A new upconversion luminescence agent, 40CdF2·60BaF2·0.8ErO3, was synthesized and its fluorescent spectra were determined. This upconversion luminescence agent can emit five upconversion fluorescent peaks sh...A new upconversion luminescence agent, 40CdF2·60BaF2·0.8ErO3, was synthesized and its fluorescent spectra were determined. This upconversion luminescence agent can emit five upconversion fluorescent peaks shown in the fluorescent spectra whose wavelengths are all below 387 nm under the excitation of 488 nm visible light. This upconversion luminescence agent was mixed into nano rutile TiO2 powder by ultrasonic and boiling dispersion and the novel doped nano TiO2 photocatalyst utilizing visible light was firstly prepared. The doped TiO2 powder was charactered by XRD and TEM and its photocatalytic activity was tested through the photocatalytic degradation of methyl orange as a model compound under the visible light irradiation emitted by six three basic color lamps. In order to compare the photocatalytic activities, the same experiment was carried out for undoped TiO2 powder. The degradation ratio of methyl orange in the presence of doped nano TiO2 powder reached 32.5% under visible light irradiation at 20 h which was obviously higher than the corresponding 1.64% in the presence of undoped nano TiO2 powder, which indicate the upconversion luminescence agent prepared as dopant can effectively turn visible lights to ultraviolet lights that are absorbed by nano TiO2 particles to produce the electron-cavity pairs. All the results show that the nano rutile TiO2 powder doped with upconversion luminescence agent is a promising photocatalyst using sunlight for treating the industry dye wastewater in great force.展开更多
The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano...The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano-sized silica（MPNS）was used as macromonomer and polymerized with maleic anhydride and styrene by initiating with BPO in toluene.The structure and properties of MPNS/SMA nano-composite were characterized by FT-IR spectra and TEM.Meanwhile,it was applied as tanning agent compared with the traditional styrene-maleic anhydride copolymer in leather.It was found that the applied leather had better quality characteristics with the addition of the nano-sized silica.展开更多
Nano SiO2/NR composites were prepared through blending nano SiO2 emulsion with natural rubber latex and then concreting with acetic acid. The emulsion nano SiO2 was prepared with Na2SiO3-9H2O and hydrochloric acid und...Nano SiO2/NR composites were prepared through blending nano SiO2 emulsion with natural rubber latex and then concreting with acetic acid. The emulsion nano SiO2 was prepared with Na2SiO3-9H2O and hydrochloric acid under the reaction of the assistant agents. The was analyzed effect of the application rates of assistant agents such as silane coupling agent, surfactant, nucleating agent and dispersant on the properties and interface structure of the nano SiO2/NR composites with IR, TEM, SEM, DMA was analyzed. An orthogonal test was arranged to select optimum condition. The results show that the best combination for preparing nano SiO2/NR composites is as follows： the rate of the silane coupling agent （TESPT）, the surfactant（dodecyl benzene sulfonate natrium）, nucleating agent（AlCl3） and dispersant（ethylene diamine tetraacetie acid） in the course of preparing nano SiO2 are 15%, 2.0%, 2.5% and 0.4%, respectively. Several replications in the experiment had produced desirable nano SiO2 products and nano SiO2/NR composites with better properties.展开更多
A study for further improving the suspension rate of alcohol-based coatings using a new nano-dispersing agent has been presented in this paper. The results of experiments show that the new nano-dispersing agent should...A study for further improving the suspension rate of alcohol-based coatings using a new nano-dispersing agent has been presented in this paper. The results of experiments show that the new nano-dispersing agent should be used in combination with organic auxiliary agent which significantly increases the suspension effect of alcohol-based coatings. By the methods, the suspension rates of 99%, 98%, 96% and 94% can be achieved at 2h, 2h, 48h and 72h, respectively. These alcohol-based coatings have characters of higher strength, lower gas evolution, better brush ability and no blister after ignition.展开更多
