Natural gas is widely used because it is environmentally friendly,particularly in reducing carbon emission and improving the Air Quality Index(AQI)around densely populated cities.China has initiated a coal-to-gas proj...Natural gas is widely used because it is environmentally friendly,particularly in reducing carbon emission and improving the Air Quality Index(AQI)around densely populated cities.China has initiated a coal-to-gas project(CGP)to improve the air quality in northern China.As a subcompany of China National Petroleum Corporation,PetroChina Natural Gas Marketing North Company has been focusing on natural gas resource allocation while considering numerous issues such as ensuring the bottom line of livelihood requirements in winter and the performance of economic indicators for an entire calendar year in the northern part of China.Therefore,the accurate prediction of natural gas consumption is important to PetroChina Natural Gas Marketing North Company.It has become a challenge to forecast natural gas consumption because the natural gas market has changed considerably because of the CGP.Natural gas consumption cannot be forecasted using conventional models.This study analyzes the characteristics of the CGP based on the data obtained from rural individual users and company users.Based on the analysis,the gas consumption in winter is predicted using two different forecasting approaches.The methods presented in this paper provide a basis for formulating effective measures for natural gas scheduling in the northern part of China.展开更多
A full two-fluid model of reacting gas-particle flows and coal combustion is used to simulate coal combustion with and without inlet natural gas added in the inlet. The simulation results for the case without natural ...A full two-fluid model of reacting gas-particle flows and coal combustion is used to simulate coal combustion with and without inlet natural gas added in the inlet. The simulation results for the case without natural gas burning is in fair agreement with the experimental results reported in references. The simulation results of different natural gas adding positions indicate that the natural gas burning can form lean oxygen combustion enviroment at the combustor inlet region and the NOx concentration is reduced. The same result can be obtained from chemical equilibrium analysis.展开更多
The target of the text is to scientifically appraise dynamic development of surface deformation in subsidence area and its influence on groundwork stability of natural pipe and then adopt some technological measures t...The target of the text is to scientifically appraise dynamic development of surface deformation in subsidence area and its influence on groundwork stability of natural pipe and then adopt some technological measures to ensure safe circulation of natural pipeline. Analysed the influence on natural pipeline from coal mining subsidence in the way of pipeline grade variation, vertical curve variation, transverse deformation, horizontal pull and compression deformation and pipe stress variation etc., and described detailed surface subsidence product and its used time among initial phase, active phase and decline phase in the course of surface movement deformation time. In the context of considering surface subsidence that doesn't reach basic latter end and residual subsidence quantity, the text confirmed the calculation method of residual deformation in surface subsidence area, and gave the technological measures about building natural gas pipeline in subsidence area finally.展开更多
Based on the present situation and trend of underground coal gasification in China and overseas, this article puts forward the basic concept, mechanism and mode of underground coal gasification, and presents the chall...Based on the present situation and trend of underground coal gasification in China and overseas, this article puts forward the basic concept, mechanism and mode of underground coal gasification, and presents the challenges, development potential and development path now faced. In China, underground coal gasification which is in accord with the clean utilization of coal can produce "artificial gas", which provides a new strategic approach to supply methane and hydrogen with Chinese characteristics before new energy sources offer large-scale supply. Coal measure strata in oil-bearing basins are developed in China, with 3.77 trillion tons coal reserves for the buried depth of 1000-3 000 m. It is initially expected that the amount of natural gas resources from underground coal gasification to be 272-332 trillion cubic meters, which are about triple the sum of conventional natural gas, or equivalent to the total unconventional natural gas resources. According to the differences of coal reaction mechanism and product composition of underground coal gasification, the underground coal gasification can be divided into three development modes, hydrogen-rich in shallow, methane-rich in medium and deep,supercritical hydrogen-rich in deep. Beyond the scope of underground mining of coal enterprises, petroleum and petrochemical enterprises can take their own integration advantages of technologies, pipeline, market and so on, to develop underground coal gasification business based on their different needs and technical maturity, to effectively exploit a large amount of coal resources cleanly and to alleviate the tight supply of natural gas. It can also be combined with using the produced hydrogen in nearby area and the CO_2 flooding and storage in adjacent oil areas to create a demonstration zone for net zero emissions of petroleum and petrochemical recycling economy. It is significant for reserving resources and technologies for the coming "hydrogen economy" era, and opening up a new path for China's "clean, low carbon, safe and efficient" modern energy system construction.展开更多
Sichuan Province boasts rich clean energy such as natural gas and hydroelectricity. In order to realize the blueprint of a beautiful China, it is both necessary and feasible for Sichuan Province to "replace coal and ...Sichuan Province boasts rich clean energy such as natural gas and hydroelectricity. In order to realize the blueprint of a beautiful China, it is both necessary and feasible for Sichuan Province to "replace coal and oil" with natural gas. Based on the actual situation of Sichuan Province, through research and investigation, rational thinking and summarization, this paper analyzes the current demand for energy supply in Sichuan, defines the development goals and ideas concerning Sichuan's 'replacement of coal and oil" with natural gas, examines the action plan related to such replacement and puts forward relevant policies and suggestions.展开更多
Natural gas and coal are the main primary energy resources used in the Romanian energy sector, 73.7% in 2011, taking into account the fuel imports. The objective of the article consists in analyzing all the processes ...Natural gas and coal are the main primary energy resources used in the Romanian energy sector, 73.7% in 2011, taking into account the fuel imports. The objective of the article consists in analyzing all the processes along the coal and the natural gas life cycle in order to assess their overall environmental impact. Two energy technologies were analyzed, for each resource: the pulverized coal combustion with supra-critical parameters and CO2 capture unit and the natural gas combined cycle. Considering the functional unit of electricity production for 1 year, it was found that the natural gas combined cycle remains the more interesting energy technology from an environmental point of view. However, the pulverized coal with supra-critical parameters equipped with a CO2 capture unit has the lowest environmental impact on the climate change. The weakest point of the coal technology is its low efficiency.展开更多
