In this paper, a reactive distillation (RD) column was applied for synthesis n-butyl acetate from n-butanol and acetic acid. The Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic model and an equilibrium stage model f...In this paper, a reactive distillation (RD) column was applied for synthesis n-butyl acetate from n-butanol and acetic acid. The Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic model and an equilibrium stage model for separation were employed to study the RD process. The results obtained from the equilibrium stage model agreed well with the experiments. The effects of operating variables on the n-butanol conversion and n-butyl acetate purity were further investigated. The optimal column configuration for the production of n-butyl acetate was designed with 5 rectifying stages, 8 reaction stages and 13 stripping stages by the simulation study. According to the simulation results, n-butanol conversion and n-butyl acetate purity all reached greater than 96%.展开更多
采用热重实验对芦苇的热解特性进行了研究,并采用2种动力学模型对不同升温速率(10、20、30℃/min)下芦苇热解过程进行了动力学研究。实验结果表明,芦苇热解主要分为水分析出阶段(30~120℃)、解聚过程阶段(120~237℃)、挥发分脱除阶段(23...采用热重实验对芦苇的热解特性进行了研究,并采用2种动力学模型对不同升温速率(10、20、30℃/min)下芦苇热解过程进行了动力学研究。实验结果表明,芦苇热解主要分为水分析出阶段(30~120℃)、解聚过程阶段(120~237℃)、挥发分脱除阶段(237~369℃)及无机物和残留有机物的分解阶段(369~682℃),并且随着升温速率的增大,热解温度特征点向高温侧偏移。模型计算结果表明,n级单一反应模型在n=1时拟合程度最高,主要遵循一级反应,活化能分别为30.70、34.60、33.01 k J/mol;分布式活化能模型计算得出的活化能处于30~116 k J/mol之间。通过对比2种模型的计算结果,得出分布式活化能模型能更好地反映芦苇的热解过程。展开更多
文摘In this paper, a reactive distillation (RD) column was applied for synthesis n-butyl acetate from n-butanol and acetic acid. The Langmuir-Hinshelwood-Hougen-Watson (LHHW) kinetic model and an equilibrium stage model for separation were employed to study the RD process. The results obtained from the equilibrium stage model agreed well with the experiments. The effects of operating variables on the n-butanol conversion and n-butyl acetate purity were further investigated. The optimal column configuration for the production of n-butyl acetate was designed with 5 rectifying stages, 8 reaction stages and 13 stripping stages by the simulation study. According to the simulation results, n-butanol conversion and n-butyl acetate purity all reached greater than 96%.
文摘采用热重实验对芦苇的热解特性进行了研究,并采用2种动力学模型对不同升温速率(10、20、30℃/min)下芦苇热解过程进行了动力学研究。实验结果表明,芦苇热解主要分为水分析出阶段(30~120℃)、解聚过程阶段(120~237℃)、挥发分脱除阶段(237~369℃)及无机物和残留有机物的分解阶段(369~682℃),并且随着升温速率的增大,热解温度特征点向高温侧偏移。模型计算结果表明,n级单一反应模型在n=1时拟合程度最高,主要遵循一级反应,活化能分别为30.70、34.60、33.01 k J/mol;分布式活化能模型计算得出的活化能处于30~116 k J/mol之间。通过对比2种模型的计算结果,得出分布式活化能模型能更好地反映芦苇的热解过程。
