The electromagnetic wave absorption(EMWA)performance of materials is affected by their dielectric and magnetic properties.Here,ferroferric oxide@N-doped residual carbon(Fe_(3)O_(4)@NRC)composites were successfully fab...The electromagnetic wave absorption(EMWA)performance of materials is affected by their dielectric and magnetic properties.Here,ferroferric oxide@N-doped residual carbon(Fe_(3)O_(4)@NRC)composites were successfully fabricated by decorating NRC with Fe_(3)O_(4)nanoparticles via a facile chemical co-precipitation method.The RC was obtained through acid treatment to remove the inorganic minerals in coal gasification fine slag.The structure,composition,thermal stability,morphology,and related EM parameters of the as-fabricated Fe_(3)O_(4)@NRC composites were thoroughly tested via analytical techniques.Notably,both the Fe_(3)O_(4)@NRC-2 and Fe_(3)O_(4)@NRC-3 composites exhibited superior EMWA capacity.When 40%mass was added,the value of minimal reflection loss(RL_(min))for Fe_(3)O_(4)@NRC-2 was-37.4 dB,and the effective absorption bandwidth(EAB,RL≤-10 dB)reached 4.16 GHz(13.84-18.00 GHz)at a thickness of 1.5 mm.Besides,the value of impedance matching was 1.00 as the RL_(min)was achieved.The results demonstrated that the EMWA performance of the composites could be adjusted by controlling the content of Fe_(3)O_(4)nanoparticles.The magnetic/carbon composites exhibited superior EMWA performance,thus promoting the resource utilization of residual carbon in coal gasification fine slag from coal gasification.展开更多
基金financially supported by the National Key Research and Development Plan of China(No.2019YFC1904304)the Anhui Provincial Natural Science Foundation(No.2008085J27)the Institute of Energy,Hefei Comprehensive National Science Center(No.19KZS203)。
文摘The electromagnetic wave absorption(EMWA)performance of materials is affected by their dielectric and magnetic properties.Here,ferroferric oxide@N-doped residual carbon(Fe_(3)O_(4)@NRC)composites were successfully fabricated by decorating NRC with Fe_(3)O_(4)nanoparticles via a facile chemical co-precipitation method.The RC was obtained through acid treatment to remove the inorganic minerals in coal gasification fine slag.The structure,composition,thermal stability,morphology,and related EM parameters of the as-fabricated Fe_(3)O_(4)@NRC composites were thoroughly tested via analytical techniques.Notably,both the Fe_(3)O_(4)@NRC-2 and Fe_(3)O_(4)@NRC-3 composites exhibited superior EMWA capacity.When 40%mass was added,the value of minimal reflection loss(RL_(min))for Fe_(3)O_(4)@NRC-2 was-37.4 dB,and the effective absorption bandwidth(EAB,RL≤-10 dB)reached 4.16 GHz(13.84-18.00 GHz)at a thickness of 1.5 mm.Besides,the value of impedance matching was 1.00 as the RL_(min)was achieved.The results demonstrated that the EMWA performance of the composites could be adjusted by controlling the content of Fe_(3)O_(4)nanoparticles.The magnetic/carbon composites exhibited superior EMWA performance,thus promoting the resource utilization of residual carbon in coal gasification fine slag from coal gasification.