Natural gas has been discovered in many anticlines in the southern margin of the Junggar Basin. However, the geochemical characteristics of natural gas in different anticlines haven’t been compared systematically, pa...Natural gas has been discovered in many anticlines in the southern margin of the Junggar Basin. However, the geochemical characteristics of natural gas in different anticlines haven’t been compared systematically, particularly, the type and source of natural gas discovered recently in Well Gaotan-1 at the Gaoquan anticline remain unclear. The gas composition characteristics and carbon and hydrogen isotope compositions in different anticlines were compared and sorted systematically to identify genetic types and source of the natural gas. The results show that most of the gas samples are wet gas, and a few are dry gas;the gas samples from the western and middle parts have relatively heavier carbon isotope composition and lighter hydrogen isotope composition, while the gas samples from the eastern part of southern basin have lighter carbon and hydrogen isotope compositions. The natural gas in the southern margin is thermogenic gas generated by freshwater-brackish water sedimentary organic matter, which can be divided into three types, coal-derived gas, mixed gas and oil-associated gas, in which coal-derived gas and mixed gas take dominance. The Jurassic coal measures is the main natural gas source rock in the southern margin, and the Permian lacustrine and the Upper Triassic lacustrine-limnetic facies source rocks are also important natural gas source rocks. The natural gas in the western part of the southern margin is derived from the Jurassic coal measures and the Permian lacustrine source rock, while the natural gas in the middle part of the southern margin is mainly derived from the Jurassic coal measures, partly from the Permian and/or the Upper Triassic source rocks, and the natural gas in the eastern part of the southern margin is originated from the Permian lacustrine source rock. The natural gas in the Qingshuihe oil and gas reservoir of Well Gaotan-1 is a mixture of coal-derived gas and oil-associated gas, of which the Jurassic and Permian source rocks contribute about half each.展开更多
The year 2017 saw explosive growth in China's natural gas market, and the apparent consumption was 235.7 billion cubic meters, up 18.2% over the same period of 2016. In 2017, China's domestic production growth...The year 2017 saw explosive growth in China's natural gas market, and the apparent consumption was 235.7 billion cubic meters, up 18.2% over the same period of 2016. In 2017, China's domestic production growth picked up significantly, reaching 145.3 billion cubic meters, an increase of 9%.Natural gas imports grew rapidly, and imported pipeline gas and imported LNG totaled 91.6 billion cubic meters. The trade volume of LNG surpassed that of pipeline gas for the first time since 2012. In 2018, the macro-economy is expected to maintain growth at a moderate-to-high rate. However, driven by favorable factors such as environmental policies, China's demand for natural gas is expected to continue to grow rapidly, and natural gas consumption will maintain double-digit growth, roughly at 12%. Nevertheless, the seasonable imbalance between natural gas supply and demand will remain conspicuous.展开更多
Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mecha...Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mechanism of carbon isotopes and the causes of abnormal carbon isotopic compositions of natural gas.At the heating rates of 2℃/h(slow)and 20℃/h(rapid),the low maturity coal samples of the Ordos Basin had the maximum yields of alkane gas of 302.74 mL/g and 230.16 mL/g,theδ13C1 ranges of-34.8‰to-23.6‰and-35.5‰to-24.0‰;δ13C2 ranges of-28.0‰to-9.0‰and-28.9‰to-8.3‰;andδ13C3 ranges of-25.8‰to-14.7‰and-26.4‰to-13.2‰,respectively.Alkane gas in the thermal simulation products of rapid temperature rise process showed obvious partial reversal of carbon isotope series at 550℃,and at other temperatures showed positive carbon isotope series.In the two heating processes,theδ13C1 turned lighter first and then heavier,and the non-monotonic variation of theδ13C1 values is because the early CH4 is from different parent materials resulted from heterogeneity of organic matter or the carbon isotope fractionation formed by activation energy difference of early enriched 12CH4 and late enriched 13CH4.The reversal of carbon isotope values of heavy hydrocarbon gas can occur not only in high to over mature shale gas(oil-type gas),but also in coal-derived gas.Through thermal simulation experiment of toluene,it is confirmed that the carbon isotope value of heavy hydrocarbon gas can be reversed and inversed at high to over mature stage.The isotope fractionation effect caused by demethylation and methyl linkage of aromatic hydrocarbons may be an important reason for carbon isotope inversion and reversal of alkane gas at the high to over mature stage.展开更多
Some of the most promising potential applications of nanotechnology to hydraulic fracturing of coal seam gas(CSG)are reviewed with a focus on Australian CSG wells.Three propitious applications were identifed:(1)Nanopa...Some of the most promising potential applications of nanotechnology to hydraulic fracturing of coal seam gas(CSG)are reviewed with a focus on Australian CSG wells.Three propitious applications were identifed:(1)Nanoparticle enhanced viscoelastic surfactants(VES)fracturing fuids to prevent fuid loss by up to 30%,made possible by the formation of pseudo-flter cakes and reducing the viscosity of the VES fuids.Besides,there is no requirement of clay control additives or biocides.(2)Nano-proppants to extend fracture networks and reduce proppant embedment by introducing them prior to the emplacement of larger proppants.Fly Ash nanoparticles can be particularly efective because of their high sphericity and mechanical strength.(3)Nanoparticle-coated proppants,to mitigate the migration of particle fnes by restricting them close to their source by adsorption,with MgO being the most efective.The use of nanotechnology in hydraulic fracturing applications is currently hindered due to a discordant regulatory environment compounded by the cost of the nanoparticles themselves,as well as,a lack of feld data to validate the technology under real downhole conditions.Although the necessary feld tests are unlikely to be conducted for as long as abundant natural gas is available,exploratory studies could pave the way for future applications.展开更多
Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas r...Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas reserves from this source rock remain low to date,and the distribution characteristics and accumulation model for the coal-formed gas are not clear.Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin.The accumulations are scattered,and dominated by middle-small sized gas fields,of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3.The commercially valuable gas fields are mainly found in the central and southern parts of the basin.Vertically,the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic,among which the Paleogene and PermoCarboniferous are the main reservoir strata.According to the transporting pathway,filling mechanism and the relationship between source rocks and reservoir,the coal-formed gas accumulation model can be defined into three types:"Upward migrated,fault transported gas"accumulation model,"Laterally migrated,sandbody transported gas"accumulation model,and"Downward migrated,sub-source,fracture transported gas"accumulation model.Source rock distribution,thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas.The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.展开更多
