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Spatiotemporal multiple coherence resonances and calcium waves in a coupled hepatocyte system 被引量:3
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作者 王宝华 陆启韶 +1 位作者 吕淑娟 郎秀锋 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第3期872-880,共9页
Spatiotemporal multiple coherence resonances coupled hepatocytes are studied. It is shown that for calcium activities induced by weak Gaussian white noise in bi-resonances in hepatocytes are induced by the interplay a... Spatiotemporal multiple coherence resonances coupled hepatocytes are studied. It is shown that for calcium activities induced by weak Gaussian white noise in bi-resonances in hepatocytes are induced by the interplay and competition between noise and coupling of cells, in other words, the cell in network can be excited either by noise or by its neighbour via gap junction which can transfer calcium ions between cells. Furthermore, the intercellular annular calcium waves induced by noise are observed, in which the wave length decreases with noise intensity augmenting but increases monotonically with coupling strength increasing. And for a fixed noise level, there is an optimal coupling strength that makes the coherence resonance reach maximum. 展开更多
关键词 multiple resonance COHERENCE intercellular calcium wave noise
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Multiple Resonance and Stability of a Motor-elastic Linkage Mechanism System 被引量:1
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作者 李兆军 蔡敢为 戴文正 《Journal of Donghua University(English Edition)》 EI CAS 2006年第4期1-6,共6页
The dynamics of a three-phase AC motor-elastic linkage mechanism system is considered. Taking the drive motor and the linkage mechanism as an integrated system, the coupling dynamic equations of the system are establi... The dynamics of a three-phase AC motor-elastic linkage mechanism system is considered. Taking the drive motor and the linkage mechanism as an integrated system, the coupling dynamic equations of the system are established by the finite element method. The multiple resonance and its stability of the system are studied using the method of multiple scales. The first order approximate solutions of the multiple resonance of the system are obtained. An algorithm for determining the stability of resonance is derived. The studies show that the multiple resonance and its stability of the system are not only related to the structure parameters of the linkage mechanism, but also to the electromagnetism parameters of the motor. At last, an experiment is given to verify the results of the theoretical analysis. 展开更多
关键词 MOTOR link mechanism multiple resonance STABILITY multiple scales method.
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MULTIPLE SOLUTIONS FOR HAMILTONIAN SYSTEMS WITH PERIODIC NONLINEARITY AND STRONG RESONANCE
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作者 刘嘉荃 《Acta Mathematica Scientia》 SCIE CSCD 1991年第4期417-423,共7页
I. Introduction In this paper we are looking for solutions of the following Hamiltonian system of second order: where x= (x1, x2) and V satisfies (V. 1) V: R×R2→R is a C1-function, 1-periodic In t, (V.2) V... I. Introduction In this paper we are looking for solutions of the following Hamiltonian system of second order: where x= (x1, x2) and V satisfies (V. 1) V: R×R2→R is a C1-function, 1-periodic In t, (V.2) V is periodic in x1 with the period T>0, (V. 3) V→O, Vx→O as |x2|→∞, uniformly in (t, x1). 展开更多
关键词 multiple SOLUTIONS FOR HAMILTONIAN systemS WITH PERIODIC NONLINEARITY AND STRONG resonance
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Spiral Waves and Multiple Spatial Coherence Resonances Induced by Colored Noise in Neuronal Network 被引量:4
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作者 TANG Zhao LI Yu-Ye +2 位作者 XI Lei JIA Bing GU Hua-Guang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2012年第1期61-67,共7页
Gaussian colored noise induced spatial patterns and spatial coherence resonances in a square lattice neuronal network composed of Morris-Lecar neurons are studied.Each neuron is at resting state near a saddle-node bif... Gaussian colored noise induced spatial patterns and spatial coherence resonances in a square lattice neuronal network composed of Morris-Lecar neurons are studied.Each neuron is at resting state near a saddle-node bifurcation on invariant circle,coupled to its nearest neighbors by electronic coupling.Spiral waves with different structures and disordered spatial structures can be alternately induced within a large range of noise intensity.By calculating spatial structure function and signal-to-noise ratio(SNR),it is found that SNR values are higher when the spiral structures are simple and are lower when the spatial patterns are complex or disordered,respectively.SNR manifest multiple local maximal peaks,indicating that the colored noise can induce multiple spatial coherence resonances.The maximal SNR values decrease as the correlation time of the noise increases.These results not only provide an example of multiple resonances,but also show that Gaussian colored noise play constructive roles in neuronal network. 展开更多
