With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling produc...With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling production.This paper studied the effect of the hot rolling order of aluminum alloy on the surface quality of strip,such as roll printing,color difference,anodic oxidation,etc.,reasonable discharge sequence and corresponding optimization measures were formulated.展开更多
The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high c...The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high current densities is still a challenge.Herein,we develop a Cu-Zn alloy/Cu-Zn aluminate oxide composite electrocatalytic system for enhanced conversion of CO_(2)to C_(2+)products.The Cu-Zn-Al-Layered Double Hydroxide(LDH) is used as a precursor to decompose into uniform Cu-Zn oxide/Cu-Zn aluminate pre-catalyst.Under electrochemical reduction,Cu-Zn oxide generates Cu-Zn alloy while Cu-Zn aluminate oxide remains unchanged.The alloy and oxide are closely stacked and arranged alternately,and the aluminate oxide induces the strong electron interaction of Cu,Zn and Al,creating a large number of highly active reaction interfaces composed of 0 to+3 valence metal sites.With the help of the interface effect,the optimized Cu_(9)Zn_(1)/Cu_(0.8)Zn_(0.2)Al_(2)O_(4)catalyst achieves a Faradaic efficiency of 88.5% for C_(2+)products at a current density of 400 mA cm^(-2)at-1.15 V versus reversible hydrogen electrode.The in-situ Raman and attenuate total reflectance-infrared absorption spectroscopy(ATR-IRAS) spectra show that the aluminate oxide at the interface significantly enhances the adsorption and activation of CO_(2)and the dissociation of H2O and strengthens the adsorption of CO intermediates,and the alloy promotes the C-C coupling to produce C_(2+)products.This work provides an efficient strategy to construct highly active reaction interfaces for industrial-scale electrochemical CO_(2)RR.展开更多
Separated preparation of prealloys and amorphous alloys results in severe solidification-remelting and beneficial element removal-readdition contradictions,which markedly increase energy consumption and emissions.This...Separated preparation of prealloys and amorphous alloys results in severe solidification-remelting and beneficial element removal-readdition contradictions,which markedly increase energy consumption and emissions.This study offered a novel strategy for the direct production of FePC amorphous soft magnetic alloys via smelting reduction of high-phosphorus iron ore(HPIO)and apatite.First,the thermodynamic conditions and equilibrium states of the carbothermal reduction reactions in HPIO were calculated,and the element content in reduced alloys was theoretically determined.The phase and structural evolutions,as well as element migration and enrichment behaviors during the smelting reduction of HPIO and Ca_(3)(PO_(4))_(2),were then experimentally verified.The addition of Ca_(3)(PO_(4))_(2)in HPIO contributes to the enrichment of the P element in reduced alloys and the subsequent development of Fe_(3)P and Fe_(2)P phases.The content of P and C elements in the range of 1.52 wt% -14.63 wt% and 0.62 wt% -2.47 wt%,respectively,can be well tailored by adding 0-50 g Ca_(3)(PO_(4))_(2)and controlling the C/O mole ratio of 0.8-1.1,which is highly consistent with the calculated results.These FePC alloys were then successfully formed into amorphous ribbons and rods.The energy consumption of the proposed strategy was estimated to be 2.00×10^(8) kJ/t,which is reduced by 30% when compared with the conventional production process.These results are critical for the comprehensive utilization of mineral resources and pave the way for the clean production of Fe-based amorphous soft magnetic alloys.展开更多
Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we...Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO_(3RR)compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH_(3)production performance was particularly outstanding,with a maximum NH_(3)yield of up to 959.6μmol/(h·cm~2).Furthermore,the Faraday efficiency(FE)was even 88.0%at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO_(3)RR.展开更多
