A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tung...A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tungsten by solvent extraction and reusing leaching agent.In the leaching process,affecting factors,such as temperature,leaching time,nitric acid and dosage of phosphoric acid,were examined on recovery of tungsten.Results show that more than 97%of tungsten could be extracted under conditions of leaching temperature of 80-90°C,HNO3 concentration of 3.0-4.0 mol/L,liquild-to-soild ratio of 10:1,H3PO4 dosage of 3 stoichiometric ratio and leaching time of 3 h.Solvent extraction was then employed for the W recovery from the leachate with a organic system of 40%(v/v)N235,30%(v/v)TBP,and 30%sulfonated kerosene.Approximately 99.93%of W was extracted and ammonium tungstate solution containing 193 g/L W was obtained with a stripping rate of 98.10%under the optimized conditions.展开更多
The pressure nitric acid leaching of alkali-pre- treated low-grade limonitic laterite, as well as removing impurity AI(III) and preparing intermediate product of nickel/cobalt sulphide from leaching liquor were inve...The pressure nitric acid leaching of alkali-pre- treated low-grade limonitic laterite, as well as removing impurity AI(III) and preparing intermediate product of nickel/cobalt sulphide from leaching liquor were investi- gated. After pretreatment, iron exists in the form of amorphous iron oxides, while nickel is adsorbed on the surface of iron oxides in the form of nickel oxide. The preferable pressure leaching conditions are determined as follows: leaching temperature of 458 K, leaching duration of 60 min, initial acidity of nitric acid of 1.90 mol.L-~ and liquid to solid ratio of 3:1 (volume to mass ratio). Under these conditions, the leaching efficiencies of Ni, Co and A1 are 95 %, 88 % and 55 %, respectively, and that of Fe is less than 1%. The loss rates of Ni and Co are 1.8 % and 1.5 %, respectively, during the step of removing impurity AI(III). The sulphide precipitation process produces the interim production of nickel/cobalt sulphides, recovering greater than 99 % of Ni and Co in the purified solution. The iron-rich (〉60 %) pressure leaching residue with low Cr, S can be further reclaimed as the raw materials for iron making.展开更多
The kinetics of nitric acid leaching of cerium was investigated for the oxidation roasted Baotou mixed rare earth concentrate. The effects of leaching temperature, HNO_3 concentration, liquidesolid ratio(L/S)and stirr...The kinetics of nitric acid leaching of cerium was investigated for the oxidation roasted Baotou mixed rare earth concentrate. The effects of leaching temperature, HNO_3 concentration, liquidesolid ratio(L/S)and stirring rate on rare earth extraction were studied. The XRD and SEM mapping analysis of the samples before and after acid leaching shows that the roasted bastnaesite is completely leached. Besides,the decomposition process of oxidizing roasting was also obtained by TGe MS and XRD. Different kinetics models were applied in this leaching process. The results of dynamic fitting show that the leaching process can be described by a new variant of the shrinking-core model. And the leaching rate is controlled by both the interfacial transfer and diffusion through the product layer. The apparent activation energy is calculated as 76.78 kJ/mol and the reaction orders with respect to HNO_3 concentrations and liquidesolid ratio are determined to be 7.609 and 2.516, respectively. Besides, an empirical rate equation is obtained to describe the process.展开更多
The physico-chemical characterization and dissolution kinetics study of a Nigerian galena ore in nitric acid has been undertaken. The effects of acid concentration, temperature, particle size, stirring speed and solid...The physico-chemical characterization and dissolution kinetics study of a Nigerian galena ore in nitric acid has been undertaken. The effects of acid concentration, temperature, particle size, stirring speed and solid/liquid ratio on the leaching of galena were investigated. The X-ray fluorescence data showed that the galena ore used in the study exists mainly as PbS. Lead (Pb) was detected as the major metal for galena with metals such as Na, Ca, Fe, Zn, Al and Mg occurring as minor elements. The XRD analysis also confirmed the originality of the galena ore as it revealed that galena exists mainly as lead sulphide (PbS). The Fourier transform infrared (FTIR) analysis also supported the XRF and XRD analysis by revealing the presence of sulphur in the ore. The scanning electron micrograph (SEM) analysis revealed a high level of crystallinity of the ore. Results of the leaching studies showed that galena dissolution in nitric acid (HNO3) increases with increasing concentration of nitric acid, temperature and stirring rate, and decreases with increasing particle diameter and solid/liquid ratio. In 10 M HNO3 at a temperature of 90°C using 75 μm particle diameter with solid/liquid ratio of 20 g/L and stirring speed of 540 rpm, about 84.5% of galena was dissolved in 150 minutes. The values of activation energy, order of reaction and Arrhenius constant calculated at the conditions above for galena were 27.01 KJ/mol, 0.93, 26.71 s-1 respectively. The mechanism of dissolution of galena was established to follow the shrinking core model for the diffusion controlled mechanism, with surface chemical reaction as the rate controlling step for the leaching process. Finally, the XRD analysis of the post-leaching residue revealed the presence of gahnite and anglesite.展开更多
基金Project(51334008) supported by the National Natural Science Foundation of China
文摘A hydrometallurgical process for tungsten extraction and recovery from scheelite is reported.The technology includes leaching scheelite using phosphoric acid as chelating agent in nitric acid solutions,extracting tungsten by solvent extraction and reusing leaching agent.In the leaching process,affecting factors,such as temperature,leaching time,nitric acid and dosage of phosphoric acid,were examined on recovery of tungsten.Results show that more than 97%of tungsten could be extracted under conditions of leaching temperature of 80-90°C,HNO3 concentration of 3.0-4.0 mol/L,liquild-to-soild ratio of 10:1,H3PO4 dosage of 3 stoichiometric ratio and leaching time of 3 h.Solvent extraction was then employed for the W recovery from the leachate with a organic system of 40%(v/v)N235,30%(v/v)TBP,and 30%sulfonated kerosene.Approximately 99.93%of W was extracted and ammonium tungstate solution containing 193 g/L W was obtained with a stripping rate of 98.10%under the optimized conditions.
