A cement factory nearby communities raise pollution concerns. This study assessed air pollution levels for respirable particulate matter (PM2.5 and PM10) and heavy metals (lead, chromium, nickel, cadmium, zinc and cop...A cement factory nearby communities raise pollution concerns. This study assessed air pollution levels for respirable particulate matter (PM2.5 and PM10) and heavy metals (lead, chromium, nickel, cadmium, zinc and copper) adjacent to a cement factory in Ewekoro and neighbouring communities (Papalantoro, Lapeleko and Itori) in Ogun State, Nigeria. Respirable particulate matter (PM2.5 and PM10) and heavy metals were measured using an ARA N-FRM cassette sampler. Each location sampled was monitored for eight continuous hours daily for 12 days. The PM2.5, PM10 and heavy metals results were compared with different standards, including those of the World Health Organization (WHO), Nigeria’s National Environmental Standard and Regulation Enforcement Agency (NESREA) and Canadian Ambient Air Quality Standards (CAAQS). The PM levels fell within 11 - 19 μg/m3 of the air management level of CAAQS, which signifies continuous actions are needed to improve air quality in the areas monitored but below the NESREA standard. The mean Cd, Cr and Ni concentrations in the cement factory area and the impacted neighbourhoods are higher than the WHO/EU permissible limits, while Zn and Cu were below the WHO/EU permissible limit. A risk assessment hazard quotient (HQ) for Cr was above the WHO/EU safe level (=1) in adults and children throµgh ingestion, inhalation and dermal contact at all the monitoring sites. The HQ for Ni and Cd was higher than the safe level in the cement factory area and Papalantoro, while Zn was at safe levels.展开更多
Since 2009, Chinese nonferrous metals industry has been carried out industry consolidation with strong support by the central government. This work examined technical efficiency of Chinese nonferrous metals firms and ...Since 2009, Chinese nonferrous metals industry has been carried out industry consolidation with strong support by the central government. This work examined technical efficiency of Chinese nonferrous metals firms and its change during the period of 2007 and 2011. Based on financial data from nonferrous metals listed companies, technical efficiency of nonferrous metal minerals mining firms and nonferrous metal smelting, pressing and processing firms was estimated respectively using the data envelopment analysis (DEA) method. It was found that, in both sectors, number of pure technical and scale inefficient firms dominated over efficient ones. Overall, their technical and scale efficiency tended to be very low after 2009. In particular, efficiency scores of nonferrous metal smelting, pressing and processing firms fluctuated greatly during the research period. And a limited number of large leading firms were able to maintain 100% efficiency score in the industry, while efficiency of most of other leading firms has declined since 2009.展开更多
Based on a new perspective of industry chain and selecting monthly data from February2006to December2015,this paper chooses eight Chinese industrial sectors to construct a SVAR model reflecting internal relationships ...Based on a new perspective of industry chain and selecting monthly data from February2006to December2015,this paper chooses eight Chinese industrial sectors to construct a SVAR model reflecting internal relationships among metal chains,analyzes the direct effects and indirect effects of international metal prices on output of various links in metal chains,then it investigates the main transmission path of international metal price shocks through decomposing the inflation pressure sources in metal chains.The results show that international metal price shocks not only affect industrial output in a direct way,but also indirectly affect the growth of output through the increased pressure on industrial inflation and then triggering a tightening of monetary policy implementation.Affected by factors such as the lack of market demand and the price transmission mechanism blocking,the direct effects of international metal price shocks mainly impact the upstream and midstream industry,while the downstream industry is mainly affected by indirect effects;in addition,the international metal price shocks have spillover effects on the industrial inflation,and transmit along the industry chain from upstream to downstream,and their strength weakens in sequence.展开更多
The productivity of China’s nonferrous metals industry during 1980-1990 has been analysed. The important factors which constrain the productivity of the nonferrous metals industry have been studied, the methods of im...The productivity of China’s nonferrous metals industry during 1980-1990 has been analysed. The important factors which constrain the productivity of the nonferrous metals industry have been studied, the methods of improving the productivity of the nonferrous metals industry have been discussed.展开更多
This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min ...This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min high-frequency data from May 10,2012 to October 21,2021,the dynamic effects of spillovers are uncovered using the time-frequency domain spillover index framework.The results show that the system connectedness weakens as the moment order gets higher whereas the total jumps connectedness is the smallest,and the spillovers of all estimators are more evident in the short term.The overall information spillovers are time-varying and influenced by major market events.Specifically,for realized volatility,copper is the largest net transmitter and silver is always a net transmitter,while zinc is the largest net receiver.For realized skewness,copper is the largest net transmitter and silver is always a net transmitter,while lead is the largest net receiver.For realized kurtosis and jumps,copper is the largest net transmitter,while aluminum is the largest net receiver.Overall,copper and silver play dominant roles in China’s precious and industrial metals markets system.展开更多
