Study of Sorption Properties of Anion Exchangers with Long-Chained Cross-Linking Agents for Tungsten Hydrometallurgy

The macroporous anion exchangers with long-chained cross-linking agents were investigated for the tungsten recovery from salt solutions.The physical-chemical characteristics of these sorbents were studied by means of sorption-desorption experiment aswell as electron and IR-spectroscopy.The anion exchangers on the basis of macroporous copolymers of methylacrylate and divinyl-ester of diethyleneglycol or tetravinyl-ester of pentaerythritol possess the exchange capacity to tungsten 2--5 times greater than the porous anion exchangers on the basis of styrene and divinylbenzene,therefore they can be used for selective tungsten recovery from comulex salt solutions.

Effect of Cross-linking Agent on Barbituric Acid-initiated Resin

To improve the tensile bond strength of denim bonding agents, the adhesion between denim and MMA resin was investigated by applying initiator systems containing 1-cyclohexyl-5-ethyl barbituric acid (CEB), copper acetyl acetonate (CAA), quaternary ammonium chloride (QAC). cupric ion, with the addition of TEGDMA, an.d pretreatment solution for denim, and an HEMA primer. The effects of a cross-linking agent on barbituric acid-initiated denim bonding resin were examined by measuring degree of conversion, molecular weight, hardness of bonding resin, and tensile bond strengths.

Degradable preformed particle gel as temporary plugging agent for low-temperature unconventional petroleum reservoirs:Effect of molecular weight of the cross-linking agent

The development of unconventional petroleum resources has gradually become an important succession for increasing oil production.However,the related engineers and researchers are paying more and more attention to the application of temporary plugging agents(TPAs)for their efficient development.TPAs can expand the stimulated reservoir volume(SRV)and facilitate the flow of oil and gas to the bottom of the well.Particle-gels used as temporary plugging agents have the characteristics of the simple injection process,good deformation,high plugging strength,and complete self-degradation performance,which have been widely applied in recent years.In this paper,five samples of DPPG polymerized by different molecular weights of cross-linking agents were prepared.In addition,infrared spectroscopy analysis,differential calorimetry scanning(DSC)analysis,static particle gel swelling and degradation performance evaluation experiments,and dynamic temporary plugging performance experiments in cores were conducted at 34°C.Results show that as the molecular weight of the cross-linking agent(at 0.01 g)in the DPPG molecule decreased from 1,000 to 200 Da,the fewer cross-linking sites of DPPG,the looser the microscopic three-dimensional mesh structure formed.The swelling ratio increased from 7 to 33 times.However,the complete degradation time increased from 40 to 210 min.Moreover,the DSC results confirmed that the higher the molecular weight of the cross-linking agent,the worse is chemical stability and the more prone it to self-degradation.DPPG samples had good temporary plugging performance in reservoir cores.DPPGs prepared by the cross-linking agent with smaller molecular weight has a stronger swelling ratio,higher gel strength,and greater plugging strength in the core permeabilities.Moreover,the degraded DPPG is less damaging to the cores.However,their slower degradation rates take a slightly longer times to reach complete degradation.The results of this paper can provide new ideas and a theoretical basis for the development of particle gel-type temporary plugging agents(TPA)with controllable degradation time in low-temperature reservoirs.It can help to expand the application range of existing DPPG reservoir conditions.

Outcomes assessment of hepatitis C virus-positive psoriatic patients treated using pegylated interferon in combination with ribavirin compared to new Direct-Acting Antiviral agents

AIM To evaluate the outcomes in biological treatment and quality of life of psoriatic patients with chronic hepatitis C(CHC) treated with new Direct-Acting Antiviral agents(DAAs) compared to pegylated interferon-2α plus ribavirin(P/R) therapy.METHODS This is a retrospective study involving psoriatic patients in biological therapy who underwent anti-hepatitis C virus(HCV) treatment at the Department of Dermatology Galeazzi Orthopaedic Institute Milan, Italy from January 2010 to November 2017. The patients were divided into two groups: patients that underwent therapy with DAAs and patients that underwent HCV treatment with P/R. Patients were assessed by a dermatologist for psoriasis symptoms, collecting Psoriasis Area Severity Index(PASI) scores and the Dermatology Quality of Life Index(DLQI). PASI and DLQI scores were evaluated 24 wk after the end of HCV treatment and were assumed as an outcome of the progression of psoriasis. Switching to a different b DMARD was considered as an inadequate response to biological therapy. The dropout of HCV therapy and sustained virological response(SVR) were considered as outcomes of HCV therapy.RESULTS Fifty-nine psoriatic patients in biological therapy underwent antiviral therapy for CHC. Of this, 27 patients were treated with DAAs and 32 with P/R. After 24 wk post treatment, the DLQI and the PASI scores were significantly lower(P < 0.001 and P < 0.005, respectively) in the DAAs group compared with P/R group. None of the patients in the DAAs group(0/27) compared to 8 patients of the P/R group(8/32) needed a shift in biological treatment.CONCLUSION DAAs seem to be more effective and safe than P/R in HCV-positive psoriatic patients on biological treatment. Fewer dermatological adverse events may be due to interferon-free therapy.