SrTiO_3 nano-crystal samples with floccule or flake crystal morphology,which were indexed as a perovskite-type crystal structure based on the results of XRD and TEM,were successfully prepared by one-step liquid reacti...SrTiO_3 nano-crystal samples with floccule or flake crystal morphology,which were indexed as a perovskite-type crystal structure based on the results of XRD and TEM,were successfully prepared by one-step liquid reaction method.And the growth mechanism of the SrTiO_3 nano-crystals under the liquid condition with/without adding the surface active agent was investigated.It was found that adding the surface active agent contributes to the processing in which the ions gathering bodies transit to a more stable phase through the chemical reaction and form the flake SrTiO_3 nano-crystals.展开更多
An experiment of producing high density polyethylene (HDPE) nano-composite filled with 4wt.% talc was presented. Acting as filler and a reinforcing agent in the HDPE, talc powder, sized at around 5 μm, was surface-tr...An experiment of producing high density polyethylene (HDPE) nano-composite filled with 4wt.% talc was presented. Acting as filler and a reinforcing agent in the HDPE, talc powder, sized at around 5 μm, was surface-treated with aluminum diethylene glycol dinitrate coupling agent before adding to the HDPE. Analyses of the reinforced HDPE nano-composite show significant improvement in its mechanical properties including, tensile strength (>26 MPa), break elongation (<1.1%), flexural strength (>22 MPa), and friction coefficients<0.11. The results demonstrate that, after surface-treated, talc can be used as a promising filling material and a reinforcing agent in making HDPE nano-composite.展开更多
The conventional foaming agents have the problems of poor adaptability and high cost during the application in different types of gas fields,especially in high temperature,high salinity,high acidic gas and high conden...The conventional foaming agents have the problems of poor adaptability and high cost during the application in different types of gas fields,especially in high temperature,high salinity,high acidic gas and high condensate oil and gas fields.In this study,the Gemini foaming agent was used as the main agent to enhance foaming and foam stability of the foaming agent,the grafted nanoparticles were used as foam stabilizer to further improve the foam stability,and the characteristic auxiliaries were added to make the foaming agent suitable for different types of gas reservoirs.Two types and six subtypes of nanoparticle foaming agents have been prepared for the main gas fields of China.The experimental evaluation results show that the overall temperature resistance,salinity resistance,H2S resistance,CO2 resistance and condensate resistance of the nanoparticle foaming agents can reach 160℃,250000 mg/L,100 mg/L,100%and 40%,respectively.The new foaming agents have been used in 8685 wells in China.Compared with conventional foaming agent,the average gas flow rate per well increased by 62.48%,the pressure difference(casing-tubing)decreased by 18.9%,and the cost dropped by 45%.The effect of reducing cost and increasing efficiency is obvious.展开更多
The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the ...The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the functional erdurance of nano finishinp wool fibers, in this paper, for the first time wool fibers were chemically modified by using NaClO aqueous and KMnO4 aqueous, and then chemically modified wool fibers and native wool fibers were treated using nano ZnO finishing agent, respectively. The launderability of wool fibers treated by nano finishing agent was investigated. The experimental results show that the chemically modified wool fibers have a good launderaility after being treated by nano ZnO finishing agent treating. The surface morphologies of wool fibers were observed by using SEM. It is got that there is a strong adbesion between nano ZnO and wool surface through XPS analysis.展开更多
A triethylenetetramine epoxy mixture was synthesized through the reaction of a low-molecular-weight liquid epoxy resin with triethylenetetramine(TETA).Then triethyltetramine(TETA)was injected dropwise into a pro-pylen...A triethylenetetramine epoxy mixture was synthesized through the reaction of a low-molecular-weight liquid epoxy resin with triethylenetetramine(TETA).Then triethyltetramine(TETA)was injected dropwise into a pro-pylene glycol methyl ether(PM)solution for chain extension reaction.A hydrophilic andflexible polyether seg-ment was introduced into the hardener molecule.The effects of TETA/DGEPG,reaction temperature and reaction time on the epoxy conversion of polyethylene glycol diglycidyl