The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer products.Here,...The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer products.Here,based on the potential crystallization principle of calcium sulfate in NH_(4)NO_(3)-H_(3)PO_(4)-H_(2)O,the deep decalcification(i.e.calcium removal)technology to achieveα-high-strength gypsum originated from freezing acidolysis-solutions has been firstly proposed and investigated.Typically,calcium can be removed from the factory-provided freezing acidolysis-solution by neutralizing it with ammonia,followed by the addition of ammonium sulfate solution.As a result,the formation of calcium sulfate in the reaction system undergoes the nucleation and growth of CaSO_(4)·2H_(2)O(DH),as well as its dissolution and crystallization into short columnarα-CaSO_(4)·0.5H_(2)O(α-HH).Remarkably,with the molar ratio of SO_(4)^(2-)/Ca^(2+)at 1.8,the degree of neutralization(NH_(3)/HNO_(3) molar ratio)at 1.7,the reaction temperature of 94℃,and the reaction time of 300 min,the decalcification rate can reach 86.89%,of which the high-strengthα-CaSO_(4)·0.5H_(2)O(α-HH)will be obtained.Noteworthy,the deep decalcification product meets the standards for the production of fine phosphates and highly water-soluble phosphate fertilizers.Consequently,the 2 h flexural strength ofα-HH is 5.3 MPa and the dry compressive strength is 36.8 MPa,which is up to the standard of commercialα-HH.展开更多
Field experiments were undertaken on sandy soils with three cropping systems at Giridih,Jharkhand,India for two years during 2012-2014.The experiments were executed in split plot design by assigning water soluble phos...Field experiments were undertaken on sandy soils with three cropping systems at Giridih,Jharkhand,India for two years during 2012-2014.The experiments were executed in split plot design by assigning water soluble phosphorus(WSP)fertilizers in main-plot and recommended dose of phosphorus(RDP)in sub-plot with three replications.The maximum economical yield of rice(4705 kg/ha),baby corn(842 kg/ha)and Chickpea(920 kg/ha)were recorded with the application of 30%WSP.The maximum economical yield of successive crops-wheat(3185 kg/ha),mustard(1720 kg/ha)and groundnut(1578 kg/ha)were recorded with the application of 30%WSP and 100%RDP treatment.Almost similar trends were noticed in terms of by-product yield,nutrient uptake and residual soil fertility status.All the levels of WSP(30%-89%)in complex fertilizers were found to be equally effective for grain yield,straw yield,nutrient uptake,and residual soil fertility.展开更多
基金supported by the National Key Research and Development Program of China(2018YFC1900206-2)Science&Technology Plan Projects of Guizhou Province(Qiankehe Service Enterprises[2018]4011)Science and Technology Support Plan Project of Guizhou Provincial:Qiankehe Support[2021]General 487。
文摘The freezing acidolysis solution of the nitric acid-phosphate fertilizer process has a high calcium content,which makes it difficult to produce fine phosphate and high water-soluble phosphate fertilizer products.Here,based on the potential crystallization principle of calcium sulfate in NH_(4)NO_(3)-H_(3)PO_(4)-H_(2)O,the deep decalcification(i.e.calcium removal)technology to achieveα-high-strength gypsum originated from freezing acidolysis-solutions has been firstly proposed and investigated.Typically,calcium can be removed from the factory-provided freezing acidolysis-solution by neutralizing it with ammonia,followed by the addition of ammonium sulfate solution.As a result,the formation of calcium sulfate in the reaction system undergoes the nucleation and growth of CaSO_(4)·2H_(2)O(DH),as well as its dissolution and crystallization into short columnarα-CaSO_(4)·0.5H_(2)O(α-HH).Remarkably,with the molar ratio of SO_(4)^(2-)/Ca^(2+)at 1.8,the degree of neutralization(NH_(3)/HNO_(3) molar ratio)at 1.7,the reaction temperature of 94℃,and the reaction time of 300 min,the decalcification rate can reach 86.89%,of which the high-strengthα-CaSO_(4)·0.5H_(2)O(α-HH)will be obtained.Noteworthy,the deep decalcification product meets the standards for the production of fine phosphates and highly water-soluble phosphate fertilizers.Consequently,the 2 h flexural strength ofα-HH is 5.3 MPa and the dry compressive strength is 36.8 MPa,which is up to the standard of commercialα-HH.
文摘Field experiments were undertaken on sandy soils with three cropping systems at Giridih,Jharkhand,India for two years during 2012-2014.The experiments were executed in split plot design by assigning water soluble phosphorus(WSP)fertilizers in main-plot and recommended dose of phosphorus(RDP)in sub-plot with three replications.The maximum economical yield of rice(4705 kg/ha),baby corn(842 kg/ha)and Chickpea(920 kg/ha)were recorded with the application of 30%WSP.The maximum economical yield of successive crops-wheat(3185 kg/ha),mustard(1720 kg/ha)and groundnut(1578 kg/ha)were recorded with the application of 30%WSP and 100%RDP treatment.Almost similar trends were noticed in terms of by-product yield,nutrient uptake and residual soil fertility status.All the levels of WSP(30%-89%)in complex fertilizers were found to be equally effective for grain yield,straw yield,nutrient uptake,and residual soil fertility.
