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气相色谱碳数规律中A,B′值与柱温的关系 被引量:2
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作者 杨军良 方正法 熊士荣 《湖南师范大学自然科学学报》 CAS 1999年第4期53-56,共4页
从lnk′( n) = An + B′和lnk′( n) = - ΔHn/( RT)+ ΔS′n/ R 的关系式中,推导出了A、B′值与柱温的关系式,并在不同的色谱柱上进行了验证.得知在一般固定液上,A和B′值与柱温倒数(1/ T... 从lnk′( n) = An + B′和lnk′( n) = - ΔHn/( RT)+ ΔS′n/ R 的关系式中,推导出了A、B′值与柱温的关系式,并在不同的色谱柱上进行了验证.得知在一般固定液上,A和B′值与柱温倒数(1/ T)有着良好的线性关系,且A值随柱温升高而减小,B′值随柱温升高而增大. 展开更多
关键词 气相色谱 碳数规律 n-烷烃 柱温 色谱柱
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Characterstics of seasonal variations of leaf n-alkanesand n-alkenes in modern higher plants in Qingjiang, Hubei Province, China 被引量:10
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作者 CUI JingWei HUANG JunHua XIE ShuCheng 《Chinese Science Bulletin》 SCIE EI CAS 2008年第17期2659-2664,共6页
On the basis of GC and GC-MS analyses, the seasonal variation of leaf lipids is observed in five plant species in Qingjiang in Hubei Province. The CPI values (carbon preference index) of n-alkanes decrease gradually f... On the basis of GC and GC-MS analyses, the seasonal variation of leaf lipids is observed in five plant species in Qingjiang in Hubei Province. The CPI values (carbon preference index) of n-alkanes decrease gradually from May to November, though the carbon number distributions and the predominant carbon number in an individual species keep unchanged. The declined CPI values might be caused by the leaf fading, which is further supported by a comparison of the defoliated leaves with the fresh leaves. This observation infers the CPI values of n-alkanes in Quaternary sediments can be used as a tool to index the humification, and thus the climatic and the environmental conditions. The plants analyzed here show a remarkable difference in n-alkanes abundance, suggesting their differential contribution to the n-alkanes identified in sediments. The abundance and the compound species of the n-alkenes detected in the plant leaves change greatly with the seasons due to the influence of temperature, with the least compounds being identified in August. 展开更多
关键词 环境变化 n-烷烃 n-烯烃 平均碳链长度 高等植物
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