In this paper, we make use of the functional spectral analysis to infer the periodicity of paleoclimate in the Hongzuisi section since about 15 ka. Through combined analysis of organic carbon isotope and CaCO\-3 conte...In this paper, we make use of the functional spectral analysis to infer the periodicity of paleoclimate in the Hongzuisi section since about 15 ka. Through combined analysis of organic carbon isotope and CaCO\-3 content, the law of paleoclimatic evolution of the Hongzuisi section is obtained. There were climatic changes from 10 ka to about 0.1 ka over the last 15 ka. Among these cycles, the cycle of several ka is most remarkable. The result indicates that functional spectral analysis is helpful for paleoclimatic study, which can provide useful information about paleoclimatic reconstruction and future forecast.展开更多
Spinel LiMn204 was synthesized by glycine-nitrate method and coated with CaCO3 in order to enhance the electrochemical performance at room temperature （25℃） and 55℃. The uncoated and CaCO3-coated LiMn204 materials...Spinel LiMn204 was synthesized by glycine-nitrate method and coated with CaCO3 in order to enhance the electrochemical performance at room temperature （25℃） and 55℃. The uncoated and CaCO3-coated LiMn204 materials were characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical tests. XRD and SEM results indicated that CaCO3 particles encapsulated the surface of the LiMn204 without causing any structural change. The charge-discharge tests showed that the specific discharge capacity fade of pristine electrode at 25 and 55℃ were 25.5% and 52%, respectively. However, surface modified cathode shows 7.4% and 29.5% loss compared to initial specific discharge capacity at 70th cycle for 25 and 55~C, respectively. The improvement of electrochemical performance is attributed to suppression of Mn2＋ dissolution into electrolyte via CaCO3 layer.展开更多
In this paper, silk sericin was employed to regulate the mineralization of calcium carbonate （CaC03）. CaCO3 composite particles were prepared by the precipita- tion reaction of sodium carbonate with calcium chloride...In this paper, silk sericin was employed to regulate the mineralization of calcium carbonate （CaC03）. CaCO3 composite particles were prepared by the precipita- tion reaction of sodium carbonate with calcium chloride solution in the presence of silk sericin. The as-prepared samples were collected at different reaction time to study the crystallization process of CaCO3 by scanning electron microscopy （SEM）, Fourier transform infrared spectroscopy （FTIR）, thermogravimetric analysis （TGA） and X-ray diffraction （XRD）. The results showed that silk sericin significantly affected the morphology and crystallographic polymorph of CaCO3. With increasing the reaction time, the crystal phase of CaCO3 transferred from calcite dominated to vaterite dominated mixtures, while the morphology of CaCO3 changed from disk-like calcite crystal to spherical vaterite crystal. These studies showed the potential of silk sericin used as a template molecule to control the growth of inorganic crystal.展开更多
基金GrantedbytheNationalNaturalScienceFoundationofChina (No .4 9972 0 5 7)
文摘In this paper, we make use of the functional spectral analysis to infer the periodicity of paleoclimate in the Hongzuisi section since about 15 ka. Through combined analysis of organic carbon isotope and CaCO\-3 content, the law of paleoclimatic evolution of the Hongzuisi section is obtained. There were climatic changes from 10 ka to about 0.1 ka over the last 15 ka. Among these cycles, the cycle of several ka is most remarkable. The result indicates that functional spectral analysis is helpful for paleoclimatic study, which can provide useful information about paleoclimatic reconstruction and future forecast.
基金supported by the Erciyes University Research Found under the code of FBA-08-439
文摘Spinel LiMn204 was synthesized by glycine-nitrate method and coated with CaCO3 in order to enhance the electrochemical performance at room temperature （25℃） and 55℃. The uncoated and CaCO3-coated LiMn204 materials were characterized by X-ray diffraction （XRD）, scanning electron microscopy （SEM） and electrochemical tests. XRD and SEM results indicated that CaCO3 particles encapsulated the surface of the LiMn204 without causing any structural change. The charge-discharge tests showed that the specific discharge capacity fade of pristine electrode at 25 and 55℃ were 25.5% and 52%, respectively. However, surface modified cathode shows 7.4% and 29.5% loss compared to initial specific discharge capacity at 70th cycle for 25 and 55~C, respectively. The improvement of electrochemical performance is attributed to suppression of Mn2＋ dissolution into electrolyte via CaCO3 layer.
文摘In this paper, silk sericin was employed to regulate the mineralization of calcium carbonate （CaC03）. CaCO3 composite particles were prepared by the precipita- tion reaction of sodium carbonate with calcium chloride solution in the presence of silk sericin. The as-prepared samples were collected at different reaction time to study the crystallization process of CaCO3 by scanning electron microscopy （SEM）, Fourier transform infrared spectroscopy （FTIR）, thermogravimetric analysis （TGA） and X-ray diffraction （XRD）. The results showed that silk sericin significantly affected the morphology and crystallographic polymorph of CaCO3. With increasing the reaction time, the crystal phase of CaCO3 transferred from calcite dominated to vaterite dominated mixtures, while the morphology of CaCO3 changed from disk-like calcite crystal to spherical vaterite crystal. These studies showed the potential of silk sericin used as a template molecule to control the growth of inorganic crystal.