The paper introduces gas to liquids (GTL) as a monetising option from a technology, marketing and project perspective. GTL is complementary to LNG and pipelines. At the same time, using natural gas as a source for fue...The paper introduces gas to liquids (GTL) as a monetising option from a technology, marketing and project perspective. GTL is complementary to LNG and pipelines. At the same time, using natural gas as a source for fuels in the form of GTL helps countries around the world to diversify their energy supplies. Furthermore, gas-based products are inherently cleaner than oil products. Shell's proprietary GTL technology or SMDS (Shell Middle Distillates Synthesis), is discussed in some detail. The paper also covers the challenges for successful implementation of GTL projects and why Shell is well positioned to take a lead in the industry on the basis of its long standing and broad experience in GTL research, plant operations, marketing and excellent track record in mega projects in the last thirty years. Shell's commitment to GTL is best demonstrated by the recent signing of a Heads of Agreement with Qatar Petroleum for the construction of the world's largest GTL plant. A key success factor is Shell's experience with marketing quantities of high quality GTL products from its 12,500 barrels per day plant at Bintulu, Malaysia since 1993. Further marketing opportunities will arise when new GTL capacity comes on-stream in the middle east when more quantities will become available to bulk users. Amongst the most interesting market will be automotive transportation, where clean GTL fuels can be positioned as an 'alternative fuel beyond oil' providing energy security to host countries. Shell is actively engaging with a number of regulators, automotive companies and governments worldwide including China, to demonstrate the performance of GTL and its cost effectiveness in reducing local emissions. An added benefit is that GTL can use existing infrastructure and requires no investment. Finally, the paper briefly discusses the coal to liquids (CTL) process as an alternative route to produce high quality GTL products and the key issues relating to the process.展开更多
China’s fossil energy is characterized by an abundance of coal and a relative lack of oil and natural gas.Developing a strategy in which coal can replace oil and natural gas is,therefore,a necessary and practical app...China’s fossil energy is characterized by an abundance of coal and a relative lack of oil and natural gas.Developing a strategy in which coal can replace oil and natural gas is,therefore,a necessary and practical approach to easing the excessive external dependence on oil and natural gas.Based on the perspective of energy security,this paper proposes a technical framework for defining the substitution of oil and natural gas with coal in China.In this framework,three substitution classifications and 11 industrialized technical routes are reviewed.Then,three scenarios(namely,the cautious scenario,baseline scenario,and positive scenario)are developed to estimate the potential of this strategy for 2020 and 2030.The results indicate that oil and natural gas replaced by coal will reach 67 to 81 Mt and 8.7 to 14.3 Gm^3 in 2020 and reach 93 to 138 Mt and 32.3 to 47.3 Gm^3 in 2030,respectively.By implementing this strategy,China’s external dependence on oil,natural gas,and primary energy is expected to be curbed at approximately 70%,40%,and 20%by 2030,respectively.This paper also demonstrates how coal,as a substitute for oil and natural gas,can contribute to carbon and pollution reduction and economic cost savings.It suggests a new direction for the development of the global coal industry and provides a crucial reference for energy transformation in China and other countries with similar energy situations.展开更多
Natural gas releasing simulation experiments were carried out in laboratory for researching the gas storage capacity in state of high temperature and high pressure and its gas releasing potential in process of tempera...Natural gas releasing simulation experiments were carried out in laboratory for researching the gas storage capacity in state of high temperature and high pressure and its gas releasing potential in process of temperature decreasing and decompression. The exiting phase state was studied through measuring gas adsorption of coal and PVT phase calculating of natural gas. Gas volume, gas molecular and isotope compositions in process of temperature decreasing and decompression were measured, natural-gas yields released from the Upper Paleozoic coal strata after later Cretaceous (K3) were calculated and the formation of the reservoir was studied combining with the geological background. The results indicate that natural gas stored in coal has still bigger releasing potential after the uplift of Upper Paleozoic strata. There exists a weak gas supply-effluent equilibrium in the reservoir of Ordos Basin, which is another possible evidence that the Upper Paleozoic gas reservoir may be a deep basin gas reservoir.展开更多
China is the largest producer and consumer of HFC-134a(1,1,1,2-tetrafluoroethane)in the world.Coal-based route is mainly adopted to produce HFC-134a,which suffers from large waste and CO_(2) emissions.Natural gas is a...China is the largest producer and consumer of HFC-134a(1,1,1,2-tetrafluoroethane)in the world.Coal-based route is mainly adopted to produce HFC-134a,which suffers from large waste and CO_(2) emissions.Natural gas is a low-carbon and clean energy resource,and no research has been found on the environment and economy of producing HFC-134a from natural gas.In this study,CML 2001 method was used to carry out the life cycle assessment of natural gas(partial oxidation)-based and natural gas(plasma cracking)-based routes(abbreviated as gas(O)-based and gas(P)-based routes,respectively),and their environmental performances were compared with coal-based and oil-based routes.Meanwhile,considering that China is vigorously promoting the transformation of energy structure,and the application of electric heating equipment to replace fossil-based heating equipment in industrial field,which has a great impact on the environmental performance of the production processes,the authors conducted a scenario analysis.The results showed that the gas(O)-based route had the most favourable environmental benefits.However,the gas(P)-based route had the highest potential for reducing environmental burdens,and its environmental benefit was the most favourable in scenario 2050.Additionally,the economic performance of the gas(P)-based route was significantly better than that of gas(O)-based and coal-based routes.展开更多
