Studies on the Characteristics of Nitrogen and Phosphorus Pollution of Natural Outcrop Springs in Wudalianchi

Objective] The research aimed to study the characteristics of nitrogen and phosphorus pollution of 30 natural outcrop springs in Wudalianchi, which provides a theoretical basis for the sustainable development and utilization and protection of Wudalianchi natural mineral resources. [Method] Choosing the 30 natural outcrop spring representatives in different regions, samples were collected in low water period, normal water period, wet period respectively, and the content of nitrogen, phosphorus and other contaminants in the samples were determined. Besides, the pollution characteristics of nitrogen and phosphorus in Wudalianchi natural outcrop spring were analyzed. [Result] The 30 natural outcrop spring in Wudalianchi area were seriously polluted by nitrogen. Total nitrogen and nitrate nitrogen were the main forms of nitrogen pollution. The content of total phosphorus and ammonia nitrogen were low. [Conclusion] The natural outcrop spring is mainly caused by agricultural non-point source pollution.

Agricultural non-point nitrogen pollution control function of dierent vegetation types in riparian wetlands: A case study in the Yellow River wetland in China

Riparian wetland is the major transition zone of matter, energy and information transfer between aquatic and terrestrial ecosystems and has important functions of water purification and non-point pollution control. Using the field experiment method and an isotope tracing technique, the agricultural non-point nitrogen pollution control function of different vegetation types in riparian wetland was studied in the Kouma Section of the Yellow River. The results showed that the retention of agricultural non-point nitrogen pollution by riparian wetland soil occurs mainly in top 0-10 cm layer. The amount of nitrogen retained by surface soils associated with three types of vegetation are 0.045 mg/g for Phragmites communis Trin Linn, 0.036 mg/g for Scirpus triqueter Linn, and 0.032 mg/g for Typha angustifolia Linn, which account for 59.21%, 56.25%, and 56.14% of the total nitrogen interception, respectively. Exogenous nitrogen in 0-10 cm soil layer changes more quickly than in other layers. One month after adding KISNO3 to the tested vegetation, nitrogen content was 77.78% for P communis Trin, 68.75% for T. angustifolia, and 8.33% for S. triqueter in the surface soil. After three months, nitrogen content was 93.33% for P. communis Trin, 72.22% for S. triqueter, and 37.50% for T. Angustifolia. There are large differences among vegetation communities respecting to purification of agricultural non-point nitrogen pollution. The nitrogen uptake amount decreases in the sequence： new shoots ofP. communis Trin （9.731 nag/g） 〉 old P. communis Trin （4.939 mg/g） 〉 S. triqueter （0.620 mg/g） 〉 T. angustifolia （0.186 mg/g）. Observations indicated that the presence of riparian wetlands as buffers on and adjacent to stream banks could be recommended to control agricultural non-point pollution.

Discussion on the Green Tax Stimulation Measure of Nitrogen Fertilizer Non-Point Source Pollution Control-Taking the Dongting Lake Area in China as a Case

A study on designing the tax of nitrogen fertilizer can provide a new method for controlling nitrogen fertilizer non-point source pollution. The tax design of nitrogen fertilizer was discussed by utilizing the external theory and the demand elasticity theory. The results indicated that the coefficient of price elasticity of nitrogen fertilizer demand is -0.21, which instructed that the market demand is in lack of elasticity in the short period and the impact of nitrogen fertilizer manufacturers is subtle. The 11 counties （cities and boroughs） in the Dongting Lake area in China, where the farmland nitrogen application surpassed the average ecological fertilization dosage, is listed to the taxation scope of nitrogen fertilizer tax. The environment loss will reduce 0.07 hundred million RMB yuan and the revenue will increase 0.89 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The loss, which was brought by the decreasing food supplies production, will be 0.58 hundred million RMB yuan and the net social benefit will be 0.38 hundred million RMB yuan following revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.49%. The variation scope of the income of farmers will range from -8.41 to 6.44%. The 5 areas, Yunxi Borough, Junshan Borough, Hanshou County, Jinshi City, and Ziyang Borough, had an increase in food supplies production after the revenue collection. The environment loss will reduce 0.01 hundred million RMB yuan and the revenue will increase 0.16 hundred million RMB yuan in the country after levying on nitrogen fertilizer. The economic benefits, which was brought by the increasing cereals production, will be 0.67 hundred million RMB yuan and the net social benefit will be 0.84 hundred million RMB yuan after revenue collection. The variation scope of the increasing expenditure of farmers will range from 0.95 to 1.06%. The variation scope of the increasing income of farmers will range from 0.69 to 6.44%. Considering the entire social welfare, taxation of nitrogen fertilizer will have more advantages than disadvantages in the Dongting Lake area.