关键词 multiple spatial coherence resonance spiral wave colored noise neuronal network
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Middle range wireless power transfer systems with multiple resonators 被引量:1
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作者 陈新 张桂香 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第6期2127-2136,共10页
The equivalent two-port network model of a middle range wireless power transfer(WPT) system was presented based on strongly coupled multiple resonators. The key parameters of the WPT system include self-inductance, re... The equivalent two-port network model of a middle range wireless power transfer(WPT) system was presented based on strongly coupled multiple resonators. The key parameters of the WPT system include self-inductance, resistance, parasitic capacitance, mutual inductance and S-parameters of coils & resonators were analyzed. The impedance matching method was used to optimize load power and transmission efficiency of the multi-resonator WPT system, and the impedance matching method was realized through adjusting the distances between the coils and resonators. Experiments show that the impedance matching method can effectively improve load power and transmission efficiency for middle range wireless power transfer systems with multiple resonators, at distances up to 3 times the coil radius with efficiency more than 70% and load power also close to 3.5 W. 展开更多
关键词 wireless power transfer middle range multiple resonators S-PARAMETERS two-port network impedance matching
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Multiple internal resonances of rotating composite cylindrical shells under varying temperature fields
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作者 Yunfei LIU Jun WANG +2 位作者 Jiaxin HU Zhaoye QIN Fulei CHU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2022年第10期1543-1554,共12页
Composite cylindrical shells,as key components,are widely employed in large rotating machines.However,due to the frequency bifurcations and dense frequency spectra caused by rotation,the nonlinear vibration usually ha... Composite cylindrical shells,as key components,are widely employed in large rotating machines.However,due to the frequency bifurcations and dense frequency spectra caused by rotation,the nonlinear vibration usually has the behavior of complex multiple internal resonances.In addition,the varying temperature fields make the responses of the system further difficult to obtain.Therefore,the multiple internal resonances of composite cylindrical shells with porosities induced by rotation with varying temperature fields are studied in this paper.Three different types of the temperature fields,the Coriolis forces,and the centrifugal force are considered here.The Hamilton principle and the modified Donnell nonlinear shell theory are used to obtain the equilibrium equations of the system,which are transformed into the ordinary differential equations(ODEs)by the multi-mode Galerkin technique.Thereafter,the pseudo-arclength continuation method,which can identify the regions of instability,is introduced to obtain the numerical results.The detailed parametric analysis of the rotating composite shells is performed.Multiple internal resonances caused by the interaction between backward and forward wave modes and the energy transfer phenomenon are detected.Besides,the nonlinear amplitude-frequency response curves are different under different temperature fields. 展开更多
关键词 multiple internal resonances rotation effect nonlinear temperature variation multi-mode Galerkin technique pseudo-arclength continuation method coupled effect
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Charge Resonance Enhanced Multiple Ionization of H2O Molecules in Intense Laser Fields
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作者 刘鸿 黎敏 +5 位作者 解西国 吴聪 邓勇开 吴成印 龚旗煌 刘运全 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第6期43-47,共5页