Microstructures of three kinds of typical product states for commercially fabricated alloy 2195 were observed.It is found that the hot-rolled plate is characterized by a fibrous structure containing fine,polygonized s...Microstructures of three kinds of typical product states for commercially fabricated alloy 2195 were observed.It is found that the hot-rolled plate is characterized by a fibrous structure containing fine,polygonized substructures;and the cold-rolled sheet was characterized by a "pan-caked" grain structure containing high density dislocation cells.The product under near peak-aging temper is proved to contain a large amount of dispersive,plate-shaped T1(Al2CuLi) precipitates,together with a small fraction of θ'(Al2Cu) plates,exhibiting a desirable combination of mechanical properties.Analyses using scanning electron microscopy reveal that many coarse,irregular-shaped Al7Cu2Fe constituent particles exist in all product states,which indicates that intermediate heat treatments have little influence on this iron-caused,detrimental phase.The formation and evolution of microstructures for different product states of alloy 2195 were discussed in view point of the commercial production condition.展开更多
For high corrosion resistance and extensively modified biodegradable Mg-based alloys and composites for bone implants,a new Mgbased matrix model prepared by powder metallurgy is discussed and developed.In this researc...For high corrosion resistance and extensively modified biodegradable Mg-based alloys and composites for bone implants,a new Mgbased matrix model prepared by powder metallurgy is discussed and developed.In this research,Mg-5 wt.%Zn alloys were selected as a case.And they were impacted by hot extrusion and aging treatments to construct microstructure with different characteristics.Their selfforming corrosion product layer in Ringer’s solution,biodegradable behavior and corrosion mechanism were minutely investigated by in vitro degradation,electrochemical corrosion and cytocompatibility.The results demonstrated the extruded Mg-5 wt.%Zn alloy aged for 96 h showed high corrosion resistance,good biocompatibility for L929 and excellent ability of maintaining sample integrity during the immersion.Significantly,the alloy showed fine-grain microstructure and uniform distributed hundred nano-sized second phases,which promoted the formation of the uniform and smooth corrosion product layer at the beginning of immersion.The corrosion product layer was more stable in chloride containing aqueous solution and could be directly formed and repaired quickly,which effectively protected the matrix from further corrosion.In addition,an ideal model of Mg-based matrix for bone tissue engineering was tried to presume and propose by discussing the causal relationship between microstructure and bio-corrosion process.展开更多
This study was carried out to investigate the possibility of titanium alloy metal powder production using low-power plasma torches.An argon DC non-transferred arc plasma torch was designed,and numerical analysis was c...This study was carried out to investigate the possibility of titanium alloy metal powder production using low-power plasma torches.An argon DC non-transferred arc plasma torch was designed,and numerical analysis was conducted to determine the plasma jet properties and wire temperature.The highest velocities inside the nozzle attachment were between 838 and 1178 m/s.The velocities of the jets at the apex were between 494 and 645 m/s for different gas flow rates.The studied plasma gas flow rates had no significant effect on the effective plasma jet length.It was shown that the plasma jet length can be estimated by numerical analysis using the temperature and velocity changes of the plasma jet over distance.It was observed that the powders produced were spherical without any satellites.As a result of this study,a plasma torch was developed and powder production was performed successfully by using relatively low torch power.展开更多
Based on the alloy Cu55Ni45 (at pct), holding the proportion of Cu to Ni in constant and in the temperature range of 1233~1573 K, the wetting angles of CuNi-0~56 at pct Ti alloys on Si3N4 have been measured by the ses...Based on the alloy Cu55Ni45 (at pct), holding the proportion of Cu to Ni in constant and in the temperature range of 1233~1573 K, the wetting angles of CuNi-0~56 at pct Ti alloys on Si3N4 have been measured by the sessile drop method. With the increase of Ti content, the wetting angles decreased. The equilibrium wetting angle was 5° when Ti content ≥32 at pct.In the case of same Ti content, the activity of Ti in CuNiTi alloy was weaker than that in CuTi alloy The cross-section of the CuNiTi-Si3N4 interface and the elements distribution were examined by scanning electron microscope with X-ray wave-dispersion spectrometer, and the reaction products formed at the interface were determined by X-ray diffiaction analysis method.展开更多