Controlling effects of forest belts on non-point source pollution of agricultural lands in Taihu Lake area, China

Taihu Lake area is one of the most developed areas in agricultural production. Application of fertilizers and pesticides in large quantities greatly aggravate environmental pollution of this area, and water pollution has worsened to an unbearable condition. Two sampling farms (respectively 1 hm2) under rape-rice rotation and wheat-rice rotation were selected as studied ecosystem and a 5-yr-old Poplar forest and 8-yr-old Metasequoia forest were chosen in the selected areas. By collecting samples of Nitrogen, Phosphorus in water, crops and underground of forest, the transfer and loss of N and P (main water pollutants) in faming ecosystem were studied, and the effects of forest belts on non-point source pollution of agricultural lands was analyzed. The results indicated that the transfer and loss of N and P vary with means of rotation, types of crops and the amount of fertilizer application. Buffering forest belts betweens farmlands and ditches can effectively stop and purify such elements as N and P in soil runoffs, thus controlling non-point source pollution of agricultural lands. When the width ratio of farmland to forest belt is 100 to 40, 50.05% losing N, 29.37% losing P can be absorbed by forest under rape-rice rotation and 30.98% N, 86.73% P can be absorbed by forest under wheat-rice rotation. When the width ratio of farmland to forest belt is 150 to 40, 33.37% losing N, 19.58% losing P can be absorbed by the forest under rape-rice rotation, and under wheat-rice rotation 20.65% lost N and 57.82% lost P can be absorbed. There is only some purification effect when the width ration of farmland to forest belt is 200 to 40. Based on model of buffering forest belts, the width ratio of farmland to forest is determined between 100 to 40 and 150 to 40, because it not only can purify water, but also occupy less farmland. It is suggested that Poplars, with the characteristics of fast-growing and high value, are suitable to be planted as shelter-forest in Taihu Lake Watershed.

Validation of an agricultural non-point source(AGNPS)pollution model for a catchment in the Jiulong River watershed,China

This study tested and evaluated the agricultural non-point source （AGNPS） model for the Wuchuan catchment, a typical agricultural area in the Jiulong River watershed, Fujian Province, China. The AGNPS model was calibrated and validated for the study area with observed data on ten storms. The data on eight storms in 2002 were used for calibration while data on two storms were used for validation of the model. Considering the lack of water quality data over a long-term series, a novel method, comparing an internal nested catchment with its surrounding catchment, was used to supplement the less long-term series data. Dual calibration and validation of the AGNPS model was obtained by this comparison. The results indicate that the correlation coefficients were 0.99 and 0.98 for runoff, 0.94 and 0.95 for the peak runoff rate of the large catchment and the small catchment, respectively, and 0.76 for the sediment of the small catchment only. Each pair of correlation coefficients is homogeneous for the same event for the two catchments. With the exception of the sediment yield and particulate phosphorus, the peak runoff rate and other nutrients were well predicted. Sensitivity analysis showed that the Soil Conservation Service curve number and rainfall quantity were the most sensitive parameters, which resulted in high output variations. Erosivity and other parameters had little influence on the hydrological and quality outputs.

