Fluid-Related Performances and Compressive Strength of Clinker-Free Cementitious Backfill Material Based on Phosphate Tailings

Phosphate tailings are usually used as backfill material in order to recycle tailings resources.This study considers the effect of the mix proportions of clinker-free binders on the fluidity,compressive strength and other key performances of cementitious backfill materials based on phosphate tailings.In particular,three solid wastes,phosphogypsum(PG),semi-aqueous phosphogypsum(HPG)and calcium carbide slag(CS),were selected to activate wet ground granulated blast furnace slag(WGGBS)and three different phosphate tailings backfill materials were prepared.Fluidity,rheology,settling ratio,compressive strength,water resistance and ion leaching behavior of backfill materials were determined.According to the results,when either PG or HPG is used as the sole activator,the fluidity properties of the materials are enhanced.Phosphate tailings backfill material activated with PG present the largest fluidity and the lowest yield stress.Furthermore,the backfill material’s compressive strength is considerably increased to 2.9 MPa at 28 days after WGGBS activation using a mix of HPG and CS,all with a settling ratio of only 1.15 percent.Additionally,all the three ratios of binder have obvious solidification effects on heavy metal ions Cu and Zn,and P in phosphate tailings.

Enhancing fly ash utilization in backfill materials treated with CO_(2)carbonation under ambient conditions

The environmental concerns resulting from coal-fired power generation that produces large amounts of CO_(2)and fly ash are of great interest.To mitigate,this study aims to develop a novel carbonated CO_(2)-fly ash-based backfill(CFBF)material under ambient conditions.The performance of CFBF was investigated for different fly ash-cement ratios and compared with non-CO_(2)reacted samples.The fresh CFBF slurry conformed to the Herschel-Bulkley model with shear thinning characteristics.After carbonation,the yield stress of the fresh slurry increased significantly by lowering fly ash ratio due to gel formation.The setting times were accelerated,resulting in approximately 40.6%of increased early strength.The final strength decreased when incorporating a lower fly ash ratio(50%and 60%),which was related to the existing heterogeneous pores caused by rapid fluid loss.The strength increased with fly ash content above 70%because additional C-S(A)-H and silica gels were characterized to precipitate on the grain surface,so the binding between particles increased.The C-S(A)-H gel was developed through the pozzolanic reaction,where CaCO_(3)was the prerequisite calcium source obtained in the CO_(2)-fly ash reaction.Furthermore,the maximum CO_(2)uptake efficiency was 1.39 mg-CO_(2)/g-CFBF.The CFBF material is feasible to co-dispose CO_(2)and fly ash in the mine goaf as negative carbon backfill materials,and simultaneously mitigates the strata movement and water lost in post-subsurface mining.

Experimental study on thermal and mechanical properties of tailings-based cemented paste backfill with CaCl_(2)·6H_(2)O/expanded vermiculite shape stabilized phase change materials

CaCl_(2)·6H_(2)O/expanded vermiculite shape stabilized phase change materials(CEV)was prepared by atmospheric impregnation method.Using gold mine tailings as aggregate of cemented paste backfill(CPB)material,the CPB with CEV added was prepared,and the specific heat capacity,thermal conductivity,and uniaxial compressive strength(UCS)of CPB with different cement-tailing ratios and CEV addition ratios were tested,the influence of the above variables on the thermal and mechanical properties of CPB was analyzed.The results show that the maximum encapsulation capacity of expanded vermiculite for CaCl_(2)·6H_(2)O is about 60%,and the melting and solidification enthalpies of CEV can reach 98.87 J/g and 97.56 J/g,respectively.For the CPB without CEV,the specific heat capacity,thermal conductivity,and UCS decrease with the decrease of cement-tailing ratio.For the CPB with CEV added,with the increase of CEV addition ratio,the specific heat capacity increases significantly,and the sensible heat storage capacity and latent heat storage capacity can be increased by at least 10.74%and 218.97%respectively after adding 12%CEV.However,the addition of CEV leads to the increase of pores,and the thermal conductivity and UCS both decrease with the increase of CEV addition.When cement-tailing ratio is 1:8 and 6%,9%,and 12%of CEV are added,the 28-days UCS of CPB is less than 1 MPa.Considering the heat storage capacity and cost price of backfill,the recommended proportion scheme of CPB material presents cement-tailing ratio of 1:6 and 12%CEV,and the most recommended heat storage/release temperature cycle range of CPB with added CEV is from 20 to 40℃.This work can provide theoretical basis for the utilization of heat storage backfill in green mines.

