Environmental Geochemistry of Mining Activities in Panzhihua Region, Southwestern China

Mining activities have created huge uncovered slopes, large areas of gangue ground and extensive tailings dams. This paper presents the environmental geochemistry of mining activities in Panzhihua region. The selected elements (Ti, V, Mo. Ni. Pb. Cu) show similar distribution patterns of concentration anomaly in topsoil. These concentration anomalies are located in V-Ti-magnetite slope, gangues dam and coal mine. The distinction between anthropogenic contamination and natural background is made available by the use of the enrichment factor in this study area. The anomalies of EF were smaller than that of concentration. The results from EF show that the selected elements anthropogenic pollution (EF>1) in topsoil were located in both the coal mining area and the V-Ti-magnetite mining area. In addition, the pollution sources of selected elements came from V-Ti-magnetite, slag, gangues, coal and other pollutants from mining activities.

Geochemistry,geochronology and Hf isotope of granitoids in the northern Alxa region:Implications for the Late Paleozoic tectonic evolution of the Central Asian Orogenic Belt

The tectonic setting of the northern Alxa region during the Late Paleozoic is highly controversial.The key to resolve this controversy is to recognize the Late Paleozoic magmatic processes in the northern Alxa.In this paper,we present new zircon U-Pb ages,Hf-isotopic compositions and whole-rock geochemical data of four granitoids along the Zhusileng-Hangwula Tectonic Belt in the northern Alxa region that could provide critical information about the tectonic evolution of this region.The zircon U-Pb data could be grouped as two phases:Late Devonian granite and diorite(ca.373-360 Ma),and Late Carboniferous granodiorite(ca.318 Ma).The Late Devonian granites and diorites are metaluminous to slightly peraluminous,with A/CNK and A/NK ratios of 0.90-1.11 and0.95-2.19,respectively.The Late Devonian diorites are characterized by high MgO,Cr and Ni contents and MgO#values,together with variableεHf(t)values from-1.0 to+1.3 and old TDM2 ages varied from 1283 Ma to 1426 Ma,indicating the primary magma was potentially derived from magma mixing of depleted mantle with Mesoproterozoic continental crust.Even though the Late Devonian granites yielded most positive and minor negative eHf(t)values between-1.1 to+5.7(three grains are negative)with two-stage model ages(TDM2)of 1003-1438 Ma,they display low MgO,Cr and Ni contents and MgO#values,suggesting that they were mainly derived from juvenile crustal materials,mixed with a small amount of ancient crust.The Late Carboniferous granitoids are metaluminous and medium-K calc-alkaline series,with A/CNK and A/NK ratios ranging from 0.88 to 0.95 and1.75 to 1.90,respectively.These rocks were potentially derived from juvenile crustal materials mixed with depleted mantle,as evidenced by their highεHf(t)values(+11.6 to+14.1)and young TDM2 ages(427 Ma to 586 Ma),as well as high Mg#values,and MgO,Ni and Cr contents.Our data,along with available sedimentary evidence and previous researches,indicate that the Late Devonian and Late Carboniferous rocks are arc-related granitoids under the subduction setting.The identification of arc-related granitoids in the northern Alxa region not only reveals the Late Paleozoic magmatic process in response to the subduction of Paleo Asian Ocean,but also provide significant constrains to the tectonic evolution of the Central Asian Orogenic Belt.

Geochronology and geochemistry of the five magmatic rocks in the Ningzhen region,China

The Ningzhen region of China is located in the easternmost part of the middle-lower Yangtze River Cu–Fe polymetallic metallogenic belt. From west to east, it comprises five main intermediate–acidic intrusive complexes: the Qilinmen, Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes. Geochemical investigations show that these five intrusive complexes exhibit high contents of SiO_2, at 64.74–73.40 wt%, Al_2O_3, at 14.15–17.37 wt%, and K_2O + Na_2O, at 6.49–8.68 wt%. The majority of the samples belong to the high-K calc-alkaline series, with a few samples plotting in the calc-alkaline and tholeiitic series. Trace element analysis shows that the samples are enriched in large ion lithophile elements(LILE) and are depleted in high field strength elements(HFSE).The chondrite-normalized rare earth element(REE) patterns are characterized by right-inclined curves, showing light rare earth element(LREE) enrichment. In addition,the(La/Yb)Nratios are high at 15.02–37.28, with an average of 29.13, and slightly negative or none Eu anomalies are present. In the(La/Yb)N–d Eu diagram, the samples plot within the crust-mantle type field. Laser ablation–inductively coupled plasma–mass spectrometry(LA–ICP–MS) zircon U–Pb dating yielded ages of122.0 ± 1.0 Ma, 106.1 ± 0.8 Ma, 108.7 ± 1.4 Ma,103.5 ± 1.9 Ma, and 96.8 ± 1.7 Ma for the Qilinmen,Anjishan, Xiashu–Gaozi, Shima, and Jianbi complexes,respectively. On the basis of this research and knowledge of several known metal deposits related to these complexes, we suggest that the Mesozoic large-scale diagenesis and metallogenesis in the Ningzhen region may have ceased at 100 Ma or about 95 Ma.