Removal of Nitrogen, Phosphorus, and Organic Pollutants From Water Using Seeding Type Immobilized Microorganisms

Objective To study the possibility of removing nitrogen, phosphorus, and organic pollutants using seeding type immobilized microorganisms. Methods Lakes P and M in Wuhan were chosen as the objects to study the removal of nitrogen, phosphorus, and organic pollutants with the seeding type immobilized microorganisms. Correlations between the quantity of heterotrophic bacteria and the total nitrogen （TN）, total phosphorus （TP）, and total organic carbon （TOC） in the two lakes were studied. The dominant bacteria were detected, inoculated to the sludge and acclimated by increasing nitrogen, phosphorus and decreasing carbon source in an intermittent, time-controlled and fixed-quantity way. The bacteria were then used to prepare the seeding type immobilized microorganisms, selecting diatomite as the adsorbent cartier. The ability and influence factors of removing nitrogen, phosphorus, and organic pollutant from water samples by the seeding type immobilized microorganisms were studied. Results The coefficients of the heterotrophic bacterial quantity correlated with TOC, TP, and TN were 0.9143, 0.8229, 0.7954 in Lake P and 0.9168, 0.7187, 0.6022 in Lake M. Ten strains of dominant heterotrophic bacteria belonging to Pseudomonas, Coccus, Aeromonas, Bacillus, and Enterobateriaceae, separately, were isolated. The appropriate conditions for the seeding type immobilized microorgansims in purifying the water sample were exposure time=24 h, pH=7.0-8.0, and quantity of the immobilized microorganisms=0.75-1g/50 mL. The removal rates of TOC, TP, and TN under the above conditions were 80.2%, 81.6%, and 86.8%, respectively. Conclusion The amount of heterotrophic bacteria in the two lakes was correlated with TOC, TP, and TN. These bacteria could be acclimatized and prepared for the immobilized microorganisms which could effectively remove nitrogen, phosphorus, and mixed organic pollutants in the water sample.

Non-Point-Source Nitrogen and Phosphorus Loadings from a Small Watershed in the Three Gorges Reservoir Area

Non-point-source pollution has become a major threat to the water quality of the Three Gorges Reservoir(TGR);however,nutrient loadings from terrestrial sources are unclear due to a lack of in situ monitoring.A representative small watershed in the central part of the TGR area was selected to monitor the loss of nitrogen(N) and phosphorous(P) continuously along with the runoff from 2007 through 2009 to understand the exact sources and loadings.Results show that the non-point-source nitrogen and phosphorus comes mainly from the storm runoff from residential areas,citrus orchards and sloping croplands,which contributes up to 76% of the loadings in this watershed.Thus,a crucial measure for controlling non-point-source pollution is to intercept storm runoff from the three sources.Paddy fields provide a sink for non-point-source N and P by intercepting the runoff and sediment along with their different forms of nitrogen and phosphorus.The N and P removal efficiency by paddy fields from residential areas is within the range of 56% to 98%.Paddy fields are an important land-use option for reducing the non-point-source loading of N and P in the TGR area.

Characteristics of diffuse pollution of nitrogen and phosphorous from a small town in the hilly area of the central Sichuan Basin,China

Hydrological and hydro-chemical monitoring of nitrogen(N) and phosphorus(P) in a small urbanized catchment was conducted in the hilly area of the central Sichuan Basin,China,from 2010 through 2011.The diffuse N and P loadings in different forms of total nitrogen(TN) and phosphorus(TP),dissolved nitrogen(DN) and phosphorus(DP),as well as particulate nitrogen(PN) and phosphorus(PP) were calculated based on runoff discharges and chemical analyses.The results revealed that the diffuse pollution concentrations of TN,DN,PN,TP,DP and PP exhibited large variations during rainfall events,with peak concentrations occurring during the initial period.For all of the measured parameters,the event mean concentrations(EMCs) were observed to clearly vary among rainfall events.The EMCs of TN,DN,PN,TP,DP and PP(for all of the observed rainfall events) were 10.04,6.62,3.42,1.30,0.47 and0.83 mg/L,respectively.The losses of diffuse N and P exhibited clear seasonal patterns and mainly occurred during the period from July through September,when the losses totaled 99.3 and 9.6 kg/ha for TN and TP,respectively,accounting for 75% and 74% of the total annual loadings.The mean annual loadings of TN and TP were 124.6 and 12.9 kg/ha,respectively.The results indicate that residential areas in the hilly areaof the central Sichuan Basin are subject to high diffuse N and P loadings,posing a serious risk to the receiving water quality.Ecological buffering belts are recommended to incorporate into the urbanized catchment to reduce diffuse pollution.

