model can reflect the dynamic characteristics of the bridge better, the analytical results can provide the theoretical basis for damage identification and health condition monitoring of the bridge. 展开更多
关键词 sensitivity analysis optimization algorithm model updating bridge structure
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Effect of Crosslink Structure of Bridge Polycarboxylate Superplasticizers on Dispersion Ability 被引量:5
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作者 毕耀 雷家珩 +1 位作者 DU Xiaodi ZHANG Anfu 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2013年第2期339-342,共4页
Bridge polycarboxylate superplasticizers(PCs) with crosslink structure were synthesized by using polyethyleneglycol di-acrylate(PEGdA), replacing partial polyethyleneglycol mono-acrylate (PEGmA) as crosslinking ... Bridge polycarboxylate superplasticizers(PCs) with crosslink structure were synthesized by using polyethyleneglycol di-acrylate(PEGdA), replacing partial polyethyleneglycol mono-acrylate (PEGmA) as crosslinking agent. Structures of bridge PCs were analyzed by gel permeation chromatography, and dispersion ability was evaluated by cement paste dispersity variation on time and rheology test. The experimental results showed that, molecular weight(MW) of bridge PCs increased with increase of PEGdA proportion, and MW distribution curve changed from Gaussian to fiat like, which meant notable increase of highly crosslinked copolymer. Bridge PCs led to decreased initial cement paste dispersity and better dispersity retention due to slow releasing. Further research showed that, PEGdA proportion had slight effect on polymerization degree of backbone, MW distribution of backbone deviated from Gaussian distribution and shoulder peaks appeared on distribution curve when PEGdA increased. 展开更多
关键词 bridge polycarboxylate superplasticizers cement paste dispersity crosslink structure polyethyleneglycol di-acrylate
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Structural Design of Roadbed and Pavement in Transition Section of Roads and Bridges
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作者 Bai Fan 《Journal of World Architecture》 2024年第4期21-26,共6页
As the lifeline of social development,road and bridge projects are the main channel to realize resource transportation and economic circulation.Ensuring the quality of road and bridge project construction is crucial f... As the lifeline of social development,road and bridge projects are the main channel to realize resource transportation and economic circulation.Ensuring the quality of road and bridge project construction is crucial for the development of society,the economy,and people’s livelihoods.This paper studies the design of roadbed pavement structures in road and bridge transition sections.It aims to provide technical references and significance for China’s road and bridge engineering design and construction units,promoting scientific and standardized design in these actions.This will contribute to the safety and stable operation of road and bridge projects,offering effective technical support.Furthermore,it seeks to foster the sustainable and healthy development of China’s road and bridge engineering on a macro level. 展开更多
关键词 Road and bridge transition section Roadbed pavement structure design Lap plate Easing transition section Drainage system
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Synthesis and Crystal Structure of the Ladder-like Organotin Complex: μ-pentaoxygen bridged penta(bis-benzyltin) bis-salicylate 被引量:7
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作者 WANG Jian-Qiu CHEN Zhi-Min ZENG Rong-Ying KUANG Dai-Zhi FENG Yong-Lan ZHANG Fu-Xing 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第12期1387-1392,共6页
A novel organotin complex of μ-pentaoxygen bridged penta(bis-benzyltin) bissalicylate has been synthesized by the reaction of bis-benzyltin oxide and salicylic acid and its structure has been determined by X-ray di... A novel organotin complex of μ-pentaoxygen bridged penta(bis-benzyltin) bissalicylate has been synthesized by the reaction of bis-benzyltin oxide and salicylic acid and its structure has been determined by X-ray diffraction. The crystal belongs to monoclinic, space group P21/n with a = 1.7206(5), b = 2.1401(6), c = 2.1488(6)nm, β= 93.325(5)°, V = 7.899(4) nm^3, Z = 4, Dc = 1.564 g/cm^3,μ(MoKα) = 16.17cm^-1, Mr = 1859.94, F(000) = 3692, R1= 0.0755 and wR2= 0.1557. According to structural analysis, the coordination geometry of tin is a distorted trigonal bipyramid, and the ladder-like structure is shaped by four Sn2O2 planar four-membered rings. 展开更多
关键词 μ-pentaoxygen bridged penta(bis-benzyltin) bis-salicylate synthesis crystal structure
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Internal Force Distribution in Steel-Concrete Composite Structure for Pylon of Cable-Stayed Bridge 被引量:5
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作者 蒲黔辉 白光亮 《Journal of Southwest Jiaotong University(English Edition)》 2009年第2期95-101,共7页