Indiscriminate handling and disposal of industrial effluents into the environment represents one of the major sources of environmental pollution which invariably affect plants, animals and humans. This study assessed ...Indiscriminate handling and disposal of industrial effluents into the environment represents one of the major sources of environmental pollution which invariably affect plants, animals and humans. This study assessed heavy metal concentration in soils and plants around industries in Agbara industrial estate, Ogun State, Nigeria. Soil and plant samples were collected from four industries and analyzed for lead (Pb), cadmium (Cd), copper (Cu), chromium (Cr) and nickel (Ni). The pH, organic matter content and cation exchange capacity of the soil samples, as well as bioaccumulation factor (BAF) and translocation factor (TF) of the plant samples were examined. The heavy metal concentration order of the soil and plant samples was Pb ?1, 50 mg kg?1, 10 mg kg?1 and 50 mg kg?1 respectively) while Cd was above WHO tolerance limit (3 mg kg?1). Also, Pb, Cd, Cu, and Cr in most plant samples were above WHO tolerance limits (10 mg kg?1, 0.30 mg kg?1, 10 mg kg?1 and 1.5 mg kg?1 respectively). Statistical differences (P Cyperus iria, Alternanthera sessilis, C. esculentus, A. brasiliana, and Megathyrsus maximus are probable accumulators of heavy metals.展开更多
In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin t...In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin thermal station had the highest concentration of Zn (141.06 mg/kg) and Cu (131.70 mg/kg). Soil from international textile had the highest level of Fe and the soil from Ni-chemtex had the highest concentration Pb and Cd was the highest in soil from Guinness (28.91 mg/kg, 59.80 mg/kg and 1.72 mg/kg respectively). The highest concentrations of the heavy metals were observed from different plants species. Analyses of variance (p < 0.05) showed that heavy metal variation in plant and soil samples were not significant (p > 0.5). There were positive correlations between the heavy metals in the soils and the plant samples indicated that the plants obtained the heavy metals from the soil. Plants having BCF values less than one had limited ability to accumulate, translocate and phytoextract heavy metals. These plants in this study with higher Bioconcentration Factor value especially those greater than one (Croton lobatus, Borreria sp., Cy-athula prostrata, Lantana camara, Ficus sp., Mimosa pudica, Eclipta prostrata, Commelina sp. etc.) were suggested for further research and assessment on their bioaccumulation abilities and phy-toremediation potential.展开更多
Wastewater mixed with industrial effluents is used for irrigation in Gadoon Industrial estate and thus contaminating soil. This soil was tested for heavy metal content by using atomic absorption spectrophotometer (per...Wastewater mixed with industrial effluents is used for irrigation in Gadoon Industrial estate and thus contaminating soil. This soil was tested for heavy metal content by using atomic absorption spectrophotometer (perkin elmer 700) and compared with control soil irrigated with tube well water at seven selected spots. Accumulation of the toxic metal was significantly greater in the soil irrigated with industrial effluent than control soil (p < 0.05). Manganese (Mn) was the most significant pollutant, accumulated up to 9.95 ppm in the soil irrigated with industrial waste water. It was found that the samples were containing Zn in the range of 1.596 - 6.288, Cu 0.202 - 1.236, Co 0.074 - 0.115, Ni 0.0002 - 0.544, Cr 0.243 - 0.936, Mn 3.667 - 9.955 and Pb 0.488 - 1.259 ppm. No sample was containing the heavy metal above the critical level mentioned in typical and unsafe heavy metal levels in soil.展开更多
Heavy metals pollution in Jiaozhou Bay was studied in Ruditapes. philippinarum, a bioindicator of seawater pollution. Heavy metals in soda industry wastes “white mud” were also studied. Comparison of microwave diges...Heavy metals pollution in Jiaozhou Bay was studied in Ruditapes. philippinarum, a bioindicator of seawater pollution. Heavy metals in soda industry wastes “white mud” were also studied. Comparison of microwave digestion method with general digestion method revealed that microwave digestion is superior to general digestion in precision, recovery, digestion speed and efficiency, etc. Cd concentration in Hongdao R. philippinarum samples exceeded the national standard by 0.046 mg/kg, that of Yinghai sample by 0.02 mg/kg, and that of Hongshiya sample by 0.22 mg/kg. Sample Pb concentration in Hongshiya was found to exceed the national standard by 0.02 mg/kg. However the heavy metals concentration in R. philippinarum near the Qingdao Alkaline Factory was complied with the standard. This was proved by Penaeus chinensis culture experiment. Therefore, the possible contamination source may come from other land areas.展开更多
