A highly efficient and selective bimetallic Pd0.88Co0.12 nanoparticle catalyst was developed for the direct N-formylation of amines by carbon monoxide. This catalyst is compatible with a wide range of substrates, affo...A highly efficient and selective bimetallic Pd0.88Co0.12 nanoparticle catalyst was developed for the direct N-formylation of amines by carbon monoxide. This catalyst is compatible with a wide range of substrates, affording various synthetically useful formamides under practical and mild reaction conditions.展开更多
基金We acknowledge financial support from the China Ministry of Science and Technology （No. 2016YFA0202801）, National Natural Science Foundation of China （No. 21371107）, Tsinghua-Peking Joint Centers for Life Sciences and CAMS Initiative for Innovative Medicine （No. 2016-I2M-3-014）.
文摘A highly efficient and selective bimetallic Pd0.88Co0.12 nanoparticle catalyst was developed for the direct N-formylation of amines by carbon monoxide. This catalyst is compatible with a wide range of substrates, affording various synthetically useful formamides under practical and mild reaction conditions.