Environmental Geochemistry of Fluorine in the Rock-Soil-Water System in the Karst Region of Central Guizhou Province

Systematic determination of and adsorption experiment on fluorine in the carbonate rock\|soil\|water system in the karst region studied in Guizhou Province, in conjunction with the mineral surface and soil chemistry data, have revealed the geochemical characteristics of F and the mechanisms of its transport and enrichment in the rock\|soil\|water system of the karst region, central Guizhou Province. Deep\|seated underground waters (-100m or lower) and soil layers in the karst region of central Guizhou are characterized by high\|F anomalies whereas shallow\|level underground and surface waters by low contents of F (mostly lower than 0.5 mg/L). Fluorine in soil and water in the region studied comes largely from Triassic marine strata dominated by gypsum\|bearing carbonate rocks. The special adsorption and desorption of F on the surface of geothite in soil layers are the important mechanisms of its transport and enrichment in the rock\|soil\|water system of the karst region studied.

Organic Matter Accumulation in the Upper Permian Dalong Formation from the Lower Yangtze Region,South China

The Late Permian was marked by a series of important geological events and widespread organic-rich black shale depositions,acting as important unconventional hydrocarbon source rocks.However,the mechanism of organic matter(OM)enrichment throughout this period is still controversial.Based on geochemical data,the marine redox conditions,paleogeographic and hydrographic environment,primary productivity,volcanism,and terrigenous input during the Late Permian in the Lower Yangtze region have been studied from the Putaoling section,Chaohu,to provide new insights into OM accumulation.Five Phases are distinguished based on the TOC and environmental variations.In Phase I,anoxic conditions driven by water restriction enhanced OM preservation.In Phase II,euxinic and cycling hydrological environments were the two most substantial controlling factors for the massive OM deposition.During Phase III,intensified terrestrial input potentially diluted the OM in sediment and the presence of oxygen in bottom water weakened the preservation condition.Phase IV was characterized by a relatively higher abundance of mercury(Hg)and TOC(peak at 16.98 wt%),indicating that enhanced volcanism potentially stimulated higher productivity and a euxinic environment.In Phase V,extremely lean OM was preserved as a result of terrestrial dilutions and decreasing primary productivity.Phases I,II and IV are characterized as the most prominent OM-rich zones due to the effective interactions of the controlling factors,namely paleogeographic,hydrographic environment,volcanism,and redox conditions.

Age and geochemical evolution of granite magmatism in Olkhon region from Caledonian syncollisional ore-free granite to the rare metal granite and pegmatite of Middle Paleozoic intraplate setting

The detailed description of two granite complexes in the Olkhon subterrane is given.The Early Paleozoic Sharanur complex was formed by granitization of gneisses of the Olkhon series.It includes migmatites,granite-gneisses,granites and pegmatites of normal alkalinity;they belong to the type of syncollisional granites.The Middle Paleozoic Aya granite complex includes mother Aya massif of amazonite-bearing granites and several types of rare-metal pegmatites.They have elevated alkalinity,low of Ba,Sr,and high LILE and HFSE elements contents.The Aya pegmatites lie in northwest cracks of stretching and associated with the rise of the territory under the influence of the North Asian plume.These cracks and pegmatites mark the beginning of a new intraplate geodynamic setting.Two geochemical types are distinguished among the pegmatites of this complex.These are amazonite pegmatites of Li-F type with Ta mineralization and complex type pegmatite with Be-Rb-Nb-Ta and Li-F mineralization(the Ilixin vein).The Tashkiney pegmatite vein is similar to Ilixin,but lies in the gneisses of the Olkhon series.It shows high concentrations of Be,Nb,Ta,as well as W,Sn,but lacks Li and F,due to a greater depth and higher temperature of the melt crystallization of this pegmatite.