The possibility of co-deposition of Li(Ⅰ)and RE(Ⅲ)has been estimated by both theoretical analysis and experimental study on the influences of temperature and concen- tration of chloride on the deposition potential.B...The possibility of co-deposition of Li(Ⅰ)and RE(Ⅲ)has been estimated by both theoretical analysis and experimental study on the influences of temperature and concen- tration of chloride on the deposition potential.Both the electrochemical and electrolytic results clearly show that Li(Ⅰ)and RE(Ⅲ)can co-deposit on the Al-Cu electrode under selected conditions.展开更多
The effect of cooling liquid used for heat exchangers on the Cu alloy corrosion products has been examined using potential-time measurements under applied current condition (anodizing), potentiodynamic polarization, X...The effect of cooling liquid used for heat exchangers on the Cu alloy corrosion products has been examined using potential-time measurements under applied current condition (anodizing), potentiodynamic polarization, X-ray diffraction (XRD) and infrared spectroscopy (IR) The corrosion products formed on the Cu alloy surface during anodizing, are Cu2O, Cu2(OH)3Cl, and Cu2S. NaCl is detected in the corrosion products. The film formation depends on the applied current and the shift of potential to nobler direction indicates its formation progress.展开更多
Nitrogen plays a vitally important role for improving properties for stainless steels in many aspects.In this paper,the physical metallurgy behavior and the beneficial effects of nitrogen on corrosion resistance and o...Nitrogen plays a vitally important role for improving properties for stainless steels in many aspects.In this paper,the physical metallurgy behavior and the beneficial effects of nitrogen on corrosion resistance and other mechanical properties of stainless steels were summarised.Based on nitrogen alloying,various stainless steel products,such as austenitic,duplex and martensitic staniless steels were developed with enhanced properties,such as corrosion resistance,mechanical strength and weldability,among other things.展开更多
The corrosion mechanism of Mg-Y alloys in 3.5% NaCl solution was investigated by electrochemical testing and SEM observation. The electrochemical results indicated that the corrosion potential of Mg-Y alloys in 3.5% N...The corrosion mechanism of Mg-Y alloys in 3.5% NaCl solution was investigated by electrochemical testing and SEM observation. The electrochemical results indicated that the corrosion potential of Mg-Y alloys in 3.5% NaCl solution increased with the increase of Y addition. The corrosion rate increased with the increase of Y addition because of the increase of Mg24Y5 intermetallic amounts. The corrosion gradually deteriorated with the increase of immersion time. The corrosion morphologies of the alloys were general corrosion for Mg-0.25Y and pitting corrosion for Mg-8Y and Mg-15Y, respectively. The main solid corrosion products were Mg（OH）2 and Mg2（OH）3C1·4H2O.展开更多
Atmospheric corrosion of aluminum alloy 2024 （AA2024） with salt lake water was simulated through a laboratory- accelerated test of cyclic wet-dry and electrochemical techniques. Effects of the soluble magnesium salt...Atmospheric corrosion of aluminum alloy 2024 （AA2024） with salt lake water was simulated through a laboratory- accelerated test of cyclic wet-dry and electrochemical techniques. Effects of the soluble magnesium salt contained in the salt water were investigated by scanning electron microscope （SEM）, transmission electron microscope （TEM）, energy dispersive spectrometer （EDS）, electron probe micro analyzer （EPMA）, X-ray diffraction （XRD）, infrared transmission spectroscope （IR）, and atmospheric corrosion monitor （ACM）. The results showed that, with the deposition, atmospheric corrosion of AA2024 could occur when the relative humidity （RH） was lower than 30%. A main crystalline component of corrosion products, layered double hydroxides （LDH）, [Mg1-xAlx（OH）2]^x＋ Clx-·mH2O （LDH-C1）, was determined, which meant that magnesium ion played an important role in the corrosion process. It not only facilitated the corrosion as a result of deliquescence, but also was involved in the corrosion process as a reactant.展开更多
文摘With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling production.This paper studied the effect of the hot rolling order of aluminum alloy on the surface quality of strip,such as roll printing,color difference,anodic oxidation,etc.,reasonable discharge sequence and corresponding optimization measures were formulated.