The waste products, such as induction furnace slag, ladle furnace slag, air pollution control dust, and ramming mass collected from major iron processing industries in Chittagong, Bangladesh were analyzed for heavy me...The waste products, such as induction furnace slag, ladle furnace slag, air pollution control dust, and ramming mass collected from major iron processing industries in Chittagong, Bangladesh were analyzed for heavy metals and naturally radioactive elements. The concentrations of heavy metals Fe, Cr, Mn, Co, Cd, Ni, Pb, Cu and Zn were obtained from atomic absorption spectrophotometer (AAS) analysis with flame atomizer and the radioactivities due to 226Ra, 232Th and 40K were determined using high purity germanium (HPGe) detector of well shielded gamma-ray counting system. From the mean specific activities of the above three natural radionuclides in the investigated samples, the radium equivalent activity (Raeq) and the external hazard index (Hex) were calculated. The study showed the prospect of contamination of environmental materials (viz., soil, water, air, plant) due to many of these investigated elements by using the collected waste products in landfill. The chemical process of ion exchange indicates that the elevated heavy metals in soil can play a role to increase the natural radioactivity of the soil. The obtained Raeq as well as Hex indicated the insignificant radiation hazard due to the activities of primordial radionuclides found in the investigated samples.展开更多
In April this year China National Nonferrous Metals Industries Corporation(CNNMIC)performed the Tenth Anniversary Ceremony.In the past decade the CNNMIC realized“fivedoublings”,i.e.the output,profits tax,fixed asset...In April this year China National Nonferrous Metals Industries Corporation(CNNMIC)performed the Tenth Anniversary Ceremony.In the past decade the CNNMIC realized“fivedoublings”,i.e.the output,profits tax,fixed assets,enterprise revenue and personal income展开更多
On the 3 April 1993,in the Great Hall of the People a ceremony of the tenth anniversarywas held by CNNMIC.The Vice-premier Li Lanqing and old leaders Fang Yi,Wang Heshouet al attended this ceremony.Lu Dong,Yuan Baohua...On the 3 April 1993,in the Great Hall of the People a ceremony of the tenth anniversarywas held by CNNMIC.The Vice-premier Li Lanqing and old leaders Fang Yi,Wang Heshouet al attended this ceremony.Lu Dong,Yuan Baohua,Gao Yangwen and Chen Jinhua et alministerial representatives are present also.The ambassadors and/or envoys from Romania,展开更多
China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non...China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non-ferrous metals such as copper, aluminium, lead, and zinc had reached 3.701 million tons, a 12.2 percent increase over the previous year; the qualification rate of principal products and the output value rate of good quality products all achieved an increase over the previous year. China has展开更多
The China Non-ferrous MetalsIndustry Corporation has putforward ten development policiesfor the Ninth Five-year Plan period,according to the central government’sinstruction to change the way of economicgrowth,and rai...The China Non-ferrous MetalsIndustry Corporation has putforward ten development policiesfor the Ninth Five-year Plan period,according to the central government’sinstruction to change the way of economicgrowth,and raise the integral quality andbenefit of the national economy:展开更多
The present study demonstrates distribution and chemical forms of heavy metals in soils of the AImalyk mining and smelting industrial area along five transects. The study area is located in Almalyk, Uzbekistan, where ...The present study demonstrates distribution and chemical forms of heavy metals in soils of the AImalyk mining and smelting industrial area along five transects. The study area is located in Almalyk, Uzbekistan, where the intensification of industrial enterprises negatively impacts the environment. The distribution of 17 heavy metals (Cu, Zn, Pb, Sc, V, Cr, Co, Ni, Ga, Rb, Sr, Y, Zr, Nb, Ba, Th, and U) were studied in 21 sampling locations (21×3=63 soil samples) along five radial transects with a total length of 60 km downwind deposition gradient. Soil samples were collected from the upper layer (0-10 cm) at 4-6 km intervals. As a result of X-ray fluorescence spectrometry analyses by using X -ray fluorescence spectroscopy (XRF, Philips Analytical Ink, USA ), a significant decrease in heavy metal (Cu, Zn, Pb) deposition was found going from the source in a downwind direction. Soil samples taken from the first location (near the pollution sources) showed higher concentrations of Cu, Zn and Pb, and lower concentrations with increasing distance from the source. Obtained data showed different impact of pollution sources to heavy metal deposition and distribution in soils. The Almalyk mining and smelting complex is the major source of Pb, Zn and Cu enrichment in soils. Distribution of other trace elements does not exceed background content and suggests lithogenic background. This allowed us to divide these elements into two groups: (1) technogenic (Cu, Zn and Pb); and (2) lithogenic (Sc, V, Cr, Co, Ni, Ga, Rb, Sr, Y, Zr, Nb, Ba, Th and U) origins.展开更多