Distributed Simulation of Non-Point Source Pollution in Ashi River Basin

In order to get a thorough understanding of non-point source pollution,it is essential to examine its temporal and spatial distribution. A physically-based distributed model,Soil and Water Assessment Tool( SWAT),was used in this research,to quantitatively estimate the NPS load and analyze the temporal and spatial distributions of NPS pollution in Ashi River Basin. The results indicated that SWAT was suitable to simulate stream-flow and water quality in Ashi River Basin. Total Nitrogen which was contributed by NPS( NPS-TN) accounted for 32. 47%-62. 61%,and Total Phosphorus which was contributed by NPS( NPS-TP)accounted for 22. 30%- 57. 85% of the total load respectively. In inter-annual timescale,both NPS-TN and NPS-TP were influenced by stream-flow and fertilizer. However,when compared with fertilizer,NPS pollution was more directly affected by stream-flow. In annual timescale,NPS-TN and NPS-TP mainly occurred in flood season( from May to September). In the aspect of space,spatial differences of NPS-TN and NPS-TP were extremely significant. The spatial variations of NPS pollution were mainly influenced by land use,precipitation,soil and slope.

Spatio-Temporal Distribution of Agricultural Non-Point Source Pollution in Binzhou City Based on Large Computer Data

Based on the relevant statistics on the agricultural non-point source pollution in Binzhou City,we studied the spatio-temporal variation in agricultural non-point source nitrogen pollution and phosphorus pollution in Binzhou City during 2008-2015. The results showed that the agricultural non-point source nitrogen pollution and phosphorus pollution in Binzhou City changed from 114400 t and 28800 t in 2008 to110600 t and 24400 t in 2015,respectively; for the non-point source nitrogen pollution sources,the proportion of chemical fertilizer,manure and domestic sewage changed from 80. 41%,10. 47% and 9. 13% in 2008 to 82. 94%,4. 77% and 12. 29% in 2015,respectively; for the non-point source phosphorus pollution sources,the proportion of chemical fertilizer,manure and domestic sewage changed from 89. 29%,8. 32% and 2. 39% in 2008 to 91. 6%,4. 78% and 3. 62% in 2015,respectively; in 2015,the non-point source nitrogen pollution was most serious in Wudi County and Huimin County and least serious in Zhanhua County; the non-point source phosphorus pollution was most serious in Zouping County and least serious in Wudi County.

Nitrogen forms and pollution load of Dianchi Lake inflow river runoff in rainy season

With the control of point source pollution in Dianchi Lake basin, and the expansion of Kunming city, non-point source pollution has become the main source pollution of urban water environment and Dianchi Lake. To reveal the nitrogen pollution characteristics in watershed, this research selected key monitoring points and sections at Baoxiang river basin in rainy season which is the peak transported time of non-point source pollution, the nitrogen and hydrological indicators are monitored systematically. The different forms of nitrogen are analyzed, the pollution load of nitrogen are calculated and studied at cardinal sections; combined with the literature data, we compared the water nitrogen characteristics of Dianchi basin and Taihu basin, the main results are as follows:(1) In summer, water nitrogen form of Baoxiang river in the Caohe area is dominated by nitrate nitrogen, while in other areas it is dominated by ammonia nitrogen which is accounted for 31%-50% of total nitrogen;(2) The water pollution loads of Baoxiang river tended to increase from upstream to downstream, from June to August the total nitrogen pollution mainly comes from urban areas and the pollution load is 166.408 t;(3) In Dianchi Lake watershed and Taihu Lake watershed nitrogen concentration of inflow river is higher than that of the lake, nitrate nitrogen concentration between inflow river and lake shows a little difference, while ammonia nitrogen concentration of inflow river is higher than that of the lake. The results can provide the theoretical basis for nonpoint source pollution control and urban water environment planning and improvement in Dianchi Lake Basin.

