Properties of Al2O3-coated nano-SiC have been compared with those of as-received SiC. The isoelectric point (IEP) of SiC changed from pH3.4 to pH7.3 after coating with the alumina precursor, which is close to that of ...Properties of Al2O3-coated nano-SiC have been compared with those of as-received SiC. The isoelectric point (IEP) of SiC changed from pH3.4 to pH7.3 after coating with the alumina precursor, which is close to that of alumina. Because both surfaces of coated SiC and AI2O3 possess higher positive charge at pH=4.5-5.0, they are uniformly dispersed in the two-phase aqueous suspensions, Then a mixed powder containing nano-SiC dispersed homogeneously into the Al2O3 matrix was achieved from flocculating the two-phase suspension. Finally, Al2O3/SiC nanocomposites were obtained by coating nano-SiC with Al2O3, in which the majority of SiC particles were located within the AI2O3 grains. The observation by transmission electron microscopy (TEM) and the analysis by the X-ray photoelectron spectroscopy (XPS) showed that cracks propagated towards the intragranular SiC rather than along grain boundaries.展开更多
The dielectric properties of nano Si/C/N composite powder and nano SiC powder at high frequencies have been studied. The nano Si/C/N composite powder and nano SiC powder were synthesized from hexamethyldisilazane ((Me...The dielectric properties of nano Si/C/N composite powder and nano SiC powder at high frequencies have been studied. The nano Si/C/N composite powder and nano SiC powder were synthesized from hexamethyldisilazane ((Me 3Si) 2NH) (Me:CH 3) and SiH 4 C 2H 2 respectively by a laser induced gas phase reaction. The complex permittivities of the nano Si/C/N composite powder and nano SiC powder were measured between 8 2GHz and 12 4GHz. The real and imaginary parts of the complex permittivities of nano Si/C/N composite powder are much higher than those of nano SiC powder. The SiC microcrystalline in the nano Si/C/N composite powder dissolved a great deal of nitrogen. The local structure around Si atoms changed by introducing N into SiC. Carbon atoms around Si were substituted by N atoms. So charged defects and quasi free electrons moved in response to the electric field, diffusion or polarization current resulted from the field propagation. The high ε″and loss factor tgδ(ε″/ε′) of Si/C/N composite powder were due to the dielectric relaxation.展开更多
Composite felts reinforced by both SiC nano-fibers(SiC-NFs)and carbon fibers were prepared at 1 273 K using Ni granules as catalyzers with different deposition time.SiC-NFs were deposited on the surface of the carbon ...Composite felts reinforced by both SiC nano-fibers(SiC-NFs)and carbon fibers were prepared at 1 273 K using Ni granules as catalyzers with different deposition time.SiC-NFs were deposited on the surface of the carbon fibers in situ by catalytic chemical vapor deposition(CCVD).The phase,microstructure and morphology of the fibers after electroplating and deposition were characterized by XRD,SEM and TEM.The results show that the SiC-NFs produced by CCVD are composed of single crystal of β-SiC.It is found that smaller nano-granules are more active as catalyzers.The resulting SiC-NFs appear more spindle-like and have a more homogeneous dispersion.The mass change of the samples before and after deposition shows that using more Ni granules results in a faster growth velocity of SiC-NFs.With the same electroplating time,the growth velocity of the SiC-NFs first increases and then decreases.At around 4 h,it reaches the maximum growth velocity,and it becomes nearly constant at around 8 h.After 8 h, the stable growth velocity of the electroplated Ni samples is faster than that of the conventional sample produced without catalyzers, because the SiC-NFs can improve the specific surface area and the activity of the surface.展开更多
为满足雷达阵面高功率密度的需求,SiC宽禁带半导体器件在电源模块应用中逐步取代传统硅功率器件。传统焊接及导电胶粘工艺存在导电性能差、热阻大、高温蠕变等缺点,无法发挥SiC功率器件高结温和高功率的优势。纳米银烧结是大功率器件最...为满足雷达阵面高功率密度的需求,SiC宽禁带半导体器件在电源模块应用中逐步取代传统硅功率器件。传统焊接及导电胶粘工艺存在导电性能差、热阻大、高温蠕变等缺点,无法发挥SiC功率器件高结温和高功率的优势。纳米银烧结是大功率器件最合适的界面互连技术之一,具有低温烧结高温使用的优点和良好的高温工作特性。文中针对高功率电源模块大电流传输对低压降及高效散热的需求,基于高功率半桥电源模块开展了SiC芯片的纳米银双面烧结工艺技术研究,突破了成型银焊片制备、纳米银焊膏高平整度点涂、无压烧结等关键技术,并通过烧结界面微观分析以及芯片剪切强度和焊片剥离强度测试对烧结工艺参数进行了优化。最后对半桥模块进行了静态测试和双脉冲测试。该模块的栅极泄漏电流<1.5 n A,开关切换时间<125 ns,漏极电压过冲<12.5%,满足产品应用需求。展开更多
Microand nano-sized SiC/fluoroelastomer （FKM） composites were prepared by a mechanical mixing method. These composites were first characterized by a rotorless rheometer. Then the effects of micro- and nano-sized SiC...Microand nano-sized SiC/fluoroelastomer （FKM） composites were prepared by a mechanical mixing method. These composites were first characterized by a rotorless rheometer. Then the effects of micro- and nano-sized SiC on hardness, static and dynamic mechanical properties of the composites were investigated. The increasing amount of the SiC filler increased the curing efficiency of the biphenyl curing system, which was evident from the rheometric properties of the resulting composites. The tensile properties of composite increased with the increasing of micro- and nano-sized SiC content. When the micro- and nano-sized SiC content was higher than 20 phr, the composites showed almost unchanged tensile properties. The increasing of the tensile property was mainly attributed to the well dispersed micro- and nano-sized SiC particles characterized by SEM images. Compared to pure FKM, the composites exhibited a higher glass transition temperature and lower tan peak value.展开更多
基金The study was supported by State Key Lab. of New Ceramics and Fine Processing of Tsinghua University Grant No. X.GZ9913.