In this work, a thorough examinations on the extractability of zinc and lead present in the steelmaking dusts using alkaline leaching process and the effectiveness of the zinc and lead separation in the resultant leac...In this work, a thorough examinations on the extractability of zinc and lead present in the steelmaking dusts using alkaline leaching process and the effectiveness of the zinc and lead separation in the resultant leaching solutions using sulfide precipitation method were made. It was found that only about 53% of zinc and over 70% of the lead could be leached out of the dusts, while the other 47% of zinc and 30% of lead were left in the leaching residues. The zinc and lead in the resultant leaching solution can be effectively and selectively separated. When the weight ratio of sodium sulfide (M.W. = 222-240) to Pb was kept at 1.8, the lead in the solution could be precipitated out quantitatively while all the zinc was remained in the solution. The zinc left in the solution can be further recovered by the addition of extra sodium sulfide with a weight ratio of sodium sulfide to the zinc over 2.6. The resultant filtrate can be recycled to the leaching of dust in the next leaching process.展开更多
Lake contamination by anthropogenic activities has become a serious threat to the aquatic ecosystem due to the presence of a high concentration of toxic heavy metals.In this study,a contaminated Lake Hussain Sagar in ...Lake contamination by anthropogenic activities has become a serious threat to the aquatic ecosystem due to the presence of a high concentration of toxic heavy metals.In this study,a contaminated Lake Hussain Sagar in India was assessed for toxic heavy metal pollutants at sites associated with industrial discharges and idol immersion activities.The observed high concentration of As,Cd,Pb,Zn,Cu,and Ni in the surface water was due to industrial effluent discharge.About 1.5 times the high concentration of the same elements were observed in surface sediments(0-10 cm)by both industrial discharges and idol immersion activities,compared to deep sediments(0-40 cm)associated only with industrial discharge.The depth-wise variation of heavy metal concentration in surface sediments is due to sorption and settling behavior of suspended solids;whereas in deep sediment,it is due to constant loading of effluents,over a period of time.The sorption capacity of surface sediments is in increasing order as Pb>Cd≥Ni>Cr>Zn>Cu,and the desorption revealed that Pb and Cu were retained to a greater extent due to high clay and organic content.By fractionation study,20-50%of Zn and 50-80%of Cd were associated with exchangeable and carbonate fraction of sediments.By risk assessment code,Zn and Cd are classified under high risk to a very high-risk category,and Cr,Pb,Ni,and Cu are classified under the medium risk category.The enrichment factor value of sediments for Cd(20.42-119.48),Zn(2.19-4.85),Cu(2.02-3.19),and Pb(2.85-7.72)signifies the significant pollution by anthropogenic activities.Therefore,this study evaluates the intensity and distribution of heavy metals in the lake environment for remediation and restoration of the lake ecosystem.展开更多
To Lich River (TLR) system receives wastewaters from a population of nearly two million people and 100 manufactories of five industrial zones in inner city Hanoi, Vietnam. To improve quality of TLR, the embankment was...To Lich River (TLR) system receives wastewaters from a population of nearly two million people and 100 manufactories of five industrial zones in inner city Hanoi, Vietnam. To improve quality of TLR, the embankment was carried out in 1998 and finished in 2002, resulted in width of 20 - 45 m, depth of 2 - 4 m, and maximum water flow capacity of 30 m3/s. Water and sediment quality indices based on heavy metal concentrations were used to evaluate current river environment compared to that of pre-embankment. Mass balance model was employed to estimate total metal loads for specific river reaches, which corresponds to various types of wastewater discharged along the river. The results indicated that currently there is about284,000 m3sediment accumulated in TLR bed, which is under high contamination of Cr, Mn, Fe, Ni Cu, Zn, As, Cd, and Pb with a total of 7347 tons of all concerned metals. Domestic-discharged river reaches received much lower metal loads, roughly 8% - 28% compared to river reaches of both domestic and industrial inputs. Total load of all nine concerned metals at the end of TLR is161.7 kg/day, which is finally discharged to Nhue River at South Hanoi. Water quality was improved much right after finishing embankment, then it gradually deteriorated. Meanwhile, sediment quality became even much worse after embankment. Relative river quality index as equal weight for both water and sediment quality indices indicated that quality of TLR was not much improved after the embankment. It even became worse due to the urbanization in recent years.展开更多
This The mineral potential in Egypt is quite high. Almost all sorts of industrial minerals such as metallic and non-metallic commodities exist in commercial amounts. However, Egypt imports many of the mineral commodit...This The mineral potential in Egypt is quite high. Almost all sorts of industrial minerals such as metallic and non-metallic commodities exist in commercial amounts. However, Egypt imports many of the mineral commodities needed for the local mineral industries. The main reason for this is that the investors, either the governmental or the private sectors, refrain from investing into the mineral industry for prospecting, evaluation, and developing the mining and mineral processing technologies. This is because the return on investment in the mining industry is generally low and the pay back period is relatively long compared with easy-to-get money projects. Another reason is the disarray of the mining laws and regulations and lack of administrative capability to deal with domestic and international investors and solve the related problems. Also, lack of skilled personnel in the field of mining and mineral processing is an additional factor for the set back of the mining industry in Egypt. This is why the mining technology in Egypt is not very far from being primitive and extremely simple, with the exception of the underground mining of coal, North of Sinai, and Abu-Tartur phosphate mining, where fully automated long wall operations are designed. Also, the recent gold and tin-tantalum-niobium projects are being designed on modern surface mining and mineral processing technologies. The present review presents an overview of the most important metallic mineral commodities in Egypt, their geological background, reserves and production rates. A brief mention of the existing technologies for their exploitation is also highlighted.展开更多
