Model Prediction and Optimal Control of Gas Oxygen Content for A Municipal Solid Waste Incineration Process

In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an optimization control method of gas oxygen content based on model predictive control.First,a stochastic configuration network is utilized to establish a prediction model of gas oxygen content.Second,an improved differential evolution algorithm that is based on parameter adaptive and t-distribution strategy is employed to address the set value of air flow.Finally,model predictive control is combined with the event triggering strategy to reduce the amount of computation and the controller's frequent actions.The experimental results show that the optimization control method proposed in this paper obtains a smaller degree of fluctuation in the air flow set value,which can ensure the tracking control performance of the gas oxygen content while reducing the amount of calculation.

Microstructural analysis of marl stabilized with municipal solid waste and nano-MgO

Municipal solid waste(MSW)is accumulating over elapsed time across the world,and it is observed in many projects associated with weak soils,such as marl.Therefore,effective solutions to the environmental problem are essential.Conventional techniques for stabilizing marl generally use substances such as lime and cement,which could exacerbate pollution.For this,some new stabilizers,e.g.nano-MgO,are used.There are large quantities of marls and MSW in Shiraz City,Iran.The present study aims to evaluate the feasibility of using nano-MgO as a green low-carbon binder to remove MSW from the environment and make construction projects more cost-effective.Consolidated drained shear tests were conducted to evaluate the mechanical behaviors of the nano-MgO treated marl specimens at high normal stresses.The marl specimens containing MSW percentages of 15%,25%,35%,and 45%and nano-MgO percentages of 0.25%,0.5%,0.75%,and 1%,were used.It is found that the marl containing 15%and 25%MSW and 0.5%nano-MgO at 28-d curing can perform cation exchange and form new cementitious products.The soils with merely MSW show good performance due to the removal of the kaolinite and the formation of brucite.However,the soil with 25%MSW and 0.5%nano-MgO shows the same strength enhancement as the specimen with the optimal nano-MgO(0.75%)through the formation of dolomite,with a 20.59%increase in strain energy(SE).

Prediction of NO_(x)concentration using modular long short-term memory neural network for municipal solid waste incineration

Air pollution control poses a major problem in the implementation of municipal solid waste incineration(MSWI).Accurate prediction of nitrogen oxides(NO_(x))concentration plays an important role in efficient NO_(x)emission controlling.In this study,a modular long short-term memory(M-LSTM)network is developed to design an efficient prediction model for NO_(x)concentration.First,the fuzzy C means(FCM)algorithm is utilized to divide the task into several sub-tasks,aiming to realize the divide-and-conquer ability for complex task.Second,long short-term memory(LSTM)neural networks are applied to tackle corresponding sub-tasks,which can improve the prediction accuracy of the sub-networks.Third,a cooperative decision strategy is designed to guarantee the generalization performance during the testing or application stage.Finally,after being evaluated by a benchmark simulation,the proposed method is applied to a real MSWI process.And the experimental results demonstrate the considerable prediction ability of the M-LSTM network.

Effects of Sulfur Compounds on Cd Partitioning in a Simulated Municipal Solid Waste Incinerator

The effect of sulfur compounds （including sulfur, sulfide, sulfite and sulfate）, initial concentration of heavy metal and operating conditions on Cd emission in municipal solid waste （MSW） incineration were investi-gated using a simulated tubular furnace and simulated MSW spiked with Cd. The concentration of Cd was meas-ured by inductively coupled plasma-atomic emission spectrometry （ICP-AES） after digesting the samples including bottom ash, fly ash and flue gas according to related USEPA methods. The results show that S and Na2S tend to in- crease Cd partitioning in bottom ash, whereas Na2SO3 and Na2SO4 tend to reduce Cd partitioning in bottom ash. The effect of sulfur compounds on Cd partitioning in bottom ash was in the sequence of Na2S〉S〉Na2SO3〉 Na2SO4. chemical equilibrium analysis is also performed to determine the effect of sorbents on Cd adsorption. The calculations show that S presents strong affinity for Cd and restrains Cd adsorption by SiO2, whereas when temperature rises to between 830℃ and 1030℃, Cd adsorption efficiency of SiO2 is over 80% and the efficiency of Al2O3 is up to 85%.

Chemical speciation and mobility of heavy metals in municipal solid waste incinerator fly ash

Chemical speciation is a significant factor that governs the toxicity and mobility of heavy metals in municipal solid waste incinerator fly ash. Sequential extraction procedure is applied to fractionate heavy metals(Pb, Zn, Cd, Cu, and Cr) into five defined groups: exchangeable, carbonate, Fe-Mn oxide, organic, and residual fractions. The mobility of heavy metals is also investigated with the aid of toxicity characteristic leaching procedure. In the fly ash sample, Pb is primarily presented in the carbonate(51%) and exchangeable(20%) fractions; Cd and Zn mainly exist as the exchangeable(83% and 49% respectively); Cu is mostly contained in the last three fractions(totally 87%); and Cr is mainly contained in the residual fraction(62%). Pb, Zn and Cd showed the high mobility in the investigation, thus might be of risk to the natural environment when municipal solid waste incinerator fly ash is landfilled or reutilized.