Adopting a steel-anchor beam and steel corbel composite structure in the anchor zone on pylon is one of the key techniques for the design of Jintang bridge, a cable-stayed bridge in Zhoushan, China. In order to ensure... Adopting a steel-anchor beam and steel corbel composite structure in the anchor zone on pylon is one of the key techniques for the design of Jintang bridge, a cable-stayed bridge in Zhoushan, China. In order to ensure the safety of the steel-concrete composite structure, a stud connector model for the joint section was put forward. Experiments were conducted to obtain the relation between load and slip of specimen, the failure pattern of stud connector, the yield bearing capacity and ultimate bearing capacity of a single stud, etc. The whole process of the structural behavior of the specimen was comprehensively analyzed. The features of the internal force distribution in the steel-concrete composite structure and the strain distribution of stud connector under different loads were emphatically studied. The test results show that the stud connector is applicable for the steel-concrete composite structure for pylon of Jintang bridge. The stud has a good ductility performance and a obvious yield process before its destruction. The stud connector basically works in a state of elasticity under a load less than the yield load. 展开更多
关键词 Stud connector Experimental research Steel-concrete composite structure Cable-stayed bridge Internal force distribution
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Synthesis and Crystal Structure of 1D Chloride Bridged Cadmium(Ⅱ) Chain
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作者 欧光川 《湖南科技学院学报》 2005年第5期113-115,共3页
Hydrothermal reaction of 1,10-phenanthroline with CdCl2·2.5H2O in aqueous solution leads to the complex of [Cd(μ-Cl)2(phen)]n (phen = 1-10-phenanthroline). The crystal structure has been determined by X-ray anal... Hydrothermal reaction of 1,10-phenanthroline with CdCl2·2.5H2O in aqueous solution leads to the complex of [Cd(μ-Cl)2(phen)]n (phen = 1-10-phenanthroline). The crystal structure has been determined by X-ray analysis. It crystallizes in monoclinic with space group C2/c, a = 16.947(3), b = 10.529(2), c = 7.235(1) , β = 110.795(3)°, V = 1208.8(3) 3, Z = 4, Dc = 1.997 g.cm-3, μ= 2.22 mm-1, F(000) = 704, R = 0.0231, Rw = 0.0626 for 1194 reflections with I > 2σ (I). In the crystal structure, the [Cd(phen)]2+ units are bridged by chloride ions to form 1D chain. The 1D chains combine through π……π interactions of phen groups to form 2D infinite molecular zipper. 展开更多
关键词 合成反应 晶体结构 氯化镉 钱恩
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Synthesis and Crystal Structure of an Azide Bridged Binuclear Zinc(Ⅱ) Dimer Containing Taurine Schiff Base [Zn_2(C_8H_9N_2O_3S)_2·(N_3)_2·(H_2O)_2]_2·_2H_2O 被引量:3
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作者 JIANG Yi-Min LI Jia-Ming +1 位作者 XIE Fu-Qing WANG Yan-Fei 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2006年第7期767-770,共4页
The title complex [Zn2L2(N3)2(H2O)2]·2H2O (L = N-(2-pyridylmethylidene) taurine) has been synthesized in a methanol-water solution. The crystal belongs to monoclinic, space group P2 1/C with a = 15.8064... The title complex [Zn2L2(N3)2(H2O)2]·2H2O (L = N-(2-pyridylmethylidene) taurine) has been synthesized in a methanol-water solution. The crystal belongs to monoclinic, space group P2 1/C with a = 15.8064(10), b = 10.5015(5), c = 17.3193(11) ,A, β= 111.314(2)°, V = 2678.2 (3) ,A ^3 C16H26N10O10S2Zn2, Mr = 713.33, Z = 4, DC = 1.769 g/cm^3, μ = 2.017 mm^-1 and F(000) = 1456. The asymmetric unit consists of two half-molecules of the complex and two water molecules. Four N and two O atoms form the coordination environment of each Zn atom, resulting in a distorted octahedral configuration. The two halves of each independent dimer are related by a crystallographic inversion centre, which lies at the centre of the ring formed by two Zn atoms and the coordinating atoms of the two azide anions. The average separation of Zn(Ⅱ)...Zn(Ⅱ) is 3.322 A. The molecules are linked by O-H...O hydrogen bonds, generating an interesting zigzag infinite chain structure in the ac plane. 展开更多
关键词 binuclear zinc complex N-(2-pyridylmethylidene)-taurine schiff base bridging azide crystal structure
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Synthesis and Crystal Structure of a Dinuclear Cu(II) Complex with Tridentate Schiff Base and Azido Bridge 被引量:1
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作者 LINHong FENGYunLong GAOShan 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第4期375-378,共4页