The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification o...The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification of industrial enterprises negatively impact on the environment.The distribution of 17 heavy metals (Cu,Zn,Pb,Sc,V,Cr,Co,Ni,Ga,Rb,Sr,Y,Zr,Nb, Ba,Th,and U)were studied in 21 sampling locations (21×3=63 soil samples)along the 5 radial transects with the total length of 60 km downwind展开更多
文摘A cement factory nearby communities raise pollution concerns. This study assessed air pollution levels for respirable particulate matter (PM2.5 and PM10) and heavy metals (lead, chromium, nickel, cadmium, zinc and copper) adjacent to a cement factory in Ewekoro and neighbouring communities (Papalantoro, Lapeleko and Itori) in Ogun State, Nigeria. Respirable particulate matter (PM2.5 and PM10) and heavy metals were measured using an ARA N-FRM cassette sampler. Each location sampled was monitored for eight continuous hours daily for 12 days. The PM2.5, PM10 and heavy metals results were compared with different standards, including those of the World Health Organization (WHO), Nigeria’s National Environmental Standard and Regulation Enforcement Agency (NESREA) and Canadian Ambient Air Quality Standards (CAAQS). The PM levels fell within 11 - 19 μg/m3 of the air management level of CAAQS, which signifies continuous actions are needed to improve air quality in the areas monitored but below the NESREA standard. The mean Cd, Cr and Ni concentrations in the cement factory area and the impacted neighbourhoods are higher than the WHO/EU permissible limits, while Zn and Cu were below the WHO/EU permissible limit. A risk assessment hazard quotient (HQ) for Cr was above the WHO/EU safe level (=1) in adults and children throµgh ingestion, inhalation and dermal contact at all the monitoring sites. The HQ for Ni and Cd was higher than the safe level in the cement factory area and Papalantoro, while Zn was at safe levels.
基金Project(70921001)supported by the National Natural Science Foundation of ChinaProject(NCET-10-0799)supported by Program for New Century Excellent Talents in University,ChinaProjects(11YJA790158)supported by Humanities and Social Sciences Planning Fund by Chinese Ministry of Education
文摘Since 2009, Chinese nonferrous metals industry has been carried out industry consolidation with strong support by the central government. This work examined technical efficiency of Chinese nonferrous metals firms and its change during the period of 2007 and 2011. Based on financial data from nonferrous metals listed companies, technical efficiency of nonferrous metal minerals mining firms and nonferrous metal smelting, pressing and processing firms was estimated respectively using the data envelopment analysis (DEA) method. It was found that, in both sectors, number of pure technical and scale inefficient firms dominated over efficient ones. Overall, their technical and scale efficiency tended to be very low after 2009. In particular, efficiency scores of nonferrous metal smelting, pressing and processing firms fluctuated greatly during the research period. And a limited number of large leading firms were able to maintain 100% efficiency score in the industry, while efficiency of most of other leading firms has declined since 2009.
基金Projects(71633006,71573282)supported by the National Natural Science Foundation of China
文摘Based on a new perspective of industry chain and selecting monthly data from February2006to December2015,this paper chooses eight Chinese industrial sectors to construct a SVAR model reflecting internal relationships among metal chains,analyzes the direct effects and indirect effects of international metal prices on output of various links in metal chains,then it investigates the main transmission path of international metal price shocks through decomposing the inflation pressure sources in metal chains.The results show that international metal price shocks not only affect industrial output in a direct way,but also indirectly affect the growth of output through the increased pressure on industrial inflation and then triggering a tightening of monetary policy implementation.Affected by factors such as the lack of market demand and the price transmission mechanism blocking,the direct effects of international metal price shocks mainly impact the upstream and midstream industry,while the downstream industry is mainly affected by indirect effects;in addition,the international metal price shocks have spillover effects on the industrial inflation,and transmit along the industry chain from upstream to downstream,and their strength weakens in sequence.
基金The project was financially supported by the Chima National Natural Science Foundation
文摘The productivity of China’s nonferrous metals industry during 1980-1990 has been analysed. The important factors which constrain the productivity of the nonferrous metals industry have been studied, the methods of improving the productivity of the nonferrous metals industry have been discussed.
