Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two m...Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two metastable states (N2 (A3 ∑ u+), N2 (a1 ∑ u)) are taken into account. The model includes the particle continuity equation, the electron energy balance equation, and Poisson抯iequation. The model ’s solved with a finite difference method. The numerical results are obtained and used to investigate the effect of time taken to add nitrogen gas and initially-induced argon plasma pressure. It is found that lower speeds of adding the nitrogen gas and varying the gas pressure can induce higher plasma density, and inversely lower electron temperature. At high-pressure discharge, the electron density increases when the proportion of nitrogen component is below 4070, while the electron density will keep constant as the nitrogen component further increases. It is also shown that with the increase of initially-induced argon plasma pressure, the density of charged particles increases~ and the electron temperature as well as the electric field decreases.展开更多
Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two meta...Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two metastable states (N 2(A3∑u+), N2 (a1 ∑u-)) are taken into account. The model includes the particle continuity equation, the electron energy balance equation, and Poisson抯equation. The model is solved with a finite difference method. The numerical results are obtained and used to investigate the effect of time taken to add nitrogen gas and initially-induced argon plasma pressure. It is found that lower speeds of adding the nitrogen gas and varying the gas pressure can induce higher plasma density, and inversely lower electron temperature. At high-pressure discharge, the electron density increases when the proportion of nitrogen component is below 40%, while the electron density will keep constant as the nitrogen component further increases. It is also shown that with the increase of initially-induced argon plasma pressure, the density of charged particles increases, and the electron temperature as well as the electric field decreases.展开更多
Optical emission spectroscopy in nitrogen glow discharge plasma is simulated, and the collision excitations and characteristic emissions of the species (N2, N2^+, N^+, N) are investigated by a Monte Carlo model fo...Optical emission spectroscopy in nitrogen glow discharge plasma is simulated, and the collision excitations and characteristic emissions of the species (N2, N2^+, N^+, N) are investigated by a Monte Carlo model for nitrogen molecular gas discharge. The excitation rates of the main excited states are calculated and the corresponding relation and relative magnitude between the distribution of excitation rate of a certain excited state and the distributions of the emission rates of various lines originating from this excited level are also explored. The simulated results are compared with the experimental measurements in two typical discharge conditions. The luminescence mechanism of the line N2^+: 391.4 nm is explained based on the microscopic plasma processes. The cathode glow in N2 discharge is found to be mainly caused by N^+ impact excitation and the intensity of cathode glow decreases with the voltage. The corresponding relation between the emission rate or intensity of the 391.4 nm line and the production rate and the density of N2^+ is also examined.展开更多
Using a combination of the Monte Carlo models of fast electrons, of molecular ions (N+) and of atomic species (N^+, Nf), the influence of the discharge pressure (P) and voltage (Vc) on the energy distributio...Using a combination of the Monte Carlo models of fast electrons, of molecular ions (N+) and of atomic species (N^+, Nf), the influence of the discharge pressure (P) and voltage (Vc) on the energy distributions of fast atomic species (N^+, Nf) produced by e^--N2s and N2^+- N2s dissociation reactions at the cathode in a nitrogen dc glow discharge was investigated. Both the angular distributions and the density distributions along the radius of the species (N^+, Nf) produced by the two dissociations at the cathode were calculated. The results show that: (1) there is an optimum discharge condition for P and Vc in order to obtain the species (N^+, Nf) at the cathode with high a density and energy, (2) when the voltage is above 800 V, the species (N^+, Nf) bombarding the cathode are mainly produced by the N^+-N2s dissociation, whereas when the voltage is below 300 V, they are mainly produced by the e-N2s dissociation, and (3) at high Voltages the incident angles of a considerable number of Nf into the cathode are quite small. The density of the species (N^+ Nf) at the cathode increases with the voltage, and when the pressure goes up to about 133 Pa, it decreases with the increasing pressure.展开更多
To analyze the effect of agricultural activity on nitrogen(N) budget at the watershed scale,a comparative study was conducted at two Japanese watersheds,the Shibetsu River watershed(SRW) and Upper-Naka River watershed...To analyze the effect of agricultural activity on nitrogen(N) budget at the watershed scale,a comparative study was conducted at two Japanese watersheds,the Shibetsu River watershed(SRW) and Upper-Naka River watershed(UNRW),and one Chinese watershed,the Jurong Reservoir watershed(JRW).The total area and the proportion of agricultural area(in parentheses) of the watersheds were 685(51%),1 299(21%),and 46 km 2(55%) for SRW,UNRW,and JRW,respectively.The main agricultural land use in SRW was forage grassland,while paddy fields occupied the highest proportion of cropland in UNRW(11% of total area) and JRW(31% of total area).The farmland surplus N was 61,48,and 205 kg N ha 1 year 1 for SRW,UNRW,and JRW,respectively.The total input and output for the whole watershed were 89 and 76,83 and 61,and 353 and 176 kg N ha 1 year 1 for SRW,UNRW,and JRW,respectively.The proportion of discharged N to net anthropogenic N input was 31%,37%,and 1.7% for SRW,UNRW,and JRW,respectively.The two watersheds in Japan showed similar proportions of discharged N to those of previous reports,while the watershed in China(JRW) showed a totally different characteristic compared to previous studies.The high N input in JRW did not increase the amount of discharged N at the outlet of the watershed due to high proportions of paddy fields and water bodies,which was an underestimated N sink at the landscape scale.展开更多
基金Project supported by the National Science Foundation of China (Grant No. 10675029)the National Basic Research Program of China (Grant Nos. 2008CB717801, 2008CB787103, 2009GB105004, and 2010GB106002)FRFCU (Grant No. DUT12ZD201)
文摘Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two metastable states (N2 (A3 ∑ u+), N2 (a1 ∑ u)) are taken into account. The model includes the particle continuity equation, the electron energy balance equation, and Poisson抯iequation. The model ’s solved with a finite difference method. The numerical results are obtained and used to investigate the effect of time taken to add nitrogen gas and initially-induced argon plasma pressure. It is found that lower speeds of adding the nitrogen gas and varying the gas pressure can induce higher plasma density, and inversely lower electron temperature. At high-pressure discharge, the electron density increases when the proportion of nitrogen component is below 4070, while the electron density will keep constant as the nitrogen component further increases. It is also shown that with the increase of initially-induced argon plasma pressure, the density of charged particles increases~ and the electron temperature as well as the electric field decreases.