A stratigraphical-geochemical study on the Chaco Paraná continental rift basin—An approach study based on regional sedimentology and drill-hole core analyses, South América

This paper is focused on a geologic “regional rift basin system pattern” and its stratigraphical-geochemical relationship. This is mainly based on the littoral shallow marine sedimentary succession paleogeography and deposits. These successions characterize the large extensional intracratonic Chaco Paraná Basin rift system. The basin is located in South America west of the Brazilian Shield. The analyzed rift basin system evolved from the Upper Cretaceous (Late Campanian-Senonian-Maastrichtian-Early Paleocene) to Quaternary time. The siliciclastic littoral shallow marine successions were deposited from Early Senonian-Maastrichtian to Late Miocene during three main successive littoral shallow marine transgressions of continental extension.; These transgressions happened over the wide pediplanized terrains of South America. These lands exist west of the more positive areas, between the Brazilian Shield and the foreland massifs that were settled in the more westernwards areas. Later, these regional foreland massifs were coupled and raised to the Andean Orogen Belt during the last 5 million years.; The extensive intracratonic pediplanized low topographic relief areas were the reservoirs of siliciclastic littoral shallow marine succession deposits during the three successive widespread vast continental littoral shallow marine transgressions.; The first transgression began at the Latest Campanian-Senonian and/or Early Maastrichtian time. After this episode, the sedimentary depositional systems continued during the Cenozoic until the Latest Miocene. These successions constitute a major allostratigraphic unit. The limit with underlying units is the regional unconformity between the regional volcanic event (Jurassic-Cretacic and interleaved eolianite sandstones) at the base and the undifferentiated Quaternary sediments (called as the Pampeano and Post-Pampeano Formations sensu lato). Based on many facies analyses there had been checked out different levels in the eustatic sea level variations within the allostratigraphic unit.; Three major stages of extensional climax were recognized and related to the stages of conspicuous eustatical sea-level variations. They happened during the Latest Senonian-Paleocene, Eocene and Miocene.; The first transgression occurred during the Upper Cretaceous-Paleocene although the sedimentary deposits related to this event are scarce, which are only a few meters in thickness. However, the Upper Cretaceous-Paleocene succession is very well recognized in the actual pre-Andean zone in the north-west of Argentina and Bolivia (the Sierras Subandinas and the meridional imbricated fault systems just joint to the actual orogen, i.e., Quebrada de Humahuaca outcrops).; During the Eocene and Middle to Latest Miocene occurred the second and third extensive regional littoral shallow marine transgressions. They are present either in well log registers as in most widespread outcrops on the entire Southamerican continent.; The regional analysis led to the deduction of long periods of tectonic quiescence, at least three of them. They may be inferred and synchronously related with eustatic highstand sea level variations that occurred during the Late Paleocene-Early Eocene, Latest Eocene-Early to Mid Oligocene and Middle-to-Late Oligocene-Early Miocene.; The structural style is related with major extensional N-S strike faultings (regional tilted and faulting blocks). On the other hand, quite a number of strike-slip faults (mainly of regional characteristic) are present crossing the area. They have a clear influence on the accommodation and transfer zones of the rift basin system. The strike is north-west to south-east on the border of the basin, to the west, in the contact with the Pampean Ridges and the narrow-meridionally-extense Sub-Andean folded trend (mainly Paleozoic units belonging to the so-called Sierras Subandinas geological province). Also, at the western edge of thestudied area, there exist many large shear zones and upthrust faults. The strike-slip regional faults dislocated the Pampean and Sub-Andean blocks due to the interaction of crossing regional tilted and fault blocks. For this reason, an en echelon regional block model is characteristic. Incipient contaminated igneous activities were associated with this cortical weak zones.; Domes, needles and necks of volcanic and sub-volcanic origin appear as the landscape of the region. A part of the igneous activity was dated on Latest Pliocene although mainly corresponding to Pleistocene and Holocene. This deduction is obvious because their morphological constitution was never eroded. The volcanic aparatous are morphologically unmodified from their extrusion to present days.; All the studied successions seem to resemble a long persisting erosive, transportation and deposition episode. This phenomenon is linked to a large regional (continental) unconformity dated at Late Cretaceous. The entire analyzed sedimentary succession deposits and their siliciclastic facies associations correspond clearly to a “heterolithic facies succession” which is very common within persisting tide-dominated depositional systems (passive margins). In fact, this is what happened during Cenozoic times (Torra, 1998b, 2001a). The heterolithic Miocene facies deposits constitute one of the best continental exposed examples.; Paleogeographical evidence showed that the Paranense and Amazonic Sea transgressions had been a littoral shallow marine connection during long time from Middle to Late Miocene. During the Late Cretaceous and Eocene periods marine connections were also active in the region. This fact is strongly supported by the tectonic and geomorphological framework of the proto-Southamerican continent, fossil remains and similar sedimentary deposits.; The geochemical results showed an outstanding similarity among the three sandy-muddy successions herein studied. Both major and trace elements always show the same geochemical patterns. Specially mentioned are the elements gallium, cesium, chromium, barium, vanadium, thorium, zirconium, rubidium and strontium because they present very constant values through all successions.; The Paranense and Amazonic epicontinental seas had been connected to the Pacific Ocean during the three marine episodes. The connections were formed by narrow inter-mountain valleys, present in the pre-Andean foreland massifs. These events occurred prior to the main orogenesis elevation of the Andean orogen belt in the last 5 to 1 Ma (Pliocene-Latest Pleistocene).; This paper shows, for the first time, a synthetic stratigraphical-geochemical “regional model” for the Chaco Paraná Basin rift system which should be largely improved in later studies. The Chaco Paraná Basin carries many unexamined-unexplored natural resources which need more regional and local studies for their evaluation. This is in spite of the area that has the problem of a significative vegetation coberture and scarce good outcrops. The development of modern techniques of data acquisition will help to overcome these difficulties.