基金the financial support from the National Natural Science Foundation of China(No.72172107)。
文摘This study reveals the time-varying spillover effects of higher moments(realized volatility,realized skewness and realized kurtosis)and jumps between China’s precious metals and industrial metals markets.Using 5-min high-frequency data from May 10,2012 to October 21,2021,the dynamic effects of spillovers are uncovered using the time-frequency domain spillover index framework.The results show that the system connectedness weakens as the moment order gets higher whereas the total jumps connectedness is the smallest,and the spillovers of all estimators are more evident in the short term.The overall information spillovers are time-varying and influenced by major market events.Specifically,for realized volatility,copper is the largest net transmitter and silver is always a net transmitter,while zinc is the largest net receiver.For realized skewness,copper is the largest net transmitter and silver is always a net transmitter,while lead is the largest net receiver.For realized kurtosis and jumps,copper is the largest net transmitter,while aluminum is the largest net receiver.Overall,copper and silver play dominant roles in China’s precious and industrial metals markets system.
文摘Indiscriminate handling and disposal of industrial effluents into the environment represents one of the major sources of environmental pollution which invariably affect plants, animals and humans. This study assessed heavy metal concentration in soils and plants around industries in Agbara industrial estate, Ogun State, Nigeria. Soil and plant samples were collected from four industries and analyzed for lead (Pb), cadmium (Cd), copper (Cu), chromium (Cr) and nickel (Ni). The pH, organic matter content and cation exchange capacity of the soil samples, as well as bioaccumulation factor (BAF) and translocation factor (TF) of the plant samples were examined. The heavy metal concentration order of the soil and plant samples was Pb ?1, 50 mg kg?1, 10 mg kg?1 and 50 mg kg?1 respectively) while Cd was above WHO tolerance limit (3 mg kg?1). Also, Pb, Cd, Cu, and Cr in most plant samples were above WHO tolerance limits (10 mg kg?1, 0.30 mg kg?1, 10 mg kg?1 and 1.5 mg kg?1 respectively). Statistical differences (P Cyperus iria, Alternanthera sessilis, C. esculentus, A. brasiliana, and Megathyrsus maximus are probable accumulators of heavy metals.
文摘In this study, eleven soil samples and twenty-twoplants samples were collected in the vicinity of eleven industries and a thermal station was analyzed for zinc, copper, iron, lead and cadmium. Soil sample from Egbin thermal station had the highest concentration of Zn (141.06 mg/kg) and Cu (131.70 mg/kg). Soil from international textile had the highest level of Fe and the soil from Ni-chemtex had the highest concentration Pb and Cd was the highest in soil from Guinness (28.91 mg/kg, 59.80 mg/kg and 1.72 mg/kg respectively). The highest concentrations of the heavy metals were observed from different plants species. Analyses of variance (p < 0.05) showed that heavy metal variation in plant and soil samples were not significant (p > 0.5). There were positive correlations between the heavy metals in the soils and the plant samples indicated that the plants obtained the heavy metals from the soil. Plants having BCF values less than one had limited ability to accumulate, translocate and phytoextract heavy metals. These plants in this study with higher Bioconcentration Factor value especially those greater than one (Croton lobatus, Borreria sp., Cy-athula prostrata, Lantana camara, Ficus sp., Mimosa pudica, Eclipta prostrata, Commelina sp. etc.) were suggested for further research and assessment on their bioaccumulation abilities and phy-toremediation potential.
文摘Wastewater mixed with industrial effluents is used for irrigation in Gadoon Industrial estate and thus contaminating soil. This soil was tested for heavy metal content by using atomic absorption spectrophotometer (perkin elmer 700) and compared with control soil irrigated with tube well water at seven selected spots. Accumulation of the toxic metal was significantly greater in the soil irrigated with industrial effluent than control soil (p < 0.05). Manganese (Mn) was the most significant pollutant, accumulated up to 9.95 ppm in the soil irrigated with industrial waste water. It was found that the samples were containing Zn in the range of 1.596 - 6.288, Cu 0.202 - 1.236, Co 0.074 - 0.115, Ni 0.0002 - 0.544, Cr 0.243 - 0.936, Mn 3.667 - 9.955 and Pb 0.488 - 1.259 ppm. No sample was containing the heavy metal above the critical level mentioned in typical and unsafe heavy metal levels in soil.
基金This study is supported by Project 973 (NO.2002CB412402), and key project of the Chinese Academy of Sciences (Grant NO.KJCX315W-215).
文摘Heavy metals pollution in Jiaozhou Bay was studied in Ruditapes. philippinarum, a bioindicator of seawater pollution. Heavy metals in soda industry wastes “white mud” were also studied. Comparison of microwave digestion method with general digestion method revealed that microwave digestion is superior to general digestion in precision, recovery, digestion speed and efficiency, etc. Cd concentration in Hongdao R. philippinarum samples exceeded the national standard by 0.046 mg/kg, that of Yinghai sample by 0.02 mg/kg, and that of Hongshiya sample by 0.22 mg/kg. Sample Pb concentration in Hongshiya was found to exceed the national standard by 0.02 mg/kg. However the heavy metals concentration in R. philippinarum near the Qingdao Alkaline Factory was complied with the standard. This was proved by Penaeus chinensis culture experiment. Therefore, the possible contamination source may come from other land areas.