Research on the Non-Point Pollution Loads in the Lake Uluabat Basin

Lake Uluabat, having an international significance and subject to the Ramsar Convention, is fed by the basin of Mustafakemalpasa Stream which runs through fertile lands utilized for livestock breeding and agriculture. In this study, total amount of nitrogen (TN) and phosphorus (TP) loads of non-point pollutants (agriculture, livestock breeding, vegetation, surface runoff and small settlements) was calculated. It was found out that most intensive pollution load stemmed from livestock breeding which causes dispersion of 13653.57 tons·year-1 of TN and 3224.45 tons·year-1 of TP into the Lake Uluabat. Additionally, seasonal changes in concentration of TN and TP were observed during the period of 2008-2009 in Lake Uluabat. It was concluded that the rise of agricultural activities in summer months was the reason underlying the increase in pollution during the months in question.

The land-sourced pollution in the Jiaozhou Bay

In recent years, natural environment of the Jiaozhou Bay has been changed largely by fast developing industry and agriculture of the cities around, from which wastewaters were generated. The size of the bay has been continuously shrunk with reduced river flows, resulting in serious contamination to the marine lives in the bay. After analyzing the basic historical data, the authors put forward a suggestion of how to protect the bay ecology for sustaining the resources in the Jiaozhou Bay.

Nitrogen and Phosphorus Loss Law and Emission Reduction Effects Under Water and Fertilizer Management Integrated Mode in Dike Paddy Field

To achieve the purpose of reducing farm non-point source pollution, we integrated site specific nitrogen management precise irrigation, controlled drainage, and wetland eco-repair system in dike area of Taihu basin. During investigation, it had given prominence for the water and fertilizer coupling effects of precise irrigation and site specific nutrient management, the characteristics of integration on controlled irrigation, controlled drainage and wetland ecosystem non-point source pollution control. Then the water and fertilizer integrated management mode of paddy field was put forward in Taihu basin where the water production efficiency increased to 1.64 kg. m-3, water saved 37.8%, fertilizer use efficiency raised 15,4%, yield raised 10%, and N, P load decreased 26%-72%. The modern agricultural and farmland ecosystems that control and cut down the farm non-point source pollution came into being, which can be a reference by Taihu basin to control its agricultural non-point source pollution and eutrophicated water body.

Reactive Stream Stabilization for Minimizing Transport of Phosphorus and Nitrogen from Agricultural Landscapes

A reactive stream stabilization (RS2) system based on aluminum as the adsorbent and garden mulch as the organic matter source was designed to minimize release of agricultural nonpoint source pollutants and installed along the bank of the Little Bogue Creek, MS in 2008. The scope of this research was to design, install and assess the performance of a field scale RS2 structure based on results from previous lab scale studies. Concentrations of alum and total organic carbon (TOC) in the RS2 test barrier and surrounding area were measured to evaluate design parameters of RS2 and the removal effectiveness was examined from soils and monitoring wells that were sampled in 2009. The mean concentration of Al from the reactive barrier was 2.1 mg/g and organic matter from the monitoring wells was 4.7 mg/L, values significantly greater than the surrounding area (p < 0.05). Soil Mehlich-3 P and total phosphorus (TP) were decreased by 55% and 30%, and 40% of the TN and 51% of the nitrate in the ground water were removed through the RS2. The design objectives have been satisfied with the installed RS2 system and the initial sampling data shows effective nutrient removal.

Opportunity and shift of nitrogen use in China

It is never an easy task for China to feed 1.4 billion people with only 7%of the world's arable land.With nearly 30%of the world's nitrogen(N)fertilizer applied,China achieves high crop yields while facing N pollution result-ing from excessive N input.Here,we calculate the farmland N budget on the national and regional scales.The N use efficiency(NUE)in China increased by 28.0%during 2005-2018.This improvement is due to the reduction in fertilization and the improvement of crop management.The fragmented farmland is changing to large-scale farmland with the increase in cultivated land area per rural population and the development of agricultural mech-anization.This opportunity brings more possibilities for precision farmland management,thus further improving NUE.The goal of an NUE of 0.6 may be achieved in the 2040s based on the current development trend.This striking N use shift in China has important implications for other developing countries.

