In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The res...In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The results show that the variation rules of the friction force, film thicknessand viscosity of the lubricant at the nanoscale are different from elastohydrodynamic lubrication （EHL）. It is speculated that these differences are attributed to the special arrangement of the molecules at the nanoscale. However, it is difficult to obtain the molecular orientation and distribution directly from the lubricant molecules in these experiments. In recent years, more and more attention has been paid to use new techniques to overcome the shortcomings of traditional experiments, including various spectral methods. The most representative achievements in the experimental research of molecular arrangement are reviewed in this paper： The change of film structure of a liquid crystal under confinement has been obtained using X-ray method. The molecular orientation change of lubricant films has been observed using absorption spectroscopy. Infrared spectroscopy has been used to measure the anisotropy of molecular orientation in the contact region when the lubricant film thickness is reduced to a few tens of nanometers. In situ Raman spectroscopy has been performed to measure the molecular orientation of the lubricant film semi-quantitatively. These results prove that confinement and shear in the contact region can change the arrangement of lubricant molecules. As a result, the lubrication characteristics are affected. The shortages of these works are also discussed based on practicable results. Further work is needed to separate the information of the solid-liquid interface from the bulk liquid film.展开更多
In current research, MWCNT-SiO_2/oil hybrid nano-lubricant viscosity is experimentally examined. By dispersing 0.05%, 0.1%, 0.2%, 0.4%, 0.8% and 1% volume of MWCNTs and SiO_2 nanoparticle into the engine oil SAE 20W50...In current research, MWCNT-SiO_2/oil hybrid nano-lubricant viscosity is experimentally examined. By dispersing 0.05%, 0.1%, 0.2%, 0.4%, 0.8% and 1% volume of MWCNTs and SiO_2 nanoparticle into the engine oil SAE 20W50, the temperature and solid volume fraction consequences were studied. At 40 to 100 ℃ temperature, the viscosities were assessed. The results indicated Newtonian behavior for the hybrid nano-lubricant. Moreover, solid volume fraction augmentation and temperature enhanced the viscosity enhancement of hybrid nano-lubricant. At highest solid volume fraction and temperature, nano-lubricant viscosity was 171% greater compared to pure 20W50. Existed models lack the ability to predict the hybrid nano-lubricant viscosity. Thus, a new correlation regarding solid volume fraction and temperature was suggested with R-squared of 0.9943.展开更多
A new kind of emulsion containing nano TiO_2 was developed through the dispersion experiment. A commercial emulsion and a prepared by our lab emulsion without nano particles were chosen as controls to test the tribolo...A new kind of emulsion containing nano TiO_2 was developed through the dispersion experiment. A commercial emulsion and a prepared by our lab emulsion without nano particles were chosen as controls to test the tribological and antibacterial properties of this new emulsion. The load carrying capacity, friction coefficient and average diameter of wear scars were tested by a four-ball machine and the comprehensive antifriction parameter ω was calculated. The wetting angle was also tested using a JC200C1 wetting angle tester. The micro surface and roughness of rolled strips were analyzed to investigate the tribological performance of the recommended new emulsion in strip production. It is shown that the new nano-emulsion possesses a higher load carrying capacity and wetting ability. Therefore the abrasive/plowing wear is reduced more efficiently with the addition of nano particles, and the micro surface is improved. The density of bacteria in the emulsions was tested after the cold rolling experiment. The emulsion breaking ratio and bacteria density were also tested in different time intervals after the cold rolling experiment. The final p H values and bacteria density of different layers of emulsions were measured and the sediment was analyzed by TEM to evaluate the antibacterial behavior of this new emulsion. It is shown that the density of microbial colonies which led to a corruption of emulsions was decreased about 90% and the effective antibacterial period was prolonged.展开更多
Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common meth...Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common method. Nano-copper was prepared by reduction in liquid phase. The different project and routine practice for preparing nano-copper were researched. The dispersion problem of nano-copper was investigated by surface treatment and high dispersion. The particles dimension, the dispersion stability and the purity of nano-copper were characterized by TEM and XRD. The conclusion indicates that the methods of the preparation and dispersion can obtain 20nm copper additive with good dispersion property in lubrication oil.展开更多