Improvement of Cemented Gangue Backfill Material with Barium Hydroxide in Acid Mine Water

As a kind of green concrete,the mechanical properties and durability of cemented gangue backfill material(CGBM)will be affected if they are in acid mine water with sulfate ions in the long term.To improve the performance of CGBM in acid mine water with sulfate ions,CGBM specimens with different doses of barium hydroxide were immersed in sulfuric acid solutions of different concentrations for 270 days.The changes of mass,ultrasonic pulse velocity(UPV)and compressive strength of the specimens at different ages were analyzed.Scanning electron microscopy(SEM)and X-ray diffraction(XRD)were used to analyze the microstructure and composition of the specimens.The results show that incorporation of barium hydroxide into CGBM specimen can promote the formation of barium sulfate precipitation and inhibit the generation of corrosion products such as ettringite.Meanwhile,barium sulfate precipitation blocks the pore channel invaded by sulfuric acid solution,delaying the progress of corrosion reaction and making the interior of CGBM specimen more complete.And the specimen with 2.0 kg/m^(3)barium hydroxide was more effective in improving performance.This study provides a basis for the ratio design of CGBM in acid mine water with sulfate ions.

CO2 sequestration characteristics in the cementitious material based on gangue backfilling mining method

The increasing anthropogenic CO2 emission and global warming has challenged the China and other countries to seek new and better ways to meet the world’s increasing need for energy while reducing greenhouse gas emissions.The overall proposition of this research is to develop a brand-new CO2 physical and chemical sequestration method by using solid waste of coal mining and cementitious material which are widely used for goaf backfilling in coal mining.This research developed a new testing system(constant temperature pressurized reaction chamber(CTPRC))to study the effects of different initial parameters on mineral carbonation such as different initial water-binder ratio,initial sample porosity and initial carbon dioxide pressure.The experimental results show that the CO2 consumption ratio is 15%,10%and 7%higher with relatively high initial water-binder ratio,initial sample porosity and initial CO2 pressure within 48 h.In addition,some physical and chemical evidence was found through the electron microscope scanning and XRD test to further explain the above test results.This proposed research will provide critical parameters for optimizing CO2 sequestration capacity in this cementitious backfilling material with forming agent.

Mass ratio design based on compaction properties of backfill materials

The backfill-mining mass ratio is the ratio of the mass of the backfill materials in the goaf to the mass of the produced raw coal during solid backfill mining and it is regarded as a direct control index of the backfill effect in solid backfill mining. To design the backfill-mining mass ratio in a solid backfill mining panel, the backfill-mining mass ratio was defined on the basis of the basic principle of solid backfill mining. In addition, the density-stress relationship of backfill materials under compaction was obtained for five types of materials to derive a design formula for backfill-mining mass ratio. Moreover, the 6304-1 backfill panel under the large-scale dam of Ji′ning No. 3 coal mine was taken as an engineering case to design the backfill-mining mass ratio. In this way, it is found that the designed backfill-mining mass ratio is 1.22, while the mean value of the measured backfill-mining mass ratio is 1.245. Besides, the maximum roof subsidence is only 340 mm which effectively guarantees the backfill effect in the panel and control of strata movement and surface subsidence.

Realizing of Optimization of Binder Backfill Material Under Certain Strength with Fuzzy Sets

The main factors deciding the compressive strength of binder backfill body are tailing density and binder dosage in binder backfill materials. Based on the antecedent of certain pulp density, the method of increasing the tailing density and reducing the binder dosage, or the manner of cutting down the tailing density and gaining the binder dosage are taken to guarantee the strength of backfill body. The problem that should be solved is how to determine the tailing density and the binder dosage rationally. This paper tries to realize the correct selection of the tailing density and the binder dosage in computer with the method of fuzzy mathematics.