The Xihu Depression in the East China Sea Shelf Basin is a large petroliferous sedimentary depression,in which oil and gas reservoirs were mainly discovered in the Pinghu Slope and the central inversion zone.The oil-g...The Xihu Depression in the East China Sea Shelf Basin is a large petroliferous sedimentary depression,in which oil and gas reservoirs were mainly discovered in the Pinghu Slope and the central inversion zone.The oil-gas source correlation in the Xihu Depression was analyzed by hydrocarbon generating thermal simulation data via gold-tube pyrolysis experiments.The results indicated that the oil and gas in the Xihu Depression were mainly derived from coal measure source rocks of the Eocene Pinghu Formation.Therefore,the identification of coal seams is extremely crucial for evaluating coal measure source rocks in the Pinghu Formation in the Xihu Depression.Geochemical and petrological characterization pointed to input of terrigenous organic matter and redox conditions of the depositional environment as factors that govern the ability of the coal measure source rocks in hydrocarbon generation in the Xihu Depression.In this regard,the sedimentary organic facies in the Pinghu Formation were classified into four predominantly terrigenous and one mixed-source subfacies,which all varied in carbon and hydrogen content.The coal measure source rocks in the carbon-and hydrogen-rich tidal flat-lagoon exhibited the highest hydrocarbon generation potential,whereas the mudstone in the neritic facies was the poorest in its hydrocarbon yield.These results suggested that the coal measure source rocks in the Pinghu Formation likely developed in the Hangzhou Slope and the Tiantai Slope,both representing promising sources for oil and gas exploration.展开更多
Since the beginning of this century, revolutionary progress has been made in the understanding of resources and in the mining technologies of the oil and gas industry. Advances in petroleum engineering technology repr...Since the beginning of this century, revolutionary progress has been made in the understanding of resources and in the mining technologies of the oil and gas industry. Advances in petroleum engineering technology represented by horizontal wells and large-scale fracturing have promoted the scale development of low-grade and unconventional oil and gas resources. After the rapid growth of natural gas production in China for more than 10 consecutive years, the replacement of conventional natural gas resources has been weak and unconventional natural gas has become the major force for increasing production. Coal based SNG(synthetic natural gas) has also become a major competitor in the domestic market. The development of CTL(coal-toliquids) and SNG industries has brought coal resources into the oil and gas product market, expanding the concept of traditional oil and gas resources. The continuous improvement of petroleum engineering technology has promoted the development of deep underground coal gasification technology, which has given economic value to the huge amount of deep coal resources that are unable to be exploited by underground mining, and provides a tremendous resource guarantee for the sustainable development of the traditional oil and gas industry. A preliminary calculation shows that deep underground coal gasification has a competitive advantage in cost compared with high-cost, low-grade, unconventional gas and coal-based natural gas. Deep underground coal gasification is a typical cross-disciplinary and cross-sectoral sophisticated technology. Domestic oil and gas enterprises have dominant advantages in the engineering technology of this field. Further technical integration innovation and multi-industry joint research are needed to eventually realize the commercial application of this deep underground coal gasification technology.展开更多
Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. The use of CBM (Coal bed methane) as an energetic resource is not much known in Spain. This work is the first step...Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. The use of CBM (Coal bed methane) as an energetic resource is not much known in Spain. This work is the first step to enhance the development of this resource in Castilla y León. A theoretical review and a state of the art description have been carried out, taking into account all the factors that can influence in the development of a CBM project. Then CBM resources have been quantified by Castilla y León accurately for every coal bed. After that, technical feasibility has been used to evaluate total amount of gas that can be recovered. The last step was to evaluate economic feasibility to know how much gas could be economically profitable. This paper covers the economic factor and exploitation options of CBM in Castilla y León, considering technical parameters together with costs and economic requirements for the tow most promising areas in north-west Spain. The main findings include that a CBM system would be feasible in Guardo-Barruelo, however, the economic feasibility will be limited to long operation time of the wells and an increase of the prices of natural gas. In North Leon, the results show a high profitability even under low natural gas prices.展开更多
Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. This gas, coalbed methane (CBM), is usually mainly formed by methane and can be considered similar to natural gas ...Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. This gas, coalbed methane (CBM), is usually mainly formed by methane and can be considered similar to natural gas as energy source. The evaluation of the techno-economic feasibility of the extraction of this gas depends on a large number of complex different factors. The work carried out covers the different aspects to simplify the first approach for CBM feasibility quantification considering a short number of indicators. A theoretical review and a state of the art description have been carried out, taking into account all the factors that can influence in the development of a CBM project. After that, technical feasibility has been used to evaluate total amount of gas that can be recovered. The last step was to evaluate economic feasibility to know how much gas could be economically profitable. Conclusions got have been used to develop a simple method for evaluating CBM economic feasibility considering just four easy known parameters of coal beds. These are: the rank, the thickness, the gas concentration, and the permeability.展开更多
基金supported by the National Natural Science Foundation of China (No. 51504271)
文摘Natural gas is widely used because it is environmentally friendly,particularly in reducing carbon emission and improving the Air Quality Index(AQI)around densely populated cities.China has initiated a coal-to-gas project(CGP)to improve the air quality in northern China.As a subcompany of China National Petroleum Corporation,PetroChina Natural Gas Marketing North Company has been focusing on natural gas resource allocation while considering numerous issues such as ensuring the bottom line of livelihood requirements in winter and the performance of economic indicators for an entire calendar year in the northern part of China.Therefore,the accurate prediction of natural gas consumption is important to PetroChina Natural Gas Marketing North Company.It has become a challenge to forecast natural gas consumption because the natural gas market has changed considerably because of the CGP.Natural gas consumption cannot be forecasted using conventional models.This study analyzes the characteristics of the CGP based on the data obtained from rural individual users and company users.Based on the analysis,the gas consumption in winter is predicted using two different forecasting approaches.The methods presented in this paper provide a basis for formulating effective measures for natural gas scheduling in the northern part of China.