Petrogenesis of the Xihuashan Granite in Southern Jiangxi Province,South China:Constraints from Zircon U-Pb Geochronology,Geochemistry and Nd Isotopes

Mesozoic granitic intrusions are widely distributed in the Nanling region, South China. Yanshanian granites are closely connected with the formation of tungsten deposits. The Xihuashan granite is a typical representative of tungsten-bearing granite. The Xihuashan granite consists mainly of medium-grained porphyritic biotite granite, medium-grained biotite granite and fine-grained twomica granite, which correspond to LA-ICP-MS zircon U-Pb ages of 555.5±0.4 Ma, 553.0±0.6 Ma and 552.8±0.9 Ma, respectively. Rocks from the Xihuashan mining area displays high SlOe （73.85% to 76.49%） and NaeO＋K20 contents （8.09% to 9.43%）, belonging to high-K calc-alkaline series. They are metaluminous to weakly peraluminous with A/CNK values ranging from 0.96 to 5.06. All granites in this study area are rich in Rb, Th, U and Pb, and depleted in Ba, Sr, P, Ti, Nb and Eu, especially depleted in medium-grained biotite granite and fine-grained two-mica granite. The medium-grained porphyritic biotite granites usually have high LREE concentrations, whereas medium-grained biotite granite and fine-grained two-mica granite displays high HREE contents. Our geochemical data reveal that the studied rocks are highly fractionated I-type granite. The magma underwent strong magma differentiation with decreasing temperature and increasing oxygen fugacity, which may explain the formation of three types of distinct granites. Variations of Rb, Sr and Ba concentrations in different type granites were controlled by fractional crystallization of biotite and feldspar. Fractional crystallization of monazite, allanite and apatite resulted in LREE changes in granite, and formation of garnet mainly caused HREE changes. Granites from the Xihuashan mining area have relatively high εd（t） values （-9.77 to -55.46）, indicating that they were probably generated by partial melting of underlying Proterozoic metasedimentary rocks with minor addition of juvenile crust or mantlederived magmas.

Early Permian–Late Triassic Magmatism in the Tuotuohe Region of the Qinghai–Tibet Plateau: Constraints on the Tectonic evolution of the Western Segment of the Jinshajiang Suture