基金financially supported by the National Natural Science Foundation of China (Nos. 51274044, 51304023, and U1302274)
文摘The pressure nitric acid leaching of alkali-pre- treated low-grade limonitic laterite, as well as removing impurity AI(III) and preparing intermediate product of nickel/cobalt sulphide from leaching liquor were investi- gated. After pretreatment, iron exists in the form of amorphous iron oxides, while nickel is adsorbed on the surface of iron oxides in the form of nickel oxide. The preferable pressure leaching conditions are determined as follows: leaching temperature of 458 K, leaching duration of 60 min, initial acidity of nitric acid of 1.90 mol.L-~ and liquid to solid ratio of 3:1 (volume to mass ratio). Under these conditions, the leaching efficiencies of Ni, Co and A1 are 95 %, 88 % and 55 %, respectively, and that of Fe is less than 1%. The loss rates of Ni and Co are 1.8 % and 1.5 %, respectively, during the step of removing impurity AI(III). The sulphide precipitation process produces the interim production of nickel/cobalt sulphides, recovering greater than 99 % of Ni and Co in the purified solution. The iron-rich (〉60 %) pressure leaching residue with low Cr, S can be further reclaimed as the raw materials for iron making.
基金Project supported by the National Basic Research Program of China(2012CBA01202)the National Natural Science Foundation of China(51174184)the Key Research Program of the Chinese Academy of Sciences(KGZD-EW-201-1)
文摘The kinetics of nitric acid leaching of cerium was investigated for the oxidation roasted Baotou mixed rare earth concentrate. The effects of leaching temperature, HNO_3 concentration, liquidesolid ratio(L/S)and stirring rate on rare earth extraction were studied. The XRD and SEM mapping analysis of the samples before and after acid leaching shows that the roasted bastnaesite is completely leached. Besides,the decomposition process of oxidizing roasting was also obtained by TGe MS and XRD. Different kinetics models were applied in this leaching process. The results of dynamic fitting show that the leaching process can be described by a new variant of the shrinking-core model. And the leaching rate is controlled by both the interfacial transfer and diffusion through the product layer. The apparent activation energy is calculated as 76.78 kJ/mol and the reaction orders with respect to HNO_3 concentrations and liquidesolid ratio are determined to be 7.609 and 2.516, respectively. Besides, an empirical rate equation is obtained to describe the process.
文摘The physico-chemical characterization and dissolution kinetics study of a Nigerian galena ore in nitric acid has been undertaken. The effects of acid concentration, temperature, particle size, stirring speed and solid/liquid ratio on the leaching of galena were investigated. The X-ray fluorescence data showed that the galena ore used in the study exists mainly as PbS. Lead (Pb) was detected as the major metal for galena with metals such as Na, Ca, Fe, Zn, Al and Mg occurring as minor elements. The XRD analysis also confirmed the originality of the galena ore as it revealed that galena exists mainly as lead sulphide (PbS). The Fourier transform infrared (FTIR) analysis also supported the XRF and XRD analysis by revealing the presence of sulphur in the ore. The scanning electron micrograph (SEM) analysis revealed a high level of crystallinity of the ore. Results of the leaching studies showed that galena dissolution in nitric acid (HNO3) increases with increasing concentration of nitric acid, temperature and stirring rate, and decreases with increasing particle diameter and solid/liquid ratio. In 10 M HNO3 at a temperature of 90°C using 75 μm particle diameter with solid/liquid ratio of 20 g/L and stirring speed of 540 rpm, about 84.5% of galena was dissolved in 150 minutes. The values of activation energy, order of reaction and Arrhenius constant calculated at the conditions above for galena were 27.01 KJ/mol, 0.93, 26.71 s-1 respectively. The mechanism of dissolution of galena was established to follow the shrinking core model for the diffusion controlled mechanism, with surface chemical reaction as the rate controlling step for the leaching process. Finally, the XRD analysis of the post-leaching residue revealed the presence of gahnite and anglesite.