基金Supported by the National Natural Science Foundation of China (No. 50376068).
文摘A full two-fluid model of reacting gas-particle flows and coal combustion is used to simulate coal combustion with and without inlet natural gas added in the inlet. The simulation results for the case without natural gas burning is in fair agreement with the experimental results reported in references. The simulation results of different natural gas adding positions indicate that the natural gas burning can form lean oxygen combustion enviroment at the combustor inlet region and the NOx concentration is reduced. The same result can be obtained from chemical equilibrium analysis.
文摘The target of the text is to scientifically appraise dynamic development of surface deformation in subsidence area and its influence on groundwork stability of natural pipe and then adopt some technological measures to ensure safe circulation of natural pipeline. Analysed the influence on natural pipeline from coal mining subsidence in the way of pipeline grade variation, vertical curve variation, transverse deformation, horizontal pull and compression deformation and pipe stress variation etc., and described detailed surface subsidence product and its used time among initial phase, active phase and decline phase in the course of surface movement deformation time. In the context of considering surface subsidence that doesn't reach basic latter end and residual subsidence quantity, the text confirmed the calculation method of residual deformation in surface subsidence area, and gave the technological measures about building natural gas pipeline in subsidence area finally.
基金Supported by the PetroChina Science and Technology Major Project(2019E-25)
文摘Based on the present situation and trend of underground coal gasification in China and overseas, this article puts forward the basic concept, mechanism and mode of underground coal gasification, and presents the challenges, development potential and development path now faced. In China, underground coal gasification which is in accord with the clean utilization of coal can produce "artificial gas", which provides a new strategic approach to supply methane and hydrogen with Chinese characteristics before new energy sources offer large-scale supply. Coal measure strata in oil-bearing basins are developed in China, with 3.77 trillion tons coal reserves for the buried depth of 1000-3 000 m. It is initially expected that the amount of natural gas resources from underground coal gasification to be 272-332 trillion cubic meters, which are about triple the sum of conventional natural gas, or equivalent to the total unconventional natural gas resources. According to the differences of coal reaction mechanism and product composition of underground coal gasification, the underground coal gasification can be divided into three development modes, hydrogen-rich in shallow, methane-rich in medium and deep,supercritical hydrogen-rich in deep. Beyond the scope of underground mining of coal enterprises, petroleum and petrochemical enterprises can take their own integration advantages of technologies, pipeline, market and so on, to develop underground coal gasification business based on their different needs and technical maturity, to effectively exploit a large amount of coal resources cleanly and to alleviate the tight supply of natural gas. It can also be combined with using the produced hydrogen in nearby area and the CO_2 flooding and storage in adjacent oil areas to create a demonstration zone for net zero emissions of petroleum and petrochemical recycling economy. It is significant for reserving resources and technologies for the coming "hydrogen economy" era, and opening up a new path for China's "clean, low carbon, safe and efficient" modern energy system construction.
文摘Sichuan Province boasts rich clean energy such as natural gas and hydroelectricity. In order to realize the blueprint of a beautiful China, it is both necessary and feasible for Sichuan Province to "replace coal and oil" with natural gas. Based on the actual situation of Sichuan Province, through research and investigation, rational thinking and summarization, this paper analyzes the current demand for energy supply in Sichuan, defines the development goals and ideas concerning Sichuan's 'replacement of coal and oil" with natural gas, examines the action plan related to such replacement and puts forward relevant policies and suggestions.
基金funded by the UEFISCDI within the National Project number 38/2012 with the title:“Technical-economic and environmental optimization of CCS technologies integration in power plants based on solid fossil fuel and renewable energy sources(biomass)”-CARBOTECH.
文摘Natural gas and coal are the main primary energy resources used in the Romanian energy sector, 73.7% in 2011, taking into account the fuel imports. The objective of the article consists in analyzing all the processes along the coal and the natural gas life cycle in order to assess their overall environmental impact. Two energy technologies were analyzed, for each resource: the pulverized coal combustion with supra-critical parameters and CO2 capture unit and the natural gas combined cycle. Considering the functional unit of electricity production for 1 year, it was found that the natural gas combined cycle remains the more interesting energy technology from an environmental point of view. However, the pulverized coal with supra-critical parameters equipped with a CO2 capture unit has the lowest environmental impact on the climate change. The weakest point of the coal technology is its low efficiency.
