Multivariate Statistical Process Monitoring and Control: Recent Developments and Applications to Chemical Industry

Multivariate statistical process monitoring and control (MSPM&C) methods for chemical process monitoring with statistical projection techniques such as principal component analysis (PCA) and partial least squares (PLS) are surveyed in this paper. The four-step procedure of performing MSPM&C for chemical process, modeling of processes, detecting abnormal events or faults, identifying the variable(s) responsible for the faults and diagnosing the source cause for the abnormal behavior, is analyzed. Several main research directions of MSPM&C reported in the literature are discussed, such as multi-way principal component analysis (MPCA) for batch process, statistical monitoring and control for nonlinear process, dynamic PCA and dynamic PLS, and on-line quality control by inferential models. Industrial applications of MSPM&C to several typical chemical processes, such as chemical reactor, distillation column, polymerization process, petroleum refinery units, are summarized. Finally, some concluding remarks and future considerations are made.

Multivariate Statistical Process Monitoring of an Industrial Polypropylene Catalyzer Reactor with Component Analysis and Kernel Density Estimation

Abstract Data-driven tools, such as principal component analysis （PCA） and independent component analysis （ICA） have been applied to different benchmarks as process monitoring methods. The difference between the two methods is that the components of PCA are still dependent while ICA has no orthogonality constraint and its latentvariables are independent. Process monitoring with PCA often supposes that process data or principal components is Gaussian distribution. However, this kind of constraint cannot be satisfied by several practical processes. To ex-tend the use of PCA, a nonparametric method is added to PCA to overcome the difficulty, and kernel density estimation （KDE） is rather a good choice. Though ICA is based on non-Gaussian distribution intormation, .KDE can help in the close monitoring of the data. Methods, such as PCA, ICA, PCA.with .KDE（KPCA）, and ICA with KDE,（KICA）, are demonstrated and. compared by applying them to a practical industnal Spheripol craft polypropylene catalyzer reactor instead of a laboratory emulator.

New Method for Multivariate Statistical Process Monitoring

A new method using discriminant analysis and control charts is proposed for monitoring multivariate process operations more reliably.Fisher discriminant analysis （FDA） is used to derive a feature discriminant direction （FDD） between each normal and fault operations,and each FDD thus decided constructs the feature space of each fault operation.Individuals control charts （XmR charts） are used to monitor multivariate processes using the process data projected onto feature spaces.Upper control limit （UCL） and lower control limit （LCL） on each feature space from normal process operation are calculated for XmR charts,and are used to distinguish fault from normal.A variation trend on an XmR chart reveals the type of relevant fault operation.Applications to Tennessee Eastman simulation processes show that this proposed method can result in better monitoring performance than principal component analysis （PCA）-based methods and can better identify step type faults on XmR charts.

Some Group Runs Based Multivariate Control Charts for Monitoring the Process Mean Vector

In this article, we propose two control charts namely, the “Multivariate Group Runs’ (MV-GR-M)” and the “Multivariate Modified Group Runs’ (MV-MGR-M)” control charts, based on the multivariate normal processes, for monitoring the process mean vector. Methods to obtain the design parameters and operations of these control charts are discussed. Performances of the proposed charts are compared with some existing control charts. It is verified that, the proposed charts give a significant reduction in the out-of-control “Average Time to Signal” (ATS) in the zero state, as well in the steady state compared to the Hotelling’s T2 and the synthetic T2 control charts.

Quality-related monitoring of papermaking wastewater treatment processes using dynamic multiblock partial least squares

Environmental problems have attracted much attention in recent years,especially for papermak-ing wastewater discharge.To reduce the loss of effluence discharge violation,quality-related multivariate statistical methods have been successfully applied to achieve a robust wastewater treatment system.In this work,a new dynamic multiblock partial least squares(DMBPLS)is pro-posed to extract the time-varying information in a large-scale papermaking wastewater treatment process.By introducing augmented matrices to input and output data,the proposed method not only handles the dynamic characteristic of data and reduces the time delay of fault detection,but enhances the interpretability of model.In addition,the DMBPLS provides a capability of fault location,which has certain guiding significance for fault recovery.In comparison with other mod-els,the DMBPLS has a superior fault detection result.Specifically,the maximum fault detection rate of the DMBPLS is improved by 35.93%and 12.5%for bias and drifting faults,respectively,in comparison with partial least squares(PLS).