Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals i...Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals include moncheite, sperrylite, daomanite, cobalt malanite and cooperite. Yixunite and damiaoite occur as immiscible globules, 1.0 to 2.0 mm in diameter. Yixunite is always in the central part of a globule. It is opaque with metallic lustre, bright white colour and black streak. HM = 5.8; VHN50 = 634 kg/mm2 (573-681 kg/ mm2); insoluble in HCl, HNO3, HF or H3PO4; no cleavage; no magnetism. Density is hard to measure because of small grain size. Calculated density = 18.21 g/cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are: Pt 82.8 (81.8-83.6), In 16.4(15.6-17.1) and total 99.2. The empirical formula (based on 4 atoms) is Pt2.993 In1.007 . The five strongest lines of X-ray diffraction (hkl, d,I) are 111, 2.30 (100); 200, 1.99 (60); 202, 1.411 (40);311, 1.203 (80); 222, 1.151(40). Space group: Pm3m with a =0.3988(3) nm and Z= 1. Damiaoite occurs as single globules or was exsolved from yixunite. Opaque with metallic lustre; bright white colour with black streak; HM = 5.3; VHN50 = 485 kg/mm2 (434-529 kg/mm2); insoluble in HC1, HNO3, HF or H3PO4; cleavage: no; magnetism: no. Density: hard to measure because of small grain size. Calculated density = 10.95 g/ cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are Pt 45.6 (45.4-46.0), In 53.5 (52.4-53.9), total 99.1. The empirical formula (based on 3 atoms) is Pt0.002 In1.998. The six strongest lines of X-ray diffraction (hkl.d,I) are 220,2.25 (100); 311,1.92 (60); 400,1.59 (60); 422,1.299 (80); 440,1.125 (60); 620,1.006 (70). Space group: Fm3m with a = 0.6364 (3) nm and Z = 4.展开更多
New strain induced melt activation(new SIMA) method was employed to prepare high-quality semisolid billet of AZ61 magnesium alloy.Optical microscopy and tensile test were used to study the microstructure and mechani...New strain induced melt activation(new SIMA) method was employed to prepare high-quality semisolid billet of AZ61 magnesium alloy.Optical microscopy and tensile test were used to study the microstructure and mechanical properties of the thixo-extruded component.The results showed that the optimal process parameters for achieving the complete filling status involved the applied pressure of 784 MPa,the pressure holding time of 90 s and the die temperature of 450 ℃.Compared to semisolid isothermal treatment,high mechanical properties such as the tensile strength of 300.5 MPa and elongation of 22% and fine microstructure were obtained in the thixo-extruded parts.With increasing the isothermal temperature and holding time,the tensile strength and elongation were increased firstly and then decreased.When the press pass was increased from 1 to 4,the tensile strength and elongation of the thixo-extruded parts were greatly enhanced and microstructure was refined obviously.展开更多
To obtain the semi-solid slurry with uniform and fine structure morphology that satisfies the requirement of rheocasting process, a new process for preparing semi-solid AI alloy slurry was developed, in which local ch...To obtain the semi-solid slurry with uniform and fine structure morphology that satisfies the requirement of rheocasting process, a new process for preparing semi-solid AI alloy slurry was developed, in which local chilling was combined with low superheat pouring and slight electromagnetic stirring (LSPSEMS). The morphology and the size of primary a-AI in the A356 alloy slurry prepared with the new process, i.e., LSPSEMS with local chilling, were investigated using MIAPS image analyzing software, and the grain refinement mechanism was discussed. The results indicate that the semi-solid primary phase consists of particle-like or globular-like a-AI, and the morphology and grain size of primary a-AI in the slurry can be markedly improved by the new process. The fine primary a-AI distributes uniformly in the slurry, which satisfies the requirement of rheocasting. Compared with the alloy prepared by LSPSEMS, the average equal-area-circle grain diameter of primary a-AI in semi-solid A356 alloy ingot prepared by the new process is decreased from 85.6μm to 68.8 μm at the central area, 112.6 μm to 77.6 μm at the transition area and is 84.7 μm in the edge area, respectively. The corresponding shape factor of primary a-AI is increased from 0.78 to 0.83, 0.54 to 0.77 and 0.28 to 0.59, respectively. In addition, the pouring temperature could be suitably raised from 620-630℃ of the traditional process to 650℃ using this technique, which is convenient for practical operation. The mechanism of grain refinement, in the new process, is that the local chilling quickens up the temperature decrease in the center of the melt. The nuclei could not grow up in a short time so the finer grains are formed in the melt.展开更多