基金supported by the National Natural Science Foundation of China (NSFC)(22075201)the National Key Research and Development Program of China (2022YFB4101800)。
文摘The electrochemical CO_(2)reduction reaction to produce multi-carbon(C_(2+)) hydrocarbons or oxygenate compounds is a promising route to obtain a renewable fuel of high energy density.However,producing C_(2+)at high current densities is still a challenge.Herein,we develop a Cu-Zn alloy/Cu-Zn aluminate oxide composite electrocatalytic system for enhanced conversion of CO_(2)to C_(2+)products.The Cu-Zn-Al-Layered Double Hydroxide(LDH) is used as a precursor to decompose into uniform Cu-Zn oxide/Cu-Zn aluminate pre-catalyst.Under electrochemical reduction,Cu-Zn oxide generates Cu-Zn alloy while Cu-Zn aluminate oxide remains unchanged.The alloy and oxide are closely stacked and arranged alternately,and the aluminate oxide induces the strong electron interaction of Cu,Zn and Al,creating a large number of highly active reaction interfaces composed of 0 to+3 valence metal sites.With the help of the interface effect,the optimized Cu_(9)Zn_(1)/Cu_(0.8)Zn_(0.2)Al_(2)O_(4)catalyst achieves a Faradaic efficiency of 88.5% for C_(2+)products at a current density of 400 mA cm^(-2)at-1.15 V versus reversible hydrogen electrode.The in-situ Raman and attenuate total reflectance-infrared absorption spectroscopy(ATR-IRAS) spectra show that the aluminate oxide at the interface significantly enhances the adsorption and activation of CO_(2)and the dissociation of H2O and strengthens the adsorption of CO intermediates,and the alloy promotes the C-C coupling to produce C_(2+)products.This work provides an efficient strategy to construct highly active reaction interfaces for industrial-scale electrochemical CO_(2)RR.
基金financially supported by the National Natural Science Foundation of China(Nos.52174217 and 52304354)the China Postdoctoral Science Foundation(No.2020M682495)。
文摘Separated preparation of prealloys and amorphous alloys results in severe solidification-remelting and beneficial element removal-readdition contradictions,which markedly increase energy consumption and emissions.This study offered a novel strategy for the direct production of FePC amorphous soft magnetic alloys via smelting reduction of high-phosphorus iron ore(HPIO)and apatite.First,the thermodynamic conditions and equilibrium states of the carbothermal reduction reactions in HPIO were calculated,and the element content in reduced alloys was theoretically determined.The phase and structural evolutions,as well as element migration and enrichment behaviors during the smelting reduction of HPIO and Ca_(3)(PO_(4))_(2),were then experimentally verified.The addition of Ca_(3)(PO_(4))_(2)in HPIO contributes to the enrichment of the P element in reduced alloys and the subsequent development of Fe_(3)P and Fe_(2)P phases.The content of P and C elements in the range of 1.52 wt% -14.63 wt% and 0.62 wt% -2.47 wt%,respectively,can be well tailored by adding 0-50 g Ca_(3)(PO_(4))_(2)and controlling the C/O mole ratio of 0.8-1.1,which is highly consistent with the calculated results.These FePC alloys were then successfully formed into amorphous ribbons and rods.The energy consumption of the proposed strategy was estimated to be 2.00×10^(8) kJ/t,which is reduced by 30% when compared with the conventional production process.These results are critical for the comprehensive utilization of mineral resources and pave the way for the clean production of Fe-based amorphous soft magnetic alloys.
基金National Natural Science Foundation of China(Nos.52225204,52173233 and 52202085)Innovation Program of Shanghai Municipal Education Commission,China(No.2021-01-07-00-03-E00109)+3 种基金Natural Science Foundation of Shanghai,China(No.23ZR1479200)“Shuguang Program”Supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission,China(No.20SG33)Fundamental Research Funds for the Central Universities,China(No.2232024Y-01)DHU Distinguished Young Professor Program,China(Nos.LZA2022001 and LZB2023002)。
文摘Highly dispersed bimetallic alloy nanoparticle electrocatalysts have been demonstrated to exhibit exceptional performance in driving the nitrate reduction reaction(NO_(3)RR)to generate ammonia(NH_(3)).In this study,we prepared mesoporous carbon nanofibers(mCNFs)functionalized with ordered PtFe alloys(O-PtFe-mCNFs)by a composite micelle interface-induced co-assembly method using poly(ethylene oxide)-block-polystyrene(PEO-b-PS)as a template.When employed as electrocatalysts,O-PtFe-mCNFs exhibited superior electrocatalytic performance for the NO_(3RR)compared to the mCNFs functionalized with disordered PtFe alloys(D-PtFe-mCNFs).Notably,the NH_(3)production performance was particularly outstanding,with a maximum NH_(3)yield of up to 959.6μmol/(h·cm~2).Furthermore,the Faraday efficiency(FE)was even 88.0%at-0.4 V vs.reversible hydrogen electrode(RHE).This finding provides compelling evidence of the potential of ordered PtFe alloy catalysts for the electrocatalytic NO_(3)RR.
