The electromotive force （e.m.f.） of solid oxide fuel cells using biomass produced gas （BPG） as the fuels is calculated at 700-1,200 K using an in-house computer program, based on thermodynamic equilibrium analysis...The electromotive force （e.m.f.） of solid oxide fuel cells using biomass produced gas （BPG） as the fuels is calculated at 700-1,200 K using an in-house computer program, based on thermodynamic equilibrium analysis. Tour program also predicts the concentration of oxygen in the fuel chamber as well as the concentration of equilibrium species such as H2, CO, CO2 and CH4. Compared with using hydrogen as a fuel, the e.m.f. for cells using BPG as the fuels is relative low and strongly influenced by carbon deposition. To remove carbon deposition, the optimum amount of H2O to add is determined at various operating temperatures. Further the e.m.f, for cells based on yttria stabilized zirconia and doped ceria as electrolytes are compared. The study reveals that when using BPG as fuel, the depression of e.m.f, for a SOFC using doped ceria as electrolyte is relatively small when compared with that using Yttria stabilized zirconia.展开更多
When one end of an air-dry igneous rock block was uniaxially loaded in laboratory, there appeared an electromotive force that made electric currents flow from the stressed volume to the unstressed volume. Quartz-free ...When one end of an air-dry igneous rock block was uniaxially loaded in laboratory, there appeared an electromotive force that made electric currents flow from the stressed volume to the unstressed volume. Quartz-free rocks such as gabbro also generated this force, stronger than quartz-bearing rocks such as granite. This indicates that the piezoelectric effect of quartz and the electrokinetic effect of pore water do not make a large contribution toward generating the electromotive force. We focus on peroxy bond that is one of the abundant lattice defects in igneous rock-forming minerals. When mechanical loading deforms the lattice structure around this defect and breaks its bond, its energy levels change and act like an accepter. As an electron is trapped at this defect from a neighbor 02- site, a positive hole is activated there. They attempt to diffuse toward the unstressed volume through the valence band and are simultaneously affected by the attractive electric force with the electrons trapped in peroxy bonds. This leads to a polarization in the stressed volume and the generation of electromotive force between the stressed and unstressed volumes. Similar electromotive force may be generated in the Earth＇s crust where inhomogeneous stress/strain is changing.展开更多
The principles of electromagnetic induction are applied in many devices and systems, including induction cookers, transformers and wireless energy transfer;however, few data are available on resonance in the electromo...The principles of electromagnetic induction are applied in many devices and systems, including induction cookers, transformers and wireless energy transfer;however, few data are available on resonance in the electromotive force (EMF) of electromagnetic induction. We studied electromagnetic induction between two circular coils of wire: one is the source coil and the other is the pickup (or induction) coil. The measured EMF versus frequency graphs reveals the existence of a resonance/anti-resonance in the EMF of electromagnetic induction through free space. We found that it is possible to control the system’s resonance and anti-resonance frequencies. In some devices, a desired resonance or antiresonance frequency is achieved by varying the size of the resonator. Here, by contrast, our experimental results show that the system’s resonance and anti-resonance frequencies can be adjusted by varying the distance between the two coils or the number of turns of the induction coil.展开更多
基金V. ACKN0WLEDGMENT This work was supported by the National Natural Science Foundation of China （No.50372066 and No.50332040）.
文摘The electromotive force （e.m.f.） of solid oxide fuel cells using biomass produced gas （BPG） as the fuels is calculated at 700-1,200 K using an in-house computer program, based on thermodynamic equilibrium analysis. Tour program also predicts the concentration of oxygen in the fuel chamber as well as the concentration of equilibrium species such as H2, CO, CO2 and CH4. Compared with using hydrogen as a fuel, the e.m.f. for cells using BPG as the fuels is relative low and strongly influenced by carbon deposition. To remove carbon deposition, the optimum amount of H2O to add is determined at various operating temperatures. Further the e.m.f, for cells based on yttria stabilized zirconia and doped ceria as electrolytes are compared. The study reveals that when using BPG as fuel, the depression of e.m.f, for a SOFC using doped ceria as electrolyte is relatively small when compared with that using Yttria stabilized zirconia.
基金partially supported by"Observation and Research Program for Prediction of Earthquakes and Volcanic Eruptions"of the Ministry of Education,Culture,Sports,Science and Technology of Japan,"FY2010 Research Incentive Assistance Program"of Educational System General Research Organization,Tokai University"Individual Research Projects"of Institute of Oceanic Development of Science and Technology,Tokai University
文摘When one end of an air-dry igneous rock block was uniaxially loaded in laboratory, there appeared an electromotive force that made electric currents flow from the stressed volume to the unstressed volume. Quartz-free rocks such as gabbro also generated this force, stronger than quartz-bearing rocks such as granite. This indicates that the piezoelectric effect of quartz and the electrokinetic effect of pore water do not make a large contribution toward generating the electromotive force. We focus on peroxy bond that is one of the abundant lattice defects in igneous rock-forming minerals. When mechanical loading deforms the lattice structure around this defect and breaks its bond, its energy levels change and act like an accepter. As an electron is trapped at this defect from a neighbor 02- site, a positive hole is activated there. They attempt to diffuse toward the unstressed volume through the valence band and are simultaneously affected by the attractive electric force with the electrons trapped in peroxy bonds. This leads to a polarization in the stressed volume and the generation of electromotive force between the stressed and unstressed volumes. Similar electromotive force may be generated in the Earth＇s crust where inhomogeneous stress/strain is changing.
文摘The principles of electromagnetic induction are applied in many devices and systems, including induction cookers, transformers and wireless energy transfer;however, few data are available on resonance in the electromotive force (EMF) of electromagnetic induction. We studied electromagnetic induction between two circular coils of wire: one is the source coil and the other is the pickup (or induction) coil. The measured EMF versus frequency graphs reveals the existence of a resonance/anti-resonance in the EMF of electromagnetic induction through free space. We found that it is possible to control the system’s resonance and anti-resonance frequencies. In some devices, a desired resonance or antiresonance frequency is achieved by varying the size of the resonator. Here, by contrast, our experimental results show that the system’s resonance and anti-resonance frequencies can be adjusted by varying the distance between the two coils or the number of turns of the induction coil.