We perform a kinetically complete measurement on the fragmentation of Coulomb explosion of 1-120 molecules in intense few-cycle linearly and circularly polarized laser fields. Both the fragmentations of 1t203+ and H... We perform a kinetically complete measurement on the fragmentation of Coulomb explosion of 1-120 molecules in intense few-cycle linearly and circularly polarized laser fields. Both the fragmentations of 1t203+ and H204+ reveal the concerted pathway of dissociation. The length of the OH bond prior to the Coulomb explosion of both molecular ions is sensitive to the laser pulse duration and laser intensity. However, the bending angle of H-O-H is less sensitive to the pulse duration and laser intensity. We introduce the mechanism of charge resonance enhanced double ionization to elucidate the triple (or quadruple) dissociative ionization dynamics of H20, in which two electrons are non-adiabatically localized at the protons of the precursor ion H2O^+ (or H2O^2+) and are released simultaneously due to the over barrier ionization in the combined laser field and molecular ionic potential. Such charge resonance enhanced multiple ionization is not suppressed in few-cycle laser fields and elliptically polarized laser fields. 展开更多
关键词 In LENGTH Charge resonance Enhanced multiple Ionization of H2O Molecules in Intense Laser Fields
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Nonlinear study of the dynamic behavior of a string-beam coupled system under combined excitations 被引量:3
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作者 Y.S. Hamed M. Sayed +1 位作者 D.-X. Cao W. Zhang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第6期1034-1051,共18页
In this paper,the nonlinear dynamic behavior of a string-beam coupled system subjected to external,parametric and tuned excitations is presented.The governing equations of motion are obtained for the nonlinear transve... In this paper,the nonlinear dynamic behavior of a string-beam coupled system subjected to external,parametric and tuned excitations is presented.The governing equations of motion are obtained for the nonlinear transverse vibrations of the string-beam coupled system which are described by a set of ordinary differential equations with two degrees of freedom.The case of 1:1 internal resonance between the modes of the beam and string,and the primary and combined resonance for the beam is considered.The method of multiple scales is utilized to analyze the nonlinear responses of the string-beam coupled system and obtain approximate solutions up to and including the second-order approximations.All resonance cases are extracted and investigated.Stability of the system is studied using frequency response equations and the phase-plane method.Numerical solutions are carried out and the results are presented graphically and discussed.The effects of the different parameters on both response and stability of the system are investigated.The reported results are compared to the available published work. 展开更多
关键词 1:1 internal resonance - String-beam - multiple scales Chaotic response Stability
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CHAOTIC BEHAVIOUR OF FORCED OSCILLATOR CONTAINING A SQUARE NONLINEAR TERM ON PRINCIPAL RESONANCE CURVES
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作者 裴钦元 李骊 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1995年第3期229-236,共8页
In this paper based on [1]we go further into the study of chaotic behaviour of theforced oscillator containing a square nonlinear term by the methods of multiple scalesand numerical simulation. Relation between the c... In this paper based on [1]we go further into the study of chaotic behaviour of theforced oscillator containing a square nonlinear term by the methods of multiple scalesand numerical simulation. Relation between the chaotic domain and principal resonance curve is discussed. By analyzing the stability of principal resonance curve weinfer that chaotic motion would occur near the frequency at which the principalresonance curve has vertical tangent.Results of numerical simulation confirm thisinference.Thus we offer an effective way to seek the chaotic motion of the systems which are hard to he investigated by Melnikoy method. 展开更多
关键词 method of multiple scales. principal resonance curve. numericalsimulation. chaotic motion
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STUDY ON LOWER ORDER HARMONIC RESONANCE OF ELASTIC LINKAGES──SUPER HARMONIC RESONANCES
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作者 Wang Yuxin,Zhang Ce, (Tianjin University) Yang Chuanmin(Tianjin University of Commerce) 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 1996年第1期49-56,共3页