基金Supported by the PetroChina Science and Technology Project(06-01A-01-02,2016A-0202)
文摘Natural gas has been discovered in many anticlines in the southern margin of the Junggar Basin. However, the geochemical characteristics of natural gas in different anticlines haven’t been compared systematically, particularly, the type and source of natural gas discovered recently in Well Gaotan-1 at the Gaoquan anticline remain unclear. The gas composition characteristics and carbon and hydrogen isotope compositions in different anticlines were compared and sorted systematically to identify genetic types and source of the natural gas. The results show that most of the gas samples are wet gas, and a few are dry gas;the gas samples from the western and middle parts have relatively heavier carbon isotope composition and lighter hydrogen isotope composition, while the gas samples from the eastern part of southern basin have lighter carbon and hydrogen isotope compositions. The natural gas in the southern margin is thermogenic gas generated by freshwater-brackish water sedimentary organic matter, which can be divided into three types, coal-derived gas, mixed gas and oil-associated gas, in which coal-derived gas and mixed gas take dominance. The Jurassic coal measures is the main natural gas source rock in the southern margin, and the Permian lacustrine and the Upper Triassic lacustrine-limnetic facies source rocks are also important natural gas source rocks. The natural gas in the western part of the southern margin is derived from the Jurassic coal measures and the Permian lacustrine source rock, while the natural gas in the middle part of the southern margin is mainly derived from the Jurassic coal measures, partly from the Permian and/or the Upper Triassic source rocks, and the natural gas in the eastern part of the southern margin is originated from the Permian lacustrine source rock. The natural gas in the Qingshuihe oil and gas reservoir of Well Gaotan-1 is a mixture of coal-derived gas and oil-associated gas, of which the Jurassic and Permian source rocks contribute about half each.
文摘The year 2017 saw explosive growth in China's natural gas market, and the apparent consumption was 235.7 billion cubic meters, up 18.2% over the same period of 2016. In 2017, China's domestic production growth picked up significantly, reaching 145.3 billion cubic meters, an increase of 9%.Natural gas imports grew rapidly, and imported pipeline gas and imported LNG totaled 91.6 billion cubic meters. The trade volume of LNG surpassed that of pipeline gas for the first time since 2012. In 2018, the macro-economy is expected to maintain growth at a moderate-to-high rate. However, driven by favorable factors such as environmental policies, China's demand for natural gas is expected to continue to grow rapidly, and natural gas consumption will maintain double-digit growth, roughly at 12%. Nevertheless, the seasonable imbalance between natural gas supply and demand will remain conspicuous.
基金Supported by the National Natural Science Foundation of China(41902160,41625009)the China Postdoctoral Science Foundation(2019M650967,2020T130721)the China National Science and Technology Major Project(2016ZX05007-001)
文摘Low maturity coal samples were taken from the Ordos Basin to conduct gold tube thermal simulation experiment in a closed system,and the characteristics of the products were analyzed to find out the fractionation mechanism of carbon isotopes and the causes of abnormal carbon isotopic compositions of natural gas.At the heating rates of 2℃/h(slow)and 20℃/h(rapid),the low maturity coal samples of the Ordos Basin had the maximum yields of alkane gas of 302.74 mL/g and 230.16 mL/g,theδ13C1 ranges of-34.8‰to-23.6‰and-35.5‰to-24.0‰;δ13C2 ranges of-28.0‰to-9.0‰and-28.9‰to-8.3‰;andδ13C3 ranges of-25.8‰to-14.7‰and-26.4‰to-13.2‰,respectively.Alkane gas in the thermal simulation products of rapid temperature rise process showed obvious partial reversal of carbon isotope series at 550℃,and at other temperatures showed positive carbon isotope series.In the two heating processes,theδ13C1 turned lighter first and then heavier,and the non-monotonic variation of theδ13C1 values is because the early CH4 is from different parent materials resulted from heterogeneity of organic matter or the carbon isotope fractionation formed by activation energy difference of early enriched 12CH4 and late enriched 13CH4.The reversal of carbon isotope values of heavy hydrocarbon gas can occur not only in high to over mature shale gas(oil-type gas),but also in coal-derived gas.Through thermal simulation experiment of toluene,it is confirmed that the carbon isotope value of heavy hydrocarbon gas can be reversed and inversed at high to over mature stage.The isotope fractionation effect caused by demethylation and methyl linkage of aromatic hydrocarbons may be an important reason for carbon isotope inversion and reversal of alkane gas at the high to over mature stage.
基金supported,in part,by the Department of Chemical Engineering,University College Londonby the Futures Industries Institute of the University of South Australia.AS gratefully acknowledges fnancial support from the Horizon 2020 project‘Science 4 Clean Energy’+2 种基金supported by grant number 764810 from the European Commissionfrom the US Department of Energy,Ofce of Basic Energy Sciences,Division of Chemical Sciences,GeosciencesBiosciences,under grant number DE-SC0006878.MM gratefully acknowledges fnancial support from the Australian research council,FT200100301.
文摘Some of the most promising potential applications of nanotechnology to hydraulic fracturing of coal seam gas(CSG)are reviewed with a focus on Australian CSG wells.Three propitious applications were identifed:(1)Nanoparticle enhanced viscoelastic surfactants(VES)fracturing fuids to prevent fuid loss by up to 30%,made possible by the formation of pseudo-flter cakes and reducing the viscosity of the VES fuids.Besides,there is no requirement of clay control additives or biocides.(2)Nano-proppants to extend fracture networks and reduce proppant embedment by introducing them prior to the emplacement of larger proppants.Fly Ash nanoparticles can be particularly efective because of their high sphericity and mechanical strength.(3)Nanoparticle-coated proppants,to mitigate the migration of particle fnes by restricting them close to their source by adsorption,with MgO being the most efective.The use of nanotechnology in hydraulic fracturing applications is currently hindered due to a discordant regulatory environment compounded by the cost of the nanoparticles themselves,as well as,a lack of feld data to validate the technology under real downhole conditions.Although the necessary feld tests are unlikely to be conducted for as long as abundant natural gas is available,exploratory studies could pave the way for future applications.