How to reduce flow resistance of nano-confined fluids to achieve a high flux is a new challenge for modern chemical engineering applications, such as membrane separation and nanofluidic devices. Traditional models are...How to reduce flow resistance of nano-confined fluids to achieve a high flux is a new challenge for modern chemical engineering applications, such as membrane separation and nanofluidic devices. Traditional models are inapplicable to explain the significant differences in the flow resistance of different liquid–solid systems.On the other hand, friction reduction in liquid nano-lubrication has received considerable attention during the past decades. Both fields are exposed to a common scientific issue regarding friction reduction during liquid–solid relative motion at nanoscale. A promising approach to control the flow resistance of nano-confined fluids is to reference the factors affecting liquid nano-lubrication. In this review, two concepts of the friction coefficient derived from fluid flow and tribology were discussed to reveal their intrinsic relations. Recent progress on low or ultra-low friction coefficients in liquid nano-lubrication was summarized based on two situations. Finally, a new strategy was introduced to study the friction coefficient based on analyzing the intermolecular interactions through an atomic force microscope(AFM), which is a cutting-point to build a new model to study flowresistance at nanoscale.展开更多
ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particle...ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particles were added at a mass ratio of 1.0%,2.0%,3.0%,and 4.0%,respectively,in base oil and their friction and wear behaviors were evaluated on a MRS-10D type four-ball wear tester.After four-ball wear tests,the morphology of the rubbing surfaces was evaluated with metallographic microscope.It was revealed that the modified nano ZnO had excellent behavior for improving anti-wear property and friction coefficient,which could greatly reduce the friction of machine parts.展开更多
The major solving ways for the material wear are surface modification and lubrication. Currently, the researches at home and abroad are all limited to the single study of either nano-lubricating oil additive or electr...The major solving ways for the material wear are surface modification and lubrication. Currently, the researches at home and abroad are all limited to the single study of either nano-lubricating oil additive or electroless deposited coating. The surface coating has high hardness and high wear resistance, however, the friction reduction performance of the coating with high hardness is not good, the thickness of the coating is limited, and the coating can not regenerate after wearing. The nano-lubricating additives have good tribological performance and self-repair function, but under heavy load, the self-repair rate to the worn surface with the nano-additives is smaller than the wearing rate of the friction pair. To solve the above problems, the Ni-W-P alloy coating and deposition process with excellent anti-wear, and suitable for industrial application were developed, the optimum bath composition and process can be obtained by studying the influence of the bath composition, temperature and PH value to the deposition rate and the plating solution stability. The tribological properties as well as anti-wear and friction reduction mechanism of wear self-repair nano-ceramic lubricating additives are also studied. The ring-block abrasion testing machine and energy dispersive spectrometer are used to explore the internal relation between the coating and the nano-lubricating oil additives, and the tribology mechanism, to seek the synergetic effect between the two. The test results show that the wear resistance of Ni-W-P alloy coating （with heat treatment and in oil with nano-ceramic additives） has increased hundreds times than 45 steel as the metal substrate in basic oil, the friction reduction performance is improved. This research breaks through the bottleneck of previous separate research of the above-mentioned two methods, and explores the combination use of the two methods in industrial field.展开更多
The coating and deposition process with excellent anti wear and suitable for industrial application were developed, and the optimum bath composition and process were obtained by studying the influence of the bath comp...The coating and deposition process with excellent anti wear and suitable for industrial application were developed, and the optimum bath composition and process were obtained by studying the influence of the bath composition, temperature and pH value on the deposition rate and the plating solution stability. Moreover, the tribological properties of nano-Cu lubricating additives and electroless deposited Ni-W-P coating as well as their synergistic effect are researched using ring-block abrasion testing machine and energy dispersive spectrometer. Research results show that Ni-W-P alloy coating and nano-Cu lubricating additive have excellent synergistic effect, e g, the wear resistance of Ni-W-P alloy coating （with heat treatment and the oil with nano-Cu additives） has increased hundreds times than 45 steel as the metal substrate with the basic oil, and zero wear is achieved, which breaks through the bottleneck of previous separate research of the above-mentioned two aspects.展开更多
The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95℃ for 3 h, followed by calcination at 400℃ for 3 h. The samples...The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95℃ for 3 h, followed by calcination at 400℃ for 3 h. The samples were characterized and analyzed by XRD, SEM, FTIR and zeta potential measurements. The products were modified with different surfactants to improve their dispersion stability, both the amount and the best zeta potential values of which were identified in this work. The surface-modified nano-particles were added at a mass fraction of 1.0%, 2.0%, 3.0%, and 4.0%, respectively, into the base oil. It was showed that the additive in base oil has good oil solubility without detectable corrosion of copper stripe, and had excellent behavior in terms of anti-wear performance and lower friction coefficient.展开更多