The superharmonic resonances of elastic linkages are studied by using the method of multiple scales under the excitation of its inertial foree。 The analyses demonstrate that the superharmonic resonances cau... The superharmonic resonances of elastic linkages are studied by using the method of multiple scales under the excitation of its inertial foree。 The analyses demonstrate that the superharmonic resonances caused by the quadratic and cubic nonlinearities due to large elastic deformations of the flexible links and multi-frequencies of the inertial force of linkages are the reason to produce the critical speeds. The results of explaining of the lower order harmonic reso- nances by“1/n' method are verified theoretically。 展开更多
关键词 Elastic linkages Harmonic resonance Superharmonic resonance Method of multiple scales
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High Permeability in Broadband of Co-sputtered [Fe-Fe_(20)Ni_(80)/Cr]_(n) Multilayer Films 被引量:1
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作者 罗创钰 LIU Xing +1 位作者 王峰 李维 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期410-416,共7页
To achieve high microwave permeability in wide-band for the micron-thick magnetic films,[Fe-Fe_(20)Ni_(80)/Cr]_(n) multilayer structure was proposed by co-sputtering Fe and FeNi to form the magnetic layers and Cr to f... To achieve high microwave permeability in wide-band for the micron-thick magnetic films,[Fe-Fe_(20)Ni_(80)/Cr]_(n) multilayer structure was proposed by co-sputtering Fe and FeNi to form the magnetic layers and Cr to form the interlayers.The multilayer structure contributes to the high permeability by reducing the coercivity and diminishing out-of-plane magnetization.The maximum imaginary permeability of[Fe-Fe_(20)Ni_(80)/Cr]_(n) multilayer film reaches a large value of 800 at 0.52 GHz even though its overall thickness exceeds 1μm.Besides,the magnetic resonance frequency of the multilayer film can be modulated from 0.52 to 1.35 GHz by adjusting the sputtering power of Fe from 0 to 86 W,and its bandwidth for μ’’>200(Δf) is as large as 2.0 GHz.The desirable broad Δf of magnetic permeability,which can be well fitted by the Landau-Lifshitz-Gilbert equations,is due to dual magnetic resonances originated from double magnetic phases of Fe and FeNi that are of different saturation magnetization.The micron-thick multilayer films with high permeability in extended waveband are promising candidate for electromagnetic noise suppression application. 展开更多
关键词 magnetron sputtering multiple magnetic resonance high permeability electromagnetic noise suppression
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Chiral multiple-resonance thermally activated delayed fluorescence materials based on chiral spiro-axis skeleton for efficient circularly polarized electroluminescence
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作者 Shi-Quan Song Xiao Han +4 位作者 Zhong-Zhong Huo Ching-Fai Yip Xian-Fang Hong Meng-Ning Ding You-Xuan Zheng 《Science China Chemistry》 SCIE EI CAS CSCD 2024年第7期2257-2264,共8页
Chiral luminescence materials have potential applications in the field of three-dimensional displays due to their circularly polarized luminescence(CPL)characteristics.However,the further development of circularly pol... Chiral luminescence materials have potential applications in the field of three-dimensional displays due to their circularly polarized luminescence(CPL)characteristics.However,the further development of circularly polarized organic light-emitting diodes(CP-OLEDs)needs to meet the requirements of high efficiency,high color purity,low cost,and high dissymmetry factor(gPLor gEL),chiral multiple resonance thermally activated delayed fluorescence(MR-TADF)materials are considered as candidates in these aspects.Herein,based on a pair of chiral spirofluorene precursors,two pairs of high-performance chiral MR-TADF emitters((R/S)-p-Spiro-DtBuCzB and(R/S)-m-Spiro-DtBuCzB)are developed,which exhibit strong emissions peaking at 491 and 502 nm in toluene with full-width at half-maximum values of 25 and 33 nm,respectively.In addition,small singlet–triplet energy gaps of 0.15 and 0.10 eV with high absolute photoluminescence efficiencies of 95.0%and 96.7%are observed for p-Spiro-DtBuCzB and m-Spiro-DtBuCzB molecules,respectively.OLEDs based on p-Spiro-DtBuCzB and m-Spiro-DtBuCzB display high maximum external quantum efficiencies of 29.6%and 33.8%,respectively.Most importantly,CP-OLEDs present symmetric circularly polarized electroluminescence spectra with|gEL|factors of 3.36×10^(-4)and 7.66×10^(-4)for devices based on(R/S)-p-Spiro-DtBuCzB and(R/S)-m-Spiro-DtBuCzB enantiomers,respectively. 展开更多
