The prediction model for inhibition effect of reinforced concrete was presented based on the Magge＇s model when the concrete surface was brushed with nitrite solution. The influence of the amount of nitrite solution ...The prediction model for inhibition effect of reinforced concrete was presented based on the Magge＇s model when the concrete surface was brushed with nitrite solution. The influence of the amount of nitrite solution on inhibiting duration was also discussed through a simulation analysis when the amount of solution were 250 g/m^2, 500 g/m^2, 1000 g/m^2 and 1500 g/m^2, respectively. The experimental results confirm that nitrite ion can diffuse well in concrete to reach an effective mol ratio from the surface of the concrete to the surface of the reinforcement, and has an effective protection for the bars against corrosion. The higher the amount of solution, the better it will accelerate getting the threshold value of mol ratio on the surface of rebar, and retarding the time for loosing the effective threshold value of mol ratio. It helps to increase the tendency of inhibiting duration and prolong the life of reinforced concrete. The nitrite solution amount is used to predict the corrosion inhibiting duration of concrete that contains chloride salt.展开更多
It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. se...It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. self-condensation in aprotic polar solvent occurs to give symmnetrical disubstituted diphenyl ethers. However. when it is substituted with moderate electron withdrawing groups, no diphenyl ethers are obtained under the same conditions, instead, corresponding carboxylates are yielded. As a result. the applicability of this reaction is distinctly clarified展开更多
Ion-exclusion/anion-exchange chromatography(IEC/AEC) on a combination of a strongly basic anion-exchange resin in the OH——form with basic eluent has been developed.The separation mechanism is based on the ion-exclus...Ion-exclusion/anion-exchange chromatography(IEC/AEC) on a combination of a strongly basic anion-exchange resin in the OH——form with basic eluent has been developed.The separation mechanism is based on the ion-exclusion/penetration effect for cations and the anion-exchange effect for anions to anion-exchange resin phase.This system is useful for simultaneous separation and determination of ammonium ion(NH+4),nitrite ion(NO-2),and nitrate ion(NO-3) in water samples.The resolution of analyte ions can be manipulated by changing the concentration of base in eluent on a polystyrene-divinylbenzene based strongly basic anion-exchange resin column.In this study,several separation columns,which consisted of different particle sizes,different functional groups and different anion-exchange capacities,were compared.As the results,the separation column with the smaller anion-exchange capacity(TSKgel Super IC-Anion) showed well-resolved separation of cations and anions.In the optimization of the basic eluent,lithium hydroxide(LiOH) was used as the eluent and the optimal concentration was concluded to be 2 mmol/L,considering the resolution of analyte ions and the whole retention times.In the optimal conditions,the relative standard deviations of the peak areas and the retention times of NH+4,NO-2,and NO-3 ranged 1.28%-3.57% and 0.54%-1.55%,respectively.The limits of detection at signal-to-noise of 3 were 4.10 μmol/L for NH+4,1.87 μmol/L for NO-2 and 2.83 μmol/L for NO-3.展开更多
基金Funded by the K C Wong Magna Fund in Ningbo University and Natural Science Foundation of Ningbo (2007A610061)
文摘The prediction model for inhibition effect of reinforced concrete was presented based on the Magge＇s model when the concrete surface was brushed with nitrite solution. The influence of the amount of nitrite solution on inhibiting duration was also discussed through a simulation analysis when the amount of solution were 250 g/m^2, 500 g/m^2, 1000 g/m^2 and 1500 g/m^2, respectively. The experimental results confirm that nitrite ion can diffuse well in concrete to reach an effective mol ratio from the surface of the concrete to the surface of the reinforcement, and has an effective protection for the bars against corrosion. The higher the amount of solution, the better it will accelerate getting the threshold value of mol ratio on the surface of rebar, and retarding the time for loosing the effective threshold value of mol ratio. It helps to increase the tendency of inhibiting duration and prolong the life of reinforced concrete. The nitrite solution amount is used to predict the corrosion inhibiting duration of concrete that contains chloride salt.
文摘It is experimentally found that different renction courses exist when mtrite ion reacts with nitrobenzenes with different electron withdrawing groups. when it is substituted with strong electron withdrawing groups. self-condensation in aprotic polar solvent occurs to give symmnetrical disubstituted diphenyl ethers. However. when it is substituted with moderate electron withdrawing groups, no diphenyl ethers are obtained under the same conditions, instead, corresponding carboxylates are yielded. As a result. the applicability of this reaction is distinctly clarified
基金supported by Grant-in-Aid for Scientific Research(23615003)in Japan Society for the Promotion of Science(JSPS)
文摘Ion-exclusion/anion-exchange chromatography(IEC/AEC) on a combination of a strongly basic anion-exchange resin in the OH——form with basic eluent has been developed.The separation mechanism is based on the ion-exclusion/penetration effect for cations and the anion-exchange effect for anions to anion-exchange resin phase.This system is useful for simultaneous separation and determination of ammonium ion(NH+4),nitrite ion(NO-2),and nitrate ion(NO-3) in water samples.The resolution of analyte ions can be manipulated by changing the concentration of base in eluent on a polystyrene-divinylbenzene based strongly basic anion-exchange resin column.In this study,several separation columns,which consisted of different particle sizes,different functional groups and different anion-exchange capacities,were compared.As the results,the separation column with the smaller anion-exchange capacity(TSKgel Super IC-Anion) showed well-resolved separation of cations and anions.In the optimization of the basic eluent,lithium hydroxide(LiOH) was used as the eluent and the optimal concentration was concluded to be 2 mmol/L,considering the resolution of analyte ions and the whole retention times.In the optimal conditions,the relative standard deviations of the peak areas and the retention times of NH+4,NO-2,and NO-3 ranged 1.28%-3.57% and 0.54%-1.55%,respectively.The limits of detection at signal-to-noise of 3 were 4.10 μmol/L for NH+4,1.87 μmol/L for NO-2 and 2.83 μmol/L for NO-3.