In this paper we present new zircon U-Pb ages,whole-rock major and trace element analyses,and zircon Hf isotopic data for magmatic rocks in the Tuotuohe region of the western segment of the Jinshajiang suture.Our aim is to constrain the Early Permian-Late Triassic tectonic evolution of the region.Zircons from the magmatic rocks of the Tuotuohe region are euhedralsubhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios （0.4-4.6）,indicating a magmatic origin.The zircon U-Pb ages obtained using LA-ICP-MS are 281 ± 1 Ma,258 ± 1 Ma,244 ± 1 Ma,and 216 ± 1 Ma,which indicate magmatism in the Early Permian-Late Triassic.A diorite from Bashihubei （BSHN） has SiO2 =57.18-59.97 wt％,Al2O3=15.70-16.53 wt％,and total alkalis （Na2O ＋ K2O） =4.46-6.34 wt％,typical of calc-alkaline and metaluminous series.A gabbro from Bashibadaoban （BSBDB） belongs to the alkaline series,and is poor in SiO2 （45.46-54.03 wt％） but rich in Al2O3 （16.19-17.39 wt％） and total alkalis （Na2O ＋ K2O =5.48-6.26 wt％）.The BSHN diorite and the BSBDB gabbro both display an enrichment of LREEs and LILEs and depletion of HFSEs,and they have no obvious Eu anomaly; they have relatively low MgO contents （2.54-4.93 wt％）,Mg# values of 43 to 52,and low Cr and Ni contents （8.07-33.6 ppm and 4.41-14.2 ppm,respectively）,indicating they differentiated from primitive mantle magmas.They have low Nb/U,Ta/ U,and Ce/Pb ratios （1.3-9.6,0.2-0.8,and 0.1-18.1,respectively）,and their initial Hf isotopic ratios range from ＋9.6 to ＋16.9 （BSHN diorite） and ＋6.5 to ＋12.6 （BSBDB gabbro）,suggesting their primary magmas were derived mainly from the partial melting of a mantle wedge that had been metasomatized by subduction fluids.Taking all the new data together,we conclude that the western and eastern segment of the Jinshajiang suture regions underwent identical processes of evolution in the Early Permian-Late Triassic：oceanic crust subduction before the Early Permian,continental collision during the Early-Middle Triassic,and post-collisional extension from the Late Triassic.

Sedimentary and Geochemical Characteristics of Sinian Cap Carbonates in the Upper Yangtze Region

A global\|scale glaciation occurred at about 600 Ma ago. As a result, the Earth became the "Snowball Earth". The glaciation came to the end abruptly when atmospheric carbon dioxide increased to such an extent as to be about 350 times the modern level because of subaerial volcanic degassing. The rapid termination of glaciation would have led to warming of the Snowball Earth and extreme greenhouse conditions would have been created. The transfer of atmospheric carbon dioxide to oceans would give rise to the rapid precipitation of calcium carbonate in warm surface seawaters, thus forming the cap carbonate rocks as observed worldwide today.\; Regionally persisting, thin layers of carbonate rocks directly and ubiquitously overlie Proterozoic glacial deposits almost on every continent, and are commonly referred to as cap carbonates. Their unusual litho\| fabrics, stratigraphically abrupt basal and upper\|level contacts and strongly negative carbonate isotopic signatures (\{δ\{\}\+\{13\}C\-\{carb.\}\} values range from -7.0‰-0‰) suggest a chemical oceanographic origin, the details of which remain unknown. It is proposed that these enigmatic deposits are related to the destabilization of gaseous hydrate in terrestrial permafrost following rapid postglacial warming and flooding of widely exposed continental shelves and internal basins.\; The authors carried out studies on the geochemistry, sedimentology and palaeontology of the Sinian cap carbonates in Guizhou and Hunan provinces, including the occurrence of cap carbonates of unusual fabrics, strongly negative carbon isotopic signatures, and a lot of bitumen nodules. From the results it is suggested that the cap carbonates were formed from solid methane seepage, and it is in agreement with Kennedy’s viewpoint (2001) that the cap carbonates resulted from the rapid precipitation of calcium carbonate in response to solid methane seepage.

Geochemical Features and Metallogenic Prediction of the Caixiashan-Weiquan Area in the East Tianshan Region

The Caixiashan-Weiquan area is an important ore concentration area in the eastern Tianshan metallogenic belt. Firstly, this paper studies geochemical features of 1564 samples of 1：200000 stream sediments of the Matoutan mapsheet, where the Caixiashan and Weiquan deposits are located. Processing, analysis and explanation of exploration geochemical data play an important role in the procedure of finding the ore, which are related to whether the measured elements content of geochemical samples can effectively guide the work of mineral exploration. As a highly nonlinear dynamical system, the neural network is more analogous to the human brains in terms of principles and features compared with conventional geochemical approaches. It can adapt itself to the environment, sum up laws, complete pattern recognition. Secondly, the authors used the Kohonen neural network to classify all samples based on 10 mineralization elements of stream sediment samples in order to determine possible mineral ores, reduce the scope of ore targets and study indicator elements of the ninth group of samples, which is the mostly closest to the deposit. The results show that the neural network can delineate metallogenic prospective areas and is effective in the discovery of deep geochemical information.