ether(DGEPG)were studied.In addition,several alternate strategies to add epoxy resin to the high-speed dispersion machine and synthesize MEA DGEBA adduct(without catalyst and with bisphenol A diglycidyl ether epoxy resin)were compared.It was found that the higher the molecular weight of triethylenetetramine,the longer the chain segment of the surface active molecule.When the equivalence ratio of amine hydrogen and epoxy group is low,the stability of lotion is good.When the ratio of amine hydrogen to epoxy group is large,the content of triethylenetetramine is small.The main objective of this study is the provision of new data and knowledge for the development of new materials in the coating and electronic industry.展开更多
The main goal of this paper is to design nanorobotic agent communication mechanisms which would yield coordinated swarm behavior. Precisely we propose a bee-inspired swarm control algorithm that allows nanorobotic age...The main goal of this paper is to design nanorobotic agent communication mechanisms which would yield coordinated swarm behavior. Precisely we propose a bee-inspired swarm control algorithm that allows nanorobotic agents communication in order to converge at a specific target. In this paper, we present experiment to test convergence speed and quality in a simulated multi-agent deployment in an environment with a single target. This is done to measure whether the use of our algorithm or random guess improves efficiency in terms of convergence and quality. The results attained from the experiments indicated that the use of our algorithm enhance the coordinated movement of agents towards the target compared to random guess.展开更多
The effect of expanding swept volume by iNanoW1.0 nanoparticles in ultra-low permeability core was studied by low-field nuclear magnetic resonance(LF-NMR)technology,and the mechanism of expanding swept volume was expl...The effect of expanding swept volume by iNanoW1.0 nanoparticles in ultra-low permeability core was studied by low-field nuclear magnetic resonance(LF-NMR)technology,and the mechanism of expanding swept volume was explained by oxygen spectrum nuclear magnetic resonance(17O-NMR)experiments and capillarity analysis.The results of the LF-NMR experiment show that the nano-sized oil-displacement agent iNanoW1.0 could increase the swept volume by 10%-20%on the basis of conventional water flooding,making water molecules get into the low permeable region with small pores that conventional water flooding could not reach.17O-NMR technique and capillary analysis proved that iNanoW1.0 nanoparticles could weaken the association of hydrogen bonds between water molecules,effectively change the structure of water molecular clusters,and thus increasing the swept volume in the low permeable region.The ability of weakening association of hydrogen bonds between water molecules of iNanoW1.0 nanoparticles increases with its mass fraction and tends to be stable after the mass fraction of 0.1%.展开更多
基金The National Natural Science Foundation of China (No.20371023)
文摘A new upconversion luminescence agent, 40CdF2·60BaF2·0.8ErO3, was synthesized and its fluorescent spectra were determined. This upconversion luminescence agent can emit five upconversion fluorescent peaks shown in the fluorescent spectra whose wavelengths are all below 387 nm under the excitation of 488 nm visible light. This upconversion luminescence agent was mixed into nano rutile TiO2 powder by ultrasonic and boiling dispersion and the novel doped nano TiO2 photocatalyst utilizing visible light was firstly prepared. The doped TiO2 powder was charactered by XRD and TEM and its photocatalytic activity was tested through the photocatalytic degradation of methyl orange as a model compound under the visible light irradiation emitted by six three basic color lamps. In order to compare the photocatalytic activities, the same experiment was carried out for undoped TiO2 powder. The degradation ratio of methyl orange in the presence of doped nano TiO2 powder reached 32.5% under visible light irradiation at 20 h which was obviously higher than the corresponding 1.64% in the presence of undoped nano TiO2 powder, which indicate the upconversion luminescence agent prepared as dopant can effectively turn visible lights to ultraviolet lights that are absorbed by nano TiO2 particles to produce the electron-cavity pairs. All the results show that the nano rutile TiO2 powder doped with upconversion luminescence agent is a promising photocatalyst using sunlight for treating the industry dye wastewater in great force.
