To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of...To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of pure zinc ferrite being reduced by iron powder was carried out.Under the optimal reduction conditions(i.e.,temperature of 260℃,NaOH concentration of 6 mol/L,liquid-to-solid ratio of 50 mL/g,and a 5-fold excess of iron powder),89%of zinc was extracted.The iron in the reduced residue exists as a magnetite phase.Subsequently,the normal pressure leaching experiment was carried out with EAF dust as raw material,and 66%zinc was leached.The main phase of zinc in normal leaching residue was determined to be zinc ferrite.Then,the normal leaching residue was reduced by iron powder under the alkaline pressure leaching system,and 66.5%of zinc was extracted.After the two-stage leaching process,the leaching rate of zinc in EAF dust can achieve 88.7%.The alkaline pressure leaching solution can be returned as the normal pressure leaching solution,and the magnetite in the alkaline pressure leaching residue can be recovered by magnetic separation.展开更多
The thermal radiation properties of pyrolytic carbon(PyC)protective coatings for monocrystalline silicon furnace prepared by different processes were tested.The changes of normal emissivity of carbon materials caused ...The thermal radiation properties of pyrolytic carbon(PyC)protective coatings for monocrystalline silicon furnace prepared by different processes were tested.The changes of normal emissivity of carbon materials caused by PyC protective coatings were discussed,and the influence of phase structure and surface appearance on the thermal radiation properties was investigated.The results show that the thermal radiation properties of PyC protective coatings with the wave band of 5-25μm are better than C/C substrate,further,normal spectral emissivity of CVD PyC coating remains basically at 0.85-0.90,and the normal total emissivity can reach0.89,which shows high thermal radiation performance.For resin PyC coating and CVD PyC coating,the degree of graphitization are 44.53%and 16.28%respectively,and the R value of Raman spectrum are 0.964and 1.384 respectively.Relatively disorder graphite structure of the latter causes various vibration modes,and the spectral emissivity is better,so the thermal radiation property of CVD PyC coating is excellent.A lot of spherical particles exists on the surface of the CVD PyC coating,and the more interface and spacing of particles reduce the number of particles per unit volume.Therefore,the scattering of thermal radiation is strongly strengthened,and the spectral emissivity is higher.展开更多
基于离散单元法,建立引入Areal Gas Distribution(AGD)技术COREX竖炉物料运动行为的DEM模型.模型计算结果与文献物理实验结果一致,证明模型的合理性.模拟结果显示,AGD竖炉内存在三种类型的流动区域:活塞流区、准停滞区及沟流区.物料运...基于离散单元法,建立引入Areal Gas Distribution(AGD)技术COREX竖炉物料运动行为的DEM模型.模型计算结果与文献物理实验结果一致,证明模型的合理性.模拟结果显示,AGD竖炉内存在三种类型的流动区域:活塞流区、准停滞区及沟流区.物料运动流型呈现Flat→波浪→W的演变过程.AGD梁下方形成的三角形空隙是还原煤气导入竖炉中心的主要煤气通道.竖炉围管区域AGD梁的安装会影响该区域物料的均匀下降,局部区域的较大法向力可能导致物料的挤压黏结,诱发围管slot堵塞.展开更多
基金Project(51504292)supported by National Natural Science Foundation of ChinaProject(2018JJ3678)supported by the Natural Science Foundation of Hunan Province,China。
文摘To recover zinc from electric arc furnace(EAF)dust,a process of primary normal pressure leaching and secondary alkaline pressure leaching is proposed.First,under the alkaline pressure leaching system,the experiment of pure zinc ferrite being reduced by iron powder was carried out.Under the optimal reduction conditions(i.e.,temperature of 260℃,NaOH concentration of 6 mol/L,liquid-to-solid ratio of 50 mL/g,and a 5-fold excess of iron powder),89%of zinc was extracted.The iron in the reduced residue exists as a magnetite phase.Subsequently,the normal pressure leaching experiment was carried out with EAF dust as raw material,and 66%zinc was leached.The main phase of zinc in normal leaching residue was determined to be zinc ferrite.Then,the normal leaching residue was reduced by iron powder under the alkaline pressure leaching system,and 66.5%of zinc was extracted.After the two-stage leaching process,the leaching rate of zinc in EAF dust can achieve 88.7%.The alkaline pressure leaching solution can be returned as the normal pressure leaching solution,and the magnetite in the alkaline pressure leaching residue can be recovered by magnetic separation.
基金Sponsored by the National High Technology Research and Development Program of China(863 Program)(Grant No.2009AA035301)the ChinaPostdoctoral Science Foundation(Grant No.2012M511544)
文摘The thermal radiation properties of pyrolytic carbon(PyC)protective coatings for monocrystalline silicon furnace prepared by different processes were tested.The changes of normal emissivity of carbon materials caused by PyC protective coatings were discussed,and the influence of phase structure and surface appearance on the thermal radiation properties was investigated.The results show that the thermal radiation properties of PyC protective coatings with the wave band of 5-25μm are better than C/C substrate,further,normal spectral emissivity of CVD PyC coating remains basically at 0.85-0.90,and the normal total emissivity can reach0.89,which shows high thermal radiation performance.For resin PyC coating and CVD PyC coating,the degree of graphitization are 44.53%and 16.28%respectively,and the R value of Raman spectrum are 0.964and 1.384 respectively.Relatively disorder graphite structure of the latter causes various vibration modes,and the spectral emissivity is better,so the thermal radiation property of CVD PyC coating is excellent.A lot of spherical particles exists on the surface of the CVD PyC coating,and the more interface and spacing of particles reduce the number of particles per unit volume.Therefore,the scattering of thermal radiation is strongly strengthened,and the spectral emissivity is higher.
文摘基于离散单元法,建立引入Areal Gas Distribution(AGD)技术COREX竖炉物料运动行为的DEM模型.模型计算结果与文献物理实验结果一致,证明模型的合理性.模拟结果显示,AGD竖炉内存在三种类型的流动区域:活塞流区、准停滞区及沟流区.物料运动流型呈现Flat→波浪→W的演变过程.AGD梁下方形成的三角形空隙是还原煤气导入竖炉中心的主要煤气通道.竖炉围管区域AGD梁的安装会影响该区域物料的均匀下降,局部区域的较大法向力可能导致物料的挤压黏结,诱发围管slot堵塞.