Lamprophyre or Lamproite Dyke in the S WTarim Block? —Discussion on the Petrogenesis of These Rocks and Their Source Region

The mineralogical, petrological and geochemical studies on Keliyang （克里阳） potassic dykes have been carried out to understand their rock types, the petrogenesis and the nature of their mantle sources. They arc potassic lamprophyre, not lamproites as the previous researchers believed. In this study, the whole-rock major and trace element compositions of another 6 lamproite dykes recently discovered are reported. Major elements were determined by X-ray fluorescence spectrometry （XRF） techniques, while REE and trace elements were determined by inductively coupled plasma mass spectrometry （ICP-MS）. They can be classified into phlogopite-diopside lamprophyre, leucite-diopside lamprophyre and granular carbonatite-bearing diopside lamprophyre on the basis of their mineral components. They are all characterized by relatively low SiO2 （41.31% --44. 84% ）, TIO2 （0.75%-0.86% ） and high MgO （7.30%-11.33%）, K2O （4.01%-6.01%） concentrations with K2O/Na2O ratios of 2.77-12.49. In addition, they display enrichment in large-ion lithophile elements （LILEs, e. g., Rb, Sr, Ba） and LREE, but a relative depletion in high-field-strength elements （HFSEs, e.g. , Nb, Ta, Zr, Hf and Ti）. They display similar chondrite-normalized REE patterns with slight negative Eu anomalies （δEu=0.64-0.82）, and high initial ^87 Sr/^86Sr ratios, which resemble those of high K/Ti and Iow-Ti potassic magmas formed in subduction-related settings. Consequently, we suggest that the parental magma was generated by partial melting of the phlogopite-amphibole-bearing garnet lherzolite within the lithospheric mantle that might have been metasomatized by a potassium-bearing fluid released from a sabdaction oceanic crust.

Tectonic Environments of Cenozoic Volcanic Rocks in China and Characteristics of the Source Regions in the Mantle

Extensive volcanism is one of the important features of Cenozoic geology in China.Based on temporal-spatial distribution,the volcanism was associated with three major different geological settings:1)the continental rift basalts in Northeast and North China;2)the tension-fault basalts on the continental margins of Southeast China; and 3) the collision-zone high-K volcanics in the Qinghai-Xizang Plateau and its vicinities.The characteristics of 'depletion in the south and enrichment in the north'of the China continental mantle are strongly supported by isotopic evidence.The Cenozoic continental cal characters,into the following geochemical provinces:1)the depleted mantle in South China;2)the primary mantle in Northeast and NorthChina; 3)the hybrid and transi-tional mantle in the region of Shandong ,Anhui,Jiangsu and northern Zhejiang;4)the depleted mantle around the Bohai Bay and the Lower Liaohe River;5)the K-metasomatic enriched mantle in the northern part of Northeast China;and 6)the re-cycled enriched mantle in the ancient subduction zone in the Qinghai-Xizang Plateau and its surround-ings.These geochemical characteristics on a regional scale must be a reflection of the nature of lithosphere evolution.

Geochemical characteristics from tests of four modern planktonic foraminiferal species in the Indonesian Throughflow region and their implications

Test geochemistry of planktonic foraminifera is an indispensable tool in reconstructing past ocean hydrological changes. It is essential to investigate region-specific implications of test geochemistry,although those established from other regions can be broadly applied. In this study, characteristics of6180 and Mg/Ca from tests of four planktonic foraminiferal species, Globigerinoides ruber sensu stricto(s.s.), Globigerinoides sacculifer, Pulleniatina obliquiloculata and Neogloboquadrina dutertrei, from 60 coretop sediment samples retrieved from the Indonesian Throughflow(ITF) region were studied. These geochemical data were compared with modern hydrographic profiles in order to assess their relations and to investigate potential implications of test geochemical parameters in reconstructing past oceanographic change in the ITF region. Calcification depths of these four species were first estimated based on comparison between measured test δ180 and predicted calcite δ^(18)O that was calculated from modern temperature and salinity. The results indicate that G. ruber s.s. and G. sacculifer calcify within the mixedlayer at 0-50 m and 20-75 m, respectively, whereas P. obliquiloculata and N. dutertrei calcify within the thermocline at around 75 to 125 m. A combined study of excess Mg/Ca(difference between measured and predicted Mg/Ca) and salinity suggests that salinity exerts a negligible impact on test Mg/Ca of these foraminiferal species in the ITF region. Comparison of test Mg/Ca-derived temperatures with temperature profiles of the upper 200 m of the water column from the seas of the ITF region also indicate calcification depths of these species, which match well with the above estimations using test δ^(18)O. It further indicates that G. sacculifer may be more sensitive in reflecting changes in the depth of the mixedlayer, highlighting a potential use of Mg/Ca temperature difference between G. ruber s.s. and G. sacculifer in reconstructing the depth of the mixed-layer in the ITF region.

