在对我国南方3种典型的水稻土有机碳团聚体分布研究的基础上,对用低能量超声波分散法分离得到的团聚体颗粒组进一步进行有机碳键合形态分析,考察不同键合态有机碳在不同粒径团聚体的分布,由此探讨这些水稻土中有机碳积累中物理作用基础...在对我国南方3种典型的水稻土有机碳团聚体分布研究的基础上,对用低能量超声波分散法分离得到的团聚体颗粒组进一步进行有机碳键合形态分析,考察不同键合态有机碳在不同粒径团聚体的分布,由此探讨这些水稻土中有机碳积累中物理作用基础上的化学机制。结果表明:钙键合态有机碳(Ca-SOC)多分布于2 000~200μm的粗团聚体颗粒组中,且在紫色水稻土中含量最高(达到9 g kg-1左右),而红壤性水稻土中最低(不到3 g kg-1);相反,铁铝键合态有机碳(Fe(Al)-SOC)趋向于在细团聚体颗粒组集中,是<2μm颗粒组中有机碳的优势组分,且以红壤性水稻土中最高(介于20~30 g kg-1之间),紫色水稻土中最低(仅为10 g kg-1左右),这与该团聚体颗粒组中铁铝氧化物的含量分布相吻合。统计分析表明,易氧化态碳(LOC)占有机碳(SOC)的比值与Ca-SOC占SOC的比值表现为正相关关系,而与Fe(Al)-SOC占SOC的比值表现为反相关关系。直径为2 000~200μm的粗团聚体中的Ca-SOC和Fe(Al)-SOC对长期不同耕作和施肥的响应最为敏感,良好的耕作施肥下水稻土有机碳的积累主要表现为Fe(Al)-SOC的增加。氧化铁铝的含量与SOC和LOC的含量之间存在一定的依变关系,说明这些土壤发生的无机组成分在有机碳的保护与稳定中发挥着重要作用,并且以红壤性水稻土粗团聚体中的氧化铁铝对有机碳的保护作用最强。由此看来,团聚体更新中物理保护的有机碳在细团聚体形成中进一步与氧化铁铝的键合可能是这些水稻土中有机碳稳定的重要机制。展开更多
Biochar is normally produced as a by-product of bioenergy. However, if biochar is produced as a co-product with bioenergy from sustainably managed forests and used for soil amendment, it could pro- vide a carbon neutr...Biochar is normally produced as a by-product of bioenergy. However, if biochar is produced as a co-product with bioenergy from sustainably managed forests and used for soil amendment, it could pro- vide a carbon neutral or even carbon negative solution for current envi- ronmental degradation problems. In this paper, we present a comprehen- sive review of biochar production as a co-product of bioenergy and its implications. We focus on biochar production with reference to biomass availability and sustainability and on bioehar utilization for its soil amendment and greenhouse gas emissions reduction properties. Past studies confirm that northwestern Ontario has a sustainable and sufficient supply of biomass feedstock that can be used to produce bioenergy, with biochar as a co-product that can replace fossil fuel consumption, increase soil productivity and sequester carbon in the long run. For the next step, we recommend that comprehensive life cycle assessment of bio- char-based bioenergy production, from raw material collection to bioehar application, with an extensive economic assessment is necessary for making this technology commercially viable in northwestern Ontario.展开更多
文摘在对我国南方3种典型的水稻土有机碳团聚体分布研究的基础上,对用低能量超声波分散法分离得到的团聚体颗粒组进一步进行有机碳键合形态分析,考察不同键合态有机碳在不同粒径团聚体的分布,由此探讨这些水稻土中有机碳积累中物理作用基础上的化学机制。结果表明:钙键合态有机碳(Ca-SOC)多分布于2 000~200μm的粗团聚体颗粒组中,且在紫色水稻土中含量最高(达到9 g kg-1左右),而红壤性水稻土中最低(不到3 g kg-1);相反,铁铝键合态有机碳(Fe(Al)-SOC)趋向于在细团聚体颗粒组集中,是<2μm颗粒组中有机碳的优势组分,且以红壤性水稻土中最高(介于20~30 g kg-1之间),紫色水稻土中最低(仅为10 g kg-1左右),这与该团聚体颗粒组中铁铝氧化物的含量分布相吻合。统计分析表明,易氧化态碳(LOC)占有机碳(SOC)的比值与Ca-SOC占SOC的比值表现为正相关关系,而与Fe(Al)-SOC占SOC的比值表现为反相关关系。直径为2 000~200μm的粗团聚体中的Ca-SOC和Fe(Al)-SOC对长期不同耕作和施肥的响应最为敏感,良好的耕作施肥下水稻土有机碳的积累主要表现为Fe(Al)-SOC的增加。氧化铁铝的含量与SOC和LOC的含量之间存在一定的依变关系,说明这些土壤发生的无机组成分在有机碳的保护与稳定中发挥着重要作用,并且以红壤性水稻土粗团聚体中的氧化铁铝对有机碳的保护作用最强。由此看来,团聚体更新中物理保护的有机碳在细团聚体形成中进一步与氧化铁铝的键合可能是这些水稻土中有机碳稳定的重要机制。
文摘Biochar is normally produced as a by-product of bioenergy. However, if biochar is produced as a co-product with bioenergy from sustainably managed forests and used for soil amendment, it could pro- vide a carbon neutral or even carbon negative solution for current envi- ronmental degradation problems. In this paper, we present a comprehen- sive review of biochar production as a co-product of bioenergy and its implications. We focus on biochar production with reference to biomass availability and sustainability and on bioehar utilization for its soil amendment and greenhouse gas emissions reduction properties. Past studies confirm that northwestern Ontario has a sustainable and sufficient supply of biomass feedstock that can be used to produce bioenergy, with biochar as a co-product that can replace fossil fuel consumption, increase soil productivity and sequester carbon in the long run. For the next step, we recommend that comprehensive life cycle assessment of bio- char-based bioenergy production, from raw material collection to bioehar application, with an extensive economic assessment is necessary for making this technology commercially viable in northwestern Ontario.