Erratum to:International Journal of Minerals, Metallurgy and Materials Volume 26, Number 9, September 2019, Page 1151https://doi.org/10.1007/s12613-019-1854-1The original version of this article unfortunately containe...Erratum to:International Journal of Minerals, Metallurgy and Materials Volume 26, Number 9, September 2019, Page 1151https://doi.org/10.1007/s12613-019-1854-1The original version of this article unfortunately contained a mistake. The presentation of Fig. 11 was incorrect. The correct version is given below:展开更多
Glass-forming ability(GFA) and mechanical properties of(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(100-x)Lu_x(x= 0-3 at%) alloys have been investigated.The GFA of Zr_(58)Nb_3Cu_(16)Ni_(13)...Glass-forming ability(GFA) and mechanical properties of(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(100-x)Lu_x(x= 0-3 at%) alloys have been investigated.The GFA of Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy is dramatically enhanced by adding Lu.The(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(98)Lu_2 alloy possesses the highest GFA in the studied Zr-Nb-Cu-Ni-Al-Lu alloys,with its critical diameter for glass formation reaching 20 mm by copper-mould casting method,while that of the Lu-free Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy is 7 mm.The critical diameters of(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(100-x)Lu_x(x =1 at%and 3 at%) alloys are 15 mm and 12 mm,respectively.The Lu addition to Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy induces the change of initial crystallization phases from face-centred-cubic Zr_2Ni and tetragonal Zr_2Ni phases for the Lu-free Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy to an icosahedral quasi-crystalline phase for the Lu-doped alloys,which may be the origin for the enhanced GFA of the Lu-doped alloys.The compressive fracture strength and plastic strain of the bulk glassy(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(98)Lu_2 alloy are1 610 MPa and 1.5%,respectively.展开更多
A new sound alloy, abbreviated to S, has been developed by the General Research Institutefor Non-ferrous Metals, Beijing. The alloy is very suitable for making trumpets, trombones, tenorhorns, saxaphones and other kin...A new sound alloy, abbreviated to S, has been developed by the General Research Institutefor Non-ferrous Metals, Beijing. The alloy is very suitable for making trumpets, trombones, tenorhorns, saxaphones and other kinds of wind instruments. Beijing Wind Instrument Factory, which is the largest one in China, has used Salloy formanufacturing 5200 type trompets, the sound performance of which has been examined with fre-quency analysis and experimented by famous musical experts. The results show that the 5200 typetrumpets made of Salloy have excellent quality, accurate intonation and ease of response at展开更多
A new process was used for producing FeAl alloy pow de rs with double consumable rotating electrodes and the powders made in this appar atus were analyzed. In this new technology, tungsten rod serves as a cathode ele ...A new process was used for producing FeAl alloy pow de rs with double consumable rotating electrodes and the powders made in this appar atus were analyzed. In this new technology, tungsten rod serves as a cathode ele ctrode, while the alloy rod as an anode electrode. The conventional rotating ele ctrode process must have an anode with pre-melting alloys; however, in this new process, using pure iron as cathode electrode and pure aluminum as anode electr ode can eliminate the step of pre-melting. The