基金supported by the National Key Technologies R&D Program of China during the 10th Five-year Plan Period
文摘Microstructures of three kinds of typical product states for commercially fabricated alloy 2195 were observed.It is found that the hot-rolled plate is characterized by a fibrous structure containing fine,polygonized substructures;and the cold-rolled sheet was characterized by a "pan-caked" grain structure containing high density dislocation cells.The product under near peak-aging temper is proved to contain a large amount of dispersive,plate-shaped T1(Al2CuLi) precipitates,together with a small fraction of θ'(Al2Cu) plates,exhibiting a desirable combination of mechanical properties.Analyses using scanning electron microscopy reveal that many coarse,irregular-shaped Al7Cu2Fe constituent particles exist in all product states,which indicates that intermediate heat treatments have little influence on this iron-caused,detrimental phase.The formation and evolution of microstructures for different product states of alloy 2195 were discussed in view point of the commercial production condition.
基金The authors acknowledge the Project(81472058)sup-ported by the National Natural Science Foundation of Chinathe financial support of the 2015 ShanDong province project of outstanding subject talent group.the project(LSD-KB1806)+2 种基金supported by the foundation of National Key labo-ratory of Shock Wave and Detonation Physics and the project(11802284)supported by the National Natural Science Foun-dation of China.The project(2017GK2120)supported by the Key Research and Development Program of Hunan Province and the Natural Science Foundation of Hunan Province of China(2018JJ2506).
文摘For high corrosion resistance and extensively modified biodegradable Mg-based alloys and composites for bone implants,a new Mgbased matrix model prepared by powder metallurgy is discussed and developed.In this research,Mg-5 wt.%Zn alloys were selected as a case.And they were impacted by hot extrusion and aging treatments to construct microstructure with different characteristics.Their selfforming corrosion product layer in Ringer’s solution,biodegradable behavior and corrosion mechanism were minutely investigated by in vitro degradation,electrochemical corrosion and cytocompatibility.The results demonstrated the extruded Mg-5 wt.%Zn alloy aged for 96 h showed high corrosion resistance,good biocompatibility for L929 and excellent ability of maintaining sample integrity during the immersion.Significantly,the alloy showed fine-grain microstructure and uniform distributed hundred nano-sized second phases,which promoted the formation of the uniform and smooth corrosion product layer at the beginning of immersion.The corrosion product layer was more stable in chloride containing aqueous solution and could be directly formed and repaired quickly,which effectively protected the matrix from further corrosion.In addition,an ideal model of Mg-based matrix for bone tissue engineering was tried to presume and propose by discussing the causal relationship between microstructure and bio-corrosion process.
基金financial supports from the Scientific and Technological Research Council of Turkey(No.215M895)。
文摘This study was carried out to investigate the possibility of titanium alloy metal powder production using low-power plasma torches.An argon DC non-transferred arc plasma torch was designed,and numerical analysis was conducted to determine the plasma jet properties and wire temperature.The highest velocities inside the nozzle attachment were between 838 and 1178 m/s.The velocities of the jets at the apex were between 494 and 645 m/s for different gas flow rates.The studied plasma gas flow rates had no significant effect on the effective plasma jet length.It was shown that the plasma jet length can be estimated by numerical analysis using the temperature and velocity changes of the plasma jet over distance.It was observed that the powders produced were spherical without any satellites.As a result of this study,a plasma torch was developed and powder production was performed successfully by using relatively low torch power.