Polychlorinated dibenzo-p-dioxins and dibenzofurans in flue gas emissions from municipal solid waste incinerators in China

Polychlorinated dibenzo-p-dioxins and furans （PCDD/Fs） emissions in flue gas from two types of municipal solid waste incinerators （MSWIs） most commonly used in China were investigated in this study. The selected incinerators include two grate-type MSWIs： MSWI-A （350 t/d） and MSWI-B 050 t/d）, and two fluidized bed MSWIs： MSWI-C （400 t/d） and MSWI-D （400 t/d）, which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber （WS） as air pollutant control device （APCD）. Results indicated that the emission concentration and the international toxic equivalents （I-TEQs） of the PCDD/Fs from the stacks were in the range of 1.210-10.273 ng/Nm^3 and 0.019-0.201 ng I-TEQ/Nm^3, respectively. They were greatly lower than the emission regulation standard of PCDD/Fs in China （1.0 ng I-TEQ/Nm^3）. However, only the PCDD/Fs emission level from MSWI-C was below 0.1 ng I-TEQ/Nm^3. Although the homologue profiles were distinct, the contributions of the 2,3,7,8-subsituted congeners to the total I-TEQ were similar among all the investigated MSWIs. Two major 2,3,7,8-substituted congeners, 2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD, account for 47% and 9% （average values） of the total I-TEQ values, respectively. The correlation between PCDD/Fs levels and composition of flue gas was also discussed.

Hydration Kinetics of Municipal Solid Wastes Incineration(MSWI) Fly Ash-Cement

Hydration heat behavior and kinetics of blended cement containing up to 20% MSWI fly ash were investigated based on its hydration heat evolution rate measured by isothermal calorimeter. Kinetics parameters, N and K, and hydration degree, Ca(OH)2 content, were also calculated and analyzed. According to the experimental results, the induction period was elongated, the second heat evolution peak was in advance, and the third hydration heat peak could be detected due to MSWI fly ash pozzolanic reaction. The hydration reaction rate was controlled by nucleation kinetics in the acceleration period and then by diffusion in the decay period, but in the deceleration period, the hydration experienced a dual controlling reaction of autocatalytic chemical reaction and diffusion. The hydration rate of blended cement was faster. Ca(OH)2 content increased before 14 days.

Geo-environmental application of municipal solid waste incinerator ash stabilized with cement

The behavior of soluble salts contained in the municipal solid waste incinerator(MSWI) ash significantly affects the strength development and hardening reaction when stabilized with cement.The present study focuses on the compaction and strength behavior of mixed specimens of cement and MSWI ash.A series of indices such as unconfined compressive strength,split tensile strength,California bearing ratio(CBR) and pH value was examined.Prior to this,the specimens were cured for 7 d,14 d,and 28 d.The test results depict that the maximum dry density(MDD) decreases and the optimum moisture content(OMC)increases with the addition of cement.The test results also reveal that the cement increases the strength of the mixed specimens.Thus,the combination of MSWI ash and cement can be used as a lightweight filling material in different structures like embankment and road construction.

Volatilization of heavy metals during incineration of municipal solid wastes

Incineration experiments with MSW, which had been impregnated with heavy metals, were presented to obtain information on the volatilization behavior of the elements cadmium(Cd), lead(Pb), and zinc(Zn) under different conditions. Experiments were carried out in a bubbling fluid bed system connected to a customized inductively coupled plasma optical emission spectroscopy(ICP-OES) for analyzing metals in the flue gas. The results indicated that the combustion temperature, the gas atmosphere, and the chlorine content in the flue gas could affect the volatilization behavior of heavy metals. In the fluidized bed combustion, a large surface area was provided by the bed sand particles, and they may act as absorbents for the gaseous ash-forming compound. Comparer with the metals Cd and Pb, the vaporization of Zn was low. The formation of stable compounds such as ZnO·Al 2O 3 could greatly decrease the metals volatilization. The presence of chlorine would enhance the volatilization of heavy metals by increasing the formation of metal chlorides. However, when the oxygen content was high, the chlorinating reaction was kinetically hindered, which heavy metals release would be delayed.