关键词 chiral spiro-axis skeleton-based material multiple resonance thermally activated delayed fluorescence circularly polarized electroluminescence dissymmetry factor external quantum efficiency
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Parameter Diversity Induced Multiple Spatial Coherence Resonances and Spiral Waves in Neuronal Network with and Without Noise 被引量:5
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作者 李玉叶 贾冰 +1 位作者 古华光 安书成 《Communications in Theoretical Physics》 SCIE CAS CSCD 2012年第5期817-824,共8页
Diversity in the neurons and noise are inevitable in the real neuronal network.In this paper,parameter diversity induced spiral waves and multiple spatial coherence resonances in a two-dimensional neuronal network wit... Diversity in the neurons and noise are inevitable in the real neuronal network.In this paper,parameter diversity induced spiral waves and multiple spatial coherence resonances in a two-dimensional neuronal network without or with noise are simulated.The relationship between the multiple resonances and the multiple transitions between patterns of spiral waves are identified.The coherence degrees induced by the diversity are suppressed when noise is introduced and noise density is increased.The results suggest that natural nervous system might profit from both parameter diversity and noise,provided a possible approach to control formation and transition of spiral wave by the cooperation between the diversity and noise. 展开更多
关键词 multiple spatial coherence resonance spiral wave DIVERSITY neuronal network
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Multiple resonances with time delays in scale-free networks of Hodgkin-Huxley neurons subjected to non-Gaussian noise 被引量:2
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作者 HAO YingHang GONG YuBing LIN Xiu WANG Li 《Science China Chemistry》 SCIE EI CAS 2011年第5期782-787,共6页
The spiking behavior with varying time delay in scale-free networks of Hodgkin-Huxley neurons with non-Gaussian noise has been studied,and the effect of non-Gaussian noise on the delay-induced spiking behavior is disc... The spiking behavior with varying time delay in scale-free networks of Hodgkin-Huxley neurons with non-Gaussian noise has been studied,and the effect of non-Gaussian noise on the delay-induced spiking behavior is discussed. It was found that multiple spatio-temporal resonances occur when the delay lengths are integer multiples of the spiking periods,and the resonances may be strengthened when the non-Gaussian noise is appropriate. This result shows that time delays can optimize the spiking temporal regularity and spatial synchronization,and appropriate non-Gaussian noise may enhance the delay-induced spiking behaviors. Our findings may help to further understand the joint roles of non-Gaussian noise and time delays in the spiking activity of scale-free neuronal networks. 展开更多
关键词 NEURON time delay non-Gaussian noise multiple resonances scale-free network
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Fast-electron-impact ionization process by 3p of hydrogen-like ions in Debye plasmas 被引量:1
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作者 祁月盈 叶丹丹 +1 位作者 王建国 屈一至 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第3期143-148,共6页
The plasma screening of fast-electron-impact-ionization by excited state(3p) of Hydrogen-like ions was investigated in the first Born approximation with a plasma screening length δ varying from 1000a0 to 10a0. The ... The plasma screening of fast-electron-impact-ionization by excited state(3p) of Hydrogen-like ions was investigated in the first Born approximation with a plasma screening length δ varying from 1000a0 to 10a0. The generalized oscillator strength densities showed dramatic changes: some accessional minima occurred along with a remarkable enhancement in certain continuum-energy domains. The double-differential cross sections exhibit not only the same structures as the Bethe surface for moderate and large momentum transfers, but also a broadened enhancement for small momentum transfers.The single-differential cross sections exhibit a near-zero-energy-enhancement and prodigious multiple-shape resonances,depending on the continuum energy and the plasma screening length. These features are analogous to those of the photoionization cross section. These findings, for both types of cross section, can be explained by processes associated with continuum electrons, as long as the potential has a short-range character. 展开更多