The tribological properties of Sialon sliding against AISI52100 steel ball under the lubrication of solid particle additives, as micro-borate particle and nano-PbS particle, were evaluated by a SRV ball-on-disc test r...The tribological properties of Sialon sliding against AISI52100 steel ball under the lubrication of solid particle additives, as micro-borate particle and nano-PbS particle, were evaluated by a SRV ball-on-disc test rig. The chemical composition of the worn surface was characterized by X-ray photoelectron spectroscopy (XPS). The morphologies of the worn surfaces of Sialon were analyzed by scanning electron microscopy (SEM). The results show that the particles can reduce the friction coefficient of the pairs and the wear volume of Sialon significantly. The wear resistance of micro-borate is superior to that of nano-PbS while the friction-reducing ability of PbS is better than that of borate. According to the XPS and SEM results, the wear resistance of PbS is mainly depended on the tribochemical film mainly composed of PbSO 4, which deposited on the worn surface with good bonding strength. No tribochemical reaction or deposited film was detected or observed on the worn surface of Sialon under the lubrication of borate, indicating that the possible physically deposited film generated from micro particle can also greatly reduce the wear volume of Sialon, though the friction reducing ability of which is inferior to that of nano PbS particle.展开更多
Aerospace aluminum alloy is the most used structural material for rockets,aircraft,spacecraft,and space stations.The deterioration of surface integrity of dry machining and the insufficient heat transfer capacity of m...Aerospace aluminum alloy is the most used structural material for rockets,aircraft,spacecraft,and space stations.The deterioration of surface integrity of dry machining and the insufficient heat transfer capacity of minimal quantity lubrication have become the bottleneck of lubrication and heat dissipation of aerospace aluminum alloy.However,the excellent thermal conductivity and tribological properties of nanofluids are expected to fill this gap.The traditional milling force models are mainly based on empirical models and finite element simulations,which are insufficient to guide industrial manufacturing.In this study,the milling force of the integral end milling cutter is deduced by force analysis of the milling cutter element and numerical simulation.The instantaneous milling force model of the integral end milling cutter is established under the condition of dry and nanofluid minimal quantity lubrication(NMQL)based on the dual mechanism of the shear effect on the rake face of the milling cutter and the plow cutting effect on the flank surface.A single factor experiment is designed to introduce NMQL and the milling feed factor into the instantaneous milling force coefficient.The average absolute errors in the prediction of milling forces for the NMQL are 13.3%,2.3%,and 7.6%in the x-,y-,and z-direction,respectively.Compared with the milling forces obtained by dry milling,those by NMQL decrease by 21.4%,17.7%,and 18.5%in the x-,y-,and z-direction,respectively.展开更多
基金Supported by National Natural Science Foundation of China(Grant Nos.51335005,51321092)
文摘In order to understand lubrication mechanism at the nanoscale, researchers have used many physical experimental approaches, such as surface force apparatus, atomic force microscopy and ball-on-disk tribometer. The results show that the variation rules of the friction force, film thicknessand viscosity of the lubricant at the nanoscale are different from elastohydrodynamic lubrication （EHL）. It is speculated that these differences are attributed to the special arrangement of the molecules at the nanoscale. However, it is difficult to obtain the molecular orientation and distribution directly from the lubricant molecules in these experiments. In recent years, more and more attention has been paid to use new techniques to overcome the shortcomings of traditional experiments, including various spectral methods. The most representative achievements in the experimental research of molecular arrangement are reviewed in this paper： The change of film structure of a liquid crystal under confinement has been obtained using X-ray method. The molecular orientation change of lubricant films has been observed using absorption spectroscopy. Infrared spectroscopy has been used to measure the anisotropy of molecular orientation in the contact region when the lubricant film thickness is reduced to a few tens of nanometers. In situ Raman spectroscopy has been performed to measure the molecular orientation of the lubricant film semi-quantitatively. These results prove that confinement and shear in the contact region can change the arrangement of lubricant molecules. As a result, the lubrication characteristics are affected. The shortages of these works are also discussed based on practicable results. Further work is needed to separate the information of the solid-liquid interface from the bulk liquid film.