基金Project supported by the National Science Foundation of China (Grant No. 10675029)the National Basic Research Program of China (Grant Nos. 2008CB717801, 2008CB787103, 2009GB105004, and 2010GB106002)FRFCU (Grant No. DUT12ZD201)
文摘Based on the fluid theory of plasma, a model is built to study the characteristics of nitrogen discharge at high pressure with induced argon plasma. In the model, species such as electrons, N2+, N4+, Ar+, and two metastable states (N 2(A3∑u+), N2 (a1 ∑u-)) are taken into account. The model includes the particle continuity equation, the electron energy balance equation, and Poisson抯equation. The model is solved with a finite difference method. The numerical results are obtained and used to investigate the effect of time taken to add nitrogen gas and initially-induced argon plasma pressure. It is found that lower speeds of adding the nitrogen gas and varying the gas pressure can induce higher plasma density, and inversely lower electron temperature. At high-pressure discharge, the electron density increases when the proportion of nitrogen component is below 40%, while the electron density will keep constant as the nitrogen component further increases. It is also shown that with the increase of initially-induced argon plasma pressure, the density of charged particles increases, and the electron temperature as well as the electric field decreases.
基金Natural Science Foundation of Hebei Province of China(Nos.A2006000123,F2006000183)
文摘Optical emission spectroscopy in nitrogen glow discharge plasma is simulated, and the collision excitations and characteristic emissions of the species (N2, N2^+, N^+, N) are investigated by a Monte Carlo model for nitrogen molecular gas discharge. The excitation rates of the main excited states are calculated and the corresponding relation and relative magnitude between the distribution of excitation rate of a certain excited state and the distributions of the emission rates of various lines originating from this excited level are also explored. The simulated results are compared with the experimental measurements in two typical discharge conditions. The luminescence mechanism of the line N2^+: 391.4 nm is explained based on the microscopic plasma processes. The cathode glow in N2 discharge is found to be mainly caused by N^+ impact excitation and the intensity of cathode glow decreases with the voltage. The corresponding relation between the emission rate or intensity of the 391.4 nm line and the production rate and the density of N2^+ is also examined.
基金supported by the Natural Science Foundation of Hebei Province,China(No.A2006000123)
文摘Using a combination of the Monte Carlo models of fast electrons, of molecular ions (N+) and of atomic species (N^+, Nf), the influence of the discharge pressure (P) and voltage (Vc) on the energy distributions of fast atomic species (N^+, Nf) produced by e^--N2s and N2^+- N2s dissociation reactions at the cathode in a nitrogen dc glow discharge was investigated. Both the angular distributions and the density distributions along the radius of the species (N^+, Nf) produced by the two dissociations at the cathode were calculated. The results show that: (1) there is an optimum discharge condition for P and Vc in order to obtain the species (N^+, Nf) at the cathode with high a density and energy, (2) when the voltage is above 800 V, the species (N^+, Nf) bombarding the cathode are mainly produced by the N^+-N2s dissociation, whereas when the voltage is below 300 V, they are mainly produced by the e-N2s dissociation, and (3) at high Voltages the incident angles of a considerable number of Nf into the cathode are quite small. The density of the species (N^+ Nf) at the cathode increases with the voltage, and when the pressure goes up to about 133 Pa, it decreases with the increasing pressure.
基金Supported by the Strategic International Cooperative Program "Comparative Study of Nitrogen Cycling and Its Impact on Water Quality in Agricultural Watersheds in Japan and China" by the Japan Science and Technology Agency and the National Natural Science Foundation of China(No.41071196)
文摘To analyze the effect of agricultural activity on nitrogen(N) budget at the watershed scale,a comparative study was conducted at two Japanese watersheds,the Shibetsu River watershed(SRW) and Upper-Naka River watershed(UNRW),and one Chinese watershed,the Jurong Reservoir watershed(JRW).The total area and the proportion of agricultural area(in parentheses) of the watersheds were 685(51%),1 299(21%),and 46 km 2(55%) for SRW,UNRW,and JRW,respectively.The main agricultural land use in SRW was forage grassland,while paddy fields occupied the highest proportion of cropland in UNRW(11% of total area) and JRW(31% of total area).The farmland surplus N was 61,48,and 205 kg N ha 1 year 1 for SRW,UNRW,and JRW,respectively.The total input and output for the whole watershed were 89 and 76,83 and 61,and 353 and 176 kg N ha 1 year 1 for SRW,UNRW,and JRW,respectively.The proportion of discharged N to net anthropogenic N input was 31%,37%,and 1.7% for SRW,UNRW,and JRW,respectively.The two watersheds in Japan showed similar proportions of discharged N to those of previous reports,while the watershed in China(JRW) showed a totally different characteristic compared to previous studies.The high N input in JRW did not increase the amount of discharged N at the outlet of the watershed due to high proportions of paddy fields and water bodies,which was an underestimated N sink at the landscape scale.