STUDIES ON TBP-NO_x——A NEW OXIDIZING AGENT PREPARED FROM NITROGEN OXIDES

Nitrogen oxides(NO_2 and NO)are absorbed by tributyl phosphorate(TBP)to fom a new complex mixture of TBP-NO_x. which is used as a selective oddizing agent to oxidize benzylalcohols to corresponding sldehydes or ketones In high yield. In the reaction process, nitrogen oxides are llberated mildly and mainly reduced to nitrogen, while tributyl phosphorate is recovered end recycled.

Building a New Socialist Countryside, Improving Commission and Agent System of “Village-level Accounting”

Rural finance is an issue concerned with rural people, improving rural financial management is important to close the relations of cadres and masses, maintain rural stability, and promote rural economic development. This article explained the main problems of village financial, the needs of introducing commission and agent system of ＂village-level accounting＂ for building a new socialist countryside, and the measures of improving commission and agent system of ＂village-level accounting＂.

Preparation of Controllable Cross-Linking Polyethylene Foaming Materials and Their Properties

In order to prepare the polyethylene materials with controlling properties,we developed two kinds of controllable cross-linking polyethylene foaming system.2,5-dimethyl-2,5-bis (tert-butyl peroxy) hexane was used as cross-linking agent and TEMPO as cross-linking inhibitor,azodicarbonamide (AC) was used as foaming agent and citric acid as foaming promoter.The density,expansion ratio,cellular structure and mechanical property of these two kinds of controllable materials were studied.Experimental results show that,properties of these two kinds of materials appear similar trend:cellular size and expansion ratio are enlarged with the amount of cross-linking inhibitor or foaming promoter increasing,while density and mechanical strength appear decreasing trend.Through comparing those two material systems’ properties,cross-linking polyethelene foaming system with citric acid as foaming promoter has better properties.

Control Effects of a New Sex Pheromone Trap and Biological Agents on Sesamia inferens Walker and Argyroploce schistaceana (Snellen)

This study was conducted to explore and seek high-efficiency and safe green control techniques on sugarcane borers,promote green control of diseases and pests of sugarcane and build a resource-conserving,environmentally friendly and sustainable governance system of diseases and pests of sugarcane.A new sex pheromone trap of sugarcane borers,abamectin· Bacillus thuringiensis (Bt) and tebufenozide were selected and applied in field trials.The use of the new sex pheromone trap of sugarcane borers (6 traps/hm 2) in combination with 0.05% abamectin·10 billion active gemmae/g B.thuringiensis (Bt) WP (1.8 kg/hm 2) or new sex pheromone trap of sugarcane borers (6 traps/hm 2) in combination with 200 g/L tebufenozide SC (1.5 L/hm 2) were the best in the sugarcane production.New sex pheromone trap of sugarcane borers should be installed in early march,and biological agents were mixed with water 900 kg per hectare and sprayed evenly sugarcane plants at the beginning of April.Their control effects of dead heart rate and bored stalk rate could be more than 69.98% and 49.09%,respectively,which were superior to that of the control pesticide 3.6% bisultap GR (90 kg/hm 2).The results showed that new sex pheromone trap of sugarcane borers in combination with abamectin· B.thuringiensis (Bt) or tebufenozide was the optimum mode of green control techniques on sugarcane borers.When it was alternately or coordinately used with other technology,it could delay the emergence and development of drug resistance,and it was worthy of widespread popularization and application in sugarcane area.