Nutrient Loss from Farmland:Research on and Application of Phosphorus Index Method

Phosphorus index method is an effective method to assess the risk of phosphorus loss,identify the critical source areas and reasonably control the agricultural non-point source pollution.The researches on phosphorus index assessment method have been started earlier in foreign countries.Currently,phosphorus index assessment method has been widely used in the United States and European countries through continuous development and improvement.However,the domestic research on non-point source phosphorus pollution assessment has just started,and the phosphorus index method that is suitable for the characteristics of agriculture in China has not yet been established.This paper summarizes and analyzes systematically the related research advances in phosphorus index method at home and abroad,and illustrates the issues presented in phosphorus index method.In addition,the researches on and application of phosphorus index method in China are discussed.

Seasonal variation of nitrogen-concentration in the surface water and its relationship with land use in a catchment of northern China

Surface waters can be contaminated by human activities in two ways: (1) by point sources, such as sewage treatment discharge and storm-water runoff; and (2) by non-point sources, such as runoff from urban and agricultural areas. With point-source pollution effectively controlled, non-point source pollution has become the most important environmental concern in the world. The formation of non-point source pollution is related to both the sources such as soil nutrient, the amount of fertilizer and pesticide applied, the amount of refuse, and the spatial complex combination of land uses within a heterogeneous landscape. Land-use change, dominated by human activities, has a significant impact on water resources and quality. In this study, fifteen surface water monitoring points in the Yuqiao Reservoir Basin, Zunhua, Hebei Province, northern China, were chosen to study the seasonal variation of nitrogen concentration in the surface water. Water samples were collected in low-flow period(June), high-flow period(July) and mean-flow period(October) from 1999 to 2000. The results indicated that the seasonal variation of nitrogen concentration in the surface water among the fifteen monitoring points in the rainfall-rich year is more complex than that in the rainfall-deficit year. It was found that the land use, the characteristics of the surface river system, rainfall, and human activities play an important role in the seasonal variation of N-concentration in surface water.

Mechanism of nitrogen loss driven by soil and water erosion in water source areas

Nitrogen(N)present in drinking water as dissolved nitrates can directly affect people’s health,making it important to control N pollution in water source areas.N pollution caused by agricultural fertilizers can be controlled by reducing the amount of fertilizer applied,but pollution caused by soil and water erosion in hilly areas can only be controlled by conservation forests.The catchment area around Fushi Reservoir was selected as a test site and mechanisms of N loss from a vertical spatial perspective through field observations were determined.The main N losses occurred from June to September,accounting for 85.9-95.9%of the annual loss,with the losses in June and July accounting for 46.0%of the total,and in August and September for 41.9%.The N leakage from the water source area was effectively reduced by 38.2%through the optimization of the stand structure of the conservation forests.Establishing well-structured forests for water conservation is crucial to ensure the security of drinking water.This preliminary research lays the foundation for revealing then loss mechanisms in water source areas and improving the control of non-point source pollution in these areas.

Agricultural Phosphorus Management for Environmental Protection: A Review

This review addresses research done over the past 40 years on different aspects of agricultural phosphorus (P) management for environmental protection. Inputs of P are essential for profitable crop production. Long-term application of P to agricultural soils has resulted in elevated levels of soil P. This accumulation may be desirable from an agronomic point of view but it represents a threat to freshwater quality. Indeed, P in runoff from agricultural land is an important component of non-point source pollution and can accelerate eutrophication of lakes and streams. Even very small amounts of P can raise the concentration above the critical value for eutrophication. Excessive eutrophication restricts water use for recreation, industry, and drinking due to the increased growth of undesirable algae and aquatic weeds. Current concerns facing the environmentally sound management of P in agriculture are similar worldwide and revolve around agricultural, economic, and environmental compromises associated with balancing productivity with environmental values. Agricultural P management strategies should be geared towards ensuring that P, a finite earth resource, is not wasted and those soils do not become so enriched with P that there is an unnecessary risk of too much P being mobilized to water from agricultural fields. Approaches, such as soil P testing and either P models or indices have been studied and implemented to mitigate agricultural P losses. Apparently, P indices are preferred instead of P models for this purpose because they are more flexible. A holistic management strategy is therefore suggested by using soil P testing in conjunction with either a P index or a P model.