Cross-scale characteristics of backfill material using NMR and fractal theory

This paper analyzed the pore structure, quantified the pore fractal dimension, calculated the grading index(GI) of mixed aggregate, and studied the relationship among GI, pore structure, and strength to describe the cross-scale characteristics of backfill, which is made from stone powder and cemented tailing. A series of experiments were conducted on stone powder cement tailings backfill(SPCTB). The GI formulas for mixed aggregates, containing stone powder and tailings, were derived based on the Füller theory. The nuclear magnetic resonance(NMR) fractal dimensions of backfills were derived using fractal geometry principles. Compared to the mesopore and macropore fractal dimensions, the correlation between micropore fractal dimension and macro-properties in terms of NMR porosity, pore structure complexity, uniaxial compression strength(UCS), and GI is the most significant. Macropore fractal dimension is generally correlated with UCS and GI and the other properties such as the shape of mixed aggregates also have an impact on fractal dimension. However, mesopore fractal dimension has no obvious relationship with macro-properties. Finally, the relationship between GI and UCS was studied, which contributed to improving backfill’s strength and optimizing gradation.

Calculation method of first collapse span with superhigh water material backfill mining

It is critical for the material to be of active supporting capacity before initial collapse ot mare root wltn supermgn water material backfill mining, and the maximum bending moment should be first calculated in order to determine the initial collapse span. In the light of principal of virtual work, the simple expression of deflection, bending moment of elastic clamped plate were deduced under the condition of vertical uniform distributed load, horizontal pressure and supporting by elastic foundation, and then, the maximal bending moment expression was derived too. At the same time, the influence degree on square clamped plate by adding horizontal pressure and elastic foundation were analyzed. The results show that the effect of horizontal pressure on maximal bending moment can be ignored when the value of horizontal pressure is two orders of magni- tude less than that of coeificient of elastic stiffness existing elastic foundation.

Creep Property of Solidifying Backfill Body of High-Water Material

On the basis of the creep test of bigh-water materisl solidifying backfill body(abb. HW body), This paper discusses its creep properties- The visco-elasto-plastic model, which shows the creep properties of HW body, is developed, and the creep contitutive equations are deduced. The visco-elastoplastic model is proved by the experiments and practice.

Study on the Themal Conductivity of Compacted Buffer/Backfill Materials

The thermal property is one of the key properties for the design of the high-level radioactive waste (HLW) repository. In this study, the thermal properties transient automatic tester (HPP-F) is uesd to study the thermal conductivity of multiphase composite buffer/backfill material including the type B-Z and B-Z-P (Here B、Z、P represents bentonite、zeolite and pyrite respectively,the same as in the following.) in different dry density and moisture conditions. The results show that for the same moisture content (dry density), thermal conductivity of specimens increases as the dry density (moisture content) increases. As a result, the type B-Z-P which is highly compacted of 1.8 g/cm3 in dry density and 17.65% in moisture content performs well, it meets the requirements of the IAEA and is easy to be compacted ,so it can be recommend as a alternative material of high level radioactive waste disposal repository buffer/backfilling materials.

REQUIREMENT OF FLUIDITY OFHIGH WATER CONTENT MATERIALS FOR THE GETWAY-SIDE BACKFILLING TECHNIQUE

Through analyzing the effects of water consumption, diameter of solid particle, and flow vefority on the fluidity of high water content material slurry, the relatinnship among the fluidity, the isotropy of the slurry, and the pumping facilities applied in getway-side backfilling has been found. And the requirment of fluidity of high water content material for the design of getway-side back filling technique is put forward in the paper.

Systematic review of mixing technology for recycling waste tailings as cemented paste backfill in mines in China

The development of industry is inseparable from the support of mining.However,mining processes consume a large amount of energy,and increased tailing emissions can have a significant impact on the environment.In the past few decades,the mining industry developed many technologies that are related to mineral energy management,of which cemented paste backfill(CPB)is one of the representative technologies.CPB has been successfully applied to mine ground control and tailings management.In CPB technology,the mixing process is the key to achieving materials with good final quality and controlled properties.However,in the preparation process,the mixed homogeneity of the CPB is difficult to achieve because of fine tailings,high solid volume fraction,and high viscosity.Most research focused on the effect of mixing ingredients on CPB properties rather than on the preparation process of the CPB.Therefore,improving the performance and reducing the production cost of CPB by optimizing the mixing process are important.This review summarizes the current studies on the mixing technology of CPB and its application status in China.Then,it compares the advantages and disadvantages of multiple mixing equipment and discusses the latest results and research hotspots in paste preparation.Finally,it concludes the challenges and development trends of mixing technology on the basis of the relevant application cases in China to promoting cement-based material mixing technology development.