Covalent Attachment of DNA to Glass Supports Using A New Silane Coupling Agent and Chemiluminescent Detection

A new kind of silane coupling agent, N- (β-aminoethyl ) - γ-aminopropyl triet hoxysilane, was used for DNA direct attachment on the surfaces of glass supports, then the immobilized DNA was hybridized with horseradish peroxidase (HRP)-labeled probe, and detected by using enhanced chemiluminescent method. In comparison with γ-aminopropyl triethoxysilane, the detection limits (S/N) of DNA were 10 pg and 75 pg respectively. Several experimental conditions of DNA attachING to glass supports were investigated, and the system of hybridization of nucleic acid on the surfaces of glass supports was developed.

THE SYNTHESIS OF ZSM-35 WITH A NEW KIND OF TEMPLATING AGENT

The present paper covers the synthesis of ZSM-35 molecular sieve with 1,6-hexanediamine as templating agent,the influence of the synthesis conditions, and a discussion concerning the crystal structures of the products.

A NEW BIFUNCTIONAL CHELATING AGENT α,ε-N,N'-BIS(L-CYSTEINYL)-L-LYSINE FOR RADIOLABELLING OF MONOCLONAL ANTIBODIES WITH TECHNETIUM-99M

α,ε-N,N'-bis(L-cysteinyl)-L-lysine was synthesized and char- acterized for the first time.It was then employed as a bifunctional chelating agent to chelate technetium-99m and subsequently conjugated to fragment F(ab')_2 of anti-gastric tumor monoclonal antibody 3G9.The radiolabelled antibody was satisfactorily stable and immunoreactive.

Performance Analysis of a Profile Control Agent for Waste Drilling Fluid Treatment

A method for the treatment of hazardous waste drilling fluids,potentially leading to environmental pollution,is considered.The waste drilling fluid is treated with an inorganic flocculant,an organic flocculant,and a pH regulator.The profile control agent consists of partially hydrolyzed polyacrylamide,formaldehyde,hexamethylenetetramine,resorcinol,phenol,and the treated waste drilling fluid itself.For a waste drilling fluid concentration of 2500 mg/L,the gelling time of the profile control agent is 25 h,and the gelling strength is 32,000 mPa.s.Compared with the profile control agent prepared by recirculated water under the same conditions,the present profile control agent displays better stability,salt-resistance,and performance.

新型农业经营主体会计代理采用意愿及其影响因素实证分析

会计代理可以节约用工成本、提高效率和促进经营目标的实现,是当前推动新型农业经营主体财务规范的重要过渡阶段。基于湖北省891份调研数据,采用有序Logistic模型检验新型农业经营主体采用会计代理意愿的影响因素。结果表明:性别、年龄、受教育水平、流动资金投资、经营类型、产业类型、毛收入、示范级别、农业培训等因素显著影响新型农业经营主体采用会计代理意愿。据此提出加强经营主体会计知识培育,强化财务规范意识,夯实会计代理基础;建立资金管理台账,关注资金流向,推动会计代理行业发展;设立专项资金支持,提供会计代理对接服务,扩大会计代理行业覆盖面等建议。

产品差异化和市场开放度对城市群空间结构的影响研究

城市群是提高地区经济增长和深入实施区域协调发展战略过程中的重要载体。本文尝试结合“新”新经济地理学模型和基于agent计算经济学对多重异质性下城市差异化对企业和人口的空间演化影响进行研究,建立了一个企业生产效率与规模、居民工资等多重异质性的两区域空间经济模型对城市间人口和企业迁移进行动态模拟以研究空间经济演化过程。结果表明:(1)无论是否存在市场进入和退出机制,小城市内部工业产品的差异性越大,越有利于企业和人口向小城市迁移,企业和人口倾向于分散。但是存在市场机制能提高城市内产品差异化对人口和企业迁移的吸引力。(2)城市群中小城市要更多的企业和人口,需要继续鼓励创新生产差异化产品,使城市内的产品更加多样化和差异化。(3)为了使城市内产品差异化发挥更大的作用,整个地区需要更加健全企业进入和退出的市场机制,使得有利可图的资本可以进入市场,同时亏损的企业能够退出市场或者转型升级和改制。

智能体:主体与客体相统一的“中介体”——兼论智能体在新闻生产中的地位和作用

认识智能体在新闻生产中的地位和作用,首先需要准确把握智能体的性质。智能体既不是“人主体”,也不是“一般人造客体”,而是人类总体能力对象化的创造物,是主体与客体相统一的“中介体”。在新闻生产实践中,新闻智能体由提供算力的动力机器系统、结成网络的传动机器系统、供给算法的控制机器系统、直接参与新闻生产的工作机器系统共同构成。就目前来看,新闻智能体是创构、保障、调适新闻生产网络体系的基础设施型生产工具,它以新闻生产数据化的方式,催生出新的新闻劳动分工,从而在人与新闻双向运动中发挥中介体作用。