关键词 near-zero-energy enhancement multiple shape resonance differential cross section Bethe surface
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Broadband perfect polarization conversion metasurfaces 被引量:1
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作者 陈红雅 王甲富 +4 位作者 马华 屈绍波 张介秋 徐卓 张安学 《Chinese Physics B》 SCIE EI CAS CSCD 2015年第1期253-257,共5页
We propose a broadband perfect polarization conversion metasurface composed of copper sheet-backed asymmetric double spilt ring resonator(DSRR). The broadband perfect polarization convertibility results from metalli... We propose a broadband perfect polarization conversion metasurface composed of copper sheet-backed asymmetric double spilt ring resonator(DSRR). The broadband perfect polarization convertibility results from metallic ground and multiple plasmon resonances of the DSRR. Physics of plasmon resonances are governed by the electric and magnetic resonances. Both the simulation and measured results show that the polarization conversion ratio(PCR) is higher than 99%for both x- and y-polarized normally incident EM waves and the fractional bandwidth is about 34.5%. The metasurface possesses the merits of high PCR and broad bandwidth, and thus has great application values in novel polarization-control devices. 展开更多
关键词 metasurface perfect polarization conversion multiple plasmon resonances
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Highly Efficient Electroluminescent Materials with High Color Purity Based on Strong Acceptor Attachment onto B-N-Containing Multiple Resonance Frameworks 被引量:1
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作者 Yincai Xu Chenglong Li +5 位作者 Zhiqiang Li Jiaxuan Wang Jianan Xue Qingyang Wang Xinliang Cai Yue Wang 《CCS Chemistry》 CAS 2022年第6期2065-2079,共15页
The development and enrichment of organic materials with narrowband emission in longer wavelength regions beyond 515 nm still remains a great challenge.Herein,a synthetic methodology for narrowband emission materials ... The development and enrichment of organic materials with narrowband emission in longer wavelength regions beyond 515 nm still remains a great challenge.Herein,a synthetic methodology for narrowband emission materials has been proposed to functionalize multiple resonance(MR)skeletons and generate a universal building block,namely,the key intermediate DtCzB-Bpin,which can be utilized to construct multifarious thermally activated delayed fluorescence(TADF)materials with high color purity through a simple one-step Suzuki coupling reaction.Based on this unique synthetic strategy,a series of efficient narrowband green TADF emitters has been constructed by localized attachment of 1,3,5-triazine and pyrimidine derivatives-based acceptors onto B–N-containing MR frameworks with 1,3-bis(3,6-di-tertbutylcarbazol-9-yl)benzene(DtCz)as the ligand.The precise modulation of the acceptor is an intelligent approach to achieve bathochromic shift and narrowband emission simultaneously.The DtCzB-TPTRZbased organic light-emitting diode(OLED)exhibits pure green emission with Commission Internationale de L’Eclairage(CIE)coordinates of(0.23,0.68),a maximum external quantum efficiency(EQE)of 30.6%,and relatively low efficiency roll-off. 展开更多
关键词 organic light-emitting diode multiple resonance narrowband emission high color purity thermally activated delayed fluorescence
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Carbazole-based Multiple Resonance Dendrimers with Narrowband Blue Emission for Solution-Processed OLEDs
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作者 Jia-Peng Liu Liang Chen +4 位作者 Lei Zhao Cui-Yan Tong Shu-Meng Wang Shi-Yang Shao Li-Xiang Wang 《Chinese Journal of Polymer Science》 SCIE EI CAS CSCD 2023年第5期802-810,I0011,共10页
Three carbazole-based multiple resonance dendrimers namely D1-BNN,D2-BNN and D3-BNN,are developed for solution-processed narrowband blue organic light-emitting diodes(OLEDs)by introducing the first-,second-,and third-... Three carbazole-based multiple resonance dendrimers namely D1-BNN,D2-BNN and D3-BNN,are developed for solution-processed narrowband blue organic light-emitting diodes(OLEDs)by introducing the first-,second-,and third-generation carbazole dendrons in periphery of boron,nitrogen-doped polycyclic aromatic hydrocarbon skeleton.Different from D1-BNN containing first-generation carbazole dendron showing moderate photoluminescent quantum efficiency(PLQY)of 68%in solid state and broadened emission bands with full-width at half maximum(FWHM)increasing from 26 nm to 34 nm upon doping concentration growing from 10 wt%to 40 wt%,D3-BNN with the third-generation carbazole dendron exhibits high PLQY of 92%and weak dependence of photoluminescent spectra on doping concentration,which can remain narrowband emissions with unchanged FWHM of 24 nm at same doping concentration range.Solution-processed OLEDs employing D3-BNN as emitter reveal blue electroluminescence at 477 nm with FWHM of 24 nm,and maximum external quantum efficiency(EQE)of 17.3%which is kept at 14.4%at doping concentration of 40 wt%,much superior than the D1-BNN devices showing maximum EQE of 13.0%that drops to 3.7%at 40 wt%doping concentration. 展开更多