文摘Based on the alloy Cu55Ni45 (at pct), holding the proportion of Cu to Ni in constant and in the temperature range of 1233~1573 K, the wetting angles of CuNi-0~56 at pct Ti alloys on Si3N4 have been measured by the sessile drop method. With the increase of Ti content, the wetting angles decreased. The equilibrium wetting angle was 5° when Ti content ≥32 at pct.In the case of same Ti content, the activity of Ti in CuNiTi alloy was weaker than that in CuTi alloy The cross-section of the CuNiTi-Si3N4 interface and the elements distribution were examined by scanning electron microscope with X-ray wave-dispersion spectrometer, and the reaction products formed at the interface were determined by X-ray diffiaction analysis method.
文摘The possibility of co-deposition of Li(Ⅰ)and RE(Ⅲ)has been estimated by both theoretical analysis and experimental study on the influences of temperature and concen- tration of chloride on the deposition potential.Both the electrochemical and electrolytic results clearly show that Li(Ⅰ)and RE(Ⅲ)can co-deposit on the Al-Cu electrode under selected conditions.
文摘The effect of cooling liquid used for heat exchangers on the Cu alloy corrosion products has been examined using potential-time measurements under applied current condition (anodizing), potentiodynamic polarization, X-ray diffraction (XRD) and infrared spectroscopy (IR) The corrosion products formed on the Cu alloy surface during anodizing, are Cu2O, Cu2(OH)3Cl, and Cu2S. NaCl is detected in the corrosion products. The film formation depends on the applied current and the shift of potential to nobler direction indicates its formation progress.
文摘Nitrogen plays a vitally important role for improving properties for stainless steels in many aspects.In this paper,the physical metallurgy behavior and the beneficial effects of nitrogen on corrosion resistance and other mechanical properties of stainless steels were summarised.Based on nitrogen alloying,various stainless steel products,such as austenitic,duplex and martensitic staniless steels were developed with enhanced properties,such as corrosion resistance,mechanical strength and weldability,among other things.
基金National Natural Science Foundation of China(No.52271107)Natural Science Foundation of Liaoning Province,China(No.2020-MS-004)Natural Science Foundation of Shandong Province,China(No.ZR2021ME241)。
基金Project(2011BAE22B01)supported by the National Key Technology R&D Program of Chinasupported by Beijing Engineering Research Center for Advanced Manufacturing and Evaluation of Special Vehicle Parts which is jointly built by Beijing North Vehicle Group Corporation and University of Science and Technology Beijing
文摘The corrosion mechanism of Mg-Y alloys in 3.5% NaCl solution was investigated by electrochemical testing and SEM observation. The electrochemical results indicated that the corrosion potential of Mg-Y alloys in 3.5% NaCl solution increased with the increase of Y addition. The corrosion rate increased with the increase of Y addition because of the increase of Mg24Y5 intermetallic amounts. The corrosion gradually deteriorated with the increase of immersion time. The corrosion morphologies of the alloys were general corrosion for Mg-0.25Y and pitting corrosion for Mg-8Y and Mg-15Y, respectively. The main solid corrosion products were Mg（OH）2 and Mg2（OH）3C1·4H2O.
基金Project(51131007) supported by the National Natural Science Foundation of China
文摘Atmospheric corrosion of aluminum alloy 2024 （AA2024） with salt lake water was simulated through a laboratory- accelerated test of cyclic wet-dry and electrochemical techniques. Effects of the soluble magnesium salt contained in the salt water were investigated by scanning electron microscope （SEM）, transmission electron microscope （TEM）, energy dispersive spectrometer （EDS）, electron probe micro analyzer （EPMA）, X-ray diffraction （XRD）, infrared transmission spectroscope （IR）, and atmospheric corrosion monitor （ACM）. The results showed that, with the deposition, atmospheric corrosion of AA2024 could occur when the relative humidity （RH） was lower than 30%. A main crystalline component of corrosion products, layered double hydroxides （LDH）, [Mg1-xAlx（OH）2]^x＋ Clx-·mH2O （LDH-C1）, was determined, which meant that magnesium ion played an important role in the corrosion process. It not only facilitated the corrosion as a result of deliquescence, but also was involved in the corrosion process as a reactant.