Progress and prospects of mining with backfill in metal mines in China

Mining is the foundation of modern industrial development.In the context of the“carbon peaking and carbon neutrality”era,countries have put forward the development strategy of“adhering to the harmonious coexistence of humans and nature.”The ongoing progress and improvement of filling mining technology have provided significant advantages,such as“green mining,safe,efficient,and low-carbon emission,”which is crucial to the comprehensive utilization of mining solid waste,environmental protection,and safety of re-mining.This review paper describes the development history of metal mine filling mining in China and the characteristics of each stage.The excitation mechanism and current research status of producing cementitious materials from blast furnace slag and other industrial wastes are then presented,and the concept of developing cementitious materials for backfill based on the whole solid waste is proposed.The advances in the mechanical characteristics of cemented backfill are elaborated on four typical levels:static mechanics,dynamic mechanics,mechanical influencing factors,and multi-scale mechanics.The working/rheological characteristics of the filling slurry are presented,given the importance of the filling materials conveying process.Finally,the future perspectives of mining with backfill are discussed based on the features of modern filling concepts to provide the necessary theoretical research value for filling mining.

A roof model and its application in solid backfilling mining

Through changing the axial load on backfilling material compaction test to reflect different overlying strata pressure on backfilling material, the stress-strain relations in the compaction process of backfilling material under the geological condition can be obtained. Based on the characteristic of overlying strata movement in backfill mining, a model of roof thin plate is established. By introducing the stress-strain relation in compaction process into the model and using RIZT method to analyze the bending deformation of roof, the bending deflection and stress distribution can be obtained. The results show that the maximum roof subsidence and maximum tensile stress occurring at the center are 255 mm and5 MPa, respectively. Tensile fracture of roof under the geological condition of Dongping Mine did not occur. The dynamic measurement results of roof in Dongping Mine verify the theoretical result from the aforementioned model, thereby suggesting the roof mechanical model is reliable. The roof thin plate model based on the compaction characteristic of backfilling material in this study is of importance to research on backfill mining theories and application of backfilling material characteristics.

A New Mode of Coal Mining Under Buildings with Paste-Like Backfill Technology

The formation of the paste like backfill technology was introduced briefly in this paper. From the actual cases of coal mines, a new mode of coal mining under buildings with the technology was proposed. And its specificity was analyzed, and a further introduction to the full sand soil solidifying material was given. The main parts of the backfill system, such as the backfill preparation system, the pipeline transportation system, the backfill systems in fully mechanized mining faces and the backfill process, were presented emphatically.

Recovery of Mining Wastes in Building Materials: A Review

The use of materials from waste in buildings compensates for the lack of natural resources, solves the problem of waste management and provides an alternative technique for protection of the environment. There are a large number of industrial wastes that are used for full or partial replacement of raw materials in some construction materials. This review assesses mining waste in concrete as a substitute for aggregates and cement;in fired bricks as a substitute for soil;and in road backfill as a substitute for soil. This paper reviews some mining tailings, mine waste rocks and some slags obtained in the exploitation and/or processing of some ores including iron, gold, lead, phosphate, copper, coal, etc. Different physical properties, mechanical properties, chemical properties, heavy metal content, mineralogic composition, geotechnical properties and environmental properties (leaching test) of the mine wastes were examined. The physical, mechanical and environmental properties of the materials obtained by substitution of raw materials by mine waste were examined and compared to reference materials. Mining waste in cementitious materials offers good compressive strengths, while the porosity of the concrete and/or mortar is a factor influencing its toxicity. As for the waste in fired bricks, fired at a temperature of 900°C or more, it offers convincing compressive and flexural strengths. The few research studies obtained on the use of mining waste in road embankments have shown that mining waste can be used as a sub-base layer and backfill as long as it is not toxic. In addition, several other mining wastes require special attention as substitutes for raw materials in construction materials, such as coltan, cobalt.