文摘The radical polymerization of maleic anhydride（MA）,styrene（ST）with the vinyl groups introduced onto the surface of the nano-sized silica via solution polymerization method was developed.The methacryloxypropyl nano-sized silica（MPNS）was used as macromonomer and polymerized with maleic anhydride and styrene by initiating with BPO in toluene.The structure and properties of MPNS/SMA nano-composite were characterized by FT-IR spectra and TEM.Meanwhile,it was applied as tanning agent compared with the traditional styrene-maleic anhydride copolymer in leather.It was found that the applied leather had better quality characteristics with the addition of the nano-sized silica.
基金Funded by the Special Fund of Basic Scientific Research of Rubber Research Institute of CATASKey Laboratory of Ministry of Agriculture for Natural Rubber Processing (No. xjszx-13 and No. xjsbywfzx2009-19, 706057)
文摘Nano SiO2/NR composites were prepared through blending nano SiO2 emulsion with natural rubber latex and then concreting with acetic acid. The emulsion nano SiO2 was prepared with Na2SiO3-9H2O and hydrochloric acid under the reaction of the assistant agents. The was analyzed effect of the application rates of assistant agents such as silane coupling agent, surfactant, nucleating agent and dispersant on the properties and interface structure of the nano SiO2/NR composites with IR, TEM, SEM, DMA was analyzed. An orthogonal test was arranged to select optimum condition. The results show that the best combination for preparing nano SiO2/NR composites is as follows： the rate of the silane coupling agent （TESPT）, the surfactant（dodecyl benzene sulfonate natrium）, nucleating agent（AlCl3） and dispersant（ethylene diamine tetraacetie acid） in the course of preparing nano SiO2 are 15%, 2.0%, 2.5% and 0.4%, respectively. Several replications in the experiment had produced desirable nano SiO2 products and nano SiO2/NR composites with better properties.
文摘A study for further improving the suspension rate of alcohol-based coatings using a new nano-dispersing agent has been presented in this paper. The results of experiments show that the new nano-dispersing agent should be used in combination with organic auxiliary agent which significantly increases the suspension effect of alcohol-based coatings. By the methods, the suspension rates of 99%, 98%, 96% and 94% can be achieved at 2h, 2h, 48h and 72h, respectively. These alcohol-based coatings have characters of higher strength, lower gas evolution, better brush ability and no blister after ignition.
文摘SrTiO_3 nano-crystal samples with floccule or flake crystal morphology,which were indexed as a perovskite-type crystal structure based on the results of XRD and TEM,were successfully prepared by one-step liquid reaction method.And the growth mechanism of the SrTiO_3 nano-crystals under the liquid condition with/without adding the surface active agent was investigated.It was found that adding the surface active agent contributes to the processing in which the ions gathering bodies transit to a more stable phase through the chemical reaction and form the flake SrTiO_3 nano-crystals.
文摘An experiment of producing high density polyethylene (HDPE) nano-composite filled with 4wt.% talc was presented. Acting as filler and a reinforcing agent in the HDPE, talc powder, sized at around 5 μm, was surface-treated with aluminum diethylene glycol dinitrate coupling agent before adding to the HDPE. Analyses of the reinforced HDPE nano-composite show significant improvement in its mechanical properties including, tensile strength (>26 MPa), break elongation (<1.1%), flexural strength (>22 MPa), and friction coefficients<0.11. The results demonstrate that, after surface-treated, talc can be used as a promising filling material and a reinforcing agent in making HDPE nano-composite.
基金Supported by the PetroChina Scientifc Research and Technological Development Project(kt2017-21-14-1).
文摘The conventional foaming agents have the problems of poor adaptability and high cost during the application in different types of gas fields,especially in high temperature,high salinity,high acidic gas and high condensate oil and gas fields.In this study,the Gemini foaming agent was used as the main agent to enhance foaming and foam stability of the foaming agent,the grafted nanoparticles were used as foam stabilizer to further improve the foam stability,and the characteristic auxiliaries were added to make the foaming agent suitable for different types of gas reservoirs.Two types and six subtypes of nanoparticle foaming agents have been prepared for the main gas fields of China.The experimental evaluation results show that the overall temperature resistance,salinity resistance,H2S resistance,CO2 resistance and condensate resistance of the nanoparticle foaming agents can reach 160℃,250000 mg/L,100 mg/L,100%and 40%,respectively.The new foaming agents have been used in 8685 wells in China.Compared with conventional foaming agent,the average gas flow rate per well increased by 62.48%,the pressure difference(casing-tubing)decreased by 18.9%,and the cost dropped by 45%.The effect of reducing cost and increasing efficiency is obvious.