effects of process variables, which include electrode rotational speed, a nd electrode diameter of the mean particle diameter were determined. Results showed that both the rotational speed and diameter of electrodes would a ffect the mean diameter of particles. There are three kinds of powders with diff erent composition produced in this study and the possible mechanisms are discuss ed. The process parameters and volume mean diameter of the powders have been cor related to find an experimental equation. The results show that when the rotational speed and the diameter of the anode el ectrode are increased, the powders size will decrease. However, the powders size will increase with cathode electrode.展开更多
基金This project was supported by the National Nature Sciences Foundation of China Grant No.49172082
文摘Yixunite and damiaoite Were found in a cobalt- and copper-bearing platinum ore vein of a contact metasomatic deposit. The chief ore minerals are bornite, chalcopyrite, magnetite and carrollite. The platinum minerals include moncheite, sperrylite, daomanite, cobalt malanite and cooperite. Yixunite and damiaoite occur as immiscible globules, 1.0 to 2.0 mm in diameter. Yixunite is always in the central part of a globule. It is opaque with metallic lustre, bright white colour and black streak. HM = 5.8; VHN50 = 634 kg/mm2 (573-681 kg/ mm2); insoluble in HCl, HNO3, HF or H3PO4; no cleavage; no magnetism. Density is hard to measure because of small grain size. Calculated density = 18.21 g/cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are: Pt 82.8 (81.8-83.6), In 16.4(15.6-17.1) and total 99.2. The empirical formula (based on 4 atoms) is Pt2.993 In1.007 . The five strongest lines of X-ray diffraction (hkl, d,I) are 111, 2.30 (100); 200, 1.99 (60); 202, 1.411 (40);311, 1.203 (80); 222, 1.151(40). Space group: Pm3m with a =0.3988(3) nm and Z= 1. Damiaoite occurs as single globules or was exsolved from yixunite. Opaque with metallic lustre; bright white colour with black streak; HM = 5.3; VHN50 = 485 kg/mm2 (434-529 kg/mm2); insoluble in HC1, HNO3, HF or H3PO4; cleavage: no; magnetism: no. Density: hard to measure because of small grain size. Calculated density = 10.95 g/ cm3. Reflective colour is bright white with a yellowish tint. Isotropic. The mean analytical results (ranges) (%) are Pt 45.6 (45.4-46.0), In 53.5 (52.4-53.9), total 99.1. The empirical formula (based on 3 atoms) is Pt0.002 In1.998. The six strongest lines of X-ray diffraction (hkl.d,I) are 220,2.25 (100); 311,1.92 (60); 400,1.59 (60); 422,1.299 (80); 440,1.125 (60); 620,1.006 (70). Space group: Fm3m with a = 0.6364 (3) nm and Z = 4.
基金Project(51075099) supported by the National Natural Science Foundation of ChinaProject(E201038) supported by the Natural Science Foundation of Heilongjiang Province,China+3 种基金Project(20090460884) supported by the China Postdoctoral Science FoundationProjects (HIT.NSRIF.2013007 and 2012038) supported by the Fundamental Research Funds for the Central Universities,ChinaProject (2011RFQXG010) supported by the Harbin City Young Scientists Foundation under the GrantProject(LBH-T1102) supported by the Specially Postdoctoral Science Foundation of Heilongjiang Province,China
文摘New strain induced melt activation(new SIMA) method was employed to prepare high-quality semisolid billet of AZ61 magnesium alloy.Optical microscopy and tensile test were used to study the microstructure and mechanical properties of the thixo-extruded component.The results showed that the optimal process parameters for achieving the complete filling status involved the applied pressure of 784 MPa,the pressure holding time of 90 s and the die temperature of 450 ℃.Compared to semisolid isothermal treatment,high mechanical properties such as the tensile strength of 300.5 MPa and elongation of 22% and fine microstructure were obtained in the thixo-extruded parts.With increasing the isothermal temperature and holding time,the tensile strength and elongation were increased firstly and then decreased.When the press pass was increased from 1 to 4,the tensile strength and elongation of the thixo-extruded parts were greatly enhanced and microstructure was refined obviously.