Effect of Moisture on Partitioning of Heavy Metals in Incineration of Municipal Solid Waste

The effect of moisture in municipal solid waste (MSW) on partitioning of lead (Pb), zinc (Zn), copper (Cu) and cadmium (Cd) was studied in a laboratory tubular furnace by using simulated MSW. The moisture in MSW influences heavy metals in following ways, to increase the moisture in flue gas and decrease the combustion temperature, to prolong the combustion time, and to prolong the releasing time of volatiles with the furnace temperature decreased by increasing the moisture. The volatilization of Pb, Zn and Cd was enhanced by increasing the moisture in MSW because of the prolonged combustion time. For Pb and Zn, the combustion time was important at higher temperature, while for Cd, it was important at low temperature. The moisture content showed slight effect on Cu partitioning. When extra chlorine was added to MSW, such as 1%PVC + 0.5%NaCl, the volatilization of Pb, Zn and Cu was enhanced by increasing the moisture because water evaporation reduced the temperature and increased devolatilization time. At higher temperature, NaCl tends to decompose and generates more free chlorine, producing more metal chlorides. Since Cd is a strong volatile heavy metal in MSW, the effect of moisture content on its volatilization is less than that of Pb, Zn or Cu during the MSW incineration.

Microstructures and thermal properties of municipal solid waste incineration fly ash

To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration （MSW1） fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of Such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.

Mechanism of high concentration phosphorus wastewater treated by municipal solid waste incineration fly ash

The mechanism of removing phosphate by MSWI(municipal solid waste incineration)fly ash was investigated by SEM(scanning electron microscopy)with EDS(energy dispersion spectrum),XRD(X-ray diffraction),FT-IR(Fourier transform infrared spectroscopy),BET(specific surface area),and BJH(pore size distribution).The results indicate that the removal rate of phosphate(100 mg/L)in 50 mL phosphorus wastewater reaches at 99.9% as the dosage of MSWI fly ash being 0.9000 g under room temperature.The specific surface area of MSWI fly ash is less than 6.1 m2/g and the total pore volume is below 0.021 cm3/g,suggesting that the absorption capacity of calcite is too weak to play an important role in phosphate removal.SEM images show that drastic changes had taken place on its specific surface shape after reaction,and EDS tests indicate that some phosphate precipitates are formed and attached onto MSWI fly ash particles.Chemical precipitation is the main manner of phosphate removal and the main reaction is: 3Ca2++2 PO4 3-+xH2O→Ca3(PO4)2↓·xH2O.Besides,XRD tests show that the composition of MSWI fly ash is complex,but CaSO4 is likely to be the main source of Ca2+.The soluble heavy metals in MSWI fly ash are stabilized by phosphate.

FORMATION MECHANISMS AND CONTROL STRATEGIES FOR DIOXINS IN INCINERATION PROCESS OF MUNICIPAL SOLID WASTES

Dioxins, which are of the most toxic materials on the earth, are principal emitted from waste incineration process. The molecular structures, toxicity parameters, such as toxicity equivalency factor, tolerable daily intake and physic-chemical properties of dioxins are briefly summarized. Three formation mechanisms of dioxins in waste incineration process, namely as de novo synthesis, mechanisms involving small organic molecular as precursors and homogenous gas phase reaction mechanism are alto reviewed. The influencing factors for dioxins formation during waste incineration process are also discussed. Three major methods for reducing dioxins emission from waste incineration process are discussed based upon the formation mechanisms and influencing factors. A new waste incineration process with low dioxins emission and low hydrogen chloride corrosion has been proposed based on multi- stage unit operation principal according to formation mechanisms of dioxins and potential production location in waste incinerators.

A perspective analysis on municipal solid waste(MSW) energy recovery in China

The paper analysed the current situation of municipal solid waste(MSW) quantity and quality in China and the changing tendencies of its composition. Further more, the energy value of MSW was discussed. To the point of the technical and economic aspects, the feasibility of the energy recovery from MSW was also analysed. The conclusion is that the energy can be effectively recovered through a landfill gas utilization process and the energy produced by an incineration process. Through a suitable energy recovery process, it is possible to improve the economic viability of a MSW treatment process.

Technology of comprehensive disposal and utilization of municipal solid waste (MSW)

The project for treating MSW of 200 tons each day was built in Yibin, Sichuan Province of China. The disposal processes are: separation and selection of usable resources; compost and fermentation of “heavy” organic waste (kitchen, garden composting rubbish); incineration of “light” waste (plastic, paper, wood and bamboo etc.) and landfill of inorganic waste. The thermal energy generated in the process can be used as 1/3 of the whole energy for drying fertilizers. In the process, there is no wastewater drainage, and air emissions can be effectively controlled by a series of measures. The sanitary and environmental indicators of disposal site meet the national standards. This project has worked well for two years. It not only disposes of and reduces the MSW, but also retrieves the resource effectively. The organic fertilizer has been applied in the ten thousand acres of fields, with productivity increase by more than 10%.