Elemental Geochemistry of a Soil Chronosequence on Basalt on Northern Hainan Island, China

With increasing soil age, the contents of Sr, Ba and ratios of Sr/Be in soils tend to decrease, whereas the contents of V, Sc, Ni, Cr, Co and ratios of Fe/Ni and Fe/Co tend to increase, as evidenced from a study on soils of different ages, developed on basalts in the northern part of Hainan Island. Ba/Nb, significantly correlative with soil age, can be used to evaluate soil evolution. By using the mass-balance method, the element migration was discussed with Ti as an immobile element. The results showed that element leaching was most intensive in the early pedogenic period. In this period (Primosols), over 90% of Ca, Mg, K and Na was leached out of soils till Ferrosol formation. The leaching of P occurred mainly at the beginning of soil development. About 60% of Si was mobilized in the stage of Cambosol formation and 80% in the stage of Ferralosol formation.

西藏冈底斯-喜马拉雅造山系区域地球化学元素背景特征及找矿预测

区域地球化学元素背景值是区域找矿预测的重要地球化学指标。选取西藏冈底斯-喜马拉雅造山系,整理统计区域地球化学数据,以算术平均值(X)加减3倍标准差(S)进行迭代剔除离群值,统计剩余数据中位数(m),查明了不同次级单元中Au、Ag、Cu等39种元素的背景值及富集特征,并进行找矿预测。结果显示,西藏冈底斯-喜马拉雅造山系区域地球化学39种元素背景变化较大,差异显著,具体表现为喜马拉雅地块富集Li、Be、Sn、W、Au、Sb、Pb、Zn等成矿元素,雅鲁藏布江结合带主要富集Au、Cr;拉达克-冈底斯-察隅弧盆系Cu、Mo、Pb、Zn、Au、Ag等成矿元素富集明显,且从北向南富集程度逐渐增高。综合分析认为,不同大地构造单元差异化的构造-岩浆演化过程导致元素差异富集,进而发育不同成矿元素组合类型的成矿作用。以此为基础,结合元素组合特征,圈定Ⅰ类找矿远景区7处、Ⅱ类找矿远景区9处和Ⅲ类远景区17处。研究结果对新一轮找矿战略突破行动具有一定的指导意义。

湘中北晚二叠世石煤元素地球化学特征

湘中北地区晚二叠世吴家坪组赋存少量石煤,其属性特征鲜明。为揭示湘中北地区石煤元素地球化学特征,采集4个湘中北地区晚二叠世石煤样品,利用X射线衍射仪、带能谱的扫描电镜、X射线荧光光谱仪、电感耦合等离子质谱仪和逐级化学提取试验,测定了石煤样品的矿物成分、常量元素和微量元素含量,进行了微量元素赋存状态分析。结果表明:湘中北地区晚二叠世石煤高灰特征显著,石煤全硫含量差异性大,以硫化铁为主,有机硫次之;石煤矿物种类较少,以石英为主,陆源碎屑输入量极大;石煤高度富集V、Cr、As、Cd、Mo和Sb,其中Cd达到了上地壳丰度的555倍;石煤微量元素赋存特征复杂,其中Ni、Zn、Sr、Mo、Cd赋存状态多样,Li、V、Cr、Cu、Rb、Zr、Ba、U和REEs赋存状态相对简单;根据湘中北晚二叠世石煤元素地球化学特征认为石煤沉积于被动大陆边缘区域,接受陆源碎屑输入,沉积物源区以长英质酸性岩为主。石煤具有海相环境沉积物特征,沉积过程受海水影响强烈,相对稳定的缺氧环境,为V、Mo等元素自生富集提供了条件。