关键词 multiple resonance DENDRIMER NARROWBAND Blue emission Solution process
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Novel boron-and sulfur-doped polycyclic aromatic hydrocarbon as multiple resonance emitter for ultrapure blue thermally activated delayed fluorescence polymers
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作者 Fan Chen Lei Zhao +7 位作者 Xingdong Wang Qingqing Yang Weili Li Hongkun Tian Shiyang Shao Lixiang Wang Xiabin Jing Fosong Wang 《Science China Chemistry》 SCIE EI CAS CSCD 2021年第4期547-551,共5页
Boron(B)-and sulfur(S)-doped polycyclic aromatic hydrocarbons(PAHs)are developed as a novel kind of multiple resonance emitters for ultrapure blue thermally activated delayed fluorescence(TADF)polymers with narrowband... Boron(B)-and sulfur(S)-doped polycyclic aromatic hydrocarbons(PAHs)are developed as a novel kind of multiple resonance emitters for ultrapure blue thermally activated delayed fluorescence(TADF)polymers with narrowband electroluminescence.The combination of electron-deficient B atom and electron-rich S atom in PAH can form an intramolecular push-pull electronic system in a rigid aromatic framework,leading to reduced singlet-triplet energy splitting and limited structure relaxation of excited states.The critical roles of S atom in determining emission properties with respect to the oxygen analogues are in two aspects:(i)reducing energy bandgap to shift emission from human-eye-insensitive ultraviolet zone to blue region,and(ii)promoting reverse intersystem crossing process by heavy-atom effect to activate TADF effect.The resulting polymer containing B,S-doped PAH as emitter and acridan as host exhibits efficient blue electroluminescence at 458 nm with small full-width at halfmaximum of 31 nm,representing the first example for ultrapure TADF polymer with narrowband electroluminescence. 展开更多
关键词 polycyclic aromatic hydrocarbon BORON SULFUR multiple resonance thermally activated delayed fluorescence
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Color-tunable circularly polarized electroluminescence from a helical chiral multiple resonance emitter with B–N bonds
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作者 Li Yuan Zhen-Long Tu +4 位作者 Jun-Wei Xu Hua-Xiu Ni Zhi-Ping Mao Wen-Ye Xu You-Xuan Zheng 《Science China Chemistry》 SCIE EI CAS CSCD 2023年第9期2612-2620,共9页
Chiral B,N-doped polycyclic aromatic hydrocarbons with circularly polarized luminescence(CPL) and small full-width at halfmaxima(FWHM) are promising multiple resonance(MR) emitters for CP organic light-emitting diodes... Chiral B,N-doped polycyclic aromatic hydrocarbons with circularly polarized luminescence(CPL) and small full-width at halfmaxima(FWHM) are promising multiple resonance(MR) emitters for CP organic light-emitting diodes(CP-OLEDs).This work presents a pair of chiral MR enantiomers,P/M-o[B-N]_(2)N_(2),featuring B–N bonds incorporated within a[7]-helicene skeleton.These enantiomers exhibit narrow 0-0 and 0-1 electronic transition bands,whose relative intensity can be fine-tuned by increasing doping concentrations,resulting in redshifts of the emission peak from 542 to 592 nm.The enantiomers show mirrorsymmetric CPL spectra with an asymmetry factor(|g_(PL)|) of 1.0×10^(-3).The hyperfluorescent CP-OLEDs with double-sensitized emitting layers display a FWHM of 33 nm,an external quantum efficiency of 25.1%,and a|g_(EL)|factor of 7.7×10^(-4).Notably,the CP-OLEDs realize color-tunable CP electroluminescence peak from 553 to 613 nm by regulating the vibrational coupling.This work provides a novel concept for the design of helical CP-MR materials and CP-OLEDs,highlighting their potential for future applications in advanced optoelectronic devices. 展开更多
关键词 chiral multiple resonance material helical chirality circularly polarized luminescence narrowband emission color-tunable circularly polarized electroluminescence
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