文摘The waste products, such as induction furnace slag, ladle furnace slag, air pollution control dust, and ramming mass collected from major iron processing industries in Chittagong, Bangladesh were analyzed for heavy metals and naturally radioactive elements. The concentrations of heavy metals Fe, Cr, Mn, Co, Cd, Ni, Pb, Cu and Zn were obtained from atomic absorption spectrophotometer (AAS) analysis with flame atomizer and the radioactivities due to 226Ra, 232Th and 40K were determined using high purity germanium (HPGe) detector of well shielded gamma-ray counting system. From the mean specific activities of the above three natural radionuclides in the investigated samples, the radium equivalent activity (Raeq) and the external hazard index (Hex) were calculated. The study showed the prospect of contamination of environmental materials (viz., soil, water, air, plant) due to many of these investigated elements by using the collected waste products in landfill. The chemical process of ion exchange indicates that the elevated heavy metals in soil can play a role to increase the natural radioactivity of the soil. The obtained Raeq as well as Hex indicated the insignificant radiation hazard due to the activities of primordial radionuclides found in the investigated samples.
文摘In April this year China National Nonferrous Metals Industries Corporation(CNNMIC)performed the Tenth Anniversary Ceremony.In the past decade the CNNMIC realized“fivedoublings”,i.e.the output,profits tax,fixed assets,enterprise revenue and personal income
文摘On the 3 April 1993,in the Great Hall of the People a ceremony of the tenth anniversarywas held by CNNMIC.The Vice-premier Li Lanqing and old leaders Fang Yi,Wang Heshouet al attended this ceremony.Lu Dong,Yuan Baohua,Gao Yangwen and Chen Jinhua et alministerial representatives are present also.The ambassadors and/or envoys from Romania,
文摘China’s non-ferrous metals industry has constantly maintained a steady, rapid and healthy development since the reform and opening to the outside world. By the end of 1994, the annual output often kinds of common non-ferrous metals such as copper, aluminium, lead, and zinc had reached 3.701 million tons, a 12.2 percent increase over the previous year; the qualification rate of principal products and the output value rate of good quality products all achieved an increase over the previous year. China has
文摘The China Non-ferrous MetalsIndustry Corporation has putforward ten development policiesfor the Ninth Five-year Plan period,according to the central government’sinstruction to change the way of economicgrowth,and raise the integral quality andbenefit of the national economy:
基金supported by NATO SPS programs as reintegration grant to Dr.Nosir Shukurov
文摘The present study demonstrates distribution and chemical forms of heavy metals in soils of the AImalyk mining and smelting industrial area along five transects. The study area is located in Almalyk, Uzbekistan, where the intensification of industrial enterprises negatively impacts the environment. The distribution of 17 heavy metals (Cu, Zn, Pb, Sc, V, Cr, Co, Ni, Ga, Rb, Sr, Y, Zr, Nb, Ba, Th, and U) were studied in 21 sampling locations (21×3=63 soil samples) along five radial transects with a total length of 60 km downwind deposition gradient. Soil samples were collected from the upper layer (0-10 cm) at 4-6 km intervals. As a result of X-ray fluorescence spectrometry analyses by using X -ray fluorescence spectroscopy (XRF, Philips Analytical Ink, USA ), a significant decrease in heavy metal (Cu, Zn, Pb) deposition was found going from the source in a downwind direction. Soil samples taken from the first location (near the pollution sources) showed higher concentrations of Cu, Zn and Pb, and lower concentrations with increasing distance from the source. Obtained data showed different impact of pollution sources to heavy metal deposition and distribution in soils. The Almalyk mining and smelting complex is the major source of Pb, Zn and Cu enrichment in soils. Distribution of other trace elements does not exceed background content and suggests lithogenic background. This allowed us to divide these elements into two groups: (1) technogenic (Cu, Zn and Pb); and (2) lithogenic (Sc, V, Cr, Co, Ni, Ga, Rb, Sr, Y, Zr, Nb, Ba, Th and U) origins.
文摘In this work, a thorough examinations on the extractability of zinc and lead present in the steelmaking dusts using alkaline leaching process and the effectiveness of the zinc and lead separation in the resultant leaching solutions using sulfide precipitation method were made. It was found that only about 53% of zinc and over 70% of the lead could be leached out of the dusts, while the other 47% of zinc and 30% of lead were left in the leaching residues. The zinc and lead in the resultant leaching solution can be effectively and selectively separated. When the weight ratio of sodium sulfide (M.W. = 222-240) to Pb was kept at 1.8, the lead in the solution could be precipitated out quantitatively while all the zinc was remained in the solution. The zinc left in the solution can be further recovered by the addition of extra sodium sulfide with a weight ratio of sodium sulfide to the zinc over 2.6. The resultant filtrate can be recycled to the leaching of dust in the next leaching process.