Comparative evaluation of processes for heavy metal removal from municipal solid waste incineration fly ash

Hydrochloric acid leaching, chloride evaporation, acetic acid leaching, and biological leaching were evaluated and compared as processes of heavy metal removal for municipal solid waste incineration fly ash(MSWFA). Six factors, namely, energy consumption, process efficiency, process handling, process cost estimation, cost reduction potential, and study progress, were used in order to find out their advantages and disadvantages and to help develop a better recovery process of heavy metals from MSWFA in terms of treatment of the waste material. Hydrochloric acid leaching process was found to be most balanced among the evaluated processes. It showed superiority on energy consumption, process cost estimation, and study progress. On the other hand, despite of its excellency in process efficiency, chloride evaporation process was most unfavorable mainly due to heavy energy dependence. Biological process, with huge potential of cost reduction, was concluded to be the second best process.

Porous Structure of Municipal Solid Waste Incineration Bottom Ash in Initial Stage of Landfill

For quantitative estimation of the intra-layer porous structure in the initial stage of landfill formation with municipal solid waste incineration (MSWI) bottom ash, the water absorption of individual MSWI bottom ash particles was measured under still-water, degassed, and agitated conditions. The ratio of the water absorption rate found for the still-water procedure to the effective absorption capacity which was the one under degassing was 35.2%. In the water flow experiment of a column filled with MSWI bottom ash, the true density of the bottom ash was higher after water flow than before, which indicated that dissolution of the soluble components of the bottom ash particle surfaces resulted in a loss of apparent particle volume that more than offset the accompanying weight loss. The volume-based water absorption rate found for the bottom ash particles following 50 mL/h water flow through the column, as a ratio to the effective absorption capacity was about 51.8% of the effective absorption capacity. In a landfill layer comprised of MSWI bottom ash, it was suggested that some regions of the ash particle interiors underwent almost no contact with water.

Incinerability Index of Municipal Solid Waste and Its Correlation with Carbon Monoxide and Nitrogen Oxides Emissions

The main objective of this study was to establish optimal incineration conditions through the analysis of pollutant formation mechanisms involved in the combustion process of a retort incinerator. Calorific values of several types of municipal solid wastes were determined and related to specific incinerability indexes. The incinerability testing concerning this study was conducted on residues with an incinerability index （II） of 123. The samples were tested under different conditions： with and without chamber preheating, varying the percentage of inlet air （25, 50 and 75% of the system capacity）, measuring the temperatures of the primary and secondary chambers, and gauging the CO and NO stack emissions with an electrochemical cell. With comparative purposes in mind, samples with indexes ofI = 112, I = 123, I = 130 and I = 132 were also tested to assess the influence of the II on pollutant emissions.

Environmental monitoring and fuzzy synthetic evaluation of municipal solid waste transfer stations in Beijing in 2001-2006

Transfer station(TS)is an integral part of present-day municipal solid waste(MSW)management systems.To provide information for the incorporation of waste facilities within the current integrated waste management system,the authors measured the existing environmental quality at five MSW TSs.Discharged wastewater,air,and noise were monitored and assayed at the five TSs in Beijing in 2001-2006 during rainy seasons(RSs)and dry seasons(DSs).Except Ammonia(NH_3)and hydrogen sulfide(H_2S),the analytical results of...

Engineering properties for high kitchen waste content municipal solid waste

Engineering properties of municipal solid waste （MSW） depend largely on the waste＇s initial compositionand degree of degradation. MSWs in developing countries usually have a high kitchen waste content（called HKWC MSW）. After comparing and analyzing the laboratory and field test results of physicalcomposition, hydraulic properties, gas generation and gas permeability, and mechanical properties forHKWC MSW and low kitchen waste content MSW （called LKWC MSW）, the following findings wereobtained： （1） HKWC MSW has a higher initial water content （IWC） than LKWC MSW, but the field capacitiesof decomposed HKWC and LKWC MSWs are similar; （2） the hydraulic conductivity and gaspermeability for HKWC MSW are both an order of magnitude smaller than those for LKWC MSW; （3）compared with LKWC MSW, HKWC MSW has a higher landfill gas （LFG） generation rate but a shorterduration and a lower potential capacity; （4） the primary compression feature for decomposed HKWCMSW is similar to that of decomposed LKWC MSW, but the compression induced by degradation ofHKWC MSW is greater than that of LKWC MSW; and （5） the shear strength of HKWC MSW changessignificantly with time and strain. Based on the differences of engineering properties between these twokinds of MSWs, the geo-environmental issues in HKWC MSW landfills were analyzed, including highleachate production, high leachate mounds, low LFG collection efficiency, large settlement and slopestability problem, and corresponding advice for the management and design of HKWC MSW landfills wasrecommended.