A novel diamagnetic-metal Cd（Ⅱ） complex with four nitroxide radicals[Cd（IM4Py）4Cl2]（IM4Py=2-（4＇-pyridinyl）-4,4,5,5-tetramethylimidazoline-1-oxyl） was synthesized and characterized by elemental analyses,IR sp...A novel diamagnetic-metal Cd（Ⅱ） complex with four nitroxide radicals[Cd（IM4Py）4Cl2]（IM4Py=2-（4＇-pyridinyl）-4,4,5,5-tetramethylimidazoline-1-oxyl） was synthesized and characterized by elemental analyses,IR spectra,UV-Vis spectra and X-ray single crystal diffraction.The complex crystallized in triclinic space group P1 with a=0.93285（14） nm,b=1.16827（18） nm,c=1.3660（2） nm,α=112.759（2）°,β=104.524（2）°,γ=92.008（3）°,V= 1.3143（3） nm3,Z=1,Dc=1.335 g/cm3,the final R1=0.0423 and wR2=0.1009.In the title complex,each Cd（Ⅱ） ion adopting a distorted octahedral geometry is coordinated by two Cl-anions and four pyridyl-N atoms from four IM4Py ligands.The magnetic measurements show the weak antiferromagnetic interactions between the nitroxide radicals.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.20901059 and 20771083)
文摘A novel diamagnetic-metal Cd（Ⅱ） complex with four nitroxide radicals[Cd（IM4Py）4Cl2]（IM4Py=2-（4＇-pyridinyl）-4,4,5,5-tetramethylimidazoline-1-oxyl） was synthesized and characterized by elemental analyses,IR spectra,UV-Vis spectra and X-ray single crystal diffraction.The complex crystallized in triclinic space group P1 with a=0.93285（14） nm,b=1.16827（18） nm,c=1.3660（2） nm,α=112.759（2）°,β=104.524（2）°,γ=92.008（3）°,V= 1.3143（3） nm3,Z=1,Dc=1.335 g/cm3,the final R1=0.0423 and wR2=0.1009.In the title complex,each Cd（Ⅱ） ion adopting a distorted octahedral geometry is coordinated by two Cl-anions and four pyridyl-N atoms from four IM4Py ligands.The magnetic measurements show the weak antiferromagnetic interactions between the nitroxide radicals.