文摘Properties of Al2O3-coated nano-SiC have been compared with those of as-received SiC. The isoelectric point (IEP) of SiC changed from pH3.4 to pH7.3 after coating with the alumina precursor, which is close to that of alumina. Because both surfaces of coated SiC and AI2O3 possess higher positive charge at pH=4.5-5.0, they are uniformly dispersed in the two-phase aqueous suspensions, Then a mixed powder containing nano-SiC dispersed homogeneously into the Al2O3 matrix was achieved from flocculating the two-phase suspension. Finally, Al2O3/SiC nanocomposites were obtained by coating nano-SiC with Al2O3, in which the majority of SiC particles were located within the AI2O3 grains. The observation by transmission electron microscopy (TEM) and the analysis by the X-ray photoelectron spectroscopy (XPS) showed that cracks propagated towards the intragranular SiC rather than along grain boundaries.
文摘The dielectric properties of nano Si/C/N composite powder and nano SiC powder at high frequencies have been studied. The nano Si/C/N composite powder and nano SiC powder were synthesized from hexamethyldisilazane ((Me 3Si) 2NH) (Me:CH 3) and SiH 4 C 2H 2 respectively by a laser induced gas phase reaction. The complex permittivities of the nano Si/C/N composite powder and nano SiC powder were measured between 8 2GHz and 12 4GHz. The real and imaginary parts of the complex permittivities of nano Si/C/N composite powder are much higher than those of nano SiC powder. The SiC microcrystalline in the nano Si/C/N composite powder dissolved a great deal of nitrogen. The local structure around Si atoms changed by introducing N into SiC. Carbon atoms around Si were substituted by N atoms. So charged defects and quasi free electrons moved in response to the electric field, diffusion or polarization current resulted from the field propagation. The high ε″and loss factor tgδ(ε″/ε′) of Si/C/N composite powder were due to the dielectric relaxation.
基金Project(2006CB600904)supported by the National Basic Research Program of China
文摘Composite felts reinforced by both SiC nano-fibers(SiC-NFs)and carbon fibers were prepared at 1 273 K using Ni granules as catalyzers with different deposition time.SiC-NFs were deposited on the surface of the carbon fibers in situ by catalytic chemical vapor deposition(CCVD).The phase,microstructure and morphology of the fibers after electroplating and deposition were characterized by XRD,SEM and TEM.The results show that the SiC-NFs produced by CCVD are composed of single crystal of β-SiC.It is found that smaller nano-granules are more active as catalyzers.The resulting SiC-NFs appear more spindle-like and have a more homogeneous dispersion.The mass change of the samples before and after deposition shows that using more Ni granules results in a faster growth velocity of SiC-NFs.With the same electroplating time,the growth velocity of the SiC-NFs first increases and then decreases.At around 4 h,it reaches the maximum growth velocity,and it becomes nearly constant at around 8 h.After 8 h, the stable growth velocity of the electroplated Ni samples is faster than that of the conventional sample produced without catalyzers, because the SiC-NFs can improve the specific surface area and the activity of the surface.
文摘为满足雷达阵面高功率密度的需求,SiC宽禁带半导体器件在电源模块应用中逐步取代传统硅功率器件。传统焊接及导电胶粘工艺存在导电性能差、热阻大、高温蠕变等缺点,无法发挥SiC功率器件高结温和高功率的优势。纳米银烧结是大功率器件最合适的界面互连技术之一,具有低温烧结高温使用的优点和良好的高温工作特性。文中针对高功率电源模块大电流传输对低压降及高效散热的需求,基于高功率半桥电源模块开展了SiC芯片的纳米银双面烧结工艺技术研究,突破了成型银焊片制备、纳米银焊膏高平整度点涂、无压烧结等关键技术,并通过烧结界面微观分析以及芯片剪切强度和焊片剥离强度测试对烧结工艺参数进行了优化。最后对半桥模块进行了静态测试和双脉冲测试。该模块的栅极泄漏电流<1.5 n A,开关切换时间<125 ns,漏极电压过冲<12.5%,满足产品应用需求。
基金Funded by the National Natural Science Foundation of China(No.50979016)
文摘Microand nano-sized SiC/fluoroelastomer （FKM） composites were prepared by a mechanical mixing method. These composites were first characterized by a rotorless rheometer. Then the effects of micro- and nano-sized SiC on hardness, static and dynamic mechanical properties of the composites were investigated. The increasing amount of the SiC filler increased the curing efficiency of the biphenyl curing system, which was evident from the rheometric properties of the resulting composites. The tensile properties of composite increased with the increasing of micro- and nano-sized SiC content. When the micro- and nano-sized SiC content was higher than 20 phr, the composites showed almost unchanged tensile properties. The increasing of the tensile property was mainly attributed to the well dispersed micro- and nano-sized SiC particles characterized by SEM images. Compared to pure FKM, the composites exhibited a higher glass transition temperature and lower tan peak value.