南岭南带河源地区花岗岩LA-ICP-MS锆石U-Pb年代学、地球化学及其地质意义

河源地区位于南岭南带,是我国重要的花岗岩型铀矿产区之一。为了进一步评价区内花岗岩的铀成矿潜力,对河源地区主要花岗岩体开展了LA-ICP-MS锆石U-Pb年代学、微量元素地球化学研究,分析了花岗岩的成岩期次、岩石类型及岩体产铀性。结果表明,新丰江岩体、柏埔岩体和五斗租岩体的年龄分别为(166.8±2.5) Ma、(150.3±2.5) Ma和(144.4±0.9) Ma,形成时代分别为中侏罗世、晚侏罗世和早白垩世早期。该区花岗岩是在岩石圈拉张-减薄背景下形成的陆内造山花岗岩,成因类型为高分异的I型花岗岩。新丰江岩体和柏埔岩体为富铀岩体,五斗租岩体结晶分异程度略低,相对贫铀。结合岩体内晚期岩浆、构造和热液活动特征,认为河源地区花岗岩铀成矿条件优越,具有较大的铀成矿潜力。

Geochronology,Geochemistry,and Sr-Nd-Hf Isotopes of the Diorite Porphyrites from the Weining Beishan Area,Ningxia Hui Autonomous Region:Constraints on Their Source and Tectonic Implications

The Weining Beishan area of Ningxia Hui Autonomous Region is located at on the western edge of the Helanshan tectonic belt,which is a tectonic joint among Alxa Block,Ordos Block,and North Qilian orogenic belt.However,the tectonic evolution of this area remains unclear due to the lack of magmatic information.This paper conducted researches on geochronology,geochemistry,and Sr-Nd-Hf isotopes of the diorite porphyrites exposed in the Weining Beishan area.The zircon U-Pb dating yields two ages of 145.0±1.1 and 146.2±1.5 Ma,and the whole-rock geochemical data indicate that the diorite porphyrites are metaluminous to weakly peraluminous and high-K calc-alkaline series.The characteristics of highly initial^(87)Sr/^(86)Sr ratios(0.70816 to 0.71047),negativeε_(Nd)(t)(−8.9 to−8.4),and negativeε_(Hf)(t)(−13.8 to−21.2)indicate that the diorite porphyrites originated from partial melting of the middle-lower ancient crust related to the North China Craton.Combined with the regional geology,we suggested that partial melting was triggered by a tectonic activity of deep faults cutting through the crust under the regional stress transformation from compressing to extension during the Late Jurassic–Early Cretaceous,which is probably related to the westward subduction of the Paleo-Pacific Plate.

西秦岭地区猪婆沟金矿成矿物质来源及矿床成因分析

猪婆沟金矿位于西秦岭之北秦岭鸳鸯镇-关子镇蛇绿混杂岩带的反“S”形构造的转折端,金矿体赋存在早古生代李子园群中,矿体的产出受NW向和NE向韧性断裂及其次级构造控制,矿体形态为脉状。矿床热液期主成矿阶段石英中包裹体主要为气液两相包裹体、含子晶三相包裹体。含子晶三相包裹体的冰点温度为-4.8~-4.3℃;气液两相包裹体的冰点温度为-5.3~-0.1℃。该阶段含子晶三相包裹体的均一温度为141.3~198.6℃,平均为160.7℃;气液两相包裹体的均一温度为128.9~285.3℃,平均为174.1℃。成矿流体的均一温度值为130~170℃,峰值范围较宽。流体盐度为1.40~8.28%NaCleqv,平均为5.84%NaCleqv,具有中低温、低盐度特征;石英δ18OH2O值为-3.29‰~4.42‰,δD值为-110.1‰~-86.6‰,成矿流体来源于原生岩浆水,在岩浆分异成矿的过程中,大气降水的含量逐渐增多。主成矿阶段黄铁矿和毒砂δ34S值为10.7‰~11.5‰,矿物质分别来源于岩浆岩和地层;Pb同位素组成相似,主要来源于造山带铅,有部分上地壳铅和地幔铅加入,成矿物质来源于岩浆岩和地层两个端元,具有多期次特征。综合分析认为,猪婆沟金矿成因类型属沉积变质-岩浆期后热液叠加改造的构造蚀变岩型金矿床。