基金supported by the National Natural Science Foundation of China(Grant Nos.50374012,51144009)the National Natural Science Foundation of Jiangxi Province(Grant No.0650047)+1 种基金the Science and Technology Program of the Education Department of Jiangxi Province(Grant No.GJJ09229)the Science Research Foundation of Jiangxi University of Science and Technology(Grant No.jxxjzd10003)
文摘To obtain the semi-solid slurry with uniform and fine structure morphology that satisfies the requirement of rheocasting process, a new process for preparing semi-solid AI alloy slurry was developed, in which local chilling was combined with low superheat pouring and slight electromagnetic stirring (LSPSEMS). The morphology and the size of primary a-AI in the A356 alloy slurry prepared with the new process, i.e., LSPSEMS with local chilling, were investigated using MIAPS image analyzing software, and the grain refinement mechanism was discussed. The results indicate that the semi-solid primary phase consists of particle-like or globular-like a-AI, and the morphology and grain size of primary a-AI in the slurry can be markedly improved by the new process. The fine primary a-AI distributes uniformly in the slurry, which satisfies the requirement of rheocasting. Compared with the alloy prepared by LSPSEMS, the average equal-area-circle grain diameter of primary a-AI in semi-solid A356 alloy ingot prepared by the new process is decreased from 85.6μm to 68.8 μm at the central area, 112.6 μm to 77.6 μm at the transition area and is 84.7 μm in the edge area, respectively. The corresponding shape factor of primary a-AI is increased from 0.78 to 0.83, 0.54 to 0.77 and 0.28 to 0.59, respectively. In addition, the pouring temperature could be suitably raised from 620-630℃ of the traditional process to 650℃ using this technique, which is convenient for practical operation. The mechanism of grain refinement, in the new process, is that the local chilling quickens up the temperature decrease in the center of the melt. The nuclei could not grow up in a short time so the finer grains are formed in the melt.
文摘Erratum to:International Journal of Minerals, Metallurgy and Materials Volume 26, Number 9, September 2019, Page 1151https://doi.org/10.1007/s12613-019-1854-1The original version of this article unfortunately contained a mistake. The presentation of Fig. 11 was incorrect. The correct version is given below:
基金Funded by the National Natural Science Foundation of China(Nos.51101133,51101134)the Encouraging Foundation for Outstanding Youth Scientists of Shandong Province,China(No.BS2012CL036)the Natural Science Foundation of Shandong Province,China(No.ZR2011EL025)
文摘Glass-forming ability(GFA) and mechanical properties of(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(100-x)Lu_x(x= 0-3 at%) alloys have been investigated.The GFA of Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy is dramatically enhanced by adding Lu.The(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(98)Lu_2 alloy possesses the highest GFA in the studied Zr-Nb-Cu-Ni-Al-Lu alloys,with its critical diameter for glass formation reaching 20 mm by copper-mould casting method,while that of the Lu-free Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy is 7 mm.The critical diameters of(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(100-x)Lu_x(x =1 at%and 3 at%) alloys are 15 mm and 12 mm,respectively.The Lu addition to Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy induces the change of initial crystallization phases from face-centred-cubic Zr_2Ni and tetragonal Zr_2Ni phases for the Lu-free Zr_(58)Nb_3Cu_(16)Ni_(13)Al_(10) alloy to an icosahedral quasi-crystalline phase for the Lu-doped alloys,which may be the origin for the enhanced GFA of the Lu-doped alloys.The compressive fracture strength and plastic strain of the bulk glassy(Zr_(0.58)Nb_(0.03)Cu_(0.16)Ni_(0.13)Al_(0.10))_(98)Lu_2 alloy are1 610 MPa and 1.5%,respectively.
文摘A new sound alloy, abbreviated to S, has been developed by the General Research Institutefor Non-ferrous Metals, Beijing. The alloy is very suitable for making trumpets, trombones, tenorhorns, saxaphones and other kinds of wind instruments. Beijing Wind Instrument Factory, which is the largest one in China, has used Salloy formanufacturing 5200 type trompets, the sound performance of which has been examined with fre-quency analysis and experimented by famous musical experts. The results show that the 5200 typetrumpets made of Salloy have excellent quality, accurate intonation and ease of response at
文摘A new process was used for producing FeAl alloy pow de rs with double consumable rotating electrodes and the powders made in this appar atus were analyzed. In this new technology, tungsten rod serves as a cathode ele ctrode, while the alloy rod as an anode electrode. The conventional rotating ele ctrode process must have an anode with pre-melting alloys; however, in this new process, using pure iron as cathode electrode and pure aluminum as anode electr ode can eliminate the step of pre-melting. The effects of process variables, which include electrode rotational speed, a nd electrode diameter of the mean particle diameter were determined. Results showed that both the rotational speed and diameter of electrodes would a ffect the mean diameter of particles. There are three kinds of powders with diff erent composition produced in this study and the possible mechanisms are discuss ed. The process parameters and volume mean diameter of the powders have been cor related to find an experimental equation. The results show that when the rotational speed and the diameter of the anode el ectrode are increased, the powders size will decrease. However, the powders size will increase with cathode electrode.