A new dinuclear copper(II) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P21/c with a =... A new dinuclear copper(II) complex ([Cu(C12H17N2O)(N3)]2, C24H34Cu2N10O2) has been synthesized and characterized by X-ray structure determination. It crystallizes in the monoclinic system, space group P21/c with a = 18.529(4), b = 10.933(2), c = 14.534(3) ?, β = 111.07(3)°, V = 2748(1) ?3, Z = 4, Mr = 621.69, F(000) = 1288, Dc = 1.503 g/cm3 and μ(MoKα) = 1.590 mm?1. The structure was refined to R = 0.0647 and wR = 0.1846 for 4406 observed reflections (I > 2σ(I)). The asymmetric unit comprises two halfmolecules. The complex is a centrosymmetric dimmer in which the copper atoms are penta-coordinated by three coordination atoms from the corresponding tridentate Schiff base ligand and two bridging azide anions. The Cu(II)…Cu(II) average distance is 3.350(1) ?. 展开更多
关键词 dimethylamino-1-propylamine SALICYLALDEHYDE Schiff base Cu(II) complex crystal structure bridging azide
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Soil Structure Interaction Effects on Pushover Analysis of Short Span RC Bridges 被引量:1
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作者 Islam M. Ezz El-Arab 《Open Journal of Civil Engineering》 2017年第3期348-361,共14页
A three dimensional finite element of nonlinear pushover analysis for short span Reinforced Concrete (RC) bridge with circular piers cross section is modeling to present effects of soil structural interaction (SSI). S... A three dimensional finite element of nonlinear pushover analysis for short span Reinforced Concrete (RC) bridge with circular piers cross section is modeling to present effects of soil structural interaction (SSI). Structural elements models are including linear foundation springs modeling, and nonlinear RC piers modeling. The paper succeeded to present the SSI effects of nonlinear pushover analysis of short spans RC bridges to determine the significant effects on dynamic characteristics and displacement capacity of short span RC bridges performance;that is increasing within range 11% to 20% compared to baseline pushover analysis of bridge without SSI effects. Results show the bridge stiffness decreases due to SSI effects on the bridge support for more flexible soils types that generates large displacement, with corresponding less base shear in bridge piers and footings by average percentage 12% and 18%, which is important for structural evaluation for new bridge construction and also, for strengthening and repair works evaluation of existing bridges. 展开更多
关键词 SOIL structure INTERACTION PUSHOVER Analysis RC bridge Nonlinear
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Synthesis and Crystal Structure of a Three-dimensional Mn(Ⅱ) Coordination Polymer with 3-(Pyrazin-2-yloxy)-pyridine and Azide Anion as Mixed Bridge Ligand 被引量:1
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作者 李红 赵红艳 +1 位作者 张士国 石敬民 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2008年第12期1511-1513,共3页
A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its c... A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its crystal structure was determined by X-ray crystallography. The crystal data: triclinic system, space group P1, with a = 6.794(4), b = 9.885(6), c = 9.947(6) A, α = 64.170(6), β= 84.190(8), γ= 85.319(8)°, V = 597.7(6)A^3, Z = 1, C18H14Mn2N18O2, Mr = 624.35, Dc = 1.735 g/cm^3, F(000) = 314 and μ = 1.117 mm^-1. In the crystal, the azide anion acts as a bridge ligand and makes adjacent Mn(Ⅱ) ions connect into a two-dimensional sheet on the ab plane, then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along 展开更多
关键词 II Synthesis and Crystal structure of a Three-dimensional Mn Coordination Polymer with 3 Pyrazin-2-yloxy pyridine and Azide Anion as Mixed bridge Ligand
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Shake table test of soil-pile groups-bridge structure interaction in liquefiable ground 被引量:16
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作者 Tang Liang Ling Xianzhang +2 位作者 Xu Pengju Gao Xia Wang Dongsheng 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2010年第1期39-50,共12页
This paper describes a shake table test study on the seismic response of low-cap pile groups and a bridge structure in liquefiable ground. The soil profile, contained in a large-scale laminar shear box, consisted of a... This paper describes a shake table test study on the seismic response of low-cap pile groups and a bridge structure in liquefiable ground. The soil profile, contained in a large-scale laminar shear box, consisted of a horizontally saturated sand layer overlaid with a silty clay layer, with the simulated low-cap pile groups embedded. The container was excited in three E1 Centro earthquake events of different levels. Test results indicate that excessive pore pressure (EPP) during slight shaking only slightly accumulated, and the accumulation mainly occurred during strong shaking. The EPP was gradually enhanced as the amplitude and duration of the input acceleration increased. The acceleration response of the sand was remarkably influenced by soil liquefaction. As soil liquefaction occurred, the peak sand displacement gradually lagged behind the input acceleration; meanwhile, the sand displacement exhibited an increasing effect on the bending moment of the pile, and acceleration responses of the pile and the sand layer gradually changed from decreasing to increasing in the vertical direction from the bottom to the top. A jump variation of the bending moment on the pile was observed near the soil interface in all three input earthquake events. It is thought that the shake table tests could provide the groundwork for further seismic performance studies of low-cap pile groups used in bridges located on liquefiable groun. 展开更多