文摘The launderability of wool fabrics treated by nano finoshing agent influences directly the functional endurance of he treated wool fabric. In order to investigate the effect of wool fibers surface modification on the functional erdurance of nano finishinp wool fibers, in this paper, for the first time wool fibers were chemically modified by using NaClO aqueous and KMnO4 aqueous, and then chemically modified wool fibers and native wool fibers were treated using nano ZnO finishing agent, respectively. The launderability of wool fibers treated by nano finishing agent was investigated. The experimental results show that the chemically modified wool fibers have a good launderaility after being treated by nano ZnO finishing agent treating. The surface morphologies of wool fibers were observed by using SEM. It is got that there is a strong adbesion between nano ZnO and wool surface through XPS analysis.
基金This work is financially supported by a University-Level Doctoral Research Start-Up Fund in 2019.
文摘A triethylenetetramine epoxy mixture was synthesized through the reaction of a low-molecular-weight liquid epoxy resin with triethylenetetramine(TETA).Then triethyltetramine(TETA)was injected dropwise into a pro-pylene glycol methyl ether(PM)solution for chain extension reaction.A hydrophilic andflexible polyether seg-ment was introduced into the hardener molecule.The effects of TETA/DGEPG,reaction temperature and reaction time on the epoxy conversion of polyethylene glycol diglycidyl ether(DGEPG)were studied.In addition,several alternate strategies to add epoxy resin to the high-speed dispersion machine and synthesize MEA DGEBA adduct(without catalyst and with bisphenol A diglycidyl ether epoxy resin)were compared.It was found that the higher the molecular weight of triethylenetetramine,the longer the chain segment of the surface active molecule.When the equivalence ratio of amine hydrogen and epoxy group is low,the stability of lotion is good.When the ratio of amine hydrogen to epoxy group is large,the content of triethylenetetramine is small.The main objective of this study is the provision of new data and knowledge for the development of new materials in the coating and electronic industry.
文摘The main goal of this paper is to design nanorobotic agent communication mechanisms which would yield coordinated swarm behavior. Precisely we propose a bee-inspired swarm control algorithm that allows nanorobotic agents communication in order to converge at a specific target. In this paper, we present experiment to test convergence speed and quality in a simulated multi-agent deployment in an environment with a single target. This is done to measure whether the use of our algorithm or random guess improves efficiency in terms of convergence and quality. The results attained from the experiments indicated that the use of our algorithm enhance the coordinated movement of agents towards the target compared to random guess.
基金Supported by the PetroChina Scientifc Research and Technological Development Project(2018A-0907).
文摘The effect of expanding swept volume by iNanoW1.0 nanoparticles in ultra-low permeability core was studied by low-field nuclear magnetic resonance(LF-NMR)technology,and the mechanism of expanding swept volume was explained by oxygen spectrum nuclear magnetic resonance(17O-NMR)experiments and capillarity analysis.The results of the LF-NMR experiment show that the nano-sized oil-displacement agent iNanoW1.0 could increase the swept volume by 10%-20%on the basis of conventional water flooding,making water molecules get into the low permeable region with small pores that conventional water flooding could not reach.17O-NMR technique and capillary analysis proved that iNanoW1.0 nanoparticles could weaken the association of hydrogen bonds between water molecules,effectively change the structure of water molecular clusters,and thus increasing the swept volume in the low permeable region.The ability of weakening association of hydrogen bonds between water molecules of iNanoW1.0 nanoparticles increases with its mass fraction and tends to be stable after the mass fraction of 0.1%.