煤矿负碳高效充填开采理论与技术构想

矿山安全高效绿色低碳开采是永恒的主题,近零冲击地压、近零生态损害以及低碳、零碳、负碳的绿色开采将成为保障我国能源安全供应与绿色低碳发展的新要求。充填开采是实现这一要求的必然途径。然而,现有充填开采原理与技术装备体系难以突破高产高效、低碳开采的技术瓶颈,对充填材料及充填模式进行变革已势在必行。针对“千米深井资源开发和千万吨产能矿井充填(两个一千)”与“近零生态损害和近零冲击地压(两个近零)”的煤炭绿色低碳开采战略目标,提出了负碳高效充填开采技术全新构想,系统阐述了负碳高效充填开采的定义与科学内涵,提出和建立了由CO_(2)、矸石与快速胶结物混合而成的负碳高孔隙充填材料结构CGIF(CO_(2)Gangue Inorganic Framework)拓扑构型与强度理论以及CGIF混合物充填体固碳理论、快速黏凝胶结材料反应动力学理论、矿区充填开采防治冲击地压等负碳高效充填理论构想;提出了矸石快速高效胶结高孔隙充填材料制备技术、快速黏凝胶结材料绿色高效制备技术、CGIF充填体负碳高效充填开采技术、多面并采高效充填开采技术与工艺、全周期立体高效充填开采防冲技术等关键技术体系。在此基础上,明确了煤矿负碳高效充填开采“基础研究—技术攻关—工程示范”的“三阶段”发展规划,构建了煤矿负碳高效充填开采理论与技术体系构想;评估了煤矿负碳高效充填CO_(2)封存能力,可望实现煤炭负碳开采、低碳利用的煤炭开发利用全过程自身实现碳中和的新格局。

煤泥基充填材料流动性与强度特性试验研究

为研究煤泥基充填材料的流动与强度特性,运用正交试验设计了以煤泥、高水、水泥、粉煤灰为组合的胶结充填材料,采用极差、方差分析及多元回归分析等方法,研究了煤泥水百分浓度(A)、高水添加比例(B)、水泥添加比例(C)、粉煤灰添加比例(D)等4个关键因素对充填材料的初凝时间、扩散度及抗压强度、抗剪强度的影响机制。试验结果表明:①煤泥基充填材料的初凝时间为52~67 min,扩散度为42.0~76.5 cm,抗压强度为0.076~0.247 MPa,抗剪强度为0.033~0.139 MPa。对于初凝时间,影响显著性有B>C>A>D;对于扩散度,有A>D>B>C;对于抗压强度,有D>C>A>B;对于抗剪强度,有C>D>A>B。②拟合出了A、B、C、D与流动性指标及强度指标的数学关系式,初凝时间与A、B成二次函数关系、与C、D均呈指数关系;扩散度与A、B、C均呈指数关系,与D呈三角函数关系;抗压强度与A、D均呈指数关系,与B、C呈二次多项式关系;抗剪强度与A、B呈二次多项式关系、与C、D均呈指数关系;在A、B、C、D等4个因素与4个参数独立拟合方程的基础上,建立4因素共同影响下煤泥基充填材料流动性及强度特性参数预计模型,并进行了验证。

干湿循环下复合激发膏体充填材料宏-细-微观强化与损伤特性

为探明盐-碱复合激发膏体充填材料的性能变化规律及干湿循环作用下充填体结构多尺度损伤机制,对以脱硫石膏和水泥熟料为复合激发剂的膏体充填材料进行多目标优化,并对最优配比下的充填体试块进行0~25次干湿循环,开展抗压强度、X射线衍射(XRD)、低场核磁共振(NMR)、扫描电镜(SEM)试验,揭示充填体宏观力学行为和微细观结构演化规律。研究结果表明:充填材料最优配比是矿渣掺量为50%,脱硫石膏与水泥熟料质量比为3:7,硅灰掺量为2.5%。随着干湿循环次数的增加,充填体宏观表现为抗压强度的折减及累积电导率升高,干湿循环10次时出现拐点,质量损失率和强度损失率分别达极小值-1.91%和-8.36%;在细观尺度上,T2谱反演良好,干湿循环作用10次后,横向弛豫时间逐渐右移且谱面积增大,表明膏体充填材料孔隙尺寸及数量随着干湿循环次数增加而增大;微观尺度上,钙矾石、石膏和方解石等侵蚀产物的膨胀结晶应力加速了微观孔隙结构的发育,反复干湿循环作用削减了C-S-H凝胶的黏聚力,由最初的堆叠蜂窝状劣化为小块状。综合宏、细、微观结构演变规律可知,孔隙结构的损伤演化与力学性能的劣化特征具有较好的同步性。