基于大语言模型的新型电力系统用户特性立体应用模式初探

随着新型负荷的广泛接入与虚拟电厂建设的不断推进,新型电力系统中多元的负荷结构与频繁的网荷交互使得用户特性应用在数据融合、特性挖掘和业务赋能面临关键挑战。因此,该文首先深入分析了用户特性的研究现状,以此为基础提出了新型电力系统用户特性立体应用模式,贯通了“多源数据-多维特性-多元模块-多样业务”的应用链路。然后,针对该模式实践中海量多源数据可用性差、特性刻画灵活性低、业务贯通复杂性高的核心技术难题,立足于近期大语言模型备受关注的显著能力与智能体应用范式,分别在自适应数据治理、对话式数据交互、自动数据分析与机器学习、多智能体应用系统架构方面提出了解决方案。进一步,更通过用电数据库交互与业扩报装接入优化的案例表明所提方案能够自动化、智能化、个性化地开展用户特性应用,有望在实际中应对用户侧业务面临的关键挑战。最后,对大语言模型赋能用户侧海量资源管控以及系统智能水平跃升进行了展望。

基于多智能体深度确定策略梯度算法的火力发电商竞价策略

火电是新型电力系统的重要支撑,研究火力发电商的竞价策略以及不同出清机制的影响,对保障其低碳高效运营具有重要意义。构建基于多智能体深度确定策略梯度算法的竞价策略模型,分析不同火力发电商组合的竞价差异化策略,优化多主体报价报量策略,探究边际统一出清、按报价支付出清和随机匹配出清3种典型出清机制的市场影响。结果表明,该策略模型可引导火力发电商采取合理的竞价方式以提高市场效率;在新能源渗透率较低时,不同出清机制对各类型机组的影响有所不同;随着新能源渗透率的提高,采用按报价支付出清机制可以兼顾经济和环境效益;当新能源渗透率达到较高水平时,采用随机匹配出清机制可有效应对市场波动风险。

加氢装置开工预硫化期间加热炉烟气SO_(2)浓度超标原因分析及对策

在加氢装置开工预硫化期间,加热炉烟气SO_(2)浓度多次异常上升甚至超标,企业被迫停止回收火炬气。通过对开工预硫化期间循环氢、低压分离器气和火炬气中硫化物的类型和含量进行分析,推测是因为所使用的硫化剂二甲基二硫醚分步分解产生的甲硫醇和甲硫醚随着火炬气进入燃料气系统,甲硫醇、甲硫醚燃烧生成的SO_(2)导致加热炉烟气中的SO_(2)浓度超标。针对这一问题,可以通过优化火炬气脱硫溶剂、使用器外真硫化催化剂、使用新型硫化剂等方式解决。

陕西省核桃黑斑病新病原的鉴定及室内药剂筛选

分离田间红仁核桃(Juglans regia ‘Robert Livermore’)病叶上的黑斑病病原细菌,通过科赫氏试验明确致病菌,并通过病原菌生化试验以及分子生物学技术明确病原菌的分类学地位。结果表明,从红仁核桃的田间核桃病叶中分离到23株菌落形态一致的细菌菌株,从中随机选取菌株进行科赫氏回接试验能引起红仁核桃叶片发病,通过生理生化表型试验,结合基于16S rDNA、gyrB、rpoD基因序列的多位点序列分析,将该病原鉴定为扁桃假单胞菌(Pseudomonas amygdali)。随后对12种药剂进行室内毒力测定,筛选出的6种药剂对该病原菌具有明显抑制作用。其中,四霉素抑菌效果最好,EC50为50.353 4 μg/mL,其他药剂抑菌效果表现为中生菌素>春雷霉素>噻菌酮>噻唑锌>氢氧化铜。

基于多主体评估的上海市工人新村更新优化策略

文章首先梳理上海市工人新村当前采用的拆除重建、综合改造、维护升级3种更新方式,并通过多主体评估与群决策方法对典型案例进行分析,总结3种更新方式在建筑性能改善、室外环境优化、更新过程与配套服务中存在的问题,进而提出相应的优化提升建议。