关键词 liquefiable ground seismic soil-pile-structure interaction pile groups of bridge shake table test
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Rock bridge slice element method in slope stability analysis based on multi-scale geological structure mapping
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作者 张发明 汪北华 +2 位作者 陈祖煜 汪小刚 贾志欣 《Journal of Central South University》 SCIE EI CAS 2008年第S2期131-137,共7页
The searching method of failure surface which consists of complex geological structures in high and steep rock slopes was studied. Based on computer simulation technology and Monte-Carlo method, three dimensional mult... The searching method of failure surface which consists of complex geological structures in high and steep rock slopes was studied. Based on computer simulation technology and Monte-Carlo method, three dimensional multi-scale geological structures such as engineering scale and statistical scale structures of the slope were simulated. The searching method of failure route which consists of joints and rock bridges was determined via simulation annealing method by considering the shear strength of joints or rock bridges in one supposed route. When shear strengths of all the supposed routes were computed, the least shear strength route was considered failure route. Then, the inclined slice of joint slices and rock bridge slices were separated according to the position of joints and rock bridges. For the rock bridge slices, by distinguishing the failure model, the force direction to the next slice was defined. Finally, the limit equilibrium equations for every slice were established, and the slope stability factor was obtained. One practical example indicates that the discussed method is more closely to the real condition. 展开更多
关键词 ROCK SLOPE three dimensional GEOLOGICAL structure ROCK bridge SLICE element method stability
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One and Two-dimensional Structures of a New Oxamido Copper(II) Complex with Phthalato Bridged
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作者 陈静 姜宗慧 +1 位作者 廖代正 闫世平 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2005年第9期1017-1020,共4页
A new o-phthalato-bridged oxamide copper(Ⅱ) complex 1, {[Cu2(oxap)](pht). 4H2O}n (oxap=N, N'-bis(2-aminopropyl)oxamide, pht= phthalate dianion), has been prepared and structurally characterized. It crystal... A new o-phthalato-bridged oxamide copper(Ⅱ) complex 1, {[Cu2(oxap)](pht). 4H2O}n (oxap=N, N'-bis(2-aminopropyl)oxamide, pht= phthalate dianion), has been prepared and structurally characterized. It crystallizes in monoclinic, space group C2/c with a=23.424(4), h=7.9696(14), c=15.727(3)A°,β=129.617(2)°, C16H28Cu2N4O10, Mr=563.50, V=2261.6(7) A°, Z=4, Dc=1.655 g/cm^3, μ(MoKα)=1.939 mm^-1, F(000) = 1160, the final R=0.0393 and wR=0.0928 for 1707 observed reflections with I〉2σ(1). Single-crystal X-ray analysis reveals that 1 displays a one-dimensional zigzag chain structure, in which each Cu(oxap) moiety adopting trans-conformation is connected by ,μ1,6-phthalate anion bridges, and these zigzag chains are further linked by another ,μ1,6-phthalate anion bridge to form a 2D sheet structure. The polar guest water molecules reside in the inter-and intrasheets to stabilize the whole crystal structure. 展开更多
关键词 PHTHALATE OXAMIDE bridgeD copper(Ⅱ) complex crystal structure HOST-GUEST
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The Assembly and Molecular Structure of a Novel One-dimensionalCyanide-bridged [Ni(pn)_2Ni(CN)_4]_n·nH_2 O Complex
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作者 Xiu Ying ZHANG Dong GUO +5 位作者 Jun Ming TANG Shu Zhong ZHAN Qing Zi HAN Chen Xia DU Yu ZHU Rui Na YANG( Department of Chemistry, Henan Normal University, Xinxiang 453002)( Assaying and Testing Centre, Zhengzhou University, Zhengzhou 450052)( Henan Chemistr 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第11期975-978,共4页
The synthesis, structure and characterization of a new one-dimensional cyanide-bridgedcomplex [Ni(pn)_2Ni(CN)4]n'nH2O (where pn = 1,2-diaminopropane) are described. The structure ofthis complex consists of a one-d... The synthesis, structure and characterization of a new one-dimensional cyanide-bridgedcomplex [Ni(pn)_2Ni(CN)4]n'nH2O (where pn = 1,2-diaminopropane) are described. The structure ofthis complex consists of a one-dimensional polymeric chain-Ni(pn)2-NC-Ni(CN)2-CN-Ni(pn)2- inwhich the Ni(II) centers are linked by two CN groups. 展开更多
关键词 Cyanide bridged complex polynuclear complex crystal structure.
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