基金financial support from the National major projects (Item No.2016ZX05006-003)
文摘Coal-formed gas generated from the Permo-Carboniferous coal measures has become one of the most important targets for deep hydrocarbon exploration in the Bohai Bay Basin,offshore eastern China.However,the proven gas reserves from this source rock remain low to date,and the distribution characteristics and accumulation model for the coal-formed gas are not clear.Here we review the coal-formed gas deposits formed from the Permo-Carboniferous coal measures in the Bohai Bay Basin.The accumulations are scattered,and dominated by middle-small sized gas fields,of which the proven reserves ranging from 0.002 to 149.4×108 m3 with an average of 44.30×108 m3 and a mid-point of 8.16×108 m3.The commercially valuable gas fields are mainly found in the central and southern parts of the basin.Vertically,the coal-formed gas is accumulated at multiple stratigraphic levels from Paleogene to Archaeozoic,among which the Paleogene and PermoCarboniferous are the main reservoir strata.According to the transporting pathway,filling mechanism and the relationship between source rocks and reservoir,the coal-formed gas accumulation model can be defined into three types:"Upward migrated,fault transported gas"accumulation model,"Laterally migrated,sandbody transported gas"accumulation model,and"Downward migrated,sub-source,fracture transported gas"accumulation model.Source rock distribution,thermal evolution and hydrocarbon generation capacity are the fundamental controlling factors for the macro distribution and enrichment of the coal-formed gas.The fault activity and the configuration of fault and caprock control the vertical enrichment pattern.
文摘The paper introduces gas to liquids (GTL) as a monetising option from a technology, marketing and project perspective. GTL is complementary to LNG and pipelines. At the same time, using natural gas as a source for fuels in the form of GTL helps countries around the world to diversify their energy supplies. Furthermore, gas-based products are inherently cleaner than oil products. Shell's proprietary GTL technology or SMDS (Shell Middle Distillates Synthesis), is discussed in some detail. The paper also covers the challenges for successful implementation of GTL projects and why Shell is well positioned to take a lead in the industry on the basis of its long standing and broad experience in GTL research, plant operations, marketing and excellent track record in mega projects in the last thirty years. Shell's commitment to GTL is best demonstrated by the recent signing of a Heads of Agreement with Qatar Petroleum for the construction of the world's largest GTL plant. A key success factor is Shell's experience with marketing quantities of high quality GTL products from its 12,500 barrels per day plant at Bintulu, Malaysia since 1993. Further marketing opportunities will arise when new GTL capacity comes on-stream in the middle east when more quantities will become available to bulk users. Amongst the most interesting market will be automotive transportation, where clean GTL fuels can be positioned as an 'alternative fuel beyond oil' providing energy security to host countries. Shell is actively engaging with a number of regulators, automotive companies and governments worldwide including China, to demonstrate the performance of GTL and its cost effectiveness in reducing local emissions. An added benefit is that GTL can use existing infrastructure and requires no investment. Finally, the paper briefly discusses the coal to liquids (CTL) process as an alternative route to produce high quality GTL products and the key issues relating to the process.
基金supported by the Major Project of the Chinese Academy of Engineering,Optimization Study on China’s Energy Structure with Carbon Constraint(Grant No:2016-ZD-07)the Project of the China Knowledge Centre for Engineering Sciences and Technology in Chinese Academy of Engineering,Professional Knowledge Service System for Energy(Grant No.CKCEST-2019-2-6).
文摘China’s fossil energy is characterized by an abundance of coal and a relative lack of oil and natural gas.Developing a strategy in which coal can replace oil and natural gas is,therefore,a necessary and practical approach to easing the excessive external dependence on oil and natural gas.Based on the perspective of energy security,this paper proposes a technical framework for defining the substitution of oil and natural gas with coal in China.In this framework,three substitution classifications and 11 industrialized technical routes are reviewed.Then,three scenarios(namely,the cautious scenario,baseline scenario,and positive scenario)are developed to estimate the potential of this strategy for 2020 and 2030.The results indicate that oil and natural gas replaced by coal will reach 67 to 81 Mt and 8.7 to 14.3 Gm^3 in 2020 and reach 93 to 138 Mt and 32.3 to 47.3 Gm^3 in 2030,respectively.By implementing this strategy,China’s external dependence on oil,natural gas,and primary energy is expected to be curbed at approximately 70%,40%,and 20%by 2030,respectively.This paper also demonstrates how coal,as a substitute for oil and natural gas,can contribute to carbon and pollution reduction and economic cost savings.It suggests a new direction for the development of the global coal industry and provides a crucial reference for energy transformation in China and other countries with similar energy situations.
文摘Natural gas releasing simulation experiments were carried out in laboratory for researching the gas storage capacity in state of high temperature and high pressure and its gas releasing potential in process of temperature decreasing and decompression. The exiting phase state was studied through measuring gas adsorption of coal and PVT phase calculating of natural gas. Gas volume, gas molecular and isotope compositions in process of temperature decreasing and decompression were measured, natural-gas yields released from the Upper Paleozoic coal strata after later Cretaceous (K3) were calculated and the formation of the reservoir was studied combining with the geological background. The results indicate that natural gas stored in coal has still bigger releasing potential after the uplift of Upper Paleozoic strata. There exists a weak gas supply-effluent equilibrium in the reservoir of Ordos Basin, which is another possible evidence that the Upper Paleozoic gas reservoir may be a deep basin gas reservoir.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.22078266 and 22008198)the Youth Innovation Team construction scientific research Project of Education Ministry of Shaanxi province,China(Grant No.22JP090)+1 种基金the Youth Talent Promotion Program of Shaanxi Association for Science and Technology(Grant No.20220602)Natural Science Basic Research Plan in Shaanxi Province of China(Grant No.2021JQ-555).