基金the support from Frontier Areas of Science and Technology—Centre of Excellence(FAST-CoE)in Sustainable Development at Indian Institute of Technology Hyderabad,funded by the Ministry of Human Resource Development,India。
文摘Lake contamination by anthropogenic activities has become a serious threat to the aquatic ecosystem due to the presence of a high concentration of toxic heavy metals.In this study,a contaminated Lake Hussain Sagar in India was assessed for toxic heavy metal pollutants at sites associated with industrial discharges and idol immersion activities.The observed high concentration of As,Cd,Pb,Zn,Cu,and Ni in the surface water was due to industrial effluent discharge.About 1.5 times the high concentration of the same elements were observed in surface sediments(0-10 cm)by both industrial discharges and idol immersion activities,compared to deep sediments(0-40 cm)associated only with industrial discharge.The depth-wise variation of heavy metal concentration in surface sediments is due to sorption and settling behavior of suspended solids;whereas in deep sediment,it is due to constant loading of effluents,over a period of time.The sorption capacity of surface sediments is in increasing order as Pb>Cd≥Ni>Cr>Zn>Cu,and the desorption revealed that Pb and Cu were retained to a greater extent due to high clay and organic content.By fractionation study,20-50%of Zn and 50-80%of Cd were associated with exchangeable and carbonate fraction of sediments.By risk assessment code,Zn and Cd are classified under high risk to a very high-risk category,and Cr,Pb,Ni,and Cu are classified under the medium risk category.The enrichment factor value of sediments for Cd(20.42-119.48),Zn(2.19-4.85),Cu(2.02-3.19),and Pb(2.85-7.72)signifies the significant pollution by anthropogenic activities.Therefore,this study evaluates the intensity and distribution of heavy metals in the lake environment for remediation and restoration of the lake ecosystem.
文摘To Lich River (TLR) system receives wastewaters from a population of nearly two million people and 100 manufactories of five industrial zones in inner city Hanoi, Vietnam. To improve quality of TLR, the embankment was carried out in 1998 and finished in 2002, resulted in width of 20 - 45 m, depth of 2 - 4 m, and maximum water flow capacity of 30 m3/s. Water and sediment quality indices based on heavy metal concentrations were used to evaluate current river environment compared to that of pre-embankment. Mass balance model was employed to estimate total metal loads for specific river reaches, which corresponds to various types of wastewater discharged along the river. The results indicated that currently there is about284,000 m3sediment accumulated in TLR bed, which is under high contamination of Cr, Mn, Fe, Ni Cu, Zn, As, Cd, and Pb with a total of 7347 tons of all concerned metals. Domestic-discharged river reaches received much lower metal loads, roughly 8% - 28% compared to river reaches of both domestic and industrial inputs. Total load of all nine concerned metals at the end of TLR is161.7 kg/day, which is finally discharged to Nhue River at South Hanoi. Water quality was improved much right after finishing embankment, then it gradually deteriorated. Meanwhile, sediment quality became even much worse after embankment. Relative river quality index as equal weight for both water and sediment quality indices indicated that quality of TLR was not much improved after the embankment. It even became worse due to the urbanization in recent years.
文摘This The mineral potential in Egypt is quite high. Almost all sorts of industrial minerals such as metallic and non-metallic commodities exist in commercial amounts. However, Egypt imports many of the mineral commodities needed for the local mineral industries. The main reason for this is that the investors, either the governmental or the private sectors, refrain from investing into the mineral industry for prospecting, evaluation, and developing the mining and mineral processing technologies. This is because the return on investment in the mining industry is generally low and the pay back period is relatively long compared with easy-to-get money projects. Another reason is the disarray of the mining laws and regulations and lack of administrative capability to deal with domestic and international investors and solve the related problems. Also, lack of skilled personnel in the field of mining and mineral processing is an additional factor for the set back of the mining industry in Egypt. This is why the mining technology in Egypt is not very far from being primitive and extremely simple, with the exception of the underground mining of coal, North of Sinai, and Abu-Tartur phosphate mining, where fully automated long wall operations are designed. Also, the recent gold and tin-tantalum-niobium projects are being designed on modern surface mining and mineral processing technologies. The present review presents an overview of the most important metallic mineral commodities in Egypt, their geological background, reserves and production rates. A brief mention of the existing technologies for their exploitation is also highlighted.
文摘The present study demonstrates the distribution of heavy metals in soils of Almalyk mining and smelting industrial area along the 5 transects.The study area is located in Almalyk,Uzbekistan,where the intensification of industrial enterprises negatively impact on the environment.The distribution of 17 heavy metals (Cu,Zn,Pb,Sc,V,Cr,Co,Ni,Ga,Rb,Sr,Y,Zr,Nb, Ba,Th,and U)were studied in 21 sampling locations (21×3=63 soil samples)along the 5 radial transects with the total length of 60 km downwind