文摘In current research, MWCNT-SiO_2/oil hybrid nano-lubricant viscosity is experimentally examined. By dispersing 0.05%, 0.1%, 0.2%, 0.4%, 0.8% and 1% volume of MWCNTs and SiO_2 nanoparticle into the engine oil SAE 20W50, the temperature and solid volume fraction consequences were studied. At 40 to 100 ℃ temperature, the viscosities were assessed. The results indicated Newtonian behavior for the hybrid nano-lubricant. Moreover, solid volume fraction augmentation and temperature enhanced the viscosity enhancement of hybrid nano-lubricant. At highest solid volume fraction and temperature, nano-lubricant viscosity was 171% greater compared to pure 20W50. Existed models lack the ability to predict the hybrid nano-lubricant viscosity. Thus, a new correlation regarding solid volume fraction and temperature was suggested with R-squared of 0.9943.
基金supported by the National Natural Science Foundation of China (contract/grant number: 51274037) affiliated to the project: "The research of lubrication model and interaction between nano-lubricating particles and rolling deformed surface."
文摘A new kind of emulsion containing nano TiO_2 was developed through the dispersion experiment. A commercial emulsion and a prepared by our lab emulsion without nano particles were chosen as controls to test the tribological and antibacterial properties of this new emulsion. The load carrying capacity, friction coefficient and average diameter of wear scars were tested by a four-ball machine and the comprehensive antifriction parameter ω was calculated. The wetting angle was also tested using a JC200C1 wetting angle tester. The micro surface and roughness of rolled strips were analyzed to investigate the tribological performance of the recommended new emulsion in strip production. It is shown that the new nano-emulsion possesses a higher load carrying capacity and wetting ability. Therefore the abrasive/plowing wear is reduced more efficiently with the addition of nano particles, and the micro surface is improved. The density of bacteria in the emulsions was tested after the cold rolling experiment. The emulsion breaking ratio and bacteria density were also tested in different time intervals after the cold rolling experiment. The final p H values and bacteria density of different layers of emulsions were measured and the sediment was analyzed by TEM to evaluate the antibacterial behavior of this new emulsion. It is shown that the density of microbial colonies which led to a corruption of emulsions was decreased about 90% and the effective antibacterial period was prolonged.
文摘Nano-copper used as lubrication oil additive has good tribological property and active self-repairing effect for friction pairs. The reduction in liquid phase for preparing nano-additive is one of the most common method. Nano-copper was prepared by reduction in liquid phase. The different project and routine practice for preparing nano-copper were researched. The dispersion problem of nano-copper was investigated by surface treatment and high dispersion. The particles dimension, the dispersion stability and the purity of nano-copper were characterized by TEM and XRD. The conclusion indicates that the methods of the preparation and dispersion can obtain 20nm copper additive with good dispersion property in lubrication oil.
基金Supported by the National Natural Science Foundation of China(21176112,21576130,21490584,51005123)Qing Lan Project,the State Key Laboratory of Materials-Oriented Chemical Engineering(KL15-03)+1 种基金Specialized Research Fund for the Doctoral Program of Higher Education(20133221110001)the Natural Science Foundation of Jiangsu Province(BK20130062)
文摘How to reduce flow resistance of nano-confined fluids to achieve a high flux is a new challenge for modern chemical engineering applications, such as membrane separation and nanofluidic devices. Traditional models are inapplicable to explain the significant differences in the flow resistance of different liquid–solid systems.On the other hand, friction reduction in liquid nano-lubrication has received considerable attention during the past decades. Both fields are exposed to a common scientific issue regarding friction reduction during liquid–solid relative motion at nanoscale. A promising approach to control the flow resistance of nano-confined fluids is to reference the factors affecting liquid nano-lubrication. In this review, two concepts of the friction coefficient derived from fluid flow and tribology were discussed to reveal their intrinsic relations. Recent progress on low or ultra-low friction coefficients in liquid nano-lubrication was summarized based on two situations. Finally, a new strategy was introduced to study the friction coefficient based on analyzing the intermolecular interactions through an atomic force microscope(AFM), which is a cutting-point to build a new model to study flowresistance at nanoscale.
基金supported by Liaoning Provincial Office of Education for Innovation Team (Project number:2006T001)Liaoning Province of Key Laboratory Project (Project number:2008403001)
文摘ZnO nanoparticles with an average size of 125 nm were prepared via homogeneous precipitation method and were characterized by SEM.The products were surface-modified by the surfactant SDS.Surface-modified nano particles were added at a mass ratio of 1.0%,2.0%,3.0%,and 4.0%,respectively,in base oil and their friction and wear behaviors were evaluated on a MRS-10D type four-ball wear tester.After four-ball wear tests,the morphology of the rubbing surfaces was evaluated with metallographic microscope.It was revealed that the modified nano ZnO had excellent behavior for improving anti-wear property and friction coefficient,which could greatly reduce the friction of machine parts.
文摘The major solving ways for the material wear are surface modification and lubrication. Currently, the researches at home and abroad are all limited to the single study of either nano-lubricating oil additive or electroless deposited coating. The surface coating has high hardness and high wear resistance, however, the friction reduction performance of the coating with high hardness is not good, the thickness of the coating is limited, and the coating can not regenerate after wearing. The nano-lubricating additives have good tribological performance and self-repair function, but under heavy load, the self-repair rate to the worn surface with the nano-additives is smaller than the wearing rate of the friction pair. To solve the above problems, the Ni-W-P alloy coating and deposition process with excellent anti-wear, and suitable for industrial application were developed, the optimum bath composition and process can be obtained by studying the influence of the bath composition, temperature and PH value to the deposition rate and the plating solution stability. The tribological properties as well as anti-wear and friction reduction mechanism of wear self-repair nano-ceramic lubricating additives are also studied. The ring-block abrasion testing machine and energy dispersive spectrometer are used to explore the internal relation between the coating and the nano-lubricating oil additives, and the tribology mechanism, to seek the synergetic effect between the two. The test results show that the wear resistance of Ni-W-P alloy coating （with heat treatment and in oil with nano-ceramic additives） has increased hundreds times than 45 steel as the metal substrate in basic oil, the friction reduction performance is improved. This research breaks through the bottleneck of previous separate research of the above-mentioned two methods, and explores the combination use of the two methods in industrial field.
文摘The coating and deposition process with excellent anti wear and suitable for industrial application were developed, and the optimum bath composition and process were obtained by studying the influence of the bath composition, temperature and pH value on the deposition rate and the plating solution stability. Moreover, the tribological properties of nano-Cu lubricating additives and electroless deposited Ni-W-P coating as well as their synergistic effect are researched using ring-block abrasion testing machine and energy dispersive spectrometer. Research results show that Ni-W-P alloy coating and nano-Cu lubricating additive have excellent synergistic effect, e g, the wear resistance of Ni-W-P alloy coating （with heat treatment and the oil with nano-Cu additives） has increased hundreds times than 45 steel as the metal substrate with the basic oil, and zero wear is achieved, which breaks through the bottleneck of previous separate research of the above-mentioned two aspects.
基金supported by the Liaoning Provincial Office of Education for Innovation Team (2006T001)Liaoning Province of Key Laboratory Project (2008403001)
文摘The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95℃ for 3 h, followed by calcination at 400℃ for 3 h. The samples were characterized and analyzed by XRD, SEM, FTIR and zeta potential measurements. The products were modified with different surfactants to improve their dispersion stability, both the amount and the best zeta potential values of which were identified in this work. The surface-modified nano-particles were added at a mass fraction of 1.0%, 2.0%, 3.0%, and 4.0%, respectively, into the base oil. It was showed that the additive in base oil has good oil solubility without detectable corrosion of copper stripe, and had excellent behavior in terms of anti-wear performance and lower friction coefficient.
基金FundedbytheNationalNaturalScienceFoundationofChi na (No .30 30 0 0 78)
文摘The tribological properties of Sialon sliding against AISI52100 steel ball under the lubrication of solid particle additives, as micro-borate particle and nano-PbS particle, were evaluated by a SRV ball-on-disc test rig. The chemical composition of the worn surface was characterized by X-ray photoelectron spectroscopy (XPS). The morphologies of the worn surfaces of Sialon were analyzed by scanning electron microscopy (SEM). The results show that the particles can reduce the friction coefficient of the pairs and the wear volume of Sialon significantly. The wear resistance of micro-borate is superior to that of nano-PbS while the friction-reducing ability of PbS is better than that of borate. According to the XPS and SEM results, the wear resistance of PbS is mainly depended on the tribochemical film mainly composed of PbSO 4, which deposited on the worn surface with good bonding strength. No tribochemical reaction or deposited film was detected or observed on the worn surface of Sialon under the lubrication of borate, indicating that the possible physically deposited film generated from micro particle can also greatly reduce the wear volume of Sialon, though the friction reducing ability of which is inferior to that of nano PbS particle.
基金upported by the National Natural Science Foundation of China (Grant Nos.51975305,51905289,52105457,and 52105264)the National Key R&D Program of China (Grant No.2020YFB2010500)+2 种基金the Key Projects of Shandong Natural Science Foundation,China (Grant Nos.ZR2020KE027,ZR2020ME158,and ZR2021QE116)the Major Science and Technology Innovation Engineering Projects of Shandong Province,China (Grant No.2019JZZY020111)the Source Innovation Project of Qingdao West Coast New Area,China (Grant Nos.2020-97 and 2020-98).
文摘Aerospace aluminum alloy is the most used structural material for rockets,aircraft,spacecraft,and space stations.The deterioration of surface integrity of dry machining and the insufficient heat transfer capacity of minimal quantity lubrication have become the bottleneck of lubrication and heat dissipation of aerospace aluminum alloy.However,the excellent thermal conductivity and tribological properties of nanofluids are expected to fill this gap.The traditional milling force models are mainly based on empirical models and finite element simulations,which are insufficient to guide industrial manufacturing.In this study,the milling force of the integral end milling cutter is deduced by force analysis of the milling cutter element and numerical simulation.The instantaneous milling force model of the integral end milling cutter is established under the condition of dry and nanofluid minimal quantity lubrication(NMQL)based on the dual mechanism of the shear effect on the rake face of the milling cutter and the plow cutting effect on the flank surface.A single factor experiment is designed to introduce NMQL and the milling feed factor into the instantaneous milling force coefficient.The average absolute errors in the prediction of milling forces for the NMQL are 13.3%,2.3%,and 7.6%in the x-,y-,and z-direction,respectively.Compared with the milling forces obtained by dry milling,those by NMQL decrease by 21.4%,17.7%,and 18.5%in the x-,y-,and z-direction,respectively.
