A hydroponic experiment was conducted to study the effect of partial replacement of NO-3-N by NH4+-N on the seedling growth and organic acid content of tomato (Lycopersicon esculentum Mill.). A completely randomized d...A hydroponic experiment was conducted to study the effect of partial replacement of NO-3-N by NH4+-N on the seedling growth and organic acid content of tomato (Lycopersicon esculentum Mill.). A completely randomized design was established with three replications and five treatments, i.e., NO-3-N/NH4+-N of 100/0, 75/25, 50/50, 25/75 and 0/100. Results showed that 25% replacement of NO3--N by NH4+-N significantly (P = 0.05) improved fresh and dry weight, revealing that a proper percentage of NH4+-N was important for tomato nitrogen nutrition. This could increase the plant growth even though tomato was a crop that preferred nitrate nutrition. Also an increase in the proportion of NH4+-N in the nutrient solution led to a significant decrease (P = 0.05) in malate, citrate and fumarate. However, the 25% NH4+-N plus 75% NO3--N treatment had no significant effect (P = 0.05) on the 2-ketoglutarate, succinate or oxalic acid content, showing that only some organic acids in tomato plants were affected. Only pyruvate increased significantly (P = 0.05), and it only increased for 25% and 50% replacement of NO3--N by NH4+-N. Metabolism of these organic acids, especially malate, citrate and fumarate, should be further studied at the molecular level in vegetables applied with different nitrogen forms.展开更多
The Haber-Bosch process is the most widely used synthetic ammonia technology at present.Since its invention,it has provided an important guarantee for global food security.However,the traditional Haber-Bosch ammonia s...The Haber-Bosch process is the most widely used synthetic ammonia technology at present.Since its invention,it has provided an important guarantee for global food security.However,the traditional Haber-Bosch ammonia synthesis process consumes a lot of energy and causes serious environmental pollution.Under the serious pressure of energy and environment,a green,clean,and sustainable ammonia synthesis route is urgently needed.Electrochemical synthesis of ammonia is a green and mild new method for preparing ammonia,which can directly convert nitrogen or nitrate into ammonia using electricity driven by solar,wind,or water energy,without greenhouse gas and toxic gas emissions.Herein,the basic mechanism of the nitrogen reduction reaction(NRR)to ammonia and nitrate reduction reaction(NO_(3)^(-))to ammonia were discussed.The representative approaches and major technologies,such as lithium mediated electrolysis and solid oxide electrolysis cell(SOEC)electrolysis for NRR,high activity catalyst and advanced electrochemical device fabrication for(NO_(3)^(-))RR and electrochemical ammonia synthesis were summarized.Based on the above discussion and analysis,the main challenges and development directions for electrochemical ammonia synthesis were further proposed.展开更多
Based on the experimental data,this study investigated the effect of sand content of muddy water on water and nitrogen transport characteristics of the single-line interference infiltration under film hole irrigation ...Based on the experimental data,this study investigated the effect of sand content of muddy water on water and nitrogen transport characteristics of the single-line interference infiltration under film hole irrigation with muddy water and fertilizer.The relationship between the single-line interference infiltration parameters,the sand content,the wetting front movement distances,and the sand content were all established.The model of the cumulative infiltration volume of per unit film pore area,the vertical and horizontal wetting front movement distance of the free surface,and the wetting front movement distance of the interference center with sand content and infiltration time were proposed.Reveal the law of the change of soil water content and the distribution of NO_(3)^(-)-N content based on different muddy water sand content.The results indicate that at the same infiltration time,as the muddy water sand content increases,the cumulative infiltration volume per unit pore area decreases.The infiltration index of the free infiltration and the single-line interference vary little when the sand content increases,mainly are around 0.64 and 0.58.The relationship between infiltration parameters a,b and the sand content is linear function.At the same location,the more the sand content,the smaller the wetting front movement distance in free surface and the single-line interference surface,the less the NO_(3)^(-)-N content.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 30270790) and National Post-doctoral Foundation of China (No. 2003033494).
文摘A hydroponic experiment was conducted to study the effect of partial replacement of NO-3-N by NH4+-N on the seedling growth and organic acid content of tomato (Lycopersicon esculentum Mill.). A completely randomized design was established with three replications and five treatments, i.e., NO-3-N/NH4+-N of 100/0, 75/25, 50/50, 25/75 and 0/100. Results showed that 25% replacement of NO3--N by NH4+-N significantly (P = 0.05) improved fresh and dry weight, revealing that a proper percentage of NH4+-N was important for tomato nitrogen nutrition. This could increase the plant growth even though tomato was a crop that preferred nitrate nutrition. Also an increase in the proportion of NH4+-N in the nutrient solution led to a significant decrease (P = 0.05) in malate, citrate and fumarate. However, the 25% NH4+-N plus 75% NO3--N treatment had no significant effect (P = 0.05) on the 2-ketoglutarate, succinate or oxalic acid content, showing that only some organic acids in tomato plants were affected. Only pyruvate increased significantly (P = 0.05), and it only increased for 25% and 50% replacement of NO3--N by NH4+-N. Metabolism of these organic acids, especially malate, citrate and fumarate, should be further studied at the molecular level in vegetables applied with different nitrogen forms.
文摘The Haber-Bosch process is the most widely used synthetic ammonia technology at present.Since its invention,it has provided an important guarantee for global food security.However,the traditional Haber-Bosch ammonia synthesis process consumes a lot of energy and causes serious environmental pollution.Under the serious pressure of energy and environment,a green,clean,and sustainable ammonia synthesis route is urgently needed.Electrochemical synthesis of ammonia is a green and mild new method for preparing ammonia,which can directly convert nitrogen or nitrate into ammonia using electricity driven by solar,wind,or water energy,without greenhouse gas and toxic gas emissions.Herein,the basic mechanism of the nitrogen reduction reaction(NRR)to ammonia and nitrate reduction reaction(NO_(3)^(-))to ammonia were discussed.The representative approaches and major technologies,such as lithium mediated electrolysis and solid oxide electrolysis cell(SOEC)electrolysis for NRR,high activity catalyst and advanced electrochemical device fabrication for(NO_(3)^(-))RR and electrochemical ammonia synthesis were summarized.Based on the above discussion and analysis,the main challenges and development directions for electrochemical ammonia synthesis were further proposed.
基金National Key R&D Program of China(2016YFC0400204)National Natural Science Foundation of China(51479161,51279157,51779205)。
文摘Based on the experimental data,this study investigated the effect of sand content of muddy water on water and nitrogen transport characteristics of the single-line interference infiltration under film hole irrigation with muddy water and fertilizer.The relationship between the single-line interference infiltration parameters,the sand content,the wetting front movement distances,and the sand content were all established.The model of the cumulative infiltration volume of per unit film pore area,the vertical and horizontal wetting front movement distance of the free surface,and the wetting front movement distance of the interference center with sand content and infiltration time were proposed.Reveal the law of the change of soil water content and the distribution of NO_(3)^(-)-N content based on different muddy water sand content.The results indicate that at the same infiltration time,as the muddy water sand content increases,the cumulative infiltration volume per unit pore area decreases.The infiltration index of the free infiltration and the single-line interference vary little when the sand content increases,mainly are around 0.64 and 0.58.The relationship between infiltration parameters a,b and the sand content is linear function.At the same location,the more the sand content,the smaller the wetting front movement distance in free surface and the single-line interference surface,the less the NO_(3)^(-)-N content.
