Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of gra...Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of grains can effectively inhibit the aggregation of active materials,improving lithium storage performance.In this work,natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion.Natural pyrite composite polyvinylpyrrolidone-modified graphite(pyrite/PG)material with uniform particle distribution is obtained by the ball milling process.The subsequent calcination process converts pyrite/PG into Fe_(1-x)Scompounded with polyvinylpyrrolidone-modified graphite(Fe_(1-x)S/PG).The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials.The as-prepared Fe_(1-x)S/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g^(-1)at 0.2 A·g^(-1)after 80 cycles and an excellent rate capability of 523.0 mAh·g^(-1)at 5 A·g^(-1).Even at a higher current density of 10 A·g^(-1),it can deliver a specific capacity of 348.0 mAh·g^(-1).Moreover,the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability.This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.展开更多
Objective Material exchange between magma and coal has recently received much attention, with published studies dedicated mainly to intrusion-related geochemical anomalies(An et al., 2017). It is found that magmatism ...Objective Material exchange between magma and coal has recently received much attention, with published studies dedicated mainly to intrusion-related geochemical anomalies(An et al., 2017). It is found that magmatism not only alters the chemical compositions of coal seams, but also brings new minerals to natural coke. Although some studies have related magmatic water to secondary minerals in the natural coke, the mineral formation展开更多
The research aimed to analyze the linkage between natural vegetation, water dynamics and pyrite （FeS2） oxidation in tidal lowlands. The research was carried out in tidal lowland Pulau Rimau, South Sumatra from Febru...The research aimed to analyze the linkage between natural vegetation, water dynamics and pyrite （FeS2） oxidation in tidal lowlands. The research was carried out in tidal lowland Pulau Rimau, South Sumatra from February to December 2010. The field observations are done by exploring several transect on land units. The field description refers to Soil Survey Staff. Water and soil samples were taken from selected key areas for laboratory analyses. The vegetation data were collected by making sample plots placed on each vegetation type with plot sizes 10 m × 10 m for secondary forests and 5 m × 5 m for shrubs and grass. The observations of surface water level were done during the river receding with units of meter above sea level （m.asl）. The results shows that pyrite formation is largely determined by the availability of natural vegetation as S （sulfur） donors, climate and uncontrolled water balance and supporting faunas such as crabs and mud shrimp. Climate and water balance as well as supporting faunas is the main supporting factors to accelerate the process of formation pyrite. Oxidized pyrite increases soil pH thus toxic to fish, arable soils, plant growth, disturbing the water quality and soil nutrient availability. Oxidized pyrite is predominantly accelerated by the dynamics of river water and disturbed natural vegetation by human activities, and the pyrite oxidation management approach is divided into three main components of technologies, namely water management, land management and commodity management.展开更多
基金financially supported by the National Natural Science Foundation of China (Nos.51974222 and 52034011)。
文摘Natural minerals-based energy materials have attracted enormous attention because of the advantages of good materials consistency,high production,environmental friendliness,and low cost.The uniform distribution of grains can effectively inhibit the aggregation of active materials,improving lithium storage performance.In this work,natural graphite is modified by polyvinylpyrrolidone to obtain modified graphite with reduced size and better dispersion.Natural pyrite composite polyvinylpyrrolidone-modified graphite(pyrite/PG)material with uniform particle distribution is obtained by the ball milling process.The subsequent calcination process converts pyrite/PG into Fe_(1-x)Scompounded with polyvinylpyrrolidone-modified graphite(Fe_(1-x)S/PG).The homogeneous grain distributions of active material can facilitate the faster transfer of electrons and promote the efficient utilization of active materials.The as-prepared Fe_(1-x)S/PG electrode exhibits a remarkably reversible specific capacity of 613.0 mAh·g^(-1)at 0.2 A·g^(-1)after 80 cycles and an excellent rate capability of 523.0 mAh·g^(-1)at 5 A·g^(-1).Even at a higher current density of 10 A·g^(-1),it can deliver a specific capacity of 348.0 mAh·g^(-1).Moreover,the dominant pseudocapacitance in redox reactions accounts for the impressive rate and cycling stability.This work provides a low-cost and facile method to fabricate natural mineral-based anode materials and apprise readers about the impact of uniform particle distribution on lithium storage performance.
基金financially supported by the National Natural Science Foundation of China (grant No. 41602173)the Anhui University Ph. D Start-up Foundation (grant No. J10113190091)
文摘Objective Material exchange between magma and coal has recently received much attention, with published studies dedicated mainly to intrusion-related geochemical anomalies(An et al., 2017). It is found that magmatism not only alters the chemical compositions of coal seams, but also brings new minerals to natural coke. Although some studies have related magmatic water to secondary minerals in the natural coke, the mineral formation
文摘The research aimed to analyze the linkage between natural vegetation, water dynamics and pyrite （FeS2） oxidation in tidal lowlands. The research was carried out in tidal lowland Pulau Rimau, South Sumatra from February to December 2010. The field observations are done by exploring several transect on land units. The field description refers to Soil Survey Staff. Water and soil samples were taken from selected key areas for laboratory analyses. The vegetation data were collected by making sample plots placed on each vegetation type with plot sizes 10 m × 10 m for secondary forests and 5 m × 5 m for shrubs and grass. The observations of surface water level were done during the river receding with units of meter above sea level （m.asl）. The results shows that pyrite formation is largely determined by the availability of natural vegetation as S （sulfur） donors, climate and uncontrolled water balance and supporting faunas such as crabs and mud shrimp. Climate and water balance as well as supporting faunas is the main supporting factors to accelerate the process of formation pyrite. Oxidized pyrite increases soil pH thus toxic to fish, arable soils, plant growth, disturbing the water quality and soil nutrient availability. Oxidized pyrite is predominantly accelerated by the dynamics of river water and disturbed natural vegetation by human activities, and the pyrite oxidation management approach is divided into three main components of technologies, namely water management, land management and commodity management.