文摘China is the largest producer and consumer of HFC-134a(1,1,1,2-tetrafluoroethane)in the world.Coal-based route is mainly adopted to produce HFC-134a,which suffers from large waste and CO_(2) emissions.Natural gas is a low-carbon and clean energy resource,and no research has been found on the environment and economy of producing HFC-134a from natural gas.In this study,CML 2001 method was used to carry out the life cycle assessment of natural gas(partial oxidation)-based and natural gas(plasma cracking)-based routes(abbreviated as gas(O)-based and gas(P)-based routes,respectively),and their environmental performances were compared with coal-based and oil-based routes.Meanwhile,considering that China is vigorously promoting the transformation of energy structure,and the application of electric heating equipment to replace fossil-based heating equipment in industrial field,which has a great impact on the environmental performance of the production processes,the authors conducted a scenario analysis.The results showed that the gas(O)-based route had the most favourable environmental benefits.However,the gas(P)-based route had the highest potential for reducing environmental burdens,and its environmental benefit was the most favourable in scenario 2050.Additionally,the economic performance of the gas(P)-based route was significantly better than that of gas(O)-based and coal-based routes.
基金The National Science and Technology Major Project under contract No.2016ZX05024-002the Exploration Project of China National Offshore Oil Corporation under contract Nos 2018OT-KT-SC-9 and 2019KT-SC-10。
文摘The Xihu Depression in the East China Sea Shelf Basin is a large petroliferous sedimentary depression,in which oil and gas reservoirs were mainly discovered in the Pinghu Slope and the central inversion zone.The oil-gas source correlation in the Xihu Depression was analyzed by hydrocarbon generating thermal simulation data via gold-tube pyrolysis experiments.The results indicated that the oil and gas in the Xihu Depression were mainly derived from coal measure source rocks of the Eocene Pinghu Formation.Therefore,the identification of coal seams is extremely crucial for evaluating coal measure source rocks in the Pinghu Formation in the Xihu Depression.Geochemical and petrological characterization pointed to input of terrigenous organic matter and redox conditions of the depositional environment as factors that govern the ability of the coal measure source rocks in hydrocarbon generation in the Xihu Depression.In this regard,the sedimentary organic facies in the Pinghu Formation were classified into four predominantly terrigenous and one mixed-source subfacies,which all varied in carbon and hydrogen content.The coal measure source rocks in the carbon-and hydrogen-rich tidal flat-lagoon exhibited the highest hydrocarbon generation potential,whereas the mudstone in the neritic facies was the poorest in its hydrocarbon yield.These results suggested that the coal measure source rocks in the Pinghu Formation likely developed in the Hangzhou Slope and the Tiantai Slope,both representing promising sources for oil and gas exploration.
文摘Since the beginning of this century, revolutionary progress has been made in the understanding of resources and in the mining technologies of the oil and gas industry. Advances in petroleum engineering technology represented by horizontal wells and large-scale fracturing have promoted the scale development of low-grade and unconventional oil and gas resources. After the rapid growth of natural gas production in China for more than 10 consecutive years, the replacement of conventional natural gas resources has been weak and unconventional natural gas has become the major force for increasing production. Coal based SNG(synthetic natural gas) has also become a major competitor in the domestic market. The development of CTL(coal-toliquids) and SNG industries has brought coal resources into the oil and gas product market, expanding the concept of traditional oil and gas resources. The continuous improvement of petroleum engineering technology has promoted the development of deep underground coal gasification technology, which has given economic value to the huge amount of deep coal resources that are unable to be exploited by underground mining, and provides a tremendous resource guarantee for the sustainable development of the traditional oil and gas industry. A preliminary calculation shows that deep underground coal gasification has a competitive advantage in cost compared with high-cost, low-grade, unconventional gas and coal-based natural gas. Deep underground coal gasification is a typical cross-disciplinary and cross-sectoral sophisticated technology. Domestic oil and gas enterprises have dominant advantages in the engineering technology of this field. Further technical integration innovation and multi-industry joint research are needed to eventually realize the commercial application of this deep underground coal gasification technology.
文摘Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. The use of CBM (Coal bed methane) as an energetic resource is not much known in Spain. This work is the first step to enhance the development of this resource in Castilla y León. A theoretical review and a state of the art description have been carried out, taking into account all the factors that can influence in the development of a CBM project. Then CBM resources have been quantified by Castilla y León accurately for every coal bed. After that, technical feasibility has been used to evaluate total amount of gas that can be recovered. The last step was to evaluate economic feasibility to know how much gas could be economically profitable. This paper covers the economic factor and exploitation options of CBM in Castilla y León, considering technical parameters together with costs and economic requirements for the tow most promising areas in north-west Spain. The main findings include that a CBM system would be feasible in Guardo-Barruelo, however, the economic feasibility will be limited to long operation time of the wells and an increase of the prices of natural gas. In North Leon, the results show a high profitability even under low natural gas prices.
文摘Coal during its carbonization process produces a gas. This gas, mainly formed by methane, can be used. This gas, coalbed methane (CBM), is usually mainly formed by methane and can be considered similar to natural gas as energy source. The evaluation of the techno-economic feasibility of the extraction of this gas depends on a large number of complex different factors. The work carried out covers the different aspects to simplify the first approach for CBM feasibility quantification considering a short number of indicators. A theoretical review and a state of the art description have been carried out, taking into account all the factors that can influence in the development of a CBM project. After that, technical feasibility has been used to evaluate total amount of gas that can be recovered. The last step was to evaluate economic feasibility to know how much gas could be economically profitable. Conclusions got have been used to develop a simple method for evaluating CBM economic feasibility considering just four easy known parameters of coal beds. These are: the rank, the thickness, the